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CN104232175A - Alcohol ether diesel oil - Google Patents

Alcohol ether diesel oil Download PDF

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Publication number
CN104232175A
CN104232175A CN201410552776.4A CN201410552776A CN104232175A CN 104232175 A CN104232175 A CN 104232175A CN 201410552776 A CN201410552776 A CN 201410552776A CN 104232175 A CN104232175 A CN 104232175A
Authority
CN
China
Prior art keywords
parts
diesel oil
alcohol
alcohol ether
ether
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410552776.4A
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Chinese (zh)
Inventor
蒙呈星
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GUANGXI FENGTAI ENERGY EXPLOSION-PROOF SCIENCE & TECHNOLOGY Co Ltd
Original Assignee
GUANGXI FENGTAI ENERGY EXPLOSION-PROOF SCIENCE & TECHNOLOGY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
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Application filed by GUANGXI FENGTAI ENERGY EXPLOSION-PROOF SCIENCE & TECHNOLOGY Co Ltd filed Critical GUANGXI FENGTAI ENERGY EXPLOSION-PROOF SCIENCE & TECHNOLOGY Co Ltd
Priority to CN201410552776.4A priority Critical patent/CN104232175A/en
Publication of CN104232175A publication Critical patent/CN104232175A/en
Pending legal-status Critical Current

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Abstract

The invention provides an alcohol ether diesel oil. The alcohol ether diesel oil is prepared from such components in parts by weight as 40-60 parts of finished diesel oil, 5-10 parts of diethyl ether, 10-35 parts of methanol, 2-5 parts of isobutanol, 10-30 parts of oleic acid, 2-5 parts of ethyl ether, 5-15 parts of triethanolamine and 2-5 parts of catalytic combustion agent, wherein the catalytic combustion agent comprises 3-8 parts of zinc peroxide, 10-18 parts of dimethyl carbonate, 20-35 parts of isooctyl nitrate and 5-8 parts of cyclohexane. The alcohol ether diesel oil is powerful in power in a motor vehicle, more environmental friendly in exhaust gas emission, good in stability and high in water resistance; besides, the alcohol ether diesel oil is capable of effectively solving the problems of low-temperature difficult start and high-temperature air resistance due to emulsion of a methyl alcohol diesel oil in water, and metal corrosion and rubber swelling caused by the methyl alcohol, and the like.

Description

Alcohol ether diesel
Technical field
The present invention relates to a kind of fuel, be specifically related to a kind of alcohol ether diesel.
Background technology
Current energy shortage becomes global problem, in China, along with the development of national economy, and the increase of the universal and recoverable amount of automobile, the contradiction of energy shortage and energy demand.Wherein, be the most critical problem with the shortage of crude oil and processed oil again, and cause rise of the oil price.Continuing of world market crude oil price is soaring, has driven the crude oil price of domestic market and the rise of processed oil price.Even if the price of crude oil and processed oil falls after rise, but falling space is also far smaller than expection.Therefore, improve China's energy structure, seek new clean substitute energy very urgent.Alcohol-ether fuel can make the economical liquid fuel of the scale operation of raw material with coal and Sweet natural gas etc., mature production technology, stores easy to use.The alcohol-ether fuel as an alternative energy has lot of advantages, and one is the wide material sources of methyl alcohol, and wherein ammonia from coal has more great meaning, and especially high to sulphur content, unsuitable civilian or industrial coal, does not affect methanol; From ammonia from coal, also can extract alcohol mixture in the multiple material lighted, then methyl alcohol is replaced gasoline as fuel, equal automobile and burn coal.Two is that alcohol ether gasoline oxygen level is high, and sufficient combustion can effectively reduce and reduce the discharge of obnoxious flavour.Three is having good burning performance of alcohol-ether fuel, effectively can eliminate the carbon deposit at each position of firing system, avoid and cause power dropping because of the formation of carbon deposit, the phenomenon such as to burn insufficient, and each operating mode exhaust temperature can be reduced, be conducive to reducing part heat load, extend the work-ing life of engine parts.Four is because methyl alcohol is a kind of solvent of excellent property in alcohol ether gasoline, effectively can eliminate fuel tank and oil piping system contamination precipitation and condensation, have good oil circuit dredging effect.Five be use alcohol ether gasoline without
Alcohol ether diesel oil for vehicles be in diesel oil by volume or weight ratio add the formulated a kind of environment friendly energy conservation fuel of a certain proportion of alcohol ether class A fuel A.Wherein, alcohol ether and diesel oil mix according to a certain percentage, by the effect of composite auxiliary solvent, make it form stable homogeneous system.Due to differing greatly of alcohol ethers and diesel oil, select suitable solubility promoter very crucial, the past adjusts the lightning of alcohol ethers by aqueous phase, but has made strict regulation to the content of W/O in the relevant criterion of alcohol ether diesel oil for vehicles fuel that country formulates now.Current alcohol ether diesel oil for vehicles fuel homogeneous system needs the amount of the solubility promoter added comparatively large, and cost is higher, and alcohol ethers blending ratio is also lower.And by means of only physical modulated and process, the lightning of alcohol ether diesel fuel, calorific value, stability do not obtain essence and solve, and commercially carry out there is larger difficulty.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of power, and come in, the alcohol ether diesel of good environmental protection.
Technical scheme provided by the invention is a kind of alcohol ether diesel, comprises the component of following weight part:
Finished diesel fuel 40 ~ 60 parts, ether 5 ~ 10 parts, methyl alcohol 10 ~ 35 parts, isopropylcarbinol 2 ~ 5 parts, oleic acid 10 ~ 30 parts, dme 2 ~ 5 parts, trolamine 5 ~ 15 parts, catalytic combustion agent 2 ~ 5 parts;
Described catalytic combustion agent comprises the component of following weight part: zinc peroxide 3 ~ 8 parts, methylcarbonate 10 ~ 18 parts, isooctyl ester nitrate 20 ~ 35 parts, hexahydroaniline 5 ~ 8 parts.
The weight part of said components is: finished diesel fuel 50 ~ 60 parts, ether 8 ~ 10 parts, methyl alcohol 25 ~ 35 parts, isopropylcarbinol 4 ~ 5 parts, oleic acid 20 ~ 30 parts, dme 2 ~ 3.5 parts, trolamine 12 ~ 15 parts, catalytic combustion agent 3 ~ 5 parts.
In above-mentioned catalytic combustion agent, the weight part of each component is: zinc peroxide 6 ~ 8 parts, methylcarbonate 10 ~ 15 parts, isooctyl ester nitrate 30 ~ 35 parts, hexahydroaniline 5 ~ 6 parts.
In above-mentioned catalytic combustion agent, the weight part of each component is: zinc peroxide 7 parts, methylcarbonate 12 parts, isooctyl ester nitrate 32 parts, hexahydroaniline 5.5 parts.
The preparation method of alcohol ether diesel of the present invention is as follows:
1) at normal temperatures and pressures, methyl alcohol, catalytic combustion agent are fully stirred in retort, generate maternal diesel oil;
2) at normal temperatures and pressures, isopropylcarbinol, ether, dme, trolamine and oleic acid are injected mixing and stirring in retort successively, form distortion alcohol ether;
3) at normal temperatures and pressures, by above-mentioned distortion alcohol ether and maternal diesel oil mix and blend, to obtain final product.
Compared with prior art, the present invention has following beneficial effect:
1) utilize catalytic combustion agent, thus power is more powerful in a motor vehicle to make alcohol ether diesel, exhaust emissions is environmental protection more.
2) alcohol ether diesel good stability of the present invention, water resisting property is strong, effectively can solve methanol diesel-oil and meet emulsifying water, cold-starting difficulty, high temperature vapour lock, and methyl alcohol is to the problem such as swelling of corrosion of metal and rubber.
3) capability of antidetonance of the present invention is good, and its cetane value is suitable with conventional diesel, to vehicle motor without obvious corrosion, can effectively extend vehicle time limit of service.
Embodiment
The present invention is further elaborated for following specific embodiment, but not as a limitation of the invention.
Embodiment 1
Alcohol ether diesel is filled a prescription: finished diesel fuel 40kg, ether 5kg, methyl alcohol 10kg, isopropylcarbinol 2kg, oleic acid 10kg, dme 2kg, trolamine 5kg, catalytic combustion agent 2kg;
The formula of described catalytic combustion agent: zinc peroxide 3kg, methylcarbonate 10kg, isooctyl ester nitrate 20kg, hexahydroaniline 5kg.
Preparation method is as follows:
1) at normal temperatures and pressures, finished diesel fuel, catalytic combustion agent are fully stirred in retort, generate maternal diesel oil;
2) at normal temperatures and pressures, methyl alcohol, isopropylcarbinol, ether, dme, trolamine and oleic acid are injected mixing and stirring in retort successively, form distortion alcohol ether;
3) at normal temperatures and pressures, by above-mentioned distortion alcohol ether and maternal diesel oil mix and blend, to obtain final product.
Embodiment 2
Alcohol ether diesel is filled a prescription: finished diesel fuel 60kg, ether 10kg, methyl alcohol 35kg, isopropylcarbinol 5kg, oleic acid 30kg, dme 5kg, trolamine 15kg, catalytic combustion agent 5kg;
The formula of described catalytic combustion agent: zinc peroxide 8kg, methylcarbonate 18kg, isooctyl ester nitrate 35kg, hexahydroaniline 8kg.
Preparation method is with embodiment 1.
Embodiment 3
Alcohol ether diesel is filled a prescription: finished diesel fuel 50kg, ether 8kg, methyl alcohol 25kg, isopropylcarbinol 4kg, oleic acid 20kg, dme 3.5kg, trolamine 12kg, catalytic combustion agent 3kg.
The formula of described catalytic combustion agent: zinc peroxide 3kg, methylcarbonate 10kg, isooctyl ester nitrate 20kg, hexahydroaniline 5kg.
Preparation method is with embodiment 1.
Embodiment 4
Alcohol ether diesel is filled a prescription: finished diesel fuel 50kg, ether 10kg, methyl alcohol 25kg, isopropylcarbinol 5kg, oleic acid 20kg, dme 3.5kg, trolamine 12kg, catalytic combustion agent 5kg.
The formula of described catalytic combustion agent: zinc peroxide 3kg, methylcarbonate 18kg, isooctyl ester nitrate 20kg, hexahydroaniline 8kg.
Preparation method is with embodiment 1.
Embodiment 5
Alcohol ether diesel is filled a prescription: finished diesel fuel 60kg, ether 8kg, methyl alcohol 35kg, isopropylcarbinol 4kg, oleic acid 30kg, dme 2kg, trolamine 15kg, catalytic combustion agent 3kg.
The formula of described catalytic combustion agent:
Zinc peroxide 8kg, methylcarbonate 10kg, isooctyl ester nitrate 35kg, hexahydroaniline 5kg.
Preparation method is with embodiment 1.
Embodiment 6
Alcohol ether diesel is filled a prescription: finished diesel fuel 55kg, ether 9kg, methyl alcohol 30kg, isopropylcarbinol 4.5kg, oleic acid 25kg, dme 3kg, trolamine 14kg, catalytic combustion agent 4kg.
The formula of described catalytic combustion agent:
Zinc peroxide 7kg, methylcarbonate 12kg, isooctyl ester nitrate 32kg, hexahydroaniline 5.5kg.
Preparation method is with embodiment 1.

Claims (4)

1. alcohol ether diesel, is characterized in that: the component comprising following weight part:
Finished diesel fuel 40 ~ 60 parts, ether 5 ~ 10 parts, methyl alcohol 10 ~ 35 parts, isopropylcarbinol 2 ~ 5 parts, oleic acid 10 ~ 30 parts, dme 2 ~ 5 parts, trolamine 5 ~ 15 parts, catalytic combustion agent 2 ~ 5 parts;
Described catalytic combustion agent comprises the component of following weight part: zinc peroxide 3 ~ 8 parts, methylcarbonate 10 ~ 18 parts, isooctyl ester nitrate 20 ~ 35 parts, hexahydroaniline 5 ~ 8 parts.
2. alcohol ether diesel according to claim 1, is characterized in that: the weight part of described component is: finished diesel fuel 50 ~ 60 parts, ether 8 ~ 10 parts, methyl alcohol 25 ~ 35 parts, isopropylcarbinol 4 ~ 5 parts, oleic acid 20 ~ 30 parts, dme 2 ~ 3.5 parts, trolamine 12 ~ 15 parts, catalytic combustion agent 3 ~ 5 parts.
3. alcohol ether diesel according to claim 1 and 2, is characterized in that: in described catalytic combustion agent, the weight part of each component is: zinc peroxide 6 ~ 8 parts, methylcarbonate 10 ~ 15 parts, isooctyl ester nitrate 30 ~ 35 parts, hexahydroaniline 5 ~ 6 parts.
4. alcohol ether diesel according to claim 3, is characterized in that: in described catalytic combustion agent, the weight part of each component is: zinc peroxide 7 parts, methylcarbonate 12 parts, isooctyl ester nitrate 32 parts, hexahydroaniline 5.5 parts.
CN201410552776.4A 2014-10-17 2014-10-17 Alcohol ether diesel oil Pending CN104232175A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410552776.4A CN104232175A (en) 2014-10-17 2014-10-17 Alcohol ether diesel oil

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410552776.4A CN104232175A (en) 2014-10-17 2014-10-17 Alcohol ether diesel oil

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CN104232175A true CN104232175A (en) 2014-12-24

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104745243A (en) * 2015-03-04 2015-07-01 张东宁 Methanol-diesel oil additive and preparation method thereof
CN105838456A (en) * 2015-01-13 2016-08-10 赵惠霖 High-cleanness diesel and preparation method thereof
CN110373234A (en) * 2019-07-08 2019-10-25 刘元彬 Inexpensive micro-emulsified methanol diesel
CN110819394A (en) * 2019-11-18 2020-02-21 国核柏斯顿新能源科技(北京)有限公司 Methanol diesel oil and preparation method thereof
CN111635790A (en) * 2020-06-12 2020-09-08 大容新能源科技(深圳)有限公司 Agricultural alcohol ether diesel fuel

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1944596A (en) * 2006-09-18 2007-04-11 鲁希诺 Composite modifying alcohol ether fuel and catalytic fuel agent
US20120090226A1 (en) * 2011-12-07 2012-04-19 Igp Energy, Inc. Fuels and fuel additives comprising butanol and pentanol
CN102559294A (en) * 2011-11-30 2012-07-11 胡显坤 Alcohol ether diesel oil
CN102876425A (en) * 2012-10-29 2013-01-16 郑州国创能源科技有限公司 Diesel cetane number improver

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1944596A (en) * 2006-09-18 2007-04-11 鲁希诺 Composite modifying alcohol ether fuel and catalytic fuel agent
CN102559294A (en) * 2011-11-30 2012-07-11 胡显坤 Alcohol ether diesel oil
US20120090226A1 (en) * 2011-12-07 2012-04-19 Igp Energy, Inc. Fuels and fuel additives comprising butanol and pentanol
CN102876425A (en) * 2012-10-29 2013-01-16 郑州国创能源科技有限公司 Diesel cetane number improver

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105838456A (en) * 2015-01-13 2016-08-10 赵惠霖 High-cleanness diesel and preparation method thereof
CN104745243A (en) * 2015-03-04 2015-07-01 张东宁 Methanol-diesel oil additive and preparation method thereof
CN110373234A (en) * 2019-07-08 2019-10-25 刘元彬 Inexpensive micro-emulsified methanol diesel
CN110819394A (en) * 2019-11-18 2020-02-21 国核柏斯顿新能源科技(北京)有限公司 Methanol diesel oil and preparation method thereof
CN111635790A (en) * 2020-06-12 2020-09-08 大容新能源科技(深圳)有限公司 Agricultural alcohol ether diesel fuel

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Application publication date: 20141224