CN104277596A - Corrosion-resistant aluminum pigment and preparation method thereof - Google Patents
Corrosion-resistant aluminum pigment and preparation method thereof Download PDFInfo
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- CN104277596A CN104277596A CN201410509442.9A CN201410509442A CN104277596A CN 104277596 A CN104277596 A CN 104277596A CN 201410509442 A CN201410509442 A CN 201410509442A CN 104277596 A CN104277596 A CN 104277596A
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- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims abstract description 29
- 229910052782 aluminium Inorganic materials 0.000 title claims abstract description 28
- 239000000049 pigment Substances 0.000 title claims abstract description 23
- 238000005260 corrosion Methods 0.000 title claims abstract description 14
- 230000007797 corrosion Effects 0.000 title claims abstract description 14
- 238000002360 preparation method Methods 0.000 title claims description 9
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000000843 powder Substances 0.000 claims abstract description 14
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000002131 composite material Substances 0.000 claims abstract description 10
- 239000002994 raw material Substances 0.000 claims abstract description 10
- 239000011347 resin Substances 0.000 claims abstract description 9
- 229920005989 resin Polymers 0.000 claims abstract description 9
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000004255 Butylated hydroxyanisole Substances 0.000 claims abstract description 7
- 235000019282 butylated hydroxyanisole Nutrition 0.000 claims abstract description 7
- CZBZUDVBLSSABA-UHFFFAOYSA-N butylated hydroxyanisole Chemical compound COC1=CC=C(O)C(C(C)(C)C)=C1.COC1=CC=C(O)C=C1C(C)(C)C CZBZUDVBLSSABA-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229940043253 butylated hydroxyanisole Drugs 0.000 claims abstract description 7
- 239000002383 tung oil Substances 0.000 claims abstract description 7
- DTGKSKDOIYIVQL-WEDXCCLWSA-N (+)-borneol Chemical compound C1C[C@@]2(C)[C@@H](O)C[C@@H]1C2(C)C DTGKSKDOIYIVQL-WEDXCCLWSA-N 0.000 claims abstract description 4
- REPVLJRCJUVQFA-UHFFFAOYSA-N (-)-isopinocampheol Natural products C1C(O)C(C)C2C(C)(C)C1C2 REPVLJRCJUVQFA-UHFFFAOYSA-N 0.000 claims abstract description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims abstract description 4
- 229930006000 Sucrose Natural products 0.000 claims abstract description 4
- 229940116229 borneol Drugs 0.000 claims abstract description 4
- CKDOCTFBFTVPSN-UHFFFAOYSA-N borneol Natural products C1CC2(C)C(C)CC1C2(C)C CKDOCTFBFTVPSN-UHFFFAOYSA-N 0.000 claims abstract description 4
- DTGKSKDOIYIVQL-UHFFFAOYSA-N dl-isoborneol Natural products C1CC2(C)C(O)CC1C2(C)C DTGKSKDOIYIVQL-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000003921 oil Substances 0.000 claims abstract description 4
- 239000005720 sucrose Substances 0.000 claims abstract description 4
- -1 sucrose fatty acid ester Chemical class 0.000 claims abstract description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 39
- 239000004411 aluminium Substances 0.000 claims description 17
- 229960004756 ethanol Drugs 0.000 claims description 15
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 12
- RGCKGOZRHPZPFP-UHFFFAOYSA-N alizarin Chemical compound C1=CC=C2C(=O)C3=C(O)C(O)=CC=C3C(=O)C2=C1 RGCKGOZRHPZPFP-UHFFFAOYSA-N 0.000 claims description 12
- 238000006243 chemical reaction Methods 0.000 claims description 12
- 229910000077 silane Inorganic materials 0.000 claims description 12
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 9
- 238000001035 drying Methods 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 6
- ZTHYODDOHIVTJV-UHFFFAOYSA-N Propyl gallate Chemical compound CCCOC(=O)C1=CC(O)=C(O)C(O)=C1 ZTHYODDOHIVTJV-UHFFFAOYSA-N 0.000 claims description 6
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 6
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 6
- VTYYLEPIZMXCLO-UHFFFAOYSA-L calcium carbonate Substances [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 6
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 6
- 230000008878 coupling Effects 0.000 claims description 6
- 239000007822 coupling agent Substances 0.000 claims description 6
