CN104140304A - A method of preparing sulfur-diammonium phosphate by adopting an acid tubular reactor - Google Patents
A method of preparing sulfur-diammonium phosphate by adopting an acid tubular reactor Download PDFInfo
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- CN104140304A CN104140304A CN201310162228.6A CN201310162228A CN104140304A CN 104140304 A CN104140304 A CN 104140304A CN 201310162228 A CN201310162228 A CN 201310162228A CN 104140304 A CN104140304 A CN 104140304A
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- Prior art keywords
- sulfuric acid
- granulator
- tablets press
- controlled
- sulfur
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- 239000002253 acid Substances 0.000 title claims abstract description 12
- 238000000034 method Methods 0.000 title claims abstract description 12
- IOZJQZLXUFXVNE-UHFFFAOYSA-N OP(O)(O)=O.N.N.S Chemical compound OP(O)(O)=O.N.N.S IOZJQZLXUFXVNE-UHFFFAOYSA-N 0.000 title abstract 3
- 239000000463 material Substances 0.000 claims abstract description 32
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 26
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 11
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000011343 solid material Substances 0.000 claims abstract description 10
- 239000011575 calcium Substances 0.000 claims abstract description 9
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 9
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims abstract description 7
- 238000005469 granulation Methods 0.000 claims abstract description 6
- 230000003179 granulation Effects 0.000 claims abstract description 6
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 6
- 238000005406 washing Methods 0.000 claims abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 5
- 238000005303 weighing Methods 0.000 claims abstract description 5
- 239000011593 sulfur Substances 0.000 claims abstract description 4
- 239000002245 particle Substances 0.000 claims description 12
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 9
- QCJQWJKKTGJDCM-UHFFFAOYSA-N [P].[S] Chemical compound [P].[S] QCJQWJKKTGJDCM-UHFFFAOYSA-N 0.000 claims description 7
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 6
- 239000004202 carbamide Substances 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- 229910021529 ammonia Inorganic materials 0.000 claims description 5
- 238000010790 dilution Methods 0.000 claims description 5
- 239000012895 dilution Substances 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 claims description 4
- 239000011248 coating agent Substances 0.000 claims description 4
- 238000000576 coating method Methods 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 4
- 239000000975 dye Substances 0.000 claims description 4
- 230000008676 import Effects 0.000 claims description 4
- 238000012856 packing Methods 0.000 claims description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract description 4
- 239000002994 raw material Substances 0.000 abstract description 3
- 210000003298 dental enamel Anatomy 0.000 abstract description 2
- 238000007865 diluting Methods 0.000 abstract description 2
- 229910052757 nitrogen Inorganic materials 0.000 abstract description 2
- 238000004806 packaging method and process Methods 0.000 abstract 2
- 239000007921 spray Substances 0.000 abstract 1
- 229910052698 phosphorus Inorganic materials 0.000 description 8
- 239000011574 phosphorus Substances 0.000 description 8
- 239000005864 Sulphur Substances 0.000 description 6
- 239000000047 product Substances 0.000 description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- 239000002689 soil Substances 0.000 description 4
- 239000005696 Diammonium phosphate Substances 0.000 description 3
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 3
- 229910000388 diammonium phosphate Inorganic materials 0.000 description 3
- 235000019838 diammonium phosphate Nutrition 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- JJEJDZONIFQNHG-UHFFFAOYSA-N [C+4].N Chemical compound [C+4].N JJEJDZONIFQNHG-UHFFFAOYSA-N 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 description 2
- FUFJGUQYACFECW-UHFFFAOYSA-L calcium hydrogenphosphate Chemical compound [Ca+2].OP([O-])([O-])=O FUFJGUQYACFECW-UHFFFAOYSA-L 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 210000003608 fece Anatomy 0.000 description 2
- 239000010871 livestock manure Substances 0.000 description 2
- 235000019837 monoammonium phosphate Nutrition 0.000 description 2
- 239000006012 monoammonium phosphate Substances 0.000 description 2
