CN104292597A - EVA luminous shoe material and preparation method thereof - Google Patents
EVA luminous shoe material and preparation method thereof Download PDFInfo
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- CN104292597A CN104292597A CN201410432870.6A CN201410432870A CN104292597A CN 104292597 A CN104292597 A CN 104292597A CN 201410432870 A CN201410432870 A CN 201410432870A CN 104292597 A CN104292597 A CN 104292597A
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- 239000000463 material Substances 0.000 title claims abstract description 67
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- 239000000843 powder Substances 0.000 claims abstract description 21
- 229920001577 copolymer Polymers 0.000 claims abstract description 17
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 17
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 15
- 235000021355 Stearic acid Nutrition 0.000 claims abstract description 14
- 239000002480 mineral oil Substances 0.000 claims abstract description 14
- 235000010446 mineral oil Nutrition 0.000 claims abstract description 14
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000008117 stearic acid Substances 0.000 claims abstract description 14
- 239000002994 raw material Substances 0.000 claims abstract description 13
- DYAHQFWOVKZOOW-UHFFFAOYSA-N Sarin Chemical compound CC(C)OP(C)(F)=O DYAHQFWOVKZOOW-UHFFFAOYSA-N 0.000 claims description 15
- 239000003795 chemical substances by application Substances 0.000 claims description 15
- 239000011347 resin Substances 0.000 claims description 15
- 229920005989 resin Polymers 0.000 claims description 15
- 229910021392 nanocarbon Inorganic materials 0.000 claims description 12
- 241000209094 Oryza Species 0.000 claims description 6
- 235000007164 Oryza sativa Nutrition 0.000 claims description 6
- 235000009566 rice Nutrition 0.000 claims description 6
- 238000005469 granulation Methods 0.000 claims description 3
- 230000003179 granulation Effects 0.000 claims description 3
- 238000007670 refining Methods 0.000 claims description 3
- 238000007493 shaping process Methods 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 2
- HIGRAKVNKLCVCA-UHFFFAOYSA-N alumine Chemical compound C1=CC=[Al]C=C1 HIGRAKVNKLCVCA-UHFFFAOYSA-N 0.000 claims description 2
- 229920000831 ionic polymer Polymers 0.000 claims description 2
- 239000011159 matrix material Substances 0.000 claims description 2
- 229910052712 strontium Inorganic materials 0.000 claims description 2
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims description 2
- 238000004020 luminiscence type Methods 0.000 abstract description 4
- 238000002834 transmittance Methods 0.000 abstract description 2
- 239000006260 foam Substances 0.000 abstract 2
- 239000008187 granular material Substances 0.000 abstract 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 1
- 229920003182 Surlyn® Polymers 0.000 abstract 1
- 239000006229 carbon black Substances 0.000 abstract 1
- 230000007613 environmental effect Effects 0.000 abstract 1
- 239000004088 foaming agent Substances 0.000 abstract 1
- 238000001746 injection moulding Methods 0.000 abstract 1
- 238000003801 milling Methods 0.000 abstract 1
- 239000000758 substrate Substances 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 11
- 230000008602 contraction Effects 0.000 description 7
- 230000005764 inhibitory process Effects 0.000 description 7
- 238000007906 compression Methods 0.000 description 6
- 230000006835 compression Effects 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 238000005286 illumination Methods 0.000 description 4
- 230000002688 persistence Effects 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 101001044940 Homo sapiens Insulin-like growth factor-binding protein 2 Proteins 0.000 description 1
- 102100022710 Insulin-like growth factor-binding protein 2 Human genes 0.000 description 1
- 101001012096 Mus musculus Epsin-2 Proteins 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000004146 energy storage Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000005284 excitation Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
- 150000003752 zinc compounds Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen
- C08L23/0853—Ethene vinyl acetate copolymers
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B1/00—Footwear characterised by the material
- A43B1/14—Footwear characterised by the material made of plastics
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
- C08J9/10—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/04—N2 releasing, ex azodicarbonamide or nitroso compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/04—Homopolymers or copolymers of ethene
- C08J2423/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2491/00—Characterised by the use of oils, fats or waxes; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses an EVA luminous shoe material and a preparation method thereof, the EVA luminous shoe material is obtained by banburying, milling and granulating a raw material EVA, an ethane-octylene copolymer (POE), surlyn, noctilucent powder, mineral oil, an AC foaming agent, a cross-linking agent BIBP, zine stearate, stearic acid, and nano white carbon black to prepare the EVA luminous shoe material granules, and the luminous shoe material granules are performed with injection moulding at once to obtain the EVA luminous shoe material. When the luminous shoe material does not foam, the light transmittance is good, haze is moderate, and the luminous shoe material is suitable for various shoe fittings and waistline substrates, has the characteristics of low density, high rebound and good mechanical property after the luminous shoe material foams, and the luminous shoe material is especially suitable for waistline for sport shoes, leisure shoes and dance shoes. The continuous luminescence time of the luminous shoe material exceeds 12 hours, and the luminous shoe material has the obvious characteristics of no requirement of power supply, overnight luminescence, energy saving and environmental protection, and has good market prospect.