- 238000010168 coupling process Methods 0.000 claims description 6
- 238000005859 coupling reaction Methods 0.000 claims description 6
- 239000012153 distilled water Substances 0.000 claims description 6
- 239000000944 linseed oil Substances 0.000 claims description 6
- 235000021388 linseed oil Nutrition 0.000 claims description 6
- 239000002480 mineral oil Substances 0.000 claims description 6
- 235000010446 mineral oil Nutrition 0.000 claims description 6
- 239000005543 nano-size silicon particle Substances 0.000 claims description 6
- 238000001291 vacuum drying Methods 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 230000008569 process Effects 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 4
- 229910021529 ammonia Inorganic materials 0.000 claims description 3
- ZWLIYXJBOIDXLL-UHFFFAOYSA-N decanedihydrazide Chemical compound NNC(=O)CCCCCCCCC(=O)NN ZWLIYXJBOIDXLL-UHFFFAOYSA-N 0.000 claims description 3
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 3
- 238000010790 dilution Methods 0.000 claims description 3
- 239000012895 dilution Substances 0.000 claims description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 3
- 239000012467 final product Substances 0.000 claims description 3
- 239000011259 mixed solution Substances 0.000 claims description 3
- 239000012046 mixed solvent Substances 0.000 claims description 3
- 239000012299 nitrogen atmosphere Substances 0.000 claims description 3
- 235000019198 oils Nutrition 0.000 claims description 3
- 238000000967 suction filtration Methods 0.000 claims description 3
- 238000005406 washing Methods 0.000 claims description 3
- 230000008901 benefit Effects 0.000 abstract description 2
- 239000006087 Silane Coupling Agent Substances 0.000 abstract 2
- 230000002349 favourable effect Effects 0.000 abstract 2
- 235000021314 Palmitic acid Nutrition 0.000 abstract 1
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 abstract 1
- 235000014113 dietary fatty acids Nutrition 0.000 abstract 1
- 229930195729 fatty acid Natural products 0.000 abstract 1
- 239000000194 fatty acid Substances 0.000 abstract 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 abstract 1
- 229940116351 sebacate Drugs 0.000 abstract 1
- CXMXRPHRNRROMY-UHFFFAOYSA-L sebacate(2-) Chemical compound [O-]C(=O)CCCCCCCCC([O-])=O CXMXRPHRNRROMY-UHFFFAOYSA-L 0.000 abstract 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 229910017518 Cu Zn Inorganic materials 0.000 description 1
- 229910017752 Cu-Zn Inorganic materials 0.000 description 1
- 229910017943 Cu—Zn Inorganic materials 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- TVZPLCNGKSPOJA-UHFFFAOYSA-N copper zinc Chemical compound [Cu].[Zn] TVZPLCNGKSPOJA-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000000047 product Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D17/00—Pigment pastes, e.g. for mixing in paints
- C09D17/004—Pigment pastes, e.g. for mixing in paints containing an inorganic pigment
- C09D17/006—Metal
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/08—Treatment with low-molecular-weight non-polymer organic compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/10—Anti-corrosive paints containing metal dust
- C09D5/103—Anti-corrosive paints containing metal dust containing Al
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
Abstract
The invention discloses a corrosion-resistant aluminum pigment. The invention is characterized in that the aluminum pigment is prepared from the following raw materials in parts by weight: 30-40 parts of micron-scale flake aluminum powder, 1-2 parts of sericite powder, 0.02-0.04 part of diamidohydrazine sebacate, 6-8 parts of ethyl orthosilicate, 0.3-0.5 part of silane coupling agent KH-550, 1-2 parts of palmitic acid, 0.5-1 part of tung oil, 1-2 parts of borneol oil, 0.5-1 part of glycol ether acetate, 3-6 parts of ethyl acetate, 0.02-0.04 part of sucrose fatty acid ester, 0.1-0.2 part of silane coupling agent A-151, 0.01-0.02 part of butylated hydroxyanisole and 1-2 parts of composite assistant. The aluminum pigment has the advantages of favorable corrosion resistance, favorable compatibility with resin and high practicality, and the corrosion of the aluminum pigment can be effectively postponed.
