CN104231467A - Anti-counterfeit polyvinyl chloride sheet and preparation method thereof - Google Patents
Anti-counterfeit polyvinyl chloride sheet and preparation method thereof Download PDFInfo
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- CN104231467A CN104231467A CN201410002989.XA CN201410002989A CN104231467A CN 104231467 A CN104231467 A CN 104231467A CN 201410002989 A CN201410002989 A CN 201410002989A CN 104231467 A CN104231467 A CN 104231467A
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- preparation
- stearate
- toughener
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- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- 229920000915 polyvinyl chloride Polymers 0.000 title claims abstract description 11
- 239000004800 polyvinyl chloride Substances 0.000 title claims abstract description 11
- 238000003756 stirring Methods 0.000 claims abstract description 17
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 14
- 239000000314 lubricant Substances 0.000 claims abstract description 12
- 229920003023 plastic Polymers 0.000 claims abstract description 10
- 239000004033 plastic Substances 0.000 claims abstract description 10
- 238000003490 calendering Methods 0.000 claims abstract description 9
- 238000002156 mixing Methods 0.000 claims abstract description 9
- 239000000463 material Substances 0.000 claims description 34
- 239000012745 toughening agent Substances 0.000 claims description 16
- 238000010792 warming Methods 0.000 claims description 12
- 239000006057 Non-nutritive feed additive Substances 0.000 claims description 11
- 239000007788 liquid Substances 0.000 claims description 10
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical group [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 8
- 150000004645 aluminates Chemical class 0.000 claims description 8
- 230000015572 biosynthetic process Effects 0.000 claims description 8
- 229920001577 copolymer Polymers 0.000 claims description 8
- 239000012043 crude product Substances 0.000 claims description 8
- -1 poly(lactic acid) Polymers 0.000 claims description 8
- 239000000843 powder Substances 0.000 claims description 8
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 4
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 4
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 4
- 239000004135 Bone phosphate Substances 0.000 claims description 4
- 239000004709 Chlorinated polyethylene Substances 0.000 claims description 4
- 239000005642 Oleic acid Substances 0.000 claims description 4
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 4
- AGXUVMPSUKZYDT-UHFFFAOYSA-L barium(2+);octadecanoate Chemical compound [Ba+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O AGXUVMPSUKZYDT-UHFFFAOYSA-L 0.000 claims description 4
- GWOWVOYJLHSRJJ-UHFFFAOYSA-L cadmium stearate Chemical compound [Cd+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O GWOWVOYJLHSRJJ-UHFFFAOYSA-L 0.000 claims description 4
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 4
- 239000008116 calcium stearate Substances 0.000 claims description 4
- 235000013539 calcium stearate Nutrition 0.000 claims description 4
- UQLDLKMNUJERMK-UHFFFAOYSA-L di(octadecanoyloxy)lead Chemical compound [Pb+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O UQLDLKMNUJERMK-UHFFFAOYSA-L 0.000 claims description 4
- 230000009977 dual effect Effects 0.000 claims description 4
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 4
- PIJPYDMVFNTHIP-UHFFFAOYSA-L lead sulfate Chemical compound [PbH4+2].[O-]S([O-])(=O)=O PIJPYDMVFNTHIP-UHFFFAOYSA-L 0.000 claims description 4
- ADFPJHOAARPYLP-UHFFFAOYSA-N methyl 2-methylprop-2-enoate;styrene Chemical compound COC(=O)C(C)=C.C=CC1=CC=CC=C1 ADFPJHOAARPYLP-UHFFFAOYSA-N 0.000 claims description 4
- 239000003921 oil Substances 0.000 claims description 4
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 4
- 229920000747 poly(lactic acid) Polymers 0.000 claims description 4
- 239000011347 resin Substances 0.000 claims description 4
- 229920005989 resin Polymers 0.000 claims description 4
- 238000005096 rolling process Methods 0.000 claims description 4
- 238000010008 shearing Methods 0.000 claims description 4
- 229920002545 silicone oil Polymers 0.000 claims description 4
- 239000003760 tallow Substances 0.000 claims description 4
- QRCJOCOSPZMDJY-UHFFFAOYSA-N valnoctamide Chemical compound CCC(C)C(CC)C(N)=O QRCJOCOSPZMDJY-UHFFFAOYSA-N 0.000 claims description 4
- 238000007493 shaping process Methods 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 7
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 239000000047 product Substances 0.000 abstract description 4
- 239000011265 semifinished product Substances 0.000 abstract 2
- 239000002985 plastic film Substances 0.000 abstract 1
- 239000012744 reinforcing agent Substances 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
- 238000005516 engineering process Methods 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000010137 moulding (plastic) Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention belongs to the technical field of plastic forming processing, and relates to an anti-counterfeit polyvinyl chloride sheet and a preparation method thereof. The preparation method comprises the following steps of: firstly uniformly mixing 160%-200% (by weight) of polyvinyl chloride and 1.1%-2.0% (by weight) of lubricating agents with 2.0%-4.0% (by weight) of processing auxiliary agents, increasing temperature to 65-75 DEG C, and stirring for 1 minute-1 hour to obtain a preparing solution; then adding 2.0%-3.0% by weight of stabilizing agents and 1.0%-3.0% by weight of reinforcing agents to the preparing solution, increasing the temperature to 75-90 DEG C, and stirring for 1 minute-1 hour to obtain a semi-finished product; finally adding 2.1%-3.0% by weight of anti-counterfeit auxiliary agents to the semi-finished product, increasing the temperature to 120-135 DEG C, stirring for 1 minute-1 hour, and then extruding, calendering, stripping and curling to prepare a product. The preparation method disclosed by the invention has the advantages of scientific formula and advanced process; the plastic sheet can emit light with a particular color under the irradiation of short-wave ultraviolet light to be conveniently identified in authenticity, so that the phenomenon of counterfeiting is effectively prevented. The method disclosed by the invention is convenient to operate, low in production cost and suitable for being popularized and applied domestically and overseas.
Description
Technical field
The present invention relates to a kind of anti-fake polychlorovinyl (PVC) sheet material and preparation method thereof, belong to plastic molding processing technology field.
Background technology
Polychlorovinyl sheet material is as wrapping material, due to the sales contest between product, often need the antiforge function increasing product, what usually adopt at present is by outer field laser anti-counterfeit label, along with the technology of laser anti-counterfeit is popularized, antifalse effect worse and worse, affects the order of market fair competition, can not meet the false proof demand that wrapping material are growing.
Summary of the invention
The object of the invention is to for above task provide a kind of can effective anti-fake polychlorovinyl sheet material preventing fake products and preparation method thereof.
The present invention is achieved by the following technical solutions:
A kind of anti-fake polychlorovinyl sheet material, comprises 85-93% polyvinyl chloride, 2.0-3.0% stablizer, 1.1-2.0% lubricant, 2.0-4.0% processing aid, 1.0-3.0% toughener and the false proof auxiliary agent of 2.1-3.0%.
Described stablizer is one or more in lead sulfate tribasic, dibasic lead phosphite, dibasic lead stearate, Zinic stearas, calcium stearate, lead stearate, cadmium stearate, barium stearate.
One or more based on described lubricant in oil, silicone oil, oleic acid, tallow.
Described processing aid is one or more in methyl methacrylate-acrylate copolymer, copolymer of methyl methacrylatestyrene, acrylonitritrile-styrene resin, chlorinatedpolyethylene.
Described toughener is one or more in DH-2 plastics toughener, DH-3 plastics toughener, poly(lactic acid).
Described false proof auxiliary agent is silicate luminescent fluorescent powder or aluminate long afterglow fluorescent material.
Described silicate luminescent fluorescent powder is Na
2y
2zrSi
2o
10or Na
5yZrSi
6o
18.
Described aluminate long afterglow fluorescent material is Eu
2srDy
2al
2o
10or La
2nd
2dy
4al
2o
15.
Production technique of the present invention comprises stirring, extrudes, rolls, peels off and batch, first liquid adjuvants is added, stir, temperature adds solid additive when reaching 65 DEG C-75 DEG C in the preparation liquid obtained, temperature adds false proof auxiliary agent when reaching 75 DEG C-90 DEG C, when temperature reaches 120 DEG C-135 DEG C, carry out extruding, roll, peel off and batching.
Compared with prior art, the invention has the beneficial effects as follows:
1. the present invention is owing to adopting new technical recipe, makes plastics sheet can send the light of special color under the irradiation of short wavelength UV linear light, is convenient to distinguish true from false, and effectively prevents from palming off phenomenon;
2. scientific formulation of the present invention, technique is advanced, and easy to operate, production cost is low, is applicable to apply both at home and abroad.
Embodiment
A kind of anti-fake polychlorovinyl sheet material, comprises 85-93% polyvinyl chloride, 2.0-3.0% stablizer, 1.1-2.0% lubricant, 2.0-4.0% processing aid, 1.0-3.0% toughener and the false proof auxiliary agent of 2.1-3.0%.
Described stablizer is one or more in lead sulfate tribasic, dibasic lead phosphite, dibasic lead stearate, Zinic stearas, calcium stearate, lead stearate, cadmium stearate, barium stearate.
One or more based on described lubricant in oil, silicone oil, oleic acid, tallow.
Described processing aid is one or more in methyl methacrylate-acrylate copolymer, copolymer of methyl methacrylatestyrene, acrylonitritrile-styrene resin, chlorinatedpolyethylene.
Described toughener is one or more in DH-2 plastics toughener, DH-3 plastics toughener, poly(lactic acid).
Described false proof auxiliary agent is silicate luminescent fluorescent powder or aluminate long afterglow fluorescent material.
Described silicate luminescent fluorescent powder is Na
2y
2zrSi
2o
10or Na
5yZrSi
6o
18.
Described aluminate long afterglow fluorescent material is Eu
2srDy
2al
2o
10or La
2nd
2dy
4al
2o
15.
Example 1:
Get 85 parts of polyvinyl chloride, 2.0 parts of lubricants and 4.0 parts of processing aid Homogeneous phase mixing, be warming up to 65 DEG C, obtain after stirring 1min preparing liquid; 3.0 parts of stablizers and 3.0 parts of tougheners are joined in described preparation liquid, is warming up to 90 DEG C, after stirring 1h, obtain crude product; 3.0 parts of false proof auxiliary agents joined in described crude product, is warming up to 135 DEG C, extrude through extrusion machine again after stirring 1h, through shearing, mixing dual function, plastify the plasticizing material into molten state; Plasticizing material is sent to rolling press and carries out calendering formation; Make after calendering formation sheet material being carried out peel off and batch.
Example 2:
Get 92.8 parts of polyvinyl chloride, 1.1 parts of lubricants and 2.0 parts of processing aid Homogeneous phase mixing, be warming up to 75 DEG C, obtain after stirring 1h preparing liquid; 2.0 parts of stablizers and 1.0 parts of tougheners are joined in described preparation liquid, is warming up to 75 DEG C, after stirring 1min, obtain crude product; 2.1 parts of false proof auxiliary agents joined in described crude product, is warming up to 120 DEG C, extrude through extrusion machine again after stirring 30min, through shearing, mixing dual function, plastify the plasticizing material into molten state; Plasticizing material is sent to rolling press and carries out calendering formation; Make after calendering formation sheet material being carried out peel off and batch.
Example 3:
Get 88.5 parts of polyvinyl chloride, 1.5 parts of lubricants and 3.0 parts of processing aid Homogeneous phase mixing, be warming up to 70 DEG C, obtain after stirring 30min preparing liquid; 2.5 parts of stablizers and 2.0 parts of tougheners are joined in described preparation liquid, is warming up to 82 DEG C, after stirring 30min, obtain crude product; 2.5 parts of false proof auxiliary agents joined in described crude product, is warming up to 128 DEG C, extrude through extrusion machine again after stirring 1min, through shearing, mixing dual function, plastify the plasticizing material into molten state; Plasticizing material is sent to rolling press and carries out calendering formation; Make after calendering formation sheet material being carried out peel off and batch.
The adjudicate two cases together ethene sheet material that method is produced thus can send the light of special color under the irradiation of short wavelength UV linear light, is convenient to distinguish true from false, and can effectively prevent from palming off phenomenon, and technique is advanced, and easy to operate, production cost is low, is applicable to apply both at home and abroad.
In sum, be only preferred embodiment of the present invention, not be used for limiting scope of the invention process, all equalizations of doing according to shape, structure, feature and the spirit described in the claims in the present invention scope change and modify, and all should be included in right of the present invention.
Claims (5)
1. an anti-fake polychlorovinyl sheet material, is characterized in that: comprise 85-93% polyvinyl chloride, 2.0-3.0% stablizer, 1.1-2.0% lubricant, 2.0-4.0% processing aid, 1.0-3.0% toughener and the false proof auxiliary agent of 2.1-3.0%;
Described stablizer is one or more in lead sulfate tribasic, dibasic lead phosphite, dibasic lead stearate, Zinic stearas, calcium stearate, lead stearate, cadmium stearate, barium stearate;
One or more based on described lubricant in oil, silicone oil, oleic acid, tallow;
Described processing aid is one or more in methyl methacrylate-acrylate copolymer, copolymer of methyl methacrylatestyrene, acrylonitritrile-styrene resin, chlorinatedpolyethylene;
Described toughener is one or more in DH-2 plastics toughener, DH-3 plastics toughener, poly(lactic acid);
Described false proof auxiliary agent is silicate luminescent fluorescent powder or aluminate long afterglow fluorescent material.
2. a kind of anti-fake polychlorovinyl sheet material according to claim 1, is characterized in that: described silicate luminescent fluorescent powder is Na
2y
2zrSi
2o
10or Na
5yZrSi
6o
18;
Described aluminate long afterglow fluorescent material is Eu
2srDy
2al
2o
10or La
2nd
2dy
4al
2o
15.
3. a preparation method for anti-fake polychlorovinyl sheet material, is characterized in that: step one, get 85-93% polyvinyl chloride, 1.1-2.0% lubricant and 2.0-4.0% processing aid Homogeneous phase mixing, is warming up to 65 DEG C-75 DEG C, obtains preparing liquid after stirring 1min-1h; Step 2,2.0-3.0% stablizer and 1.0-3.0% toughener to be joined in described preparation liquid, be warming up to 75 DEG C-90 DEG C, after stirring 1min-1h, obtain crude product; Step 3, false proof for 2.1-3.0% auxiliary agent to be joined in described crude product, be warming up to 120 DEG C-135 DEG C, shaping through forcing machine again after stirring 1min-1h, through shearing, mixing dual function, plastify the plasticizing material into molten state; Step 4, described plasticizing material is sent to rolling press carries out calendering formation; Step 5, calendering formation sheet material carried out peel off and batch after make.
4. the preparation method of anti-fake polychlorovinyl sheet material according to claim 3, is characterized in that: described stablizer is one or more in lead sulfate tribasic, dibasic lead phosphite, dibasic lead stearate, Zinic stearas, calcium stearate, lead stearate, cadmium stearate, barium stearate;
One or more based on described lubricant in oil, silicone oil, oleic acid, tallow;
Described processing aid is one or more in methyl methacrylate-acrylate copolymer, copolymer of methyl methacrylatestyrene, acrylonitritrile-styrene resin, chlorinatedpolyethylene;
Described toughener is one or more in DH-2 plastics toughener, DH-3 plastics toughener, poly(lactic acid);
Described false proof auxiliary agent is silicate luminescent fluorescent powder or aluminate long afterglow fluorescent material.
5. the preparation method of anti-fake polychlorovinyl sheet material according to claim 4, is characterized in that: described silicate luminescent fluorescent powder is Na
2y
2zrSi
2o
10or Na
5yZrSi
6o
18;
Described aluminate long afterglow fluorescent material is Eu
2srDy
2al
2o
10or La
2nd
2dy
4al
2o
15.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410002989.XA CN104231467A (en) | 2014-01-03 | 2014-01-03 | Anti-counterfeit polyvinyl chloride sheet and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410002989.XA CN104231467A (en) | 2014-01-03 | 2014-01-03 | Anti-counterfeit polyvinyl chloride sheet and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104231467A true CN104231467A (en) | 2014-12-24 |
Family
ID=52220436
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410002989.XA Pending CN104231467A (en) | 2014-01-03 | 2014-01-03 | Anti-counterfeit polyvinyl chloride sheet and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104231467A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110157202A (en) * | 2018-02-07 | 2019-08-23 | 山东联星能源集团有限公司 | A kind of superhard pitch and preparation method thereof |
| CN114806107A (en) * | 2022-05-18 | 2022-07-29 | 丽星塑料制品(安徽)有限公司 | Ultraviolet photochromic cosmetics hose |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH058573A (en) * | 1991-07-01 | 1993-01-19 | Dainippon Printing Co Ltd | Thermal transfer sheet |
| JPH1135762A (en) * | 1997-07-15 | 1999-02-09 | Mitsubishi Plastics Ind Ltd | Long afterglow heat-shrinkable tube |
| CN1483760A (en) * | 2002-09-18 | 2004-03-24 | 江苏琼花高科技股份有限公司 | Anti-fake polychlorovinyl sheet material and productive process thereof |
| CN1769366A (en) * | 2004-10-27 | 2006-05-10 | 中国石油化工股份有限公司 | A long afterglow luminescent thermoplastic composition and its preparation method |
| CN101857704A (en) * | 2010-05-28 | 2010-10-13 | 河南谢人安防门帘有限公司 | Luminous energy-saving polyvinyl chloride plastics and preparation method thereof |
-
2014
- 2014-01-03 CN CN201410002989.XA patent/CN104231467A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH058573A (en) * | 1991-07-01 | 1993-01-19 | Dainippon Printing Co Ltd | Thermal transfer sheet |
| JPH1135762A (en) * | 1997-07-15 | 1999-02-09 | Mitsubishi Plastics Ind Ltd | Long afterglow heat-shrinkable tube |
| CN1483760A (en) * | 2002-09-18 | 2004-03-24 | 江苏琼花高科技股份有限公司 | Anti-fake polychlorovinyl sheet material and productive process thereof |
| CN1769366A (en) * | 2004-10-27 | 2006-05-10 | 中国石油化工股份有限公司 | A long afterglow luminescent thermoplastic composition and its preparation method |
| CN101857704A (en) * | 2010-05-28 | 2010-10-13 | 河南谢人安防门帘有限公司 | Luminous energy-saving polyvinyl chloride plastics and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110157202A (en) * | 2018-02-07 | 2019-08-23 | 山东联星能源集团有限公司 | A kind of superhard pitch and preparation method thereof |
| CN114806107A (en) * | 2022-05-18 | 2022-07-29 | 丽星塑料制品(安徽)有限公司 | Ultraviolet photochromic cosmetics hose |
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|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
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| RJ01 | Rejection of invention patent application after publication | ||
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Application publication date: 20141224 |