Description
Technical field
The invention belongs to technical field of polymer materials, particularly a kind of EVA luminous shoe material and preparation method thereof.
Background technology
Noctilucent material, belong to the one of embedded photoluminescent material, that a class can absorb and excites luminous energy (daylight or light) and store, after removing excitation light source, again the energy stored is slowly released in the form of light, the whole process luminescent material of sustainable several even tens hours.Noctilucent material can repeat the process of absorb light-luminescence-storage-luminescence again, does not consume electric energy, is a kind of energy storage, energy-conservation " green " luminescent material, has been widely used in the fields such as fire-fighting emergent, military installations, communications and transportation, building decoration.But these application are all that only have very thin one deck at body surface, easily come off, work-ing life is not long using noctilucent material as a kind of coating or be mixed in coating.In the composite, the factor affecting noctilucent material luminous intensity and time of persistence is a lot, certain material in formula or certain technique in the course of processing all may have quenching effect, and noctilucent material is directly added to the influence factor in footwear material formula by there be limited evidence currently of people research.
Summary of the invention
In order to make up the deficiencies in the prior art, the present invention adopts the ethylene-octene copolymer of comprehensive mechanical property excellence; Use transparent, that gloss is soft, tear strength is high sarin resin; Add the ultra-fine luminescent powder that luminous intensity is high, time of persistence is long, obtain the EVA luminous shoe material that a kind of luminous intensity is high, time of persistence is long, the continuous illumination time more than 12 hours, and provides the preparation method of described EVA luminous shoe material, technique is simple, is applicable to producing in enormous quantities.
For achieving the above object, the solution that the present invention takes is: a kind of EVA luminous shoe material, is made up of obtained: EVA, ethylene-octene copolymer (POE), sarin resin, luminescent powder, mineral oil, AC whipping agent, crosslinking agent B IBP, Zinic stearas, stearic acid, Nano carbon white following raw material.
Further, the weight part of each raw material is as follows:
EVA 50 parts
Ethylene-octene copolymer (POE) 15-25 parts
Sarin resin 10-25 parts
Luminescent powder 5-15 parts
2-5 parts, mineral oil
AC whipping agent 0-3 part
Crosslinking agent B IBP 1-2 part
Zinic stearas 1-2 part
Stearic acid 4-10 parts
Nano carbon white 2-5 parts.
Preferred further, each component presses row parts by weight:
EVA 50 parts
Ethylene-octene copolymer (POE) 15-25 parts
Sarin resin 10-25 parts
Luminescent powder 6-12 parts
2-5 parts, mineral oil
Crosslinking agent B IBP 1-1.5 part
Zinic stearas 1-1.5 part
Stearic acid 7-9 parts
Nano carbon white 2-3 parts.
Preferred further, each component presses row parts by weight:
EVA 50 parts
Ethylene-octene copolymer (POE) 15-25 parts
Sarin resin 10-25 parts
Luminescent powder 10-13 parts
3-4 parts, mineral oil
AC whipping agent 1.5-3 parts
Crosslinking agent B IBP 1.5-2 parts
Zinic stearas 1.5-2 parts
Stearic acid 6-8 parts
Nano carbon white 2-4 parts.
Further: ethylene-octene copolymer is that melt temperature is greater than 75 degree, tensile strength is greater than the ethylene-octene copolymer of 15MPa; Sarin resin is the ethylene-methyl methacrylate that E.I.Du Pont Company produces is the ionic polymer of matrix; Luminescent powder is ultra-fine alumine acid strontium long afterglow luminescent powder.
