CN104152029B - A kind of high-temperature resistant nano hole thermal insulation coatings and preparation method - Google Patents
A kind of high-temperature resistant nano hole thermal insulation coatings and preparation method Download PDFInfo
- Publication number
- CN104152029B CN104152029B CN201410434538.3A CN201410434538A CN104152029B CN 104152029 B CN104152029 B CN 104152029B CN 201410434538 A CN201410434538 A CN 201410434538A CN 104152029 B CN104152029 B CN 104152029B
- Authority
- CN
- China
- Prior art keywords
- thermal insulation
- temperature resistant
- insulation coatings
- rotating speed
- powder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000000576 coating method Methods 0.000 title claims abstract description 76
- 238000009413 insulation Methods 0.000 title claims abstract description 44
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- 239000000835 fiber Substances 0.000 claims abstract description 46
- 239000000843 powder Substances 0.000 claims abstract description 40
- 239000011248 coating agent Substances 0.000 claims abstract description 39
- 239000002270 dispersing agent Substances 0.000 claims abstract description 28
- 239000013530 defoamer Substances 0.000 claims abstract description 19
- 239000004964 aerogel Substances 0.000 claims abstract description 13
- 239000002904 solvent Substances 0.000 claims abstract description 12
- 239000000945 filler Substances 0.000 claims abstract description 10
- 239000007822 coupling agent Substances 0.000 claims abstract description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 53
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 53
- 238000003756 stirring Methods 0.000 claims description 39
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 22
- 239000013078 crystal Substances 0.000 claims description 21
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical group [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 16
- 229910000077 silane Inorganic materials 0.000 claims description 16
- 239000008367 deionised water Substances 0.000 claims description 14
- 229910021641 deionized water Inorganic materials 0.000 claims description 14
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 11
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 claims description 11
- 229910052863 mullite Inorganic materials 0.000 claims description 11
- 229910052710 silicon Inorganic materials 0.000 claims description 11
- 239000010703 silicon Substances 0.000 claims description 11
- 239000000839 emulsion Substances 0.000 claims description 9
- 229920005749 polyurethane resin Polymers 0.000 claims description 8
- 239000004925 Acrylic resin Substances 0.000 claims description 6
- 229920000178 Acrylic resin Polymers 0.000 claims description 6
- 239000002202 Polyethylene glycol Substances 0.000 claims description 6
- 239000003638 chemical reducing agent Substances 0.000 claims description 6
- 239000002105 nanoparticle Substances 0.000 claims description 6
- 229920001223 polyethylene glycol Polymers 0.000 claims description 6
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 5
- 229910001928 zirconium oxide Inorganic materials 0.000 claims description 5
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 3
- 230000002301 combined effect Effects 0.000 claims description 3
- 229920000058 polyacrylate Polymers 0.000 claims description 3
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims description 3
- 235000019982 sodium hexametaphosphate Nutrition 0.000 claims description 3
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 3
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims description 3
- 239000004965 Silica aerogel Substances 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
- 239000011863 silicon-based powder Substances 0.000 claims description 2
- 229920002050 silicone resin Polymers 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 10
- 239000011159 matrix material Substances 0.000 abstract description 5
- 238000000034 method Methods 0.000 abstract description 3
- 230000008901 benefit Effects 0.000 abstract description 2
- 239000011148 porous material Substances 0.000 description 21
- 229910002012 Aerosil® Inorganic materials 0.000 description 18
- 239000000377 silicon dioxide Substances 0.000 description 13
- 229910052681 coesite Inorganic materials 0.000 description 12
- 229910052906 cristobalite Inorganic materials 0.000 description 12
- 239000002994 raw material Substances 0.000 description 12
- 229910052682 stishovite Inorganic materials 0.000 description 12
- 229910052905 tridymite Inorganic materials 0.000 description 12
- 229910052814 silicon oxide Inorganic materials 0.000 description 11
- 230000000694 effects Effects 0.000 description 7
- 239000002518 antifoaming agent Substances 0.000 description 6
- 229910052593 corundum Inorganic materials 0.000 description 6
- 239000005543 nano-size silicon particle Substances 0.000 description 6
- 150000003376 silicon Polymers 0.000 description 6
- 229910001845 yogo sapphire Inorganic materials 0.000 description 6
- 229920001909 styrene-acrylic polymer Polymers 0.000 description 5
- 238000005245 sintering Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 2
- 239000011256 inorganic filler Substances 0.000 description 2
- 229910003475 inorganic filler Inorganic materials 0.000 description 2
- 229910010272 inorganic material Inorganic materials 0.000 description 2
- 239000011147 inorganic material Substances 0.000 description 2
- 239000002086 nanomaterial Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000005303 weighing Methods 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 239000000378 calcium silicate Substances 0.000 description 1
- 229910052918 calcium silicate Inorganic materials 0.000 description 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 229910052878 cordierite Inorganic materials 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000007943 implant Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000012774 insulation material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000000693 micelle Substances 0.000 description 1
- 239000004005 microsphere Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000011858 nanopowder Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000010451 perlite Substances 0.000 description 1
- 235000019362 perlite Nutrition 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Chemical compound [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
- MTPVUVINMAGMJL-UHFFFAOYSA-N trimethyl(1,1,2,2,2-pentafluoroethyl)silane Chemical compound C[Si](C)(C)C(F)(F)C(F)(F)F MTPVUVINMAGMJL-UHFFFAOYSA-N 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
- Thermal Insulation (AREA)
Abstract
The invention belongs to high-temperature energy-saving coating material field, be specifically related to a kind of high-temperature resistant nano hole thermal insulation coatings and preparation method。Described coating is made up of the component of following weight portion: aerogel powder 5-15 part, filler 10-20 part, and length is chopped fiber 5-10 part of 1-3mm, film forming matter 30-40 part, solvent 10-50 part；It is possible to additionally incorporate the defoamer of the dispersant of 0.1-0.2 part, the coupling agent of 0.15-0.3 part and 0.05-0.15 part。High-temperature resistant nano hole of the present invention thermal insulation coatings provides the benefit that: 1) lower thermal conductivity；2) high temperature resistant；3) under high temperature, (more than 600 DEG C) are strong with matrix bonding force；4) technique is simple。
Description
Technical field
The invention belongs to high-temperature energy-saving coating material field, be specifically related to a kind of high-temperature resistant nano hole thermal insulation coatings and preparation method。
Technical background
World today's mineral resources energy worsening shortages, the development of world industry in serious threat。Industrial Stoves power consumption accounts for the 25%～40% of total energy consumption, mainly due to heat by furnace lining and furnace outer wall deterioration, therefore, develop the high temperature high efficiency energy-saving and heat-insulating paint being applied in Industrial Stoves inwall, thus it is significant to improving resource utilization by furnace lining and furnace outer wall deterioration to reduce heat。
Nano-pore heat-barrier material refers to the bore dia porous material at nano-scale of material internal。The mechanism of heat insulation of nano-pore heat-barrier material is mainly reflected in the following aspects。First, the contact area between nano-particle is less, and therefore, its thermal conductivity is also little compared with other heat-barrier materials；Secondly, according to molecular motion and collision theory, gas heat-transfer mutually collides mainly by the high-velocity molecular of high temperature side and the low speed molecule of low temperature side and realizes, due to main component N in air2And O2Mean free path be about 70nm, so when the aperture of material internal is less than this critical dimension, the convection heat transfer' heat-transfer by convection of gas molecule is suppressed, thus obtaining ratio without convected air lower thermal conductivity。At present, high temperature resistant heat insulation coating on domestic and international high temperature kiln is of a great variety, but mostly unsatisfactory in technical performance and result of use, is primarily due to the pore structure within prepared thermal insulation coatings and is in macro-scale, thermal conductivity is higher, and effect of heat insulation is not ideal enough；Adopting foam plastics on the other hand is that raw material uses temperature not high, is mainly used in hot water pipeline and building trade。Patent of invention " a kind of nano ceramic high-temperature-resistant thermal-insulation coating and its preparation method and application " (number of patent application: 200610113748.8) is with ceramic fine bead, perlite, glass microballoon etc. for primary raw material, the internal aperture of these raw materials is all in macro-scale, belong to traditional insulation materials, nano material needs to form through stirring, drying and dehydrating and grinding, and technics comparing is complicated。Patent of invention " a kind of nano thermal insulation coating " (number of patent application: 201210554146.1) is main with nano-aluminum phosphate, nano manganese oxide, nano zircite, nano titanium carbide, nano-pearl rock, nanometer calcium silicate powder for raw material, the coating of preparation can be used only in room temperature or middle low temperature environment, is used in that these raw materials of hot environment are easily sintered, crystal is grown up and lost the character of nano material。Patent of invention " a kind of high temperature resistant heat insulation coating " (number of patent application: 201310245274.2) selects heat stable resin, hollow microsphere inorganic filler, needle-like cordierite powder, graphite, molybdenum bisuphide are raw material, the aperture of this insulating moulding coating is bigger, the thermal conductivity of graphite raw material is higher and oxidizable under high temperature, therefore uses temperature not high。If thermal insulation coatings can be realized at high temperature can keep the character of nano-pore structure, to improving the energy-conservation significant of Industrial Stoves。
Summary of the invention
It is an object of the invention to provide a kind of high-temperature resistant nano hole thermal insulation coatings and preparation method。
The present invention seeks to be achieved through the following technical solutions:
A kind of high-temperature resistant nano hole thermal insulation coatings, described coating is made up of the component of following weight portion: aerogel powder 5-15 part, filler 10-20 part, length is chopped fiber 5-10 part of 1-3mm, film forming matter 30-40 part, solvent 10-50 part, it is possible to additionally incorporate the defoamer of the dispersant of 0.1-0.2 part, the coupling agent of 0.15-0.3 part and 0.05-0.15 part。
Described filler is one or more arbitrary proportions mixing in nano oxidized silica flour, nano alumina powder, nano oxidized zirconium powder。
Described aerogel powder is the silica aerogel powder with nanoaperture structure that Zhong Shankebang chemical materials Technology Co., Ltd. produces, and powder diameter is sized to 1-100 micron。
Described chopped fiber is one or more in zirconia crystal fiber, alpha-alumina crystals fiber, mullite crystal fiber and high aluminum fiber。
Described film forming matter is one or more arbitrary proportions mixing in silicone resin emulsion, polyurethane resin, acrylic resin, Ludox and styrene-acrylic emulsion。
Described solvent is one or both in ethanol or deionized water；Described dispersant is the one in the polyethylene glycol type water reducer CAMTMENTFS10 that sodium tripolyphosphate, sodium hexameta phosphate, ammonium polyacrylate and BASF Aktiengesellschaft produce；Described coupling agent is silane coupler；Described defoamer is the one in organic silicon defoamer or polyether-modified silicon defoaming agent。
Raw material used in the present invention can be commercially available, and specification meets country or industry standard。
The preparation method of above-mentioned high-temperature resistant nano hole thermal insulation coatings, its preparation method is: weigh solvent according to proportioning and dispersant is put in homogenizer and stirred 5-10 minute with the rotating speed of 500-1000rpm, make dispersant be completely dissolved in solvent；Add nano-sized filler powder by proportioning to stir with the rotating speed of 5000-8000rpm, high rotating speed and dispersant combined effect are fully opened soft-agglomerated for nanometer powder part, it is evenly distributed in solvent, the aerosil adding respective amount after stirring 10-30 minute is stirred for 10-30 minute with identical rotating speed, can make on the one hand that aerogel powder is fully dispersed to be opened, on the other hand nanometer powder and aerogel powder be mixed uniformly；It is subsequently adding film forming matter to stir 10-30 minute with the rotating speed of 1000-2000rpm, if film forming matter is easily caused emulsion breaking containing emulsion rotating speed is too high and loses due effect；Finally it is sequentially added into chopped fiber, defoamer and coupling agent by proportioning to stir 30-60 minute with the rotating speed of 1000-2000rpm, namely obtains high-temperature resistant nano hole thermal insulation coatings。
Chopped fiber plays skeleton function in the coating, can keep the stability of coating on the one hand, and the high temperature sintering that can reduce coating on the other hand shrinks, reduces the high-temperature heat conductivity of coating and the effect of hinder coating cracking；Defoamer can eliminate the foam in coating and improve the mobility of coating；Coupling agent can improve the room temperature cementability of coating and matrix (material that coating to be brushed), and hinder coating ftractures。
It is an object of the invention to thermal insulation coatings and be internally formed nano-pore structure。The present invention selects aerosil to be primary raw material, and it is possible to additionally incorporate some nanometer powders is implant, forms nanopore network structure with the chopped fiber that length is 1-3mm for skeleton。SiO2Aerogel powder has the nanoscale pore structure of complexity, SiO2Aeroge is different from the porous material of macroscopic void, and the thermal conductivity that its very thin nanostructured makes material is extremely low, has great specific surface area, and the scattering of light, sound is all much smaller than traditional porous material。SiO2The nanoaperture of aeroge and the crooked route of fiber multihole network structure prevent the gaseous heat conduction of air and the solid state heat conduction of gel skeleton respectively, can also blocking radiant heat by dopen Nano powder。This 3 aspect combined effect, has almost blocked all approach of hot transmission, has made SiO2Aeroge plays good insulation effect。SiO2The heat conductivity of aeroge is at 0.013W/ (m K) below, far below the heat conductivity [0.025W/ (m K)] of still air under room temperature, and have that density is low, water proof fire retardant, environmental protection, anti-soda acid are corrosion-resistant, the not easily feature such as aging, long service life。The present invention selects SiO2Aeroge and nanometer powder are as the raw material preparing nano-pore thermal insulation coatings, it is possible to make coating possess the construction features of nano-pore, have ultralow thermal conductivity and SiO2Airsetting rubber powder belongs to the inorganic material of loose shape, adds high-temperature fibre and Nano filling can ensure that coating at high temperature uses。
The difficult point of the technology of the present invention is in that SiO2Sintering shrinkage under the dispersibility of aeroge and high temperature。SiO2Aeroge belongs to and is connected with each other solid micelle, through surface modification with process the SiO making very hydrophobic performance2Aerogel powder, aerogel powder is in a solvent through high-speed stirred and dispersant, and its dispersion effect neither be very good。After nanometer powder and dispersant are sufficiently stirred for by the present invention again and SiO2Aeroge stirs together, and aeroge soft-agglomerated to nanometer powder and part is scatter by dispersant, and scattered nano-particles filled is opened soft-agglomerated for major part aeroge to aeroge is internal by high-speed stirred, so can realize nanometer powder and SiO2Aeroge good dispersion。SiO2Aeroge is all made up of colloidal particle, at high temperature uses (more than 600 DEG C) easily generation sintering shrinkage cause the cracking of coating and come off, affects serviceability。Resistant to elevated temperatures chopped fiber is joined in thermal insulation coatings by the present invention, plays the effect of skeleton in coating, plays the effect hindering aeroge sintering shrinkage on the one hand, and the intensity and the porosity that improve coating on the other hand reduce heat conductivity。
High-temperature resistant nano hole of the present invention thermal insulation coatings provides the benefit that:
1) lower thermal conductivity。The present invention selects the aerosil with nano-pore structure to be primary raw material, and the thermal conductivity of aerosil is at 0.013W/ (m K) below, it is possible to make coating have relatively low thermal conductivity。Mutually pile up can form nano-pore structure it addition, the nanometer powder that the present invention selects is filler with aeroge, coating adds chopped fiber and is possible not only to improve the intensity of coating and the thermal conductivity of coating can be reduced。
2) high temperature resistant。The present invention selects several inorganic material to combine, and selects fiber to reduce coating shrinkage, select resistant to elevated temperatures inorganic filler to improve the use temperature of coating in coating, and the coating maximum operation (service) temperature prepared by the present invention is up to 1000 DEG C。
3) under high temperature, (more than 600 DEG C) are strong with matrix bonding force。Major part thermal insulation coatings uses the not high one side of temperature to be because coating itself based on Organic substance, and pore structure is formed by Organic substance；Selecting organic bond on the other hand, when temperature is too high, coating easily comes off。The nano-sized filler that the present invention selects at high temperature can interpenetrate with refractory material matrix, be sintered to one can ensure that coating and matrix are completely embedded, and coating does not fall off。
4) technique is simple。The present invention is raw materials used needs not move through mixing, drying, broken and grinding, and coating once stirs and can use。
Detailed description of the invention
In conjunction with the embodiment provided, the present invention is illustrated:
Embodiment 1: a kind of high-temperature resistant nano hole thermal insulation coatings, it is made up of following weight portion, the aerosil of nano-pore structure 5 parts, nano zircite 3 parts, nano silicon oxide 10 parts, nano aluminium oxide 7 parts, alpha-alumina crystals chopped fiber 2 parts, mullite crystal chopped fiber 3 parts, high alumina chopped fiber (Al2O3>=40w%) 5 parts, organic siliconresin 30 parts, deionized water 30 parts, ethanol 5 parts, polyethylene glycol type water reducer CAMTMENTFS10 dispersant 0.15 part that BASF Aktiengesellschaft produces, silane coupler 0.3 part, organic silicon defoamer 0.05 part。
According to said ratio weigh deionized water, ethanol and dispersant put into homogenizer stirs 10 minutes with the rotating speed of 500rpm after add after corresponding nano zircite, aluminium oxide and silicon oxide powder stir 30 minutes with the rotating speed of 8000rpm, the aerosil adding respective amount is stirred for 10 minutes with the rotating speed of 8000rpm；It is subsequently adding organic siliconresin to stir 30 minutes with the rotating speed of 2000rpm；Finally it is sequentially added into chopped fiber, organic silicon defoamer and silane coupler by proportioning to stir 30 minutes with the rotating speed of 2000rpm, namely obtains high-temperature resistant nano hole thermal insulation coatings。
Embodiment 2: a kind of high-temperature resistant nano hole thermal insulation coatings and preparation method, it is made up of following weight portion, the aerosil of nano-pore structure 10 parts, nano silicon oxide 10 parts, nano aluminium oxide 7 parts, mullite crystal chopped fiber 3 parts, high alumina chopped fiber (Al2O3>=40w%) 2 parts, polyurethane resin 40 parts, deionized water 10 parts, ethanol 18 parts, polyethylene glycol type water reducer CAMTMENTFS20 dispersant 0.2 part that additional BASF Aktiengesellschaft produces, silane coupler 0.15 part, organic silicon defoamer 0.15 part。
According to said ratio weigh deionized water, ethanol and dispersant put into homogenizer stirs 5 minutes with the rotating speed of 1000rpm after add after corresponding nano aluminium oxide and silicon oxide powder stir 10 minutes with the rotating speed of 8000rpm, the aerosil adding respective amount is stirred for 30 minutes with the rotating speed of 8000rpm；It is subsequently adding polyurethane resin to stir 10 minutes with the rotating speed of 1000rpm；Finally it is sequentially added into mullite crystal chopped fiber and high alumina chopped fiber, organic silicon defoamer and silane coupler by proportioning to stir 60 minutes with the rotating speed of 1000rpm, namely obtains high-temperature resistant nano hole thermal insulation coatings。
Embodiment 3: a kind of high-temperature resistant nano hole thermal insulation coatings and preparation method, is made up of following weight portion, the aerosil of nano-pore structure 15 parts, nano silicon oxide 10 parts, crystal of zirconium oxide chopped fiber 3 parts, high alumina chopped fiber (Al2O3>=40w%) 2 parts, polyurethane resin 30 parts, Ludox 10 parts, deionized water 30 parts, ethanol 10 parts, polyethylene glycol type water reducer CAMTMENTFS10 dispersant 0.15 part that BASF Aktiengesellschaft produces, silane coupler 0.3 part, polyether-modified silicon defoaming agent 0.05 part。
According to said ratio weigh deionized water, ethanol and dispersant put into homogenizer stirs 10 minutes with the rotating speed of 800rpm after add after corresponding nano oxidized Si powder stirs 20 minutes with the rotating speed of 6000rpm, the aerosil adding respective amount is stirred for 20 minutes with the rotating speed of 6000rpm；It is subsequently adding polyurethane resin and Ludox to stir 15 minutes with the rotating speed of 800rpm；Finally it is sequentially added into crystal of zirconium oxide chopped fiber and high alumina chopped fiber, polyether-modified silicon defoaming agent and silane coupler by proportioning to stir 45 minutes with the rotating speed of 800rpm, namely obtains high-temperature resistant nano hole thermal insulation coatings。
Embodiment 4: a kind of high-temperature resistant nano hole thermal insulation coatings and preparation method, it is made up of following weight portion, the aerosil of nano-pore structure 10 parts, nano zircite 5 parts, nano silicon oxide 10 parts, nano aluminium oxide 5 parts, alpha-alumina crystals chopped fiber 5 parts, mullite crystal chopped fiber (Al2O3>=40w%) 5 parts, acrylic resin 30 parts, Ludox 20 parts, deionized water 25 parts, additional sodium tripolyphosphate dispersant 0.15 part, silane coupler 0.2 part, polyether-modified silicon defoaming agent 0.1 part。
Weighing deionized water according to said ratio and dispersant is put into and added after corresponding nano zircite, aluminium oxide and silicon oxide powder stir 10 minutes with the rotating speed of 5000rpm after stirring 5 minutes with the rotating speed of 500rpm in homogenizer, the aerosil adding respective amount is stirred for 30 minutes with the rotating speed of 5000rpm；It is subsequently adding acrylic resin and Ludox to stir 10 minutes with the rotating speed of 1000rpm；Finally it is sequentially added into aluminium oxide and mullite crystal chopped fiber, organic silicon defoamer and silane coupler by proportioning to stir 30 minutes with the rotating speed of 1000rpm, namely obtains high-temperature resistant nano hole thermal insulation coatings。
Embodiment 5: a kind of high-temperature resistant nano hole thermal insulation coatings and preparation method, it is made up of following weight portion, the aerosil of nano-pore structure 10 parts, nano zircite 10 parts, nano silicon oxide 5 parts, nano aluminium oxide 5 parts, crystal of zirconium oxide chopped fiber 2 parts, mullite crystal chopped fiber 3 parts, styrene-acrylic emulsion 30 parts, Ludox 15 parts, ethanol 40 parts, ammonium polyacrylate dispersant 0.15 part, silane coupler 0.2 part, organic silicon defoamer 0.05 part。
Weighing ethanol according to said ratio and dispersant is put into and added after corresponding nano zircite, aluminium oxide and silicon oxide powder stir 10 minutes with the rotating speed of 7000rpm after stirring 8 minutes with the rotating speed of 600rpm in homogenizer, the aerosil adding respective amount is stirred for 25 minutes with the rotating speed of 7000rpm；It is subsequently adding styrene-acrylic emulsion and Ludox to stir 10 minutes with the rotating speed of 1500rpm；Finally it is sequentially added into zirconium oxide and mullite crystal chopped fiber, organic silicon defoamer and silane coupler by proportioning to stir 50 minutes with the rotating speed of 1500rpm, namely obtains high-temperature resistant nano hole thermal insulation coatings。
Embodiment 6: a kind of high-temperature resistant nano hole thermal insulation coatings and preparation method, is made up of following weight portion, the aerosil of nano-pore structure 5 parts, nano alumina powder 20 parts, high alumina chopped fiber (Al2O3>=40w%) 10 parts, acrylic resin 10 parts, styrene-acrylic emulsion 25 parts, deionized water 20 parts, ethanol 15 parts, sodium hexameta phosphate dispersant 0.2 part, silane coupler 0.2 part, polyether-modified silicon defoaming agent 0.1 part。
According to said ratio weigh deionized water, ethanol and dispersant put into homogenizer stirs 7 minutes with the rotating speed of 1000rpm after add after corresponding Nano-sized Alumina Powder stirs 15 minutes with the rotating speed of 6000rpm, the aerosil adding respective amount is stirred for 25 minutes with the rotating speed of 6000rpm；It is subsequently adding acrylic resin and styrene-acrylic emulsion to stir 10 minutes with the rotating speed of 1600rpm；Finally it is sequentially added into high alumina chopped fiber, polyether-modified silicon defoaming agent and silane coupler by proportioning to stir 35 minutes with the rotating speed of 1600rpm, namely obtains high-temperature resistant nano hole thermal insulation coatings。
Embodiment 7: a kind of high-temperature resistant nano hole thermal insulation coatings and preparation method, is made up of following weight portion, the aerosil of nano-pore structure 10 parts, nano silicon oxide 20 parts, mullite crystal chopped fiber 3 parts, high alumina chopped fiber (Al2O3>=40w%) 2 parts, polyurethane resin 30 parts, deionized water 20 parts, ethanol 30 parts, polyethylene glycol type water reducer CAMTMENTFS10 dispersant 0.1 part that additional BASF Aktiengesellschaft produces, silane coupler 0.15 part, organic silicon defoamer 0.15 part。
According to said ratio weigh deionized water, ethanol and dispersant put into homogenizer stirs 5 minutes with the rotating speed of 7000rpm after add after corresponding nano aluminium oxide and silicon oxide powder stir 30 minutes with the rotating speed of 5000rpm, the aerosil adding respective amount is stirred for 30 minutes with the rotating speed of 5000rpm；It is subsequently adding polyurethane resin to stir 10 minutes with the rotating speed of 1000rpm；Finally it is sequentially added into mullite crystal chopped fiber and high alumina chopped fiber, organic silicon defoamer and silane coupler by proportioning to stir 60 minutes with the rotating speed of 1000rpm, namely obtains high-temperature resistant nano hole thermal insulation coatings。
Claims (5)
1. a high-temperature resistant nano hole thermal insulation coatings, it is characterized in that described coating is made up of the component of following weight portion: aerogel powder 5-15 part, filler 10-20 part, length is chopped fiber 5-10 part of 1-3mm, film forming matter 30-40 part, solvent 10-50 part, it is possible to additionally incorporate the defoamer of the dispersant of 0.1-0.2 part, the coupling agent of 0.15-0.3 part and 0.05-0.15 part；The preparation method of a kind of high-temperature resistant nano hole thermal insulation coatings, weighs solvent according to proportioning and dispersant is put in homogenizer and stirred 5-10 minute with the rotating speed of 500-1000rpm, make dispersant be completely dissolved in solvent；Add filler by proportioning to stir with the rotating speed of 5000-8000rpm, high rotating speed and dispersant combined effect are fully opened soft-agglomerated for filler part, it is evenly distributed in solvent, add aerogel powder after stirring 10-30 minute and be stirred for 10-30 minute with identical rotating speed, can make on the one hand that aerogel powder is fully dispersed to be opened, on the other hand nanometer powder and aerogel powder be mixed uniformly；It is subsequently adding film forming matter to stir 10-30 minute with the rotating speed of 1000-2000rpm；Finally it is sequentially added into chopped fiber, defoamer and coupling agent by proportioning to stir 30-60 minute with the rotating speed of 1000-2000rpm, namely obtains high-temperature resistant nano hole thermal insulation coatings；Described aerogel powder is the silica aerogel powder with nanoaperture structure, and powder diameter is 1-100 micron；Described filler is the mixture of one or more arbitrary proportions in nano oxidized Si powder, Nano-sized Alumina Powder, nano zirconium oxide powder。
2. a kind of high-temperature resistant nano hole as claimed in claim 1 thermal insulation coatings, it is characterised in that described chopped fiber is one or more in zirconia crystal fiber, alpha-alumina crystals fiber, mullite crystal fiber and high aluminum fiber。
3. a kind of high-temperature resistant nano hole as claimed in claim 1 thermal insulation coatings, it is characterised in that described film forming matter is one or more arbitrary proportions mixing in silicone resin emulsion, waterborne polyurethane resin, water-borne acrylic resin, Ludox。
4. a kind of high-temperature resistant nano hole as claimed in claim 1 thermal insulation coatings, it is characterised in that described solvent is one or both in ethanol and deionized water。
5. a kind of high-temperature resistant nano hole as claimed in claim 1 thermal insulation coatings, it is characterised in that described dispersant is the one in sodium tripolyphosphate, sodium hexameta phosphate, ammonium polyacrylate and polyethylene glycol type water reducer；Described coupling agent is silane coupler；Described defoamer is organic silicon defoamer。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410434538.3A CN104152029B (en) | 2014-08-29 | 2014-08-29 | A kind of high-temperature resistant nano hole thermal insulation coatings and preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410434538.3A CN104152029B (en) | 2014-08-29 | 2014-08-29 | A kind of high-temperature resistant nano hole thermal insulation coatings and preparation method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104152029A CN104152029A (en) | 2014-11-19 |
| CN104152029B true CN104152029B (en) | 2016-06-22 |
Family
ID=51877665
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410434538.3A Active CN104152029B (en) | 2014-08-29 | 2014-08-29 | A kind of high-temperature resistant nano hole thermal insulation coatings and preparation method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104152029B (en) |
Families Citing this family (37)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104496496B (en) * | 2014-12-10 | 2016-11-09 | 中国京冶工程技术有限公司 | Wet spray material wear-resisting toughener and preparation method thereof |
| CN105038496A (en) * | 2015-07-08 | 2015-11-11 | 当涂县科辉商贸有限公司 | Nanometer Al2O3 composite aerosil thermal-insulation heat-preserving paint and preparation method thereof |
| CN105038527A (en) * | 2015-07-30 | 2015-11-11 | 安徽荣达阀门有限公司 | Valve antifouling powder coating with functions of sound absorption and noise reduction and preparation method of valve antifouling powder coating |
| CN105153892A (en) * | 2015-07-30 | 2015-12-16 | 安徽荣达阀门有限公司 | High/low-temperature-resistant valve antifouling powdery paint and manufacturing method thereof |
| CN105062291B (en) * | 2015-09-07 | 2016-08-31 | 章俊 | A kind of preparation method of fireproof coating |
| CN105367033A (en) * | 2015-11-19 | 2016-03-02 | 浙江大学自贡创新中心 | Flame retardant and heat preservation slurry |
| CN105461279A (en) * | 2015-11-19 | 2016-04-06 | 浙江大学自贡创新中心 | Preparation method of flame-retardant thermal-insulation slurry |
| CN105461350B (en) * | 2015-11-19 | 2017-12-29 | 浙江大学自贡创新中心 | Coating structure with fire-retardant heat insulation function |
| CN105330335B (en) * | 2015-11-19 | 2017-10-03 | 浙江大学自贡创新中心 | The preparation method of coating structure with fire-retardant heat insulation function |
| CN106007483A (en) * | 2016-05-13 | 2016-10-12 | 郝飞虎 | Exterior wall coating |
| CN106567474B (en) * | 2016-10-28 | 2019-05-10 | 王贵然 | A kind of silica nanometer aeroge hollow glass microballoon compound fireproof heat-preservation board material and preparation method thereof |
| CN106634570B (en) * | 2016-12-13 | 2019-07-05 | 中钢集团洛阳耐火材料研究院有限公司 | A kind of high temperature height radiation crack resistence energy-saving coatings and preparation method |
| CN106928832B (en) * | 2017-04-21 | 2019-11-22 | 中国平煤神马能源化工集团有限责任公司 | A kind of high temperature resistant anti-infrared radiance decaying energy-saving coatings |
| CN107254224A (en) * | 2017-06-28 | 2017-10-17 | 奇华光电（昆山）股份有限公司 | A kind of atomizing aeroge |
| WO2019069404A1 (en) * | 2017-10-04 | 2019-04-11 | 日立化成株式会社 | Coating liquid, coating film production method, and coating film |
| WO2019069411A1 (en) * | 2017-10-04 | 2019-04-11 | 日立化成株式会社 | Coating solution, method for producing coating film, and coating film |
| WO2019069412A1 (en) * | 2017-10-04 | 2019-04-11 | 日立化成株式会社 | Coating solution, method for producing coating film, and coating film |
| CN107903753A (en) * | 2017-12-07 | 2018-04-13 | 龚贤飞 | A kind of nanometer molybdenum disilicide high-temperature resistant coating |
| CN108178944A (en) * | 2017-12-22 | 2018-06-19 | 北京首创纳米科技有限公司 | A kind of fire-type adiabatic heat-insulation putty and preparation method thereof |
| CN108977063A (en) * | 2018-07-18 | 2018-12-11 | 安徽诺辰新型材料有限公司 | Nano composite heat insulation coating and preparation method thereof |
| CN108911770A (en) * | 2018-08-16 | 2018-11-30 | 德清县都德利耐材有限公司 | Composition silicate high-temperature coatings |
| CN110054918A (en) * | 2019-05-09 | 2019-07-26 | 平顶山学院 | A kind of cracking resistance inorganic heat preservation coating |
| CN110066598A (en) * | 2019-05-28 | 2019-07-30 | 河南嘉和节能科技有限公司 | A kind of high temperature anti-dropout infrared radiative energy-saving coating |
| CN110305582B (en) * | 2019-07-24 | 2021-04-09 | 浙江德创环保科技股份有限公司 | High-temperature-resistant baffle door and manufacturing method thereof |
| CN110860450A (en) * | 2019-11-01 | 2020-03-06 | 河南爱彼爱和新材料有限公司 | Composite aerogel fiber spray coating and preparation process thereof |
| CN110713782B (en) * | 2019-11-06 | 2021-12-14 | 宁波瑞凌新能源科技有限公司 | Transparent cooling coating and preparation method thereof |
| CN111604237B (en) * | 2020-05-11 | 2023-03-31 | 中海油常州涂料化工研究院有限公司 | Preparation method of metal substrate heat-insulation protective coating structure and metal substrate heat-insulation protective coating structure |
| CN111534131B (en) * | 2020-05-11 | 2022-08-16 | 中海油常州涂料化工研究院有限公司 | Heat-insulating coating and preparation method thereof |
| CN111500138A (en) * | 2020-05-21 | 2020-08-07 | 成都玉龙化工有限公司 | Heat-insulating coating and preparation method thereof |
| CN112226103A (en) * | 2020-07-29 | 2021-01-15 | 南京工业大学 | A kind of aerogel paint and preparation method |
