CN104164113B - A kind of pottery unsaturated polyester coating - Google Patents
A kind of pottery unsaturated polyester coating Download PDFInfo
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- CN104164113B CN104164113B CN201410455176.6A CN201410455176A CN104164113B CN 104164113 B CN104164113 B CN 104164113B CN 201410455176 A CN201410455176 A CN 201410455176A CN 104164113 B CN104164113 B CN 104164113B
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Abstract
Disclosure one pottery unsaturated polyester coating, its raw material is: epoxy acrylate, dipentaerythritol acrylate, Aska-Rid., benzoin dimethylether, water, M-phthalic acid, coloring pigment, NVP, butyl maleate, triisocyanate, cross-linking agent, maleic anhydride, Borax, adipic acid and clay; Product glossiness 90%-110%, hot strength 3-5MPa; Surface drying time 20-30s, does solid work 15-25min, without foaming, obscission after immersion 10-30d in water; Saturated calcium hydroxide soaks 5-15d is non-foaming, elephant skin; Product rub resistance and hardness are high, it is possible to current material is replaced in the widespread production not division of history into periods.
Description
Technical field
The application belongs to paint field, particularly relates to a kind of pottery unsaturated polyester coating.
Background technology
The domestic ceramics yield of domestic product accounts for global about 70%, and display art ceramic yield is the 65% of the whole world, and architectural pottery yield also accounts for Gross World Product half of the country. China industry occupies very important status in world's building material industry. And popularizing along with humanity concept, and the composition of novel harmonious society, design a kind of pottery unsaturated polyester coating wrinkle resistant, not tacky, that dryness is good and be very important.
Summary of the invention
Solve the technical problem that:
The application is for above-mentioned technical problem, it is provided that a kind of pottery unsaturated polyester coating, solve existing pottery unsaturated polyester coating crease easily, drying time length, chemical resistance and the technical problem such as water-resistance is poor.
Technical scheme:
A kind of pottery unsaturated polyester coating, the raw materials by weight portion proportioning of described pottery unsaturated polyester coating is as follows: epoxy acrylate 100 parts; Dipentaerythritol acrylate 30-40 part; Aska-Rid. 15-25 part; Benzoin dimethylether 35-45 part; Water 80-100 part; M-phthalic acid 10-20 part; Coloring pigment 5-15 part; NVP 20-30 part; Butyl maleate 25-35 part; Triisocyanate 25-45 part; Cross-linking agent 1-10 part; Maleic anhydride 15-35 part; Borax 10-30 part; Adipic acid 5-25 part; Clay 20-40 part.
As a preferred technical solution of the present invention: the raw materials by weight portion proportioning of described pottery unsaturated polyester coating is as follows: epoxy acrylate 100 parts; Dipentaerythritol acrylate 35 parts; Aska-Rid. 20 parts; Benzoin dimethylether 40 parts; 90 parts of water; M-phthalic acid 15 parts; Coloring pigment 10 parts; NVP 25 parts; Butyl maleate 30 parts; Triisocyanate 35 parts; Cross-linking agent 5 parts; Maleic anhydride 25 parts; Borax 20 parts; Adipic acid 15 parts; Clay 30 parts.
As a preferred technical solution of the present invention: described coloring pigment adopts iron oxide red or phthalocyanine blue.
As a preferred technical solution of the present invention: described cross-linking agent adopts hexamethoxymethyl melamine.
Beneficial effect:
A kind of pottery unsaturated polyester coating above technical scheme of employing of the present invention compared with prior art, has following technical effect that 1, product glossiness 90%-110%, hot strength 3-5MPa; 2, surface drying time 20-30s, does solid work 15-25min, without foaming, obscission after immersion 10-30d in water; 3, in saturated calcium hydroxide, soak that 5-15d is non-foaming, elephant skin; 4, product rub resistance and hardness are high, it is possible to current material is replaced in the widespread production not division of history into periods.
Detailed description of the invention
Embodiment 1:
A kind of pottery unsaturated polyester coating, its raw materials by weight portion proportioning is as follows: epoxy acrylate 100 parts; Dipentaerythritol acrylate 30 parts; Aska-Rid. 15 parts; Benzoin dimethylether 35 parts; 80 parts of water; M-phthalic acid 10 parts; Phthalocyanine blue 5 parts; NVP 20 parts; Butyl maleate 25 parts; Triisocyanate 25 parts; Hexamethoxymethyl melamine 1 part; Maleic anhydride 15 parts; Borax 10 parts; Adipic acid 5 parts; Clay 20 parts.
By above-mentioned raw materials in a kettle., limit logical nitrogen limit stirring, after mix homogeneously, it is warming up to 180 DEG C of reaction 1h, is continuously heating to 210 DEG C, after reaction 1h, namely obtain product.
Product glossiness 90%, hot strength 3MPa; Surface drying time 30s, does solid work 25min, without foaming, obscission after immersion 10d in water; Saturated calcium hydroxide soaks 5d is non-foaming, elephant skin.
Embodiment 2:
A kind of pottery unsaturated polyester coating, its raw materials by weight portion proportioning is as follows: epoxy acrylate 100 parts; Dipentaerythritol acrylate 40 parts; Aska-Rid. 25 parts; Benzoin dimethylether 45 parts; 100 parts of water; M-phthalic acid 20 parts; Phthalocyanine blue 15 parts; NVP 30 parts; Butyl maleate 35 parts; Triisocyanate 45 parts; Hexamethoxymethyl melamine 10 parts; Maleic anhydride 35 parts; Borax 30 parts; Adipic acid 25 parts; Clay 40 parts.
By above-mentioned raw materials in a kettle., limit logical nitrogen limit stirring, after mix homogeneously, it is warming up to 180 DEG C of reaction 1h, is continuously heating to 230 DEG C, after reaction 1h, namely obtain product.
Product glossiness 100%, hot strength 4MPa; Surface drying time 25s, does solid work 20min, without foaming, obscission after immersion 20d in water; Saturated calcium hydroxide soaks 10d is non-foaming, elephant skin.
Embodiment 3:
A kind of pottery unsaturated polyester coating, its raw materials by weight portion proportioning is as follows: epoxy acrylate 100 parts; Dipentaerythritol acrylate 35 parts; Aska-Rid. 20 parts; Benzoin dimethylether 40 parts; 90 parts of water; M-phthalic acid 15 parts; Iron oxide red 10 parts; NVP 25 parts; Butyl maleate 30 parts; Triisocyanate 35 parts; Hexamethoxymethyl melamine 5 parts; Maleic anhydride 25 parts; Borax 20 parts; Adipic acid 15 parts; Clay 30 parts.
By above-mentioned raw materials in a kettle., limit logical nitrogen limit stirring, after mix homogeneously, it is warming up to 180 DEG C of reaction 1h, is continuously heating to 220 DEG C, after reaction 1h, namely obtain product.
Product glossiness 110%, hot strength 5MPa; Surface drying time 20s, does solid work 15min, without foaming, obscission after immersion 30d in water; Saturated calcium hydroxide soaks 15d is non-foaming, elephant skin.
Compositions all components in above example all can be commercially available.
Above-described embodiment is only intended to present disclosure is illustrated, rather than restriction, and the therefore any change in the implication suitable with claims of the present invention and scope, all it is believed that be included in the scope of claims.
Claims (1)
1. a pottery unsaturated polyester coating, it is characterised in that the raw materials by weight portion proportioning of described pottery unsaturated polyester coating is as follows: epoxy acrylate 100 parts; Dipentaerythritol acrylate 35 parts; Aska-Rid. 20 parts; Benzoin dimethylether 40 parts; 90 parts of water; M-phthalic acid 15 parts; Coloring pigment 10 parts; NVP 25 parts; Butyl maleate 30 parts; Triisocyanate 35 parts; Cross-linking agent 5 parts; Maleic anhydride 25 parts; Borax 20 parts; Adipic acid 15 parts; Clay 30 parts;
Described coloring pigment adopts iron oxide red or phthalocyanine blue;
Described cross-linking agent adopts hexamethoxymethyl melamine.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410455176.6A CN104164113B (en) | 2014-09-09 | 2014-09-09 | A kind of pottery unsaturated polyester coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410455176.6A CN104164113B (en) | 2014-09-09 | 2014-09-09 | A kind of pottery unsaturated polyester coating |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104164113A CN104164113A (en) | 2014-11-26 |
| CN104164113B true CN104164113B (en) | 2016-06-15 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201410455176.6A Active CN104164113B (en) | 2014-09-09 | 2014-09-09 | A kind of pottery unsaturated polyester coating |
Country Status (1)
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| CN (1) | CN104164113B (en) |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1028433C (en) * | 1989-02-01 | 1995-05-17 | 北京大学 | Photo-curing composition and preparation method and application thereof |
| CA2141516A1 (en) * | 1994-06-13 | 1995-12-14 | John D. Blizzard | Radiation-curable oligomer-based coating composition |
| US20080262144A1 (en) * | 2004-10-19 | 2008-10-23 | Degussa Gmbh | Aqueous, Radiation-Hardenable Resins, Method for the Production Thereof, and Use of the Same |
| EP1845141B1 (en) * | 2006-03-13 | 2009-09-09 | Mitsubishi Gas Chemical Company, Inc. | Antifogging coating composition |
| JP2008189943A (en) * | 2008-05-12 | 2008-08-21 | Chugoku Marine Paints Ltd | Photocurable coating composition capable of embossed design finish coating, base material coated with embossed design finish, and coating method for embossed design finish on substrate surface |
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| CN104164113A (en) | 2014-11-26 |
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Effective date of registration: 20240115 Address after: 273400 Tanyi Town Industrial Park, Feixian County, Linyi City, Shandong Province Patentee after: Shandong Litong Chemical Co.,Ltd. Address before: 215101 room 4721, Tianlong building, 378 Pearl River Road, Wuzhong District, Suzhou, Jiangsu Patentee before: SUZHOU SHENGPULA NEW MATERIAL TECHNOLOGY Co.,Ltd. |