A kind of preparation method preparing aforementioned EVA luminous shoe material, it is characterized in that: precise all raw material, first banburying is carried out in other raw materials mixing except crosslinking agent B IBP and AC whipping agent, adjustment banburying temperature controls as 97-100 DEG C, keep 4-6min, then crosslinking agent B IBP and AC whipping agent is added, continue banburying to heat up, drop temperature is 110-112 DEG C, banburying carries out out refining after terminating, granulation, obtain EVA noctilucence material rice, again EVA noctilucence material rice is put into the hopper of shot board, shaping through a shot, control temperature is at 178-180 degree, obtain EVA luminous shoe material.
By adopting preceding solution, the invention has the beneficial effects as follows: relative to prior art, the preparation method of described EVA luminous shoe material, has following characteristics:
1, the EVA luminous shoe material that the present invention obtains has the features such as low density, rebound degree is high, mechanical property is good.High-melting-point POE and high VA content EVA arranges in pairs or groups and uses, and while improving dimension stability, improves rebound degree, and can keep good mechanical property, broken the raw-material broad idea that elastomer material selects good springiness, hardness partially soft as far as possible.
2, the present invention uses the sarin resin that high transparency, gloss are soft, tear strength is high, improves the toughness of material, transmittance, anti-scratch performance, improves the surface gloss of material, improve the adhesive property of material simultaneously, improve the stripping strength of footwear material.
3, the present invention adopts many kinds of measures to guarantee the illumination effect of luminescent powder.Use ultra-fine luminescent powder, add mineral oil, guarantee that luminescent powder is uniformly dispersed in the material; Increase the lubricity of stearic acid dosage raising material system, add zinc compound less, in reduction complete processing, mechanical friction is on the impact of luminescent powder as far as possible, and guarantee that the luminous intensity of EVA luminous shoe material is high, time of persistence is long, the continuous illumination time was more than 12 hours.
Embodiment
Now the present invention is further described in conjunction with specific embodiments.
Embodiment 1:
In the present embodiment, EVA luminous shoe material is made up of by weight following component:
EVA 40W 40 parts, EVA 5110J 10 parts, ethylene-octene copolymer (POE) 8,540 21 parts, sarin resin 8,940 18 parts, luminescent powder 12 parts, 3 parts, mineral oil, AC whipping agent 2.8 parts, crosslinking agent B IBP2 part, Zinic stearas 1.8 parts, stearic acid 7 parts, Nano carbon white 3 parts.
First banburying is carried out in other raw materials mixing except crosslinking agent B IBP and AC whipping agent, adjustment banburying temperature controls to be 98 DEG C, keeps 5min, then adds crosslinking agent B IBP and AC whipping agent, continue banburying to heat up, drop temperature is 110 DEG C, and refining, granulation are carried out out in banburying after terminating, obtain EVA noctilucence material rice, again EVA noctilucence material rice is put into the hopper of shot board, shaping through a shot, control temperature, at 178 degree, obtains EVA luminous shoe material.
The above-mentioned EVA luminous shoe material prepared, density 0.227 g/cm
3, shore hardness 47, rebound degree 57%, permanent compression flexure 39%, dimensional contraction 0.8%, tear strength 12N/mm, unit elongation 298%, tensile strength 2.3MPa, split tear 2.8N/mm, color inhibition test 5 grades.
Embodiment 2:
In the present embodiment, a kind of preparation method of EVA luminous shoe material is identical with the preparation method in embodiment 1, and difference is:
4 parts, mineral oil, AC whipping agent 0 part, crosslinking agent B IBP 1.5 parts, stearic acid 9 parts, Nano carbon white 2 parts.
The above-mentioned EVA luminous shoe material prepared, density 0.929 g/cm
3, shore hardness 71, rebound degree 46%, dimensional contraction 0.2%, tear strength 48N/mm, unit elongation 610%, tensile strength 14MPa, color inhibition test 4 grades.
Embodiment 3:
In the present embodiment, a kind of preparation method of EVA luminous shoe material is identical with the preparation method in embodiment 1, and difference is:
EVA 40W 50 parts, ethylene-octene copolymer 8,450 25 parts, sarin resin 8,940 10 parts, Nano carbon white 5 parts.
The above-mentioned EVA luminous shoe material prepared, density 0.231 g/cm
3, shore hardness 50, rebound degree 59%, permanent compression flexure 46%, dimensional contraction 1.3%, tear strength 10N/mm, unit elongation 332%, tensile strength 2.4MPa, split tear 2.6N/mm, color inhibition test 4-5 level.
Embodiment 4:
In the present embodiment, a kind of preparation method of EVA luminous shoe material is identical with the preparation method in embodiment 1, and difference is:
EVA 40W 25 parts, EVA E260F 25 parts, ethylene-octene copolymer 8,440 15 parts, sarin resin 8,920 25 parts, luminescent powder 5 parts, 2 parts, mineral oil, stearic acid 4 parts, Nano carbon white 2 parts.
The above-mentioned EVA luminous shoe material prepared, density 0.204 g/cm
3, shore hardness 46, rebound degree 54%, permanent compression flexure 37%, dimensional contraction 1.4%, tear strength 13N/mm, unit elongation 286%, tensile strength 1.9MPa, split tear 2.1N/mm, color inhibition test 5 grades.
Embodiment 5:
In the present embodiment, a kind of preparation method of EVA luminous shoe material is identical with the preparation method in embodiment 1, and difference is:
EVA 40W 10 parts, EVA E180F 40 parts, luminescent powder 15 parts, 5 parts, mineral oil, stearic acid 10 parts.
The above-mentioned EVA luminous shoe material prepared, density 0.273 g/cm
3, shore hardness 52, rebound degree 51%, permanent compression flexure 42%, dimensional contraction 0.6%, tear strength 9N/mm, unit elongation 264%, tensile strength 1.9MPa, split tear 2.1N/mm, color inhibition test 4 grades.
After the data preparation of above-described embodiment 1 ~ 5, obtain as following table 1(note: shore hardness is tested according to HG/T2489-93, GB2411-80, rebound degree test adopts GT-7042-RE type impact elasticity test machine, permanent compression flexure is tested according to HG/T 2876-2009, dimensional contraction is tested according to ISO 20873:2001, tear strength tests straight shape test piece according to GB/T 529-2008, unit elongation and tensile strength are tested according to GB/T 528-2009, split tear is tested according to GB/T 3903.29-2008, and color inhibition test is tested according to HG/T 3689-2001):
| Embodiment | 1 | 2 | 3 | 4 | 5 |
| Density (g/cm 3) | 0.227 | 0.929 | 0.231 | 0.204 | 0.273 |
| Shore hardness | 47 | 71 | 50 | 46 | 52 |
| Rebound degree (%) | 57 | 46 | 59 | 54 | 51 |
| Permanent compression flexure (%) | 39 | -- | 46 | 37 | 42 |
| Dimensional contraction (%) | 0.8 | 0.2 | 1.3 | 1.4 | 0.6 |
| Tear strength (N/mm) | 12 | 48 | 10 | 13 | 9 |
| Unit elongation (%) | 298 | 610 | 332 | 286 | 264 |
| Tensile strength (MPa) | 2.3 | 14 | 2.4 | 2.3 | 1.9 |
| Split tear (N/mm) | 2.8 | -- | 2.6 | 2.9 | 2.1 |
| Color inhibition test (A method) | 5 grades | 4 grades | 4-5 level | 5 grades | 4 grades |
Table 1: the performance perameter synopsis of EVA luminous shoe material prepared by embodiment 1 ~ 5.
In sum, the EVA luminous shoe material prepared according to technical solution of the present invention, there is the features such as low density, high resilience, mechanical property be good, the continuous illumination time was more than 12 hours, in addition need not the distinguishing feature such as power supply, all night luminescence, energy-conserving and environment-protective, be particularly suitable as the end in all kinds of footwear accessory, footwear, have good market outlook, and easily realize suitability for industrialized production.
Above, be only the embodiment utilizing this origination techniques content, the modification that any those skilled in the art use this creation to do, change, all belong to the scope of the claims that this creation is advocated, and be not limited to those disclosed embodiments.
Claims (8)
1. an EVA luminous shoe material, is characterized in that: be made up of obtained following raw material: EVA, ethylene-octene copolymer (POE), sarin resin, luminescent powder, mineral oil, AC whipping agent, crosslinking agent B IBP, Zinic stearas, stearic acid, Nano carbon white.
2. EVA luminous shoe material according to claim 1, is characterized in that: the weight part of each raw material is as follows:
EVA 50 parts
Ethylene-octene copolymer (POE) 15-25 parts
Sarin resin 10-25 parts
Luminescent powder 5-15 parts
2-5 parts, mineral oil
AC whipping agent 0-3 part
Crosslinking agent B IBP 1-2 part
Zinic stearas 1-2 part
Stearic acid 4-10 parts
Nano carbon white 2-5 parts.
3. EVA luminous shoe material according to claim 1 and 2, is characterized in that: be prepared from by following raw materials in part by weight by following component:
EVA 50 parts
Ethylene-octene copolymer (POE) 15-25 parts
Sarin resin 10-25 parts
Luminescent powder 6-12 parts
2-5 parts, mineral oil
AC whipping agent 0 part
Crosslinking agent B IBP 1-1.5 part
Zinic stearas 1-1.5 part
Stearic acid 7-9 parts
Nano carbon white 2-3 parts.
4. EVA luminous shoe material according to claim 1 and 2, is characterized in that: be prepared from by following raw materials in part by weight by following component:
EVA 50 parts
Ethylene-octene copolymer (POE) 15-25 parts
Sarin resin 10-25 parts
Luminescent powder 10-13 parts
3-4 parts, mineral oil
AC whipping agent 1.5-3 parts
Crosslinking agent B IBP 1.5-2 parts
Zinic stearas 1.5-2 parts
Stearic acid 6-8 parts
Nano carbon white 2-4 parts.
5. EVA luminous shoe material according to claim 1 or 2, is characterized in that: ethylene-octene copolymer is that melt temperature is greater than 75 degree, tensile strength is greater than the ethylene-octene copolymer of 15MPa.
6. EVA luminous shoe material according to claim 1 or 2, is characterized in that: sarin resin is the ethylene-methyl methacrylate that E.I.Du Pont Company produces is the ionic polymer of matrix.
7. EVA luminous shoe material according to claim 1 or 2, is characterized in that: luminescent powder is ultra-fine alumine acid strontium long afterglow luminescent powder.
8. prepare the preparation method of the arbitrary described EVA luminous shoe material of claim 1-7 for one kind, it is characterized in that: precise all raw material, first banburying is carried out in other raw materials mixing except crosslinking agent B IBP and AC whipping agent, adjustment banburying temperature controls as 97-100 DEG C, keep 4-6min, then crosslinking agent B IBP and AC whipping agent is added, continue banburying to heat up, drop temperature is 110-112 DEG C, banburying carries out out refining after terminating, granulation, obtain EVA noctilucence material rice, again EVA noctilucence material rice is put into the hopper of shot board, shaping through a shot, control temperature is at 178-180 degree, obtain EVA luminous shoe material.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410432870.6A CN104292597A (en) | 2014-08-28 | 2014-08-28 | EVA luminous shoe material and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410432870.6A CN104292597A (en) | 2014-08-28 | 2014-08-28 | EVA luminous shoe material and preparation method thereof |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104789169A (en) * | 2015-04-09 | 2015-07-22 | 茂泰(福建)鞋材有限公司 | Rubber bonding film, preparation method of rubber bonding film as well as method for using rubber bonding film for bonding soles |
| CN105400056A (en) * | 2015-11-18 | 2016-03-16 | 吴江市风尚鞋厂 | Rubber and plastic micropore shoe material and preparation method thereof |
| CN107200911A (en) * | 2016-03-16 | 2017-09-26 | 青岛科技大学 | A kind of ultra-light high-elastic environment-friendly sole and preparation method thereof |
