CN104211333A - Heat insulation wall hollow brick made of urea formaldehyde foam plastic powder, and making method thereof - Google Patents
Heat insulation wall hollow brick made of urea formaldehyde foam plastic powder, and making method thereof Download PDFInfo
- Publication number
- CN104211333A CN104211333A CN201410402292.1A CN201410402292A CN104211333A CN 104211333 A CN104211333 A CN 104211333A CN 201410402292 A CN201410402292 A CN 201410402292A CN 104211333 A CN104211333 A CN 104211333A
- Authority
- CN
- China
- Prior art keywords
- powder
- urea
- parts
- clay
- hollow brick
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000843 powder Substances 0.000 title claims abstract description 45
- 239000011464 hollow brick Substances 0.000 title claims abstract description 26
- 229920003023 plastic Polymers 0.000 title claims abstract description 26
- 239000004033 plastic Substances 0.000 title claims abstract description 26
- ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 title claims abstract description 24
- 238000009413 insulation Methods 0.000 title claims abstract description 23
- 239000004639 urea-formaldehyde foam Substances 0.000 title abstract 3
- 238000000034 method Methods 0.000 title description 2
- 239000004927 clay Substances 0.000 claims abstract description 23
- 239000002699 waste material Substances 0.000 claims abstract description 17
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 14
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 claims abstract description 14
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000004202 carbamide Substances 0.000 claims abstract description 10
- 239000002994 raw material Substances 0.000 claims abstract description 8
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 7
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 7
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 7
- 239000004568 cement Substances 0.000 claims abstract description 7
- 239000011521 glass Substances 0.000 claims abstract description 7
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 7
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229920001807 Urea-formaldehyde Polymers 0.000 claims description 21
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- 238000002360 preparation method Methods 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- FKKAGFLIPSSCHT-UHFFFAOYSA-N 1-dodecoxydodecane;sulfuric acid Chemical compound OS(O)(=O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC FKKAGFLIPSSCHT-UHFFFAOYSA-N 0.000 claims description 6
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 6
- 239000004575 stone Substances 0.000 claims description 6
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 3
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 3
- 239000012615 aggregate Substances 0.000 claims description 3
- 239000004411 aluminium Substances 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 239000006185 dispersion Substances 0.000 claims description 3
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 claims description 3
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 3
- 239000010455 vermiculite Substances 0.000 claims description 3
- 229910052902 vermiculite Inorganic materials 0.000 claims description 3
- 235000019354 vermiculite Nutrition 0.000 claims description 3
- 239000011787 zinc oxide Substances 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 2
- 230000008929 regeneration Effects 0.000 claims description 2
- 238000011069 regeneration method Methods 0.000 claims description 2
- 239000011449 brick Substances 0.000 abstract 1
- SMVRDGHCVNAOIN-UHFFFAOYSA-L disodium;1-dodecoxydodecane;sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC SMVRDGHCVNAOIN-UHFFFAOYSA-L 0.000 abstract 1
- 239000003292 glue Substances 0.000 abstract 1
- 239000004566 building material Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Landscapes
- Porous Artificial Stone Or Porous Ceramic Products (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a heat insulation wall hollow brick made of urea formaldehyde foam plastic powder. The brick is made by using the following raw materials, by weight, 20-30 parts of the urea formaldehyde foam plastic powder, 20-30 parts of modified nanometer potter's clay, 10-15 parts of waste glass aggregate, 8-10 parts of cement, 8-10 parts of cobblestone, 10-12 parts of kaolin powder, 2-4 parts of titanium dioxide, 4-6 parts of polyvinyl alcohol glue powder, 2-4 parts of urea, 2-4 parts of calcium nitrate, 2-4 parts of sodium lauryl ether sulfate and 8-10 parts of water. The heat insulation wall hollow brick has the advantages of light weight, low price, good heat insulation and flame retardation effects, realization of higher indexes than national standards, reduction of the resource waste by using waste plastics as a raw material, reduction of the pollution to environment, and changing of wastes into valuables.
Description
Technical field
The present invention relates to building material field, specifically belong to insulation wall hollow brick that a kind of urea-formaldehyde foamed plastics powder makes and preparation method thereof.
Background technology
Traditional hollow brick is with clay, shale etc. for main raw material, makes, light weight, intensity is high, insulation, sound insulation and noise reduction performance be good through Feedstock treating, shaping, sintering.
Along with the development of construction industry, day by day increase the demand of hollow brick, manufacture the waste of conventional hollow brick and will waste the resources such as a large amount of clays, cost is high, contaminate environment when firing.The new raw material of research hollow brick, novel process become the developing direction of hollow brick manufacturer.
Summary of the invention
Insulation wall hollow brick that the object of the present invention is to provide a kind of urea-formaldehyde foamed plastics powder to make and preparation method thereof, aerating hollow brick of the present invention is low from heavy and light, price, insulation, flame resistance effect are good, indices is all higher than national standard.
Technical scheme of the present invention is as follows:
The insulation wall hollow brick that a kind of urea-formaldehyde foamed plastics powder is made, it is characterized in that, it is made up of the component raw material of following weight part: urea-formaldehyde foamed plastics powder 20-30, modified Nano potter's clay 20-30, waste glass aggregate 10-15, cement 8-10, stone 8-10, kaolin powder 10-12, titanium dioxide 2-4, polyvinyl alcohol rubber powder 4-6, urea 2-4, nitrocalcite 2-4, dodecyl ether sulfate 2-4, water 8-10
The preparation method of described modified Nano potter's clay: potter's clay being joined concentration is soak 20-30min in the sodium hydroxide solution of 10-15%, then pulling out in input and put into concentration is soak 1-2 hour in the magnesium chloride solution of 8-10%, pull potter's clay out, again with the urea of the rosin of potter's clay quality 1-2%, 1-2%, the zinc oxide of 4-5%, the molybdic oxide of 1-3%, the expanded vermiculite mixing of 2-3%, reheat 120-130 DEG C and stir 20-30 minute, add aluminium scrap powder again, high speed dispersion, oven dry grinds to form 400-450 order powder, obtains modified Nano potter's clay.
The insulation wall hollow brick that described use urea-formaldehyde foamed plastics powder is made, is characterized in that: described urea-formaldehyde foamed plastics powder is the powder that the waste and old urea-formaldehyde foamed plastics of regeneration is broken into that particle diameter is less than 0.4cm.
The preparation method of the insulation wall hollow brick that described use urea-formaldehyde foamed plastics powder is made, is characterized in that, comprise the following steps:
First by formula rate urea-formaldehyde foamed plastics powder, modified Nano potter's clay, waste glass aggregate, cement, stone, kaolin powder, titanium dioxide are dropped in whipping device and fully stirs 5-10 minute, then polyvinyl alcohol rubber powder, urea, nitrocalcite, dodecyl ether sulfate, water stirring 15-20 minute is being added successively, base, depanning, natural curing are to dry, again 700-800 DEG C of roasting, the obtained insulation wall hollow brick of cooling
.
The present invention compared with prior art tool has the following advantages:
Foam powder insulation wall hollow brick of the present invention aerating of the present invention hollow brick is low from heavy and light, price, insulation, flame resistance effect are good, indices is all higher than national standard, waste or used plastics is utilized to decrease the waste of resource as raw material, reduce the pollution of environment, achieve and turn waste into wealth.
Embodiment
The insulation wall hollow brick that a kind of urea-formaldehyde foamed plastics powder is made, it is made up of the component raw material of following weight (kg): urea-formaldehyde foamed plastics powder 28, modified Nano potter's clay 28, waste glass aggregate 14, cement 9, stone 10, kaolin powder 11, titanium dioxide 3, polyvinyl alcohol rubber powder 5, urea 3, nitrocalcite 3, dodecyl ether sulfate 2, water 10
Wherein, the preparation method of modified Nano potter's clay: potter's clay being joined concentration is soak 25min in the sodium hydroxide solution of 10-15%, then pulling and put into concentration out in input is soak 2 hours in the magnesium chloride solution of 9%, pull potter's clay out, again with the rosin of potter's clay quality 2%, 1% urea, 4% zinc oxide, the molybdic oxide of 2%, the expanded vermiculite mixing of 2.5%, reheat 125 DEG C to stir 25 minutes, add aluminium scrap powder again, high speed dispersion, oven dry grinds to form 400-450 order powder, obtains modified Nano potter's clay.
The preparation method of the insulation wall hollow brick made with urea-formaldehyde foamed plastics powder, comprises the following steps:
First by formula rate urea-formaldehyde foamed plastics powder, modified Nano potter's clay, waste glass aggregate, cement, stone, kaolin powder, titanium dioxide are dropped in whipping device and fully stirs 5-10 minute, then polyvinyl alcohol rubber powder, urea, nitrocalcite, dodecyl ether sulfate, water stirring 15-20 minute is being added successively, base, depanning, natural curing are to dry, again 700-800 DEG C of roasting, the obtained insulation wall hollow brick of cooling.
