CN104130675A - Scraping-resistant UV matt varnish applied to matt membranes and preparation method thereof - Google Patents
Scraping-resistant UV matt varnish applied to matt membranes and preparation method thereof Download PDFInfo
- Publication number
- CN104130675A CN104130675A CN201410372189.7A CN201410372189A CN104130675A CN 104130675 A CN104130675 A CN 104130675A CN 201410372189 A CN201410372189 A CN 201410372189A CN 104130675 A CN104130675 A CN 104130675A
- Authority
- CN
- China
- Prior art keywords
- mute
- resistant
- parts
- scratch
- oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The invention relates to the field of matt varnish, and especially relates to scraping-resistant UV matt varnish applied to matt membranes and a preparation method thereof. The scraping-resistant UV matt varnish applied to matt membranes consists of, in parts by weight, 5-15 parts of epoxy acrylic resin, 20-35 parts of modified acrylic resin, 50-65 parts of an acrylic acid monomer, 10-15 parts of a photoinitiator, 5-15 parts of a matting agent, and 1-5 parts of an auxiliary agent. The preparation method comprises: a, adding the acrylic acid monomer and the matting agent into a stirring pot to pre-disperse, and mixing uniformly with stirring; b, continuing to add epoxy acrylic resin, modified acrylic resin, the acrylic acid monomer, the photoinitiator and the auxiliary agent into the stirring pot, and mixing uniformly with stirring to prepare a varnish material; and c, filtering the varnish material, so as to obtain the matt varnish. The scraping-resistant UV matt varnish has relatively good scraping resistance when applied to matt membranes, and is fine in handfeel, low in matt degree, excellent in visual effect, excellent in adhesive force and excellent in wear resistance.
Description
Technical field
The present invention relates to the mute oil tech of UV field, relate in particular to a kind of mute oil of scratch-resistant UV for mute film and preparation method thereof.
Background technology
Along with social development, nowadays people to the appearance effect of paper product, for example the requirement of dumb light effect is more and more higher, and because the mute oil of UV is because of features such as its special dumb light effect, levelling property is good, soft handles, be widely used in all kinds of packing producer.Yet; the current mute oil of UV on the market; the flatting silica that mostly adds inorganic silicon dioxide type; when this type of inorganic flatting silica particle diameter is larger, flatting efficiency is better; when dried coating film, the molecule of aerosil can form the reflection acquisition delustring outward appearance that slightly rough surface reduces light in film coated surface; the inorganic flatting silica of this class is just filled in coating the inside; do not participate in reaction; under external force; be easy to be scraped; show scratch-resistant performance not good, use in addition on mute film sticking power also not good.Therefore, the above problem is urgently to be resolved hurrily.
Summary of the invention
The object of the invention is to for the deficiencies in the prior art, and a kind of mute oil of scratch-resistant UV for mute film and preparation method thereof is provided, the mute oily scratch-resistant of this UV is good, strong adhesion, mute degree is low, visual effect is good.
The present invention is achieved through the following technical solutions.
For the mute oil of scratch-resistant UV of mute film, it is comprised of the component of following weight part:
Epoxy acrylic resin 5-15 part
Modified acroleic acid resinoid 20-35 part
Acrylic monomer 50-65 part
Light trigger 10-15 part
Matting agent 5-15 part
Auxiliary agent 1-5 part.
Preferably, a kind of mute oil of scratch-resistant UV for mute film, it is comprised of the component of following weight part:
Epoxy acrylic resin 8-12 part
Modified acroleic acid resinoid 25-30 part
Acrylic monomer 55-60 part
Light trigger 12-14 part
Matting agent 8-12 part
Auxiliary agent 2-4 part.
More preferred, a kind of mute oil of scratch-resistant UV for mute film, it is comprised of the component of following weight part:
10 parts of epoxy acrylic resins
28 parts of modified acroleic acid resinoids
56 parts of acrylic monomers
13 parts of light triggers
10 parts of matting agents
3 parts of auxiliary agents.
Wherein, described matting agent is the organic matting agent that contains carbon-carbon double bond and active methylol.This organic matting agent is the organic polymer that the model of U.S. Albemarle Corporation is M5, the M5 organic polymer of the refined treasured of the U.S. is a kind of fluffy powder of porousness with high-specific surface area, low bulk density, it is the granule that the ultimate particle that is 0.1-0.15um by median size is gathered into about 5-9um, make it have higher void content and extremely inhomogeneous size distribution, thereby it possesses excellent extinction effect, simultaneously it also tool have the following advantages: not thickening, very little to the viscosity of coating and flowability affects, easily disperse; Except being suitable for solvent-based system, be also particularly suitable for water-based system; High (the refractive index D of transparency
20=1.607) do not absorb ultraviolet ray, be particularly suitable for UV curing system; The soft suitable order of paint film, flexible, and have soft hand feel, be suitable for the application of leatherware and internal decoration of car; To the sticking power of paint film, snappiness, scratch resistance, wear-resistingly have substantial help.0.6% the active methylol containing in the M5 organic polymer of the refined treasured of the U.S. can participate in crosslinked in the process of coating resin film forming, promote paint film contraction to be gathered into even concavo-convex surface and produce delustring, also hardness and the attrition resistance of paint film have been strengthened simultaneously, the scratch-resistant performance that has greatly improved the mute oil of UV, flatting efficiency is high.
Wherein, epoxy acrylic resin is the bisphenol-A epoxy acrylic resin that the model of Dongguan Hong Shi functional materials Science and Technology Ltd. is OG4705K3, it is as main body filmogen, has greatly improved wear resistance and the glossiness of the film body that the mute oil of scratch-resistant UV forms after ultraviolet light polymerization; Acrylic resin modified is modified polyurethane acrylic resin, it is as filmogen, has greatly improved sticking power and the snappiness of the film body that the mute oil of scratch-resistant UV forms after ultraviolet light polymerization.
Wherein, described acrylic monomer is 1, any one in 6 hexanediyl esters, tripropylene glycol diacrylate, Viscoat 295, or be 1, any two kinds of ratios in 1-3:2-4 in 6 hexanediyl esters, tripropylene glycol diacrylate, Viscoat 295 are mixed the mixture forming, or be that 1,6 hexanediyl ester, tripropylene glycol diacrylate, Viscoat 295 three mix the mixture forming in the ratio of 2-4:1-3:1-2.The adjustable system viscosity of acrylic monomer, improves laser curing velocity.
Wherein, described light trigger is the mixture of any one or a few and tertiary amine aided initiