CN104212225A - Antibacterial durable aqueous polyurethane printing ink - Google Patents
Antibacterial durable aqueous polyurethane printing ink Download PDFInfo
- Publication number
- CN104212225A CN104212225A CN201410395398.3A CN201410395398A CN104212225A CN 104212225 A CN104212225 A CN 104212225A CN 201410395398 A CN201410395398 A CN 201410395398A CN 104212225 A CN104212225 A CN 104212225A
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- China
- Prior art keywords
- parts
- ink
- aqueous polyurethane
- stirring
- printing ink
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920002635 polyurethane Polymers 0.000 title claims abstract description 18
- 239000004814 polyurethane Substances 0.000 title claims abstract description 18
- 230000000844 anti-bacterial effect Effects 0.000 title abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- BCZXFFBUYPCTSJ-UHFFFAOYSA-L Calcium propionate Chemical compound [Ca+2].CCC([O-])=O.CCC([O-])=O BCZXFFBUYPCTSJ-UHFFFAOYSA-L 0.000 claims abstract description 9
- 229920000858 Cyclodextrin Polymers 0.000 claims abstract description 9
- 235000010331 calcium propionate Nutrition 0.000 claims abstract description 9
- 239000004330 calcium propionate Substances 0.000 claims abstract description 9
- 239000008367 deionised water Substances 0.000 claims abstract description 9
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 9
- 239000002994 raw material Substances 0.000 claims abstract description 8
- 239000000839 emulsion Substances 0.000 claims abstract description 7
- 239000012467 final product Substances 0.000 claims abstract description 7
- 239000011347 resin Substances 0.000 claims abstract description 5
- 229920005989 resin Polymers 0.000 claims abstract description 5
- 239000006185 dispersion Substances 0.000 claims abstract description 4
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 15
- YZOUYRAONFXZSI-SBHWVFSVSA-N (1S,3R,5R,6R,8R,10R,11R,13R,15R,16R,18R,20R,21R,23R,25R,26R,28R,30R,31S,33R,35R,36R,37S,38R,39S,40R,41S,42R,43S,44R,45S,46R,47S,48R,49S)-5,10,15,20,25,30,35-heptakis(hydroxymethyl)-37,39,40,41,42,43,44,45,46,47,48,49-dodecamethoxy-2,4,7,9,12,14,17,19,22,24,27,29,32,34-tetradecaoxaoctacyclo[31.2.2.23,6.28,11.213,16.218,21.223,26.228,31]nonatetracontane-36,38-diol Chemical compound O([C@@H]([C@H]([C@@H]1OC)OC)O[C@H]2[C@@H](O)[C@@H]([C@@H](O[C@@H]3[C@@H](CO)O[C@@H]([C@H]([C@@H]3O)OC)O[C@@H]3[C@@H](CO)O[C@@H]([C@H]([C@@H]3OC)OC)O[C@@H]3[C@@H](CO)O[C@@H]([C@H]([C@@H]3OC)OC)O[C@@H]3[C@@H](CO)O[C@@H]([C@H]([C@@H]3OC)OC)O3)O[C@@H]2CO)OC)[C@H](CO)[C@H]1O[C@@H]1[C@@H](OC)[C@H](OC)[C@H]3[C@@H](CO)O1 YZOUYRAONFXZSI-SBHWVFSVSA-N 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- 239000003973 paint Substances 0.000 claims description 7
- 238000002360 preparation method Methods 0.000 claims description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- XOLBLPGZBRYERU-UHFFFAOYSA-N SnO2 Inorganic materials O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims description 6
- 229920002125 Sokalan® Polymers 0.000 claims description 6
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 6
- 125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 claims description 6
- 239000012752 auxiliary agent Substances 0.000 claims description 6
- 238000000498 ball milling Methods 0.000 claims description 6
- 229960001631 carbomer Drugs 0.000 claims description 6
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 6
- 229960004418 trolamine Drugs 0.000 claims description 6
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 claims description 3
- 229930195725 Mannitol Natural products 0.000 claims description 3
- WMGSQTMJHBYJMQ-UHFFFAOYSA-N aluminum;magnesium;silicate Chemical compound [Mg+2].[Al+3].[O-][Si]([O-])([O-])[O-] WMGSQTMJHBYJMQ-UHFFFAOYSA-N 0.000 claims description 3
- 239000001913 cellulose Substances 0.000 claims description 3
- 229920002678 cellulose Polymers 0.000 claims description 3
- HGAZMNJKRQFZKS-UHFFFAOYSA-N chloroethene;ethenyl acetate Chemical compound ClC=C.CC(=O)OC=C HGAZMNJKRQFZKS-UHFFFAOYSA-N 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- 239000003995 emulsifying agent Substances 0.000 claims description 3
- 239000000594 mannitol Substances 0.000 claims description 3
- 235000010355 mannitol Nutrition 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 229940059574 pentaerithrityl Drugs 0.000 claims description 3
- 238000012545 processing Methods 0.000 claims description 3
- 239000002002 slurry Substances 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- 239000000049 pigment Substances 0.000 abstract description 6
- 231100000331 toxic Toxicity 0.000 abstract description 4
- 230000002588 toxic effect Effects 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 3
- 241001122767 Theaceae Species 0.000 abstract 2
- 150000008442 polyphenolic compounds Chemical class 0.000 abstract 2
- 235000013824 polyphenols Nutrition 0.000 abstract 2
- 239000001116 FEMA 4028 Substances 0.000 abstract 1
- LZBCVRCTAYKYHR-UHFFFAOYSA-N acetic acid;chloroethene Chemical compound ClC=C.CC(O)=O LZBCVRCTAYKYHR-UHFFFAOYSA-N 0.000 abstract 1
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- SNAAJJQQZSMGQD-UHFFFAOYSA-N aluminum magnesium Chemical compound [Mg].[Al] SNAAJJQQZSMGQD-UHFFFAOYSA-N 0.000 abstract 1
- 229960004853 betadex Drugs 0.000 abstract 1
- 229920003086 cellulose ether Polymers 0.000 abstract 1
- 239000000758 substrate Substances 0.000 abstract 1
- 239000012855 volatile organic compound Substances 0.000 abstract 1
- 239000002253 acid Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 230000001464 adherent effect Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000000549 coloured material Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention relates to the field of printing ink, and in particular to an antibacterial durable aqueous polyurethane printing ink. The printing ink is composed of the following raw materials by weight: 4-5 parts of methylated-beta-cyclodextrin, 0.1-0.2 part of calcium propionate, 1-3 parts of tea polyphenols, 6-8 parts of binary vinyl chloride-acetate, 2-4 parts of cellulose ether, 4-7 parts of magnesium aluminum silicate, 30-50 parts of deionized water, 15-18 parts of an aqueous pigment, 2-3 parts of pentaerythritol, 20-25 parts of a waterborne polyurethane emulsion and 2-4 parts of an auxiliary. The printing ink of the invention has low toxic volatile organic compound content, and little harm to environment and human body; methylated-bet-cyclodextrin, calcium propionate and tea polyphenols can improve the dispersion and compatibility with resin of the aqueous pigment, but also endow the pigment with certain antibacterial and mildewproof effect, improve the durability of the color. The final product has strong adhesive ability even ink color, and clear and beautiful appurtenance on a substrate, does not easily mold or fall off, and has high safety and wide scope of application.
Description
Technical field
The present invention relates to printing-ink field, be specifically related to the durable aqueous polyurethane printing-ink of a kind of germ resistance.
Background technology
Printing-ink is a kind of common printed matter coloured material, and forming primarily of compositions such as pigment, low-melting ink vehicle, stopping composition, is the pulpous state adherent that a class is coloured, have certain degree of mobilization.Want to obtain gratifying printing effect, to the color of ink in actual use procedure, printing adaptability, rate of drying has certain requirement, also to possess water-fast according to environment for use simultaneously, fast light, acid and alkali-resistance, the features such as low toxic and environment-friendly, following printing-ink developing direction must be towards low toxicity, quick-drying, the future development of the naturally various and multifunction of color, but the inadequate environmental protection of existing ink ubiquity, viscosity controls uneven, not good and partial properties good ink such as to hold at high price at the shortcoming with base material sticking power, therefore, the composition and engineering of necessary improvement printing-ink, the transition of quickening industry, to reach the production model of high-efficiency environment friendly.
Summary of the invention
The object of the invention is to, provide a kind of germ resistance durable aqueous polyurethane printing-ink, and make it have good printing performance, to achieve these goals, the technical solution used in the present invention is as follows:
The durable aqueous polyurethane printing-ink of a kind of germ resistance, it is characterized in that, this ink is made up of the raw material of following weight part: methyl-β-cyclodextrin 4-5, calcium propionate 0.1-0.2, tea-polyphenol 1-3, binary vinyl chloride-vinyl acetate resin 6-8, ether of cellulose 2-4, neusilin 4-7, deionized water 30-50, water-based paint 15-18, tetramethylolmethane 2-3, aqueous polyurethane emulsion 20-25, auxiliary agent 2-4;
The raw material of following weight part is comprised: carbomer 3-5, trolamine 1-2, nano-stannic oxide 2-3, emulsifier op-10 4-5, ferric acetyl acetonade 0.1-0.2, dehydrated alcohol 20-25, N.F,USP MANNITOL 4-5 in described auxiliary agent, preparation method is: first add in dehydrated alcohol by carbomer, trolamine, after dispersed with stirring 40-50min, add nano-stannic oxide, ferric acetyl acetonade again, mixture ball milling 1-2h after stirring, add other remaining component subsequently, continue dispersion 40-50min, to obtain final product.
The solid content of described aqueous polyurethane emulsion is 45-55%.
The durable aqueous polyurethane printing-ink of described a kind of germ resistance, its preparation method is as follows:
(1) first water-based paint is dropped in deionized water, solution is heated to 40-50 DEG C, after stirring and dissolving is uniformly dispersed, drop into methyl-β-cyclodextrin, calcium propionate, tea-polyphenol, for subsequent use after continuing dispersed with stirring 1-2h;
(2) step (1) gained material is mixed with other remaining component, drop in homogenizer, after the rotating speed dispersed with stirring 2-3h of 1200-1500 rev/min, again compound is dropped into ball-milling processing in ball mill, the particle diameter of gained slurry is made to be 5-20 μm, and use deionized water adjusting viscosity, to obtain final product.
Water color ink advantage prepared by the present invention is: the principle that first have followed low toxic and environment-friendly in the preparation of raw material, toxic volatile organic content is low, little to the harm of environment and human body, after the materials such as methyl-β-cyclodextrin, calcium propionate, tea-polyphenol mix with water-based paint, the dispersiveness of pigment and the consistency with resin can be improved, also make pigment have certain antibacterial and mouldproof effect simultaneously, improve the persistency of color; Water-based polyurethane ink prepared by the present invention coheres that ability is strong, and uniform color, is printed on after on base material clear attractive in appearance, not easily mouldyly comes off, and security is high, is applicable to multiple environment for use.
Embodiment
Embodiment
Printing-ink prepared by the present embodiment is made up of the raw material of following weight part: methyl-β-cyclodextrin 5, calcium propionate 0.1, tea-polyphenol 3, binary vinyl chloride-vinyl acetate resin 8, ether of cellulose 4, neusilin 7, deionized water 45, water-based paint 15, tetramethylolmethane 3, aqueous polyurethane emulsion 25, auxiliary agent 4; Wherein auxiliary agent is made up of the raw material of following weight part: carbomer 4, trolamine 2, nano-stannic oxide 3, emulsifier op-10 5, ferric acetyl acetonade 0.1, dehydrated alcohol 25, N.F,USP MANNITOL 5, preparation method is: first add in dehydrated alcohol by carbomer, trolamine, after dispersed with stirring 50min, add nano-stannic oxide, ferric acetyl acetonade again, mixture ball milling 1.5h after stirring, add other remaining component subsequently, continue dispersion 50min, to obtain final product.
The solid content of the aqueous polyurethane emulsion adopted is 50%.
The preparation method of this printing-ink is as follows:
(1) first water-based paint is dropped in deionized water, solution is heated to 40-50 DEG C, after stirring and dissolving is uniformly dispersed, drop into methyl-β-cyclodextrin, calcium propionate, tea-polyphenol, for subsequent use after continuing dispersed with stirring 2h;
(2) step (1) gained material is mixed with other remaining component, drop in homogenizer, after the rotating speed dispersed with stirring 2.5h of 1500 revs/min, then compound is dropped into ball-milling processing in ball mill, the particle diameter making gained slurry is 10 μm, to obtain final product.
The performance test results of ink of the present invention is:
| Test item | Detected result |
| Form and aspect | Consistent with standard colour card |
[0019]?
| Viscosity (coating No. 4 cups, s/25 DEG C) | 20.3 |
| Tinting strength (%) | 100 |
| First dryness (mm) | 18 |
| Gloss (60 DEG C, specular gloss instrument) | 63.2％ |
| Attachment fastness (%) | 96.4 |
| Acid and alkali-resistance, water tolerance | Well |
| Package stability (5 DEG C-30 DEG C) | Well |
Above-mentioned test is all followed relevant criterion and is carried out.
Claims (3)
1. the durable aqueous polyurethane printing-ink of germ resistance, it is characterized in that, this printing-ink is made up of the raw material of following weight part: methyl-β-cyclodextrin 4-5, calcium propionate 0.1-0.2, tea-polyphenol 1-3, binary vinyl chloride-vinyl acetate resin 6-8, ether of cellulose 2-4, neusilin 4-7, deionized water 30-50, water-based paint 15-18, tetramethylolmethane 2-3, aqueous polyurethane emulsion 20-25, auxiliary agent 2-4;
Described auxiliary agent is made up of the raw material of following weight part: carbomer 3-5, trolamine 1-2, nano-stannic oxide 2-3, emulsifier op-10 4-5, ferric acetyl acetonade 0.1-0.2, dehydrated alcohol 20-25, N.F,USP MANNITOL 4-5, preparation method is: first add in dehydrated alcohol by carbomer, trolamine, after dispersed with stirring 40-50min, add nano-stannic oxide, ferric acetyl acetonade again, mixture ball milling 1-2h after stirring, add other remaining component subsequently, continue dispersion 40-50min, to obtain final product.
2. the durable aqueous polyurethane printing-ink of a kind of germ resistance as claimed in claim 1, is characterized in that, the solid content of described aqueous polyurethane emulsion is 40-55%.