After testing, the unit weight of the hollow brick that obtains of the present embodiment, thermal conductivity, bearing capacity are respectively: 1230kg/m3,0.189w/ (m.K), 3.46Mpa.
Claims (3)
1. the insulation wall hollow brick made with urea-formaldehyde foamed plastics powder, it is characterized in that, it is made up of the component raw material of following weight part: urea-formaldehyde foamed plastics powder 20-30, modified Nano potter's clay 20-30, waste glass aggregate 10-15, cement 8-10, stone 8-10, kaolin powder 10-12, titanium dioxide 2-4, polyvinyl alcohol rubber powder 4-6, urea 2-4, nitrocalcite 2-4, dodecyl ether sulfate 2-4, water 8-10
The preparation method of described modified Nano potter's clay: potter's clay being joined concentration is soak 20-30min in the sodium hydroxide solution of 10-15%, then pulling out in input and put into concentration is soak 1-2 hour in the magnesium chloride solution of 8-10%, pull potter's clay out, again with the urea of the rosin of potter's clay quality 1-2%, 1-2%, the zinc oxide of 4-5%, the molybdic oxide of 1-3%, the expanded vermiculite mixing of 2-3%, reheat 120-130 DEG C and stir 20-30 minute, add aluminium scrap powder again, high speed dispersion, oven dry grinds to form 400-450 order powder, obtains modified Nano potter's clay.
2. the insulation wall hollow brick made of urea-formaldehyde foamed plastics powder according to claim 1, is characterized in that: described urea-formaldehyde foamed plastics powder is the powder that the waste and old urea-formaldehyde foamed plastics of regeneration is broken into particle diameter and is less than 0.4cm.
3. the preparation method of the insulation wall hollow brick made with urea-formaldehyde foamed plastics powder as claimed in claim 1, is characterized in that, comprise the following steps:
first by formula rate urea-formaldehyde foamed plastics powder, modified Nano potter's clay, waste glass aggregate, cement, stone, kaolin powder, titanium dioxide are dropped in whipping device and fully stirs 5-10 minute, then polyvinyl alcohol rubber powder, urea, nitrocalcite, dodecyl ether sulfate, water stirring 15-20 minute is being added successively, base, depanning, natural curing are to dry, again 700-800 DEG C of roasting, the obtained insulation wall hollow brick of cooling.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410402292.1A CN104211333B (en) | 2014-08-15 | 2014-08-15 | Insulation wall hollow brick that a kind of urea-formaldehyde foamed plastics powder is made and preparation method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410402292.1A CN104211333B (en) | 2014-08-15 | 2014-08-15 | Insulation wall hollow brick that a kind of urea-formaldehyde foamed plastics powder is made and preparation method thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
CN104211333A true CN104211333A (en) | 2014-12-17 |
CN104211333B CN104211333B (en) | 2015-11-18 |
Family
ID=52093299
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201410402292.1A Expired - Fee Related CN104211333B (en) | 2014-08-15 | 2014-08-15 | Insulation wall hollow brick that a kind of urea-formaldehyde foamed plastics powder is made and preparation method thereof |
Country Status (1)
Country | Link |
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CN (1) | CN104211333B (en) |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB575834A (en) * | 1944-03-31 | 1946-03-07 | Benedetto Mazzocchi | Improvements in or relating to setting compositions |
CN1057659A (en) * | 1990-06-23 | 1992-01-08 | 龙昂 | Composite heat insulatant thermal insulation material |
CN1421486A (en) * | 2001-11-29 | 2003-06-04 | 李建军 | Heat insulating polystyrene foam grain brick |
CN103539398A (en) * | 2012-07-16 | 2014-01-29 | 湖南工程学院 | Polystyrene foam aggregate concrete insulation building block |
-
2014
- 2014-08-15 CN CN201410402292.1A patent/CN104211333B/en not_active Expired - Fee Related
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB575834A (en) * | 1944-03-31 | 1946-03-07 | Benedetto Mazzocchi | Improvements in or relating to setting compositions |
CN1057659A (en) * | 1990-06-23 | 1992-01-08 | 龙昂 | Composite heat insulatant thermal insulation material |
CN1421486A (en) * | 2001-11-29 | 2003-06-04 | 李建军 | Heat insulating polystyrene foam grain brick |
CN103539398A (en) * | 2012-07-16 | 2014-01-29 | 湖南工程学院 | Polystyrene foam aggregate concrete insulation building block |
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Publication number | Publication date |
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CN104211333B (en) | 2015-11-18 |
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C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
CF01 | Termination of patent right due to non-payment of annual fee | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20151118 Termination date: 20160815 |