CN104151896B - Radiation curing epoxy coating used by a kind of pottery - Google Patents
Radiation curing epoxy coating used by a kind of pottery Download PDFInfo
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- CN104151896B CN104151896B CN201410431516.1A CN201410431516A CN104151896B CN 104151896 B CN104151896 B CN 104151896B CN 201410431516 A CN201410431516 A CN 201410431516A CN 104151896 B CN104151896 B CN 104151896B
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- acrylic acid
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- 238000003847 radiation curing Methods 0.000 title claims abstract description 17
- 229920006334 epoxy coating Polymers 0.000 title claims abstract description 13
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 21
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 15
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000002994 raw material Substances 0.000 claims abstract description 13
- 239000004843 novolac epoxy resin Substances 0.000 claims abstract description 11
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims abstract description 11
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims abstract description 11
- 239000004926 polymethyl methacrylate Substances 0.000 claims abstract description 10
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 8
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims abstract description 8
- VHRYZQNGTZXDNX-UHFFFAOYSA-N methacryloyl chloride Chemical compound CC(=C)C(Cl)=O VHRYZQNGTZXDNX-UHFFFAOYSA-N 0.000 claims abstract description 8
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims abstract description 8
- FALRKNHUBBKYCC-UHFFFAOYSA-N 2-(chloromethyl)pyridine-3-carbonitrile Chemical compound ClCC1=NC=CC=C1C#N FALRKNHUBBKYCC-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 7
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims abstract description 7
- 229940014800 succinic anhydride Drugs 0.000 claims abstract description 7
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 7
- -1 polyethylene terephthalate Polymers 0.000 claims abstract description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 10
- JYZIHLWOWKMNNX-UHFFFAOYSA-N benzimidazole Chemical compound C1=C[CH]C2=NC=NC2=C1 JYZIHLWOWKMNNX-UHFFFAOYSA-N 0.000 claims description 7
- MSAHTMIQULFMRG-UHFFFAOYSA-N 1,2-diphenyl-2-propan-2-yloxyethanone Chemical compound C=1C=CC=CC=1C(OC(C)C)C(=O)C1=CC=CC=C1 MSAHTMIQULFMRG-UHFFFAOYSA-N 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 2
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims description 2
- 239000012965 benzophenone Substances 0.000 claims description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims 3
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims 2
- 239000002202 Polyethylene glycol Substances 0.000 claims 1
- 150000008064 anhydrides Chemical class 0.000 claims 1
- 235000019253 formic acid Nutrition 0.000 claims 1
- 239000003999 initiator Substances 0.000 claims 1
- 150000004702 methyl esters Chemical class 0.000 claims 1
- 229920001223 polyethylene glycol Polymers 0.000 claims 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract description 10
- 238000005187 foaming Methods 0.000 abstract description 10
- 239000000463 material Substances 0.000 abstract description 10
- 238000001035 drying Methods 0.000 abstract description 8
- 239000007787 solid Substances 0.000 abstract description 8
- 241000406668 Loxodonta cyclotis Species 0.000 abstract description 5
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical class [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 abstract description 5
- 229920000139 polyethylene terephthalate Polymers 0.000 abstract description 4
- 239000005020 polyethylene terephthalate Substances 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical compound C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 abstract 1
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 abstract 1
- APWFFUVXHHQZBH-UHFFFAOYSA-N octan-2-yl nitrite prop-2-enoic acid Chemical compound N(=O)OC(C)CCCCCC.C(C=C)(=O)O APWFFUVXHHQZBH-UHFFFAOYSA-N 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 description 15
- 238000000576 coating method Methods 0.000 description 15
- 239000004927 clay Substances 0.000 description 6
- 239000003973 paint Substances 0.000 description 6
- 238000010792 warming Methods 0.000 description 6
- 239000003822 epoxy resin Substances 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 229920000647 polyepoxide Polymers 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 235000010215 titanium dioxide Nutrition 0.000 description 5
- 150000002148 esters Chemical class 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 229910052573 porcelain Inorganic materials 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 229910052925 anhydrite Inorganic materials 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 238000005524 ceramic coating Methods 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- ZAFNJMIOTHYJRJ-UHFFFAOYSA-N Diisopropyl ether Chemical compound CC(C)OC(C)C ZAFNJMIOTHYJRJ-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 239000002033 PVDF binder Substances 0.000 description 1
- 208000037656 Respiratory Sounds Diseases 0.000 description 1
- 229910000004 White lead Inorganic materials 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 230000003471 anti-radiation Effects 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- JSLMNNPQKHONFW-UHFFFAOYSA-N benzene naphthalene-1-carboxylic acid Chemical compound C1(=CC=CC2=CC=CC=C12)C(=O)O.C1=CC=CC=C1 JSLMNNPQKHONFW-UHFFFAOYSA-N 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 229910052571 earthenware Inorganic materials 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000012847 fine chemical Substances 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- MJVGBKJNTFCUJM-UHFFFAOYSA-N mexenone Chemical group OC1=CC(OC)=CC=C1C(=O)C1=CC=C(C)C=C1 MJVGBKJNTFCUJM-UHFFFAOYSA-N 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 229910052604 silicate mineral Inorganic materials 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- KUCOHFSKRZZVRO-UHFFFAOYSA-N terephthalaldehyde Chemical compound O=CC1=CC=C(C=O)C=C1 KUCOHFSKRZZVRO-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of pottery radiation curing epoxy coating, raw material is: novolac epoxy resin, Kynoar, 3 Carbimide. propylene, polymethyl methacrylate, methacrylic chloride, ethyl acrylate, light trigger, acrylic acid 2 Octyl Nitrite, acrylic acid, polyethylene terephthalate, cross-linking agent, glycerol, succinic anhydride, titanium dioxide and benzimidazole；Product glossiness 130% 150%, hardness 6 9H；Surface drying time 1 3min, does solid work 5 15min, soaks nothing foaming, obscission after 5 7d in 5% hydrochloric acid solution；In saturated calcium hydroxide, soak that 10 14d are non-foaming, elephant skin；Product scrub resistance 1,800 2000 times, can be with the widespread production not division of history into periods for current material.
Description
Technical field
The application belongs to paint field, particularly relates to a kind of pottery radiation curing epoxy resin and is coated with
Material.
Background technology
Pottery be with natural clay and various natural minerals for primary raw material through pulverizing mixing,
The various goods of the material that molding and calcining prepare.In the past people be fabricated to potter's clay specially
In the kiln of door, the article of high-temperature firing are referred to as pottery, and pottery is the general name of pottery and porcelain.Pottery
The traditional concept of porcelain refers to all artificial industry with Inorganic nonmetal mineral such as clays as raw material
Product.It include by clay or containing the mixture of clay through mixing, shape, calcining and make
Various goods.Broadly fall into its model to the finest fine pottery and porcelain by the most coarse earthenware
Enclose.Primary raw material for it is that the silicate mineral taking from nature is (such as clay, quartz
Deng), therefore with industry such as glass, methacrylic chloride mud, enamel, refractory materials, belong to together
Category in " silicate industry ".Special cermacis is as Modern appliances, radio, aviation,
The industry such as atomic energy, metallurgy, machinery, chemistry and electronic computer, space technology, new energy
The developing by leaps and bounds and grow up of the most advanced branches of science technology such as source exploitation.Master used by these potteries
Wanting raw material is no longer clay, Anhydrite, quartz, and some bases not also use some clays or Anhydrite,
But be more to use pure oxide and there is the raw material of property, manufacturing process with
Performance requirement is the most different.
Coating is typically based on resin or oil, and adds or be not added with face, filler, uses organic solvent
Or the thick liquid of water modulation, also occur in that the coating new varieties with solid forms existence are such as
Powdery paints.Though the form (liquid or solid) of all kinds of coating coating varieties, at least
Should be made up of two or three basis.I.e. it is divided into main film forming substance；Film forming subsidiary material matter
And auxiliary film forming matter.Coating can be coated on surface of bottom material and form tough and tensile continuous film (paint film)
Liquid or solid macromolecular material.It is once called as paint, paint.It is mainly used to play by painting surface
Decoration and protective effect.Some coating also has specific function, as high temperature resistant, cold-resistant, anti-
Radiation etc..Coating is widely used in the aspects such as building, boats and ships, vehicle, metallic article.According to
The classification of modern current chemical products, coating belongs to fine chemical product.Modern coating is just
Progressively becoming a polyfunctional engineering material of class, be an important row in chemical industry
Industry.
Ceramic coating weatherability and processing characteristics are excellent, bear dirty and resistant to damage.Conventional pottery
Although coating resistant to damage, but if the parts after application are curved processing, easily produce
Crackle, and fluorine resin paints and organic coating, easily damaged by sandstone, dust etc..Cause
This, the appearance of ceramic coating, receive the favor of ceramic industry, and the infiltration of forward other industry,
Promise well.And popularizing along with humanity concept, and the composition of novel harmonious society, design
The pottery spoke that a kind of good mechanical property, coating are strong, chemical stability good and adhesive force is excellent
Penetrate cured epoxy resin coating to be very important.
Summary of the invention
Solve the technical problem that:
The application is for above-mentioned technical problem, it is provided that a kind of pottery radiation curing epoxy resin is coated with
Material, solve existing pottery radiation curing epoxy coating chemical stability and poor adhesive force,
The technical problems such as solidification is slow.
Technical scheme:
A kind of pottery uses radiation curing epoxy coating, described pottery radiation curing asphalt mixtures modified by epoxy resin
The raw materials by weight portion proportioning of grease coating material is as follows: novolac epoxy resin 100 parts；Polyvinylidene fluoride
Alkene 40-50 part；3-Carbimide. propylene 70-80 part；Polymethyl methacrylate 10-30 part；
Methacrylic chloride 80-100 part；Ethyl acrylate 1-3 part；Light trigger 10-20 part；
Acrylic acid-2-ethyl caproite 1-5 part；Acrylic acid 30-40 part；Polyethylene terephthalate
Ester 10-20 part；Cross-linking agent 1-2 part；Glycerol 5-15 part；Succinic anhydride 50-60 part；Titanium
White lead 30-40 part；Benzimidazole 0.3-0.5 part.
As a preferred technical solution of the present invention: described pottery radiation curing epoxy resin
The raw materials by weight portion proportioning of coating is as follows: novolac epoxy resin 100 parts；Kynoar
45 parts；3-Carbimide. propylene 75 parts；Polymethyl methacrylate 20 parts；Methacryl
Chlorine 90 parts；Ethyl acrylate 2 parts；Light trigger 15 parts；Acrylic acid-2-ethyl caproite 3
Part；35 parts of acrylic acid；Polyethylene terephthalate 15 parts；Cross-linking agent 1.5 parts；Sweet
Oil 10 parts；Succinic anhydride 55 parts；Titanium dioxide 35 parts；Benzimidazole 0.4 part.
As a preferred technical solution of the present invention: described light trigger uses benzoin isopropyl
Ether or benzophenone.
As a preferred technical solution of the present invention: described cross-linking agent uses styrene.
Beneficial effect:
A kind of pottery radiation curing epoxy coating of the present invention uses above technical side
Case compared with prior art, has following technical effect that 1, product glossiness 130%-150%,
Hardness 6-9H；2, surface drying time 1-3min, does solid work 5-15min, soaks in 5% hydrochloric acid solution
Without foaming, obscission after bubble 5-7d；3, in saturated calcium hydroxide, 10-14d is soaked not
Foaming, elephant skin；4, product scrub resistance 1800-2000 time, can with widespread production the most constantly
Replace current material.
Detailed description of the invention
Embodiment 1:
Radiation curing epoxy coating used by a kind of pottery, and its raw materials by weight portion proportioning is such as
Under: novolac epoxy resin 100 parts；Kynoar 40 parts；3-Carbimide. propylene 70 parts；
Polymethyl methacrylate 10 parts；Methacrylic chloride 80 parts；Ethyl acrylate 1 part；Two
Benzophenone 10 parts；Acrylic acid-2-ethyl caproite 1 part；30 parts of acrylic acid；Poly-terephthaldehyde
Acid glycol ester 10 parts；Styrene 1 part；Glycerol 5 parts；Succinic anhydride 50 parts；Titanium dioxide
30 parts；Benzimidazole 0.3 part.
By novolac epoxy resin, Kynoar, 3-Carbimide. propylene and poly-methyl methacrylate
Ester puts in reactor, is warming up to 60 DEG C, after stirring 1h, adds surplus stock, is warming up to
70 DEG C, mixing 2-3h, finished product is coated on pottery, with ultraviolet light polymerization is after drying
Can.
Product glossiness 130%%, hardness 6H；Surface drying time 3min, does solid work 15min,
5% hydrochloric acid solution soaks nothing foaming, obscission after 5d；Saturated calcium hydroxide soaks
10d is non-foaming, elephant skin, product scrub resistance 1800 times.
Embodiment 2:
Radiation curing epoxy coating used by a kind of pottery, and its raw materials by weight portion proportioning is such as
Under: novolac epoxy resin 100 parts；Kynoar 50 parts；3-Carbimide. propylene 80 parts；
Polymethyl methacrylate 30 parts；Methacrylic chloride 100 parts；Ethyl acrylate 3 parts；
Benzoin isopropyl ether 20 parts；Acrylic acid-2-ethyl caproite 5 parts；40 parts of acrylic acid；Poly-right
PET 20 parts；Styrene 2 parts；Glycerol 15 parts；Succinic anhydride 60 parts；
Titanium dioxide 40 parts；Benzimidazole 0.5 part.
By novolac epoxy resin, Kynoar, 3-Carbimide. propylene and poly-methyl methacrylate
Ester puts in reactor, is warming up to 60 DEG C, after stirring 1h, adds surplus stock, is warming up to
70 DEG C, mixing 2-3h, finished product is coated on pottery, with ultraviolet light polymerization is after drying
Can.
Product glossiness 140%, hardness 8H；Surface drying time 2min, does solid work 10min, 5%
Hydrochloric acid solution soaks nothing foaming, obscission after 6d；12d is soaked in saturated calcium hydroxide
Non-foaming, elephant skin, product scrub resistance 1900 times.
Embodiment 3:
Radiation curing epoxy coating used by a kind of pottery, and its raw materials by weight portion proportioning is such as
Under: novolac epoxy resin 100 parts；Kynoar 45 parts；3-Carbimide. propylene 75 parts；
Polymethyl methacrylate 20 parts；Methacrylic chloride 90 parts；Ethyl acrylate 2 parts；Peace
The fragrant diisopropyl ether 15 parts of breath；Acrylic acid-2-ethyl caproite 3 parts；35 parts of acrylic acid；Poly-to benzene
Naphthalate 15 parts；Styrene 1.5 parts；Glycerol 10 parts；Succinic anhydride 55 parts；
Titanium dioxide 35 parts；Benzimidazole 0.4 part.
By novolac epoxy resin, Kynoar, 3-Carbimide. propylene and poly-methyl methacrylate
Ester puts in reactor, is warming up to 60 DEG C, after stirring 1h, adds surplus stock, is warming up to
70 DEG C, mixing 2-3h, finished product is coated on pottery, with ultraviolet light polymerization is after drying
Can.
Product glossiness 150%, hardness 9H；Surface drying time 1min, does solid work 5min, 5%
Hydrochloric acid solution soaks nothing foaming, obscission after 7d；14d is soaked in saturated calcium hydroxide
Non-foaming, elephant skin, product scrub resistance 2000 times.
Compositions all components in above example all can be commercially available.
Above-described embodiment is only intended to be illustrated present disclosure rather than limit, because of
This any change in the implication suitable with claims of the present invention and scope, all should
It is considered to be included within the scope of the claims.
Claims (2)
1. radiation curing epoxy coating used by a pottery, it is characterised in that described pottery is used
The raw materials by weight portion proportioning of radiation curing epoxy coating is as follows: novolac epoxy resin
100 parts；Kynoar 40-50 part；3-Carbimide. propylene 70-80 part；Polymethyl
Acid methyl ester 10-30 part；Methacrylic chloride 80-100 part；Ethyl acrylate 1-3 part；Light
Initiator 10-20 part；Acrylic acid-2-ethyl caproite 1-5 part；Acrylic acid 30-40 part；Poly-
Ethylene glycol terephthalate 10-20 part；Cross-linking agent 1-2 part；Glycerol 5-15 part；Fourth two
Anhydride 50-60 part；Titanium dioxide 30-40 part；Benzimidazole 0.3-0.5 part；
Described light trigger uses benzoin isopropyl ether or benzophenone；
Described cross-linking agent uses styrene.
A kind of pottery radiation curing epoxy coating the most according to claim 1,
It is characterized in that the raw materials by weight portion of described pottery radiation curing epoxy coating is joined
Ratio is as follows: novolac epoxy resin 100 parts；Kynoar 45 parts；3-Carbimide. propylene 75
Part；Polymethyl methacrylate 20 parts；Methacrylic chloride 90 parts；Ethyl acrylate 2 parts；
Light trigger 15 parts；Acrylic acid-2-ethyl caproite 3 parts；35 parts of acrylic acid；Poly-to benzene two
Formic acid glycol ester 15 parts；Cross-linking agent 1.5 parts；Glycerol 10 parts；Succinic anhydride 55 parts；
Titanium dioxide 35 parts；Benzimidazole 0.4 part.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410431516.1A CN104151896B (en) | 2014-08-28 | 2014-08-28 | Radiation curing epoxy coating used by a kind of pottery |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410431516.1A CN104151896B (en) | 2014-08-28 | 2014-08-28 | Radiation curing epoxy coating used by a kind of pottery |
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| CN104151896B true CN104151896B (en) | 2016-08-17 |
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| CN104530301B (en) * | 2014-12-04 | 2016-01-27 | 佛山市高明同德化工有限公司 | Thermoplastic acrylic resin that a kind of high tenacity high temperature cabonization does not remain and preparation method thereof |
| CN104710911B (en) * | 2015-03-08 | 2017-05-03 | 宁波高新区夏远科技有限公司 | Skid-resistant coating for towel rail and preparation method of skid-resistant coating |
| CN104910658A (en) * | 2015-06-18 | 2015-09-16 | 黎司华 | Curable epoxy resin composition |
| CN105368184A (en) * | 2015-11-25 | 2016-03-02 | 安徽圣德建材科技有限公司 | Antibacterial polyvinylidene fluoride powder coating |
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| DE102005024246A1 (en) * | 2005-05-27 | 2006-11-30 | Degussa Ag | Copolymers, a process for their preparation and the use as binders |
| CN102796441B (en) * | 2012-09-12 | 2014-12-24 | 江南大学 | Novel polyphenol photocuring antibacterial paint |
| CN103031034B (en) * | 2012-12-12 | 2016-07-06 | 澳达树熊涂料(惠州)有限公司 | A kind of white finish paint optical curing of UV coating and preparation method thereof |
| CN103834272A (en) * | 2014-03-04 | 2014-06-04 | 芜湖市艾德森自动化设备有限公司 | Ultraviolet-curable coating material with antibacterial and antioxidant effects and preparation method thereof |
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