| CN112341930B (en) * | 2020-10-29 | 2021-11-02 | 陕西天璇涂层科技有限公司 | High-temperature-resistant resin-based integrated composite material and preparation method thereof |
| CN113053584B (en) * | 2021-03-11 | 2022-06-14 | 昆明理工大学 | A kind of nickel-cobalt alloy/aluminum alloy/copper alloy ultra-high temperature wire and preparation method thereof |
| CN113149625A (en) * | 2021-03-19 | 2021-07-23 | 河南嘉和节能科技有限公司 | High-temperature-resistant heat-insulating ash material for coke oven smoke guide hole cover and preparation method thereof |
| CN114836975B (en) * | 2022-05-25 | 2024-04-05 | 绍兴市暖壹节能科技有限公司 | Composite fiber-based material for heat insulation of pipeline and preparation method thereof |
| CN115851010B (en) * | 2022-12-14 | 2023-12-12 | 富思特新材料科技发展股份有限公司 | Inorganic coating and preparation method and application thereof |
| CN117186672A (en) * | 2023-07-19 | 2023-12-08 | 浣江实验室 | Ablation-resistant inorganic heat insulation coating and preparation method thereof |
| CN117070083A (en) * | 2023-08-16 | 2023-11-17 | 中国科学院苏州纳米技术与纳米仿生研究所 | Flexible ceramic coating and preparation method and application thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1990799A (en) * | 2005-12-27 | 2007-07-04 | 财团法人工业技术研究院 | High temperature insulation coating |
| CN103031049A (en) * | 2012-12-21 | 2013-04-10 | 青岛格尔美环保涂料有限公司 | Aqueous glass insulating paint and preparation method thereof |
| CN103333542A (en) * | 2013-07-04 | 2013-10-02 | 河南工业大学 | Silica aerogel microsphere composite thermal insulation coating |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101137657B1 (en) * | 2009-11-04 | 2012-04-20 | 이재환 | Emulsion aerogel composition |
-
2014
- 2014-08-29 CN CN201410434538.3A patent/CN104152029B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1990799A (en) * | 2005-12-27 | 2007-07-04 | 财团法人工业技术研究院 | High temperature insulation coating |
| CN103031049A (en) * | 2012-12-21 | 2013-04-10 | 青岛格尔美环保涂料有限公司 | Aqueous glass insulating paint and preparation method thereof |
| CN103333542A (en) * | 2013-07-04 | 2013-10-02 | 河南工业大学 | Silica aerogel microsphere composite thermal insulation coating |
Non-Patent Citations (2)
| Title |
|---|
| 硅气凝胶/空心玻璃微珠保温涂料的研制;李建涛 等;《涂料工业》;20130731;第43卷(第7期);第25页第1栏第2段，"1 实验部分"的内容，第27页"2.5硅气凝胶保温涂料的保温机理"的内容 * |
| 薄层外墙纳米隔热涂料的研制;刘成楼 等;《涂料技术与文摘》;20140731;第35卷(第7期);第15-18,22页 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104152029A (en) | 2014-11-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104152029B (en) | A kind of high-temperature resistant nano hole thermal insulation coatings and preparation method | |
| Hou et al. | Novel whisker-reinforced Al2O3–SiO2 aerogel composites with ultra-low thermal conductivity | |
| EP2424824B1 (en) | Method for coating a substrate with a composite | |
| CN101734903A (en) | Nano silica dioxide heat-insulating material and preparation method thereof | |
| Shoukry et al. | Thermo-physical properties of nanostructured lightweight fiber reinforced cementitious composites | |
| CN105036733B (en) | Infrared high shielding nucleocapsid structure opacifier and its preparation method and application | |
| CN109721312A (en) | A kind of A grades of non-ignitable aeroge polyphenylene heat insulation slab and preparation method thereof | |
| Gu et al. | Novel high‐temperature‐resistant Y2SiO5 aerogel with ultralow thermal conductivity | |
| CN110713737A (en) | Fireproof and heat-insulating inorganic mineral coating for buildings and preparation method thereof | |
| KR20200014376A (en) | Insulation products for the production of insulating materials or for the refractory industry, the corresponding insulating materials and products and their use | |
| CN102910887A (en) | Inorganic nanometer gas condensation sand insulation material and preparation method thereof | |
| US20240369174A1 (en) | Hybrid insulating compound for use in systems requiring high power of thermal insulation | |
| CN105884313A (en) | High-performance silicon dioxide aerogel thermal mortar and preparation method thereof | |
| CN109111806A (en) | A kind of dedicated heat-proof coating material preparation method of environmental protection package | |
| JP2020521716A (en) | Method for producing composite particles and insulating materials for the production of insulating products for the building materials industry and corresponding use | |
| CN103073257A (en) | Thermal insulation composite and preparation method thereof | |
| CN105712670A (en) | Intelligent thermal-insulation fire-proof nano material and production method thereof | |
| CN102807326B (en) | Polymer-modified low temperature foaming glass thermal insulation material and preparation method thereof | |
| CN107954740A (en) | Corrosion-resistant micropore alumine light fire brick and preparation method thereof | |
| CN107954700A (en) | Corrosion-resistant corundum refractory brick and preparation method thereof | |
| CN103146343B (en) | Energy-saving anti-thermal-radiation air-coated blocking adhesive coating and preparation method and application method thereof | |
| CN113404175A (en) | Paper-surface gypsum board and preparation method thereof | |
| CN108977063A (en) | Nano composite heat insulation coating and preparation method thereof | |
| Yang et al. | Direct-writing assembly of high-strength hierarchical porous mullite-based lattices with a multiscale reinforcing strategy | |
| Duan et al. | Preparation of Porous Si2N2O/SiC Ceramics by Microwave Sintering |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |