CN104209092B - A kind of factory air adsorbent and preparation method thereof - Google Patents
A kind of factory air adsorbent and preparation method thereof Download PDFInfo
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Abstract
本发明公开了一种工厂用空气吸附剂,包括:活性炭:40‑60份;高锰酸钾:10‑15份;硅胶:5‑10份;消石灰:5‑10份;改性硅藻土:5‑10份。本发明同时公开了起制备方法。本发明所述方法制备得到的吸附剂对氮氧化物、硫氧化物、氨等有害气体的吸附能力很高,且具有很好的耐水性,且在使用过程中,没有粉尘产生,操作方便,非常适于在工业上应用。The invention discloses an air adsorbent for factories, comprising: activated carbon: 40-60 parts; potassium permanganate: 10-15 parts; silica gel: 5-10 parts; slaked lime: 5-10 parts; modified diatomite : 5‑10 servings. The invention also discloses a preparation method. The adsorbent prepared by the method of the present invention has a high adsorption capacity for nitrogen oxides, sulfur oxides, ammonia and other harmful gases, and has good water resistance, and in the process of use, no dust is generated, and the operation is convenient. Very suitable for industrial applications.
Description
技术领域 technical field
本发明涉及一种空气吸附剂及其制备方法,特别是涉及一种工厂用空气吸附剂的制备方法。 The invention relates to an air adsorbent and a preparation method thereof, in particular to a preparation method of an air adsorbent for a factory.
背景技术 Background technique
如何处理工厂生产过程中产生的氮氧化物、硫氧化物、氨等有害气体,一直是困扰许多国家的环保问题,如果处理不及时或者不合理,会造成严重饿空气污染,而目前的处理方法,其处理效果并不是很理想,最终排放的气体无法稳定地达到国家规定的排放标准,因此一直未得到推广应用。 How to deal with harmful gases such as nitrogen oxides, sulfur oxides, and ammonia produced in the production process of factories has always been an environmental protection issue that plagues many countries. If the treatment is not timely or reasonable, it will cause serious air pollution. However, the current treatment methods , its treatment effect is not very ideal, and the final discharged gas cannot stably meet the emission standards stipulated by the state, so it has not been popularized and applied.
发明内容 Contents of the invention
为了克服现有技术的不足,本发明的目的在于提供一种耐水性好、吸附效果优异的工厂用空气吸附剂及其制备方法。 In order to overcome the deficiencies of the prior art, the purpose of the present invention is to provide a kind of factory air adsorbent with good water resistance and excellent adsorption effect and its preparation method.
本发明是通过以下技术方案来实现的: The present invention is achieved through the following technical solutions:
一种工厂用空气吸附剂,其特征在于,包括以下组分且各组分的重量份数分别为: A kind of factory air adsorbent is characterized in that, comprises following component and the parts by weight of each component are respectively:
活性炭:40-60份; Activated carbon: 40-60 parts;
高锰酸钾:10-15份; Potassium permanganate: 10-15 parts;
硅胶:5-10份; Silica gel: 5-10 parts;
消石灰:5-10份; Slaked lime: 5-10 parts;
改性硅藻土:5-10份。 Modified diatomaceous earth: 5-10 parts.
进一步,所述的工厂用空气吸附剂,包括以下组分且各组分的重量份数分别为: Further, the air adsorbent for factory includes the following components and the parts by weight of each component are respectively:
活性炭:50份; Activated carbon: 50 parts;
高锰酸钾:10份; Potassium permanganate: 10 parts;
硅胶: 10份; Silica gel: 10 parts;
消石灰: 10份; Slaked lime: 10 parts;
改性硅藻土:10份。 Modified diatomaceous earth: 10 parts.
且所述的改性硅藻土包括以下组分,且各组分的重量份数分别为: And the modified diatomite includes the following components, and the parts by weight of each component are respectively:
硅藻土:70-90份; Diatomite: 70-90 parts;
偶联剂:1-3份; Coupling agent: 1-3 parts;
苯甲酸钠:1-3份。 Sodium benzoate: 1-3 parts.
而所述的内偶联剂则为硅烷偶联剂KH550。 The internal coupling agent is the silane coupling agent KH550.
此外,所述的改性硅藻土的制备方法为:首先将硅藻土于煅烧炉中在500-550℃的温度条件下煅烧5-6h,然后取出、冷却、经酸洗、过滤、洗涤后按照重量分数比加入偶联剂和苯甲酸钠,经研磨过150目筛、干燥后得到粉末状的改性硅藻土。 In addition, the preparation method of the modified diatomite is as follows: first, calcinate the diatomite in a calciner at a temperature of 500-550°C for 5-6 hours, then take it out, cool it, pickle it, filter it, and wash it. Finally, a coupling agent and sodium benzoate are added according to the weight fraction ratio, and powdery modified diatomite is obtained after being ground through a 150-mesh sieve and dried.
而上述的工厂用空气吸附剂的制备方法,其特征在于,包括以下步骤:将活性炭:40-60份;高锰酸钾:10-15份;硅胶:5-10份;消石灰:5-10份;改性硅藻土:5-10份混合后,加入混合后原料总重量50-80%的水后混炼成型后干燥得到目标产物。 And the preparation method of above-mentioned factory air adsorbent is characterized in that, comprises the following steps: with active carbon: 40-60 parts; Potassium permanganate: 10-15 parts; Silica gel: 5-10 parts; Slaked lime: 5-10 parts Parts; Modified diatomaceous earth: 5-10 parts after mixing, add 50-80% of the total weight of the mixed raw materials in water, knead and shape, then dry to obtain the target product.
其中,干燥步骤中的干燥温度为100-120℃。 Wherein, the drying temperature in the drying step is 100-120°C.
本发明的有益效果是:本发明所述方法制备得到的吸附剂对氮氧化物、硫氧化物、氨等有害气体的吸附能力很高,且具有很好的耐水性,且在使用过程中,没有粉尘产生,操作方便,非常适于在工业上应用。 The beneficial effects of the present invention are: the adsorbent prepared by the method of the present invention has a high adsorption capacity for harmful gases such as nitrogen oxides, sulfur oxides, and ammonia, and has good water resistance, and during use, No dust generation, easy operation, very suitable for industrial applications.
具体实施方式 detailed description
下面将结合具体实施例,详细说明本发明的具体实施方式: The specific implementation manner of the present invention will be described in detail below in conjunction with specific embodiment:
实施例Example 11 ::
将活性炭:40份;高锰酸钾:10份;硅胶: 10份;消石灰: 10份;改性硅藻土:5份混合后,加入混合后原料总重量50%的水后混炼成型后,在100℃的温度条件下干燥得到工厂用空气吸附剂。在本实施例中,所述的改性硅藻土包括硅藻土:70份;硅烷偶联剂KH55:1份;苯甲酸钠:3份,且所述的改性硅藻土的制备方法为:首先将硅藻土于煅烧炉中在500℃的温度条件下煅烧6h,然后取出、冷却、经酸洗、过滤、洗涤后按照重量分数比加入偶联剂和苯甲酸钠,经研磨过150目筛、干燥后得到粉末状的改性硅藻土。 Activated carbon: 40 parts; potassium permanganate: 10 parts; silica gel: 10 parts; slaked lime: 10 parts; , dried at a temperature of 100°C to obtain an air adsorbent for factory use. In this example, the modified diatomite includes diatomite: 70 parts; silane coupling agent KH55: 1 part; sodium benzoate: 3 parts, and the preparation method of the modified diatomite is as follows: : First, diatomite is calcined in a calciner at a temperature of 500°C for 6 hours, then taken out, cooled, pickled, filtered, washed, and then added with a coupling agent and sodium benzoate according to the weight fraction ratio, and ground through a 150-mesh Sieve and dry to obtain powdery modified diatomite.
实施例Example 22 ::
将活性炭:60份;高锰酸钾:15份;硅胶:5份;消石灰:5份;改性硅藻土:10份混合后,加入混合后原料总重量80%的水后混炼成型后,在120℃的温度条件下干燥得到工厂用空气吸附剂。在本实施例中,所述的改性硅藻土包括硅藻土:90份;硅烷偶联剂KH55:3份;苯甲酸钠:1份,且所述的改性硅藻土的制备方法为:首先将硅藻土于煅烧炉中在550℃的温度条件下煅烧5h,然后取出、冷却、经酸洗、过滤、洗涤后按照重量分数比加入偶联剂和苯甲酸钠,经研磨过150目筛、干燥后得到粉末状的改性硅藻土。 Activated carbon: 60 parts; potassium permanganate: 15 parts; silica gel: 5 parts; slaked lime: 5 parts; , and dried at a temperature of 120° C. to obtain an air adsorbent for factory use. In this example, the modified diatomite includes diatomite: 90 parts; silane coupling agent KH55: 3 parts; sodium benzoate: 1 part, and the preparation method of the modified diatomite is as follows: : First, diatomite is calcined in a calciner at a temperature of 550°C for 5 hours, then taken out, cooled, pickled, filtered, washed, and then added coupling agent and sodium benzoate according to the weight fraction ratio, and ground through 150 mesh Sieve and dry to obtain powdery modified diatomite.
实施例Example 33 ::
将活性炭:50份;高锰酸钾:12份;硅胶:8份;消石灰:8份;改性硅藻土:8份混合后,加入混合后原料总重量70%的水后混炼成型后,在110℃的温度条件下干燥得到工厂用空气吸附剂。在本实施例中,所述的改性硅藻土包括硅藻土:80份;硅烷偶联剂KH55:2份;苯甲酸钠:2份,且所述的改性硅藻土的制备方法为:首先将硅藻土于煅烧炉中在530℃的温度条件下煅烧5h,然后取出、冷却、经酸洗、过滤、洗涤后按照重量分数比加入偶联剂和苯甲酸钠,经研磨过150目筛、干燥后得到粉末状的改性硅藻土。 Activated carbon: 50 parts; potassium permanganate: 12 parts; silica gel: 8 parts; slaked lime: 8 parts; , and dried at a temperature of 110° C. to obtain an air adsorbent for factory use. In this embodiment, the modified diatomite includes 80 parts of diatomite; silane coupling agent KH55: 2 parts; sodium benzoate: 2 parts, and the preparation method of the modified diatomite is as follows: : First, diatomite is calcined in a calciner at a temperature of 530°C for 5 hours, then taken out, cooled, pickled, filtered, washed, and then added coupling agent and sodium benzoate according to the weight fraction ratio, and ground through 150 mesh Sieve and dry to obtain powdery modified diatomite.
实施例Example 44
将活性炭:50份;高锰酸钾:10份;硅胶: 10份;消石灰: 10份;改性硅藻土:10份混合后,加入混合后原料总重量80%的水后混炼成型后,在110℃的温度条件下干燥得到工厂用空气吸附剂。在本实施例中,所述的改性硅藻土包括硅藻土:80份;硅烷偶联剂KH55:2份;苯甲酸钠:2份,且所述的改性硅藻土的制备方法为:首先将硅藻土于煅烧炉中在520℃的温度条件下煅烧6h,然后取出、冷却、经酸洗、过滤、洗涤后按照重量分数比加入偶联剂和苯甲酸钠,经研磨过150目筛、干燥后得到粉末状的改性硅藻土。 Activated carbon: 50 parts; potassium permanganate: 10 parts; silica gel: 10 parts; slaked lime: 10 parts; , and dried at a temperature of 110° C. to obtain an air adsorbent for factory use. In this embodiment, the modified diatomite includes 80 parts of diatomite; silane coupling agent KH55: 2 parts; sodium benzoate: 2 parts, and the preparation method of the modified diatomite is as follows: : First, diatomite is calcined in a calciner at a temperature of 520°C for 6 hours, then taken out, cooled, pickled, filtered, washed, and then added coupling agent and sodium benzoate according to the weight fraction ratio, and ground through 150 mesh Sieve and dry to obtain powdery modified diatomite.
根据上述实施例1-4所述的方法制备得到的工厂用空气吸附剂的吸附性能如表1所示: The adsorption performance of the factory air adsorbent prepared according to the method described in above-mentioned embodiment 1-4 is as shown in table 1:
表1:工厂用空气吸附剂的吸附性能: Table 1: Adsorption performance of air adsorbents used in factories:
由表1可知:本发明所述的方法制备得到的工厂用空气吸附剂的吸附性能非常好,吸附效率高,且在使用过程中,没有粉尘产生,操作方便,非常适于在工业上应用。 It can be seen from Table 1 that the factory air adsorbent prepared by the method of the present invention has very good adsorption performance, high adsorption efficiency, no dust generation during use, easy operation, and is very suitable for industrial application.
以上已以较佳实施例公开了本发明,然其并非用以限制本发明,凡采用等同替换或者等效变换方式所获得的技术方案,均落在本发明的保护范围之内。 The above has disclosed the present invention with preferred embodiments, but it is not intended to limit the present invention, and all technical solutions obtained by adopting equivalent replacement or equivalent transformation methods fall within the protection scope of the present invention.
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