- 230000008635 plant growth Effects 0.000 description 2
- 239000011573 trace mineral Substances 0.000 description 2
- 235000013619 trace mineral Nutrition 0.000 description 2
- DWNBOPVKNPVNQG-LURJTMIESA-N (2s)-4-hydroxy-2-(propylamino)butanoic acid Chemical compound CCCN[C@H](C(O)=O)CCO DWNBOPVKNPVNQG-LURJTMIESA-N 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- JGIATAMCQXIDNZ-UHFFFAOYSA-N calcium sulfide Chemical compound [Ca]=S JGIATAMCQXIDNZ-UHFFFAOYSA-N 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000008034 disappearance Effects 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 230000012010 growth Effects 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 230000001863 plant nutrition Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 description 1
- 229910000165 zinc phosphate Inorganic materials 0.000 description 1
Landscapes
- Fertilizers (AREA)
Abstract
The invention relates to the field of sulfur-diammonium phosphate and provides a method of preparing sulfur-diammonium phosphate by adopting an acid tubular reactor. The method is characterized in that: raw materials containing nitrogen, phosphor, sulfur, calcium and other elements are weighed by an automatic weighing batch feeder according to a formula ratio, fed steadily into a smasher, mixed, and smashed into a material having a size not higher than 1 mm; the qualified smashed material is required to be 70% of the total materials; the material is fed into a rotor drum granulator by a conveyer belt; in the granulator, sulfuric acid and washing water, which are diluted by the acid tubular reactor, are sprayed onto the solid material in the granulator, and liquid ammonia is injected by an embedded spray tube and reacted with the sulfuric acid in the solid material in the granulator and participates in granulation; and packaging and stacking are performed finally by an automatic packaging machine and a robot stacking system. By adoption of the technical scheme, the method has characteristics of simple structure and using safety, omits a sulfuric acid diluting tank, a sulfuric acid pump, an enamel reaction kettle, and other equipment, and largely saves the equipment cost.
Description
Technical field
The present invention relates to sulphur phosphorus two ammonium fields, is a kind of method that adopts acid tube reactor to prepare sulphur phosphorus two ammoniums.
Background technology
Northern China soil generally lacks phosphorus, therefore peasant has the custom of application of phosphoric acid two ammoniums, conventionally the required phosphorus of farm crop is 8, and diammonium phosphate contains 40 more than phosphorus, excessive application of phosphoric acid two ammoniums make phosphorus content severe overweight in soil, in water-soluble phosphorus and soil, zinc reacts and produces the nonabsorbable zinc phosphate of farm crop, thus the disappearance of trace element in causing in soil, and disease and pest occurs.Sulphur phosphorus two ammoniums nitrogenous 18 that my company uses this technology to produce, phosphorous 20-26, sulfur-bearing, calcium 20-26, in general, 18-25 nitrogen are that crop growth is necessary, 20-26 phosphorus also just in time meets plant growth needs, sulphur, calcium is also the needed middle trace element of plant growth, this product can replace diammonium phosphate completely, diammonium phosphate has to the mesotrophy elements such as sulphur calcium to be rejected in order to pursue the high threshold values (industrial goods are the highest by 46%) of phosphorus, and in agriculture industrialization more and more deep today, sulphur and calcium have become increasingly the plant nutrition source that lacks.The peasant in many places has to spend high price to remove to buy the special product that supplements sulphur and calcium, has not only increased economic input, has also increased operating cost.Therefore, sulphur phosphorus two ammoniums, as a kind of relatively inexpensive polyelement composite fertilizer, also will play very important effect to the development of Chinese agriculture.
?
Summary of the invention
Object of the present invention is exactly that a kind of method that adopts acid tube reactor to prepare sulphur phosphorus two ammoniums will be provided.This method has overcome traditional propylhomoserin method and has produced that sulphur phosphorus two ammoniums are expensive, the shortcoming of high energy consumption, reduces costs to greatest extent.
Technical scheme of the present invention is: it is characterized in that by contain the pantogen such as nitrogen phosphate and sulfur, calcium material according to formula rate by the material of evenly sending into pulverizer after automatic weighing batch charger metering and carry out be broken into≤1 ㎜ of powder mix, pulverize qualified material and require to reach 70 ﹪ of total material; Material is in travelling belt enters rotary drum granulator, in tablets press, sulfuric acid and washing water are sprayed on the solid materials in tablets press after by acid tube reactor dilution, and liquefied ammonia, by burying a formula jet pipe ejection, participates in granulation with the sulfuric acid reaction in solid materials in tablets press; Prilling temperature is controlled at 65 DEG C-85 DEG C, pH value and is controlled between 5.8-6.2, and tablets press outlet material balling ratio should be in 80% left and right; Material enters dryer and dries, how many import and temperature outs are controlled according to urea content in formula, through twice cooling and three sub-sieve of a cooler, No. two coolers, particle temperature is controlled to normal temperature, the even finished particle that particle is greater than 2.5 ㎜, be less than 4.5 ㎜ sends into that finished product coating machine dyes and anti-caking processing, finally by automatic packing machine and robot palletizing system pack, piling.
Due to adopt technique scheme, have simple in structure, use safe feature, it has reduced the equipment such as sulfuric acid thinning tank, sulfuric acid pump, enamel reaction still, has greatly saved equipment cost.Present method is carried out diluting reaction by the vitriol oil and steam in acid tube reactor; sulfuric acid after dilution is above nozzle is sprayed on the tablets press bed of material; mix and react with pipe embedded typ liquefied ammonia; the chemical heat that reaction occurs is carried out granulation; material moisture is reduced; wherein temperature raising amplitude can reach 10-20 DEG C, thereby and not mainly improves and also greatly reduce energy consumption by steam.
Embodiment
Below in conjunction with embodiment, the present invention is further illustrated.
Embodiment 1: each automatic weighing batch charger opening for feed numerical value is arranged as follows: 58% monoammonium phosphate 400kg, secondary calcium phosphate 80kg, urea 127 kg, 25% dry ammonia chloride 200kg, carbon ammonium 50 kg, 99.9% SULPHUR POWDER 128kg, these raw materials are evenly sent into pulverizer and carried out the material of be broken into≤1 ㎜ of powder mix, pulverize qualified material and require to reach 70 ﹪ of total material.Material is in travelling belt enters rotary drum granulator; in tablets press; the 40 kg vitriol oils and washing water are sprayed on the solid materials in tablets press after by acid tube reactor dilution, and 25 kg liquefied ammonia, by burying a formula jet pipe ejection, participate in granulation with the sulfuric acid reaction in solid materials in tablets press.Prilling temperature is controlled at 65 DEG C-85 DEG C, pH value and is controlled between 5.8-6.2, and tablets press outlet material balling ratio should be in 80% left and right.Material enters dryer and dries, how many import and temperature outs are controlled according to urea content in formula, through twice cooling and three sub-sieve of a cooler, No. two coolers, particle temperature is controlled to normal temperature, the even finished particle that particle is greater than 2.5 ㎜, be less than 4.5 ㎜ sends into that finished product coating machine dyes and anti-caking processing, finally by automatic packing machine and robot palletizing system pack, piling.Now obtaining containing N-P2O5 is 18-20, the compound manure that moderate-element S and Ca content are 26.
Embodiment 2: each automatic weighing batch charger opening for feed numerical value is arranged as follows: 58% monoammonium phosphate 525kg, 20% secondary calcium phosphate 100kg, urea 95 kg, 25% dry ammonia chloride 200kg, carbon ammonium 50 kg, 99.9% SULPHUR POWDER 25kg, these raw materials are evenly sent into pulverizer and carried out the material of be broken into≤1 ㎜ of powder mix, pulverize qualified material and require to reach 70 ﹪ of total material.Material is in travelling belt enters rotary drum granulator; in tablets press; the 30 kg vitriol oils and washing water are sprayed on the solid materials in tablets press after by acid tube reactor dilution, and 25 kg liquefied ammonia, by burying a formula jet pipe ejection, participate in granulation with the sulfuric acid reaction in solid materials in tablets press.Prilling temperature is controlled at 65 DEG C-85 DEG C, pH value and is controlled between 5.8-6.2, and tablets press outlet material balling ratio should be in 80% left and right.Material enters dryer and dries, how many import and temperature outs are controlled according to urea content in formula, through twice cooling and three sub-sieve of a cooler, No. two coolers, particle temperature is controlled to normal temperature, the even finished particle that particle is greater than 2.5 ㎜, be less than 4.5 ㎜ sends into that finished product coating machine dyes and anti-caking processing, finally by automatic packing machine and robot palletizing system pack, piling.Now obtaining containing N-P2O5 is 18-26, the compound manure that moderate-element S and Ca content are 20.
Claims (1)
1. a method that adopts acid tube reactor to prepare sulphur phosphorus two ammoniums, it is characterized in that by contain the pantogen such as nitrogen phosphate and sulfur, calcium material according to formula rate by the material of evenly sending into pulverizer after automatic weighing batch charger metering and carry out be broken into≤1 ㎜ of powder mix, pulverize qualified material and require to reach 70 ﹪ of total material; Material is in travelling belt enters rotary drum granulator, in tablets press, sulfuric acid and washing water are sprayed on the solid materials in tablets press after by acid tube reactor dilution, and liquefied ammonia, by burying a formula jet pipe ejection, participates in granulation with the sulfuric acid reaction in solid materials in tablets press; Prilling temperature is controlled at 65 DEG C-85 DEG C, pH value and is controlled between 5.8-6.2, and tablets press outlet material balling ratio should be in 80% left and right; Material enters dryer and dries, how many import and temperature outs are controlled according to urea content in formula, through twice cooling and three sub-sieve of a cooler, No. two coolers, particle temperature is controlled to normal temperature, the even finished particle that particle is greater than 2.5 ㎜, be less than 4.5 ㎜ sends into that finished product coating machine dyes and anti-caking processing, finally by automatic packing machine and robot palletizing system pack, piling.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310162228.6A CN104140304A (en) | 2013-05-07 | 2013-05-07 | A method of preparing sulfur-diammonium phosphate by adopting an acid tubular reactor |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310162228.6A CN104140304A (en) | 2013-05-07 | 2013-05-07 | A method of preparing sulfur-diammonium phosphate by adopting an acid tubular reactor |
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| CN104140304A true CN104140304A (en) | 2014-11-12 |
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| CN201310162228.6A Pending CN104140304A (en) | 2013-05-07 | 2013-05-07 | A method of preparing sulfur-diammonium phosphate by adopting an acid tubular reactor |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107746300A (en) * | 2017-09-07 | 2018-03-02 | 龙蟒大地农业有限公司 | A kind of ammonium two-nutrient compound fertilizer of sulphur phosphorus two and the method using the ammonium two-nutrient compound fertilizer of phosphorus ammonium by-product production sulphur phosphorus two |
| CN108752097A (en) * | 2018-06-13 | 2018-11-06 | 贵阳开磷化肥有限公司 | A kind of preparation method of simple substance sulfenyl phosphorus ammonium slow-release fertilizer |
| CN113008595A (en) * | 2021-02-26 | 2021-06-22 | 中冶东方工程技术有限公司 | Robot comprehensive sampling and sample preparation system and method in metallurgical industry |
| CN115197019A (en) * | 2022-08-05 | 2022-10-18 | 安徽辉隆集团五禾生态肥业有限公司 | Special humic acid type compound fertilizer for wheat and production process and equipment thereof |
| CN115259955A (en) * | 2022-08-05 | 2022-11-01 | 安徽辉隆集团五禾生态肥业有限公司 | Potassium sulfate type compound fertilizer, preparation method and special extrusion screening pulverizer |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4134750A (en) * | 1977-07-25 | 1979-01-16 | Tennessee Valley Authority | Granular ammonium phosphate sulfate and urea-ammonium phosphate sulfate using a common pipe-cross reactor |
| CN101717289A (en) * | 2009-11-30 | 2010-06-02 | 天津芦阳化肥股份有限公司 | Method for producing Nitrogen-Phosphorus-Potassium compound fertilizer by ammonia and acid tubular reactor |
| CN101792354A (en) * | 2010-04-07 | 2010-08-04 | 中盐安徽红四方股份有限公司 | Color drought-resistance water-retention sustained-release compound fertilizer and method for producing same |
| CN102617243A (en) * | 2012-04-16 | 2012-08-01 | 瓮福（集团）有限责任公司 | Production formula of granular chloramine nitrogen fertilizer and preparation method thereof |
| CN202785661U (en) * | 2012-08-14 | 2013-03-13 | 湖北茂盛生物有限公司 | Acid tube reactor |
-
2013
- 2013-05-07 CN CN201310162228.6A patent/CN104140304A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4134750A (en) * | 1977-07-25 | 1979-01-16 | Tennessee Valley Authority | Granular ammonium phosphate sulfate and urea-ammonium phosphate sulfate using a common pipe-cross reactor |
| CN101717289A (en) * | 2009-11-30 | 2010-06-02 | 天津芦阳化肥股份有限公司 | Method for producing Nitrogen-Phosphorus-Potassium compound fertilizer by ammonia and acid tubular reactor |
| CN101792354A (en) * | 2010-04-07 | 2010-08-04 | 中盐安徽红四方股份有限公司 | Color drought-resistance water-retention sustained-release compound fertilizer and method for producing same |
| CN102617243A (en) * | 2012-04-16 | 2012-08-01 | 瓮福（集团）有限责任公司 | Production formula of granular chloramine nitrogen fertilizer and preparation method thereof |
| CN202785661U (en) * | 2012-08-14 | 2013-03-13 | 湖北茂盛生物有限公司 | Acid tube reactor |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107746300A (en) * | 2017-09-07 | 2018-03-02 | 龙蟒大地农业有限公司 | A kind of ammonium two-nutrient compound fertilizer of sulphur phosphorus two and the method using the ammonium two-nutrient compound fertilizer of phosphorus ammonium by-product production sulphur phosphorus two |
| CN107746300B (en) * | 2017-09-07 | 2021-08-13 | 龙蟒大地农业有限公司 | Sulfur-phosphorus-diammonium binary compound fertilizer and method for producing sulfur-phosphorus-diammonium binary compound fertilizer by utilizing phosphorus-ammonium byproduct |
| CN108752097A (en) * | 2018-06-13 | 2018-11-06 | 贵阳开磷化肥有限公司 | A kind of preparation method of simple substance sulfenyl phosphorus ammonium slow-release fertilizer |
| CN113008595A (en) * | 2021-02-26 | 2021-06-22 | 中冶东方工程技术有限公司 | Robot comprehensive sampling and sample preparation system and method in metallurgical industry |
| CN115197019A (en) * | 2022-08-05 | 2022-10-18 | 安徽辉隆集团五禾生态肥业有限公司 | Special humic acid type compound fertilizer for wheat and production process and equipment thereof |
| CN115259955A (en) * | 2022-08-05 | 2022-11-01 | 安徽辉隆集团五禾生态肥业有限公司 | Potassium sulfate type compound fertilizer, preparation method and special extrusion screening pulverizer |
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Application publication date: 20141112 |