| CN108822393A (en) * | 2018-07-16 | 2018-11-16 | 东莞市兴茂橡塑科技有限公司 | A kind of footwear material efficient noctilucence master batch and noctilucence footwear material |
| CN108864557A (en) * | 2018-05-29 | 2018-11-23 | 福建师范大学 | A kind of Sports shoe sole ultralight injection ion/covalent cross-linking closed pore formula foamed polymer material and preparation method thereof |
| CN110305384A (en) * | 2019-07-01 | 2019-10-08 | 石狮市王氏兄弟鞋材有限公司 | A kind of anti-skidding buoyancy plastic plate of noctilucence and preparation method thereof |
| CN113388185A (en) * | 2021-06-22 | 2021-09-14 | 厦门联合信诺新材料有限公司 | EVA (ethylene-vinyl acetate copolymer) foaming material as well as preparation method and application thereof |
| CN114479255A (en) * | 2022-01-17 | 2022-05-13 | 茂泰(福建)鞋材有限公司 | Environment-friendly foaming material based on EVA (ethylene-vinyl acetate copolymer) waste material and treatment method of EVA waste material |
| CN114854122A (en) * | 2022-06-24 | 2022-08-05 | 厦门冠颜塑化科技有限公司 | A kind of luminous EVA foam shoe material and preparation method thereof |
| CN116693973A (en) * | 2023-07-10 | 2023-09-05 | 佛山市创意新材料科技有限公司 | Semitransparent luminous sole and preparation method thereof |
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| CN104789169B (en) * | 2015-04-09 | 2017-01-04 | 茂泰(福建)鞋材有限公司 | A kind of rubber bound film and preparation method thereof and for bond sole time using method |
| CN104789169A (en) * | 2015-04-09 | 2015-07-22 | 茂泰(福建)鞋材有限公司 | Rubber bonding film, preparation method of rubber bonding film as well as method for using rubber bonding film for bonding soles |
| CN105400056A (en) * | 2015-11-18 | 2016-03-16 | 吴江市风尚鞋厂 | Rubber and plastic micropore shoe material and preparation method thereof |
| CN107200911B (en) * | 2016-03-16 | 2019-11-05 | 青岛科技大学 | Ultra-light high-elastic environment-friendly sole and preparation method thereof |
| CN107200911A (en) * | 2016-03-16 | 2017-09-26 | 青岛科技大学 | A kind of ultra-light high-elastic environment-friendly sole and preparation method thereof |
| CN108864557A (en) * | 2018-05-29 | 2018-11-23 | 福建师范大学 | A kind of Sports shoe sole ultralight injection ion/covalent cross-linking closed pore formula foamed polymer material and preparation method thereof |
| CN108864557B (en) * | 2018-05-29 | 2021-04-20 | 福建师范大学 | Ultralight injection ion/covalent crosslinking closed-pore type foaming polymer material for sneaker sole and preparation method thereof |
| CN108822393A (en) * | 2018-07-16 | 2018-11-16 | 东莞市兴茂橡塑科技有限公司 | A kind of footwear material efficient noctilucence master batch and noctilucence footwear material |
| CN110305384A (en) * | 2019-07-01 | 2019-10-08 | 石狮市王氏兄弟鞋材有限公司 | A kind of anti-skidding buoyancy plastic plate of noctilucence and preparation method thereof |
| CN113388185A (en) * | 2021-06-22 | 2021-09-14 | 厦门联合信诺新材料有限公司 | EVA (ethylene-vinyl acetate copolymer) foaming material as well as preparation method and application thereof |
| CN113388185B (en) * | 2021-06-22 | 2023-09-29 | 厦门联合信诺新材料有限公司 | EVA foaming material and preparation method and application thereof |
| CN114479255A (en) * | 2022-01-17 | 2022-05-13 | 茂泰(福建)鞋材有限公司 | Environment-friendly foaming material based on EVA (ethylene-vinyl acetate copolymer) waste material and treatment method of EVA waste material |
| CN114479255B (en) * | 2022-01-17 | 2023-11-14 | 茂泰(福建)新材料科技有限公司 | An environmentally friendly foaming material based on EVA waste material and a method for processing EVA waste material |
| CN114854122A (en) * | 2022-06-24 | 2022-08-05 | 厦门冠颜塑化科技有限公司 | A kind of luminous EVA foam shoe material and preparation method thereof |
| CN116693973A (en) * | 2023-07-10 | 2023-09-05 | 佛山市创意新材料科技有限公司 | Semitransparent luminous sole and preparation method thereof |
| CN116693973B (en) * | 2023-07-10 | 2024-03-19 | 佛山市创意新材料科技有限公司 | Semitransparent luminous sole and preparation method thereof |
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