Description
Technical field
The present invention relates to metallic pigment field, be specifically related to a kind of protection against corrosion aluminium pigment and preparation method thereof.
Background technology
Metallic pigment are the metallicss with lamellar morphology, its role is to decorate or special process performance gives goods with a kind of metallic color outward appearance for target or feature.The purposes of metallic pigment can be roughly divided into top coat (coating, ink, powder coating etc.) and plastics.In these purposes, make use of the characteristic that metallic pigment are total: high metal luster, high covering power and even thin layers film can be formed.Aluminium powder, Cu-Zn alloy powder and zinc powder are current most widely used metallic pigment.In industrial application, metallic pigment must possess the performance of higher acid-alkali-corrosive-resisting, could meet the needs of people.
Summary of the invention
The object of this invention is to provide a kind of protection against corrosion aluminium pigment.
The present invention is achieved by the following technical solutions:
A kind of protection against corrosion aluminium pigment, it is made up of the raw material of following weight parts:
Micron-sized flake aluminum 30-40, sericite in powder 1-2, sebacic dihydrazide 0.02-0.04, tetraethoxy 6-8, silane resin acceptor kh-550 0.3-0.5, palmitinic acid 1-2, tung oil 0.5-1, borneol oil 1-2, ethylene glycol ether acetate 0.5-1, ethyl acetate 3-6, sucrose fatty ester 0.02-0.04, silane coupling A-151 0.1-0.2, butylated hydroxy anisole 0.01-0.02, composite assistant 1-2;
Composite assistant is made up of the raw material of following weight part:
Nano-calcium carbonate 30-40, nano silicon 5-10, titanate coupling agent 0.5-1, white mineral oil 1-2, linseed oil 1-2, alizarin assistant 0.5-1, Tenox PG 0.5-1;
The preparation method of composite assistant:
Nano-calcium carbonate and nano silicon are added suitable quantity of water, add titanate coupling agent after mixing, 60-80 DEG C is fully stirred 0.5-1h, adds the mixed solution of white mineral oil, linseed oil, Tenox PG and alizarin assistant after drying, 110-130 DEG C is fully stirred 0.5-1h, to obtain final product.
A preparation method for protection against corrosion aluminium pigment, comprises the following steps:
(1) mixed solvent of ammoniacal liquor, distilled water and ethanol is prepared as component A, with alcohol dilution tetraethoxy as B component; Micron-sized flake aluminum is added in appropriate dehydrated alcohol, add silane coupling A-151, after stirred under nitrogen atmosphere 0.5-1h, with 1-2 drip/rate of addition of s drips component A and B component simultaneously respectively, dropping limit, limit is stirred, dropwise rear 40-45 DEG C of reaction 6-8h, with absolute ethanol washing after suction filtration, vacuum-drying, weight ratio=the 1:2:5 of ammoniacal liquor, distilled water and ethanol in described component A, described ammonia concn is 25%, the weight ratio=1:2 of ethanol and tetraethoxy in described B component;
(2) in reaction vessel, add aluminium powder, sericite in powder and ethanol in proper amount after process in (1), silane resin acceptor kh-550 is added after being uniformly mixed, 60-80 DEG C of heated and stirred back flow reaction 3-6h, rear drying is repeatedly washed with ethanol, add palmitinic acid, tung oil, butylated hydroxy anisole and q. s. toluene again, 30-40 DEG C of stirring reaction 1-2h, repeatedly washs after centrifugal, vacuum-drying;
(3) after mixing with all the other raw materials, 50-60 DEG C is stirred 1-2h, takes out final vacuum and is drying to obtain.
Advantage of the present invention is:
1. by the improvement of recipe optimization, make aluminium pigment have good non-corrosibility, effectively can delay the corrosion of aluminium pigment.
2., by the surface modification of aluminium powder, improve the hydrophobicity of aluminium pigment and the dispersing property in resin, good, practical with the consistency of resin.
Embodiment
Non-limiting examples of the present invention is as follows:
Embodiment 1
A kind of protection against corrosion aluminium pigment, is prepared from by the component raw material of following weight (kg):
Micron-sized flake aluminum 35, sericite in powder 1.5, sebacic dihydrazide 0.03, tetraethoxy 7, silane resin acceptor kh-550 0.4, palmitinic acid 1.5, tung oil 0.8, borneol oil 1.5, ethylene glycol ether acetate 0.7, ethyl acetate 5, sucrose fatty ester 0.03, silane coupling A-151 0.15, butylated hydroxy anisole 0.015, composite assistant 1.5;
Wherein, composite assistant is made up of the raw material of following weight (kg):
Nano-calcium carbonate 35, nano silicon 8, titanate coupling agent 0.8, white mineral oil 1.5, linseed oil 1.5, alizarin assistant 0.8, Tenox PG 0.8;
The preparation method of composite assistant:
Nano-calcium carbonate and nano silicon are added suitable quantity of water, add titanate coupling agent after mixing, 80 DEG C are fully stirred 0.5h, add the mixed solution of white mineral oil, linseed oil, Tenox PG and alizarin assistant after drying, 120 DEG C are fully stirred 0.5h, to obtain final product.
Its preparation method comprises the following steps:
(1) mixed solvent of ammoniacal liquor, distilled water and ethanol is prepared as component A, with alcohol dilution tetraethoxy as B component; Micron-sized flake aluminum is added in appropriate dehydrated alcohol, add silane coupling A-151, after stirred under nitrogen atmosphere 0.5h, drip component A and B component respectively with the rate of addition of 1/s, dropping limit, limit is stirred simultaneously, dropwise rear 40 DEG C of reaction 8h, with absolute ethanol washing after suction filtration, vacuum-drying, the weight ratio=1:2:5 of ammoniacal liquor, distilled water and ethanol in described component A, described ammonia concn is 25%, the weight ratio=1:2 of ethanol and tetraethoxy in described B component;
(2) in reaction vessel, add aluminium powder, sericite in powder and ethanol in proper amount after process in (1), silane resin acceptor kh-550 is added after being uniformly mixed, 80 DEG C of heated and stirred back flow reaction 3h, rear drying is repeatedly washed with ethanol, add palmitinic acid, tung oil, butylated hydroxy anisole and q. s. toluene again, 40 DEG C of stirring reaction 2h, repeatedly wash after centrifugal, vacuum-drying;
(3) mix latter 60 DEG C with all the other raw materials and stir 1h, take out final vacuum and be drying to obtain.
Through inspection, the pigment coated surfacing of aluminium of the present embodiment is smooth, and glossiness is good, and corrosion resistance nature is good.NaOH solution product being put into pH=11 processes, and in 30d, no hydrogen produces.
Claims (2)
1. a protection against corrosion aluminium pigment, is characterized in that it is made up of the raw material of following weight parts:
Micron-sized flake aluminum 30-40, sericite in powder 1-2, sebacic dihydrazide 0.02-0.04, tetraethoxy 6-8, silane resin acceptor kh-550 0.3-0.5, palmitinic acid 1-2, tung oil 0.5-1, borneol oil 1-2, ethylene glycol ether acetate 0.5-1, ethyl acetate 3-6, sucrose fatty ester 0.02-0.04, silane coupling A-151 0.1-0.2, butylated hydroxy anisole 0.01-0.02, composite assistant 1-2;
Described composite assistant is made up of the raw material of following weight part:
Nano-calcium carbonate 30-40, nano silicon 5-10, titanate coupling agent 0.5-1, white mineral oil 1-2, linseed oil 1-2, alizarin assistant 0.5-1, Tenox PG 0.5-1;
The preparation method of described composite assistant is:
Nano-calcium carbonate and nano silicon are added suitable quantity of water, add titanate coupling agent after mixing, 60-80 DEG C is fully stirred 0.5-1h, adds the mixed solution of white mineral oil, linseed oil, Tenox PG and alizarin assistant after drying, 110-130 DEG C is fully stirred 0.5-1h, to obtain final product.
2. the preparation method of protection against corrosion aluminium pigment according to claim 1, is characterized in that, comprise the following steps:
(1) mixed solvent of ammoniacal liquor, distilled water and ethanol is prepared as component A, with alcohol dilution tetraethoxy as B component; Micron-sized flake aluminum is added in appropriate dehydrated alcohol, add silane coupling A-151, after stirred under nitrogen atmosphere 0.5-1h, with 1-2 drip/rate of addition of s drips component A and B component simultaneously respectively, dropping limit, limit is stirred, dropwise rear 40-45 DEG C of reaction 6-8h, with absolute ethanol washing after suction filtration, vacuum-drying, weight ratio=the 1:2:5 of ammoniacal liquor, distilled water and ethanol in described component A, described ammonia concn is 25%, the weight ratio=1:2 of ethanol and tetraethoxy in described B component;
(2) in reaction vessel, add aluminium powder, sericite in powder and ethanol in proper amount after process in (1), silane resin acceptor kh-550 is added after being uniformly mixed, 60-80 DEG C of heated and stirred back flow reaction 3-6h, rear drying is repeatedly washed with ethanol, add palmitinic acid, tung oil, butylated hydroxy anisole and q. s. toluene again, 30-40 DEG C of stirring reaction 1-2h, repeatedly washs after centrifugal, vacuum-drying;
(3) after mixing with all the other raw materials, 50-60 DEG C is stirred 1-2h, takes out final vacuum and is drying to obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410509442.9A CN104277596A (en) | 2014-09-29 | 2014-09-29 | Corrosion-resistant aluminum pigment and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410509442.9A CN104277596A (en) | 2014-09-29 | 2014-09-29 | Corrosion-resistant aluminum pigment and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104277596A true CN104277596A (en) | 2015-01-14 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410509442.9A Pending CN104277596A (en) | 2014-09-29 | 2014-09-29 | Corrosion-resistant aluminum pigment and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104277596A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107892872A (en) * | 2017-12-29 | 2018-04-10 | 常盛杰 | One kind has metallic light sensation paint |
| CN110878178A (en) * | 2019-12-18 | 2020-03-13 | 河南兴安新型建筑材料有限公司 | Nano SiO2Film-coated flaky aluminum pigment and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1777653A (en) * | 2003-04-18 | 2006-05-24 | 默克专利股份有限公司 | Antimicrobial pigments. |
| US20080314284A1 (en) * | 2004-12-24 | 2008-12-25 | Bangyin Li | Highly Anti-Corrosive Thin Platelet-Like Metal Pigments, Preparing Method of the Same, and Colored Interference Pigments Having Metallic Luster Based on the Same |
| CN101384674A (en) * | 2006-02-14 | 2009-03-11 | 东洋铝株式会社 | Colored metallic pigment, process for producing the same, and coating composition and cosmetic preparation comprising said colored metallic pigment |
| CN101541891A (en) * | 2006-11-14 | 2009-09-23 | 旭化成化学株式会社 | Metal pigment composition |
-
2014
- 2014-09-29 CN CN201410509442.9A patent/CN104277596A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1777653A (en) * | 2003-04-18 | 2006-05-24 | 默克专利股份有限公司 | Antimicrobial pigments. |
| US20080314284A1 (en) * | 2004-12-24 | 2008-12-25 | Bangyin Li | Highly Anti-Corrosive Thin Platelet-Like Metal Pigments, Preparing Method of the Same, and Colored Interference Pigments Having Metallic Luster Based on the Same |
| CN101384674A (en) * | 2006-02-14 | 2009-03-11 | 东洋铝株式会社 | Colored metallic pigment, process for producing the same, and coating composition and cosmetic preparation comprising said colored metallic pigment |
| CN101541891A (en) * | 2006-11-14 | 2009-09-23 | 旭化成化学株式会社 | Metal pigment composition |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107892872A (en) * | 2017-12-29 | 2018-04-10 | 常盛杰 | One kind has metallic light sensation paint |
| CN110878178A (en) * | 2019-12-18 | 2020-03-13 | 河南兴安新型建筑材料有限公司 | Nano SiO2Film-coated flaky aluminum pigment and preparation method thereof |
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Application publication date: 20150114 |
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