3. the durable aqueous polyurethane printing-ink of a kind of germ resistance as claimed in claim 1, its preparation method is as follows:
(1) first water-based paint is dropped in deionized water, solution is heated to 40-50 DEG C, after stirring and dissolving is uniformly dispersed, drop into methyl-β-cyclodextrin, calcium propionate, tea-polyphenol, for subsequent use after continuing dispersed with stirring 1-2h;
(2) step (1) gained material is mixed with other remaining component, drop in homogenizer, after the rotating speed dispersed with stirring 2-3h of 1200-1500 rev/min, again compound is dropped into ball-milling processing in ball mill, the particle diameter of gained slurry is made to be 5-20 μm, and use deionized water adjusting viscosity, to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410395398.3A CN104212225A (en) | 2014-08-12 | 2014-08-12 | Antibacterial durable aqueous polyurethane printing ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410395398.3A CN104212225A (en) | 2014-08-12 | 2014-08-12 | Antibacterial durable aqueous polyurethane printing ink |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104212225A true CN104212225A (en) | 2014-12-17 |
Family
ID=52094147
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410395398.3A Pending CN104212225A (en) | 2014-08-12 | 2014-08-12 | Antibacterial durable aqueous polyurethane printing ink |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104212225A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105907166A (en) * | 2016-05-06 | 2016-08-31 | 安徽雅美油墨有限公司 | Modified waterborne polyurethane dying ink for textile and preparation method thereof |
| CN110343423A (en) * | 2019-07-19 | 2019-10-18 | 聚隆(福建)包装有限公司 | Environmental-protection water-based ink, environment protection type high-strength damping corrugated case and preparation method thereof |
| CN112341585A (en) * | 2020-11-05 | 2021-02-09 | 青岛科技大学 | Redispersible waterborne polyurethane powder and preparation method thereof |
| CN114907719A (en) * | 2022-06-23 | 2022-08-16 | 武汉信息传播职业技术学院 | Waterborne polyurethane printing ink and printing method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5854320A (en) * | 1995-08-03 | 1998-12-29 | Sakura Color Products Corporation | Water base erasable ink compositions |
| WO2006097502A1 (en) * | 2005-03-18 | 2006-09-21 | Imaje S.A. | Ink composition for continuous deflected ink jet printing |
| CN101429359A (en) * | 2008-12-08 | 2009-05-13 | 山西鹰鲲科技有限公司 | Water-based plastic composite inner-printing ink |
| CN102002280A (en) * | 2009-09-01 | 2011-04-06 | 尚盟运动用品(惠阳)有限公司 | Low-temperature quick-drying type thermosetting ink |
| CN102108224A (en) * | 2010-12-30 | 2011-06-29 | 周震 | Washable water-soluble ink for marker pens for painting on surfaces of plastic toys |
| CN103666055A (en) * | 2013-11-25 | 2014-03-26 | 铜陵方正塑业科技有限公司 | Photo-cured and environment-friendly screen printing ink and preparation method thereof |
-
2014
- 2014-08-12 CN CN201410395398.3A patent/CN104212225A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5854320A (en) * | 1995-08-03 | 1998-12-29 | Sakura Color Products Corporation | Water base erasable ink compositions |
| WO2006097502A1 (en) * | 2005-03-18 | 2006-09-21 | Imaje S.A. | Ink composition for continuous deflected ink jet printing |
| CN101429359A (en) * | 2008-12-08 | 2009-05-13 | 山西鹰鲲科技有限公司 | Water-based plastic composite inner-printing ink |
| CN102002280A (en) * | 2009-09-01 | 2011-04-06 | 尚盟运动用品(惠阳)有限公司 | Low-temperature quick-drying type thermosetting ink |
| CN102108224A (en) * | 2010-12-30 | 2011-06-29 | 周震 | Washable water-soluble ink for marker pens for painting on surfaces of plastic toys |
| CN103666055A (en) * | 2013-11-25 | 2014-03-26 | 铜陵方正塑业科技有限公司 | Photo-cured and environment-friendly screen printing ink and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105907166A (en) * | 2016-05-06 | 2016-08-31 | 安徽雅美油墨有限公司 | Modified waterborne polyurethane dying ink for textile and preparation method thereof |
| CN110343423A (en) * | 2019-07-19 | 2019-10-18 | 聚隆(福建)包装有限公司 | Environmental-protection water-based ink, environment protection type high-strength damping corrugated case and preparation method thereof |
| CN112341585A (en) * | 2020-11-05 | 2021-02-09 | 青岛科技大学 | Redispersible waterborne polyurethane powder and preparation method thereof |
| CN114907719A (en) * | 2022-06-23 | 2022-08-16 | 武汉信息传播职业技术学院 | Waterborne polyurethane printing ink and printing method thereof |
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| C06 | Publication | ||
| PB01 | Publication | ||
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Application publication date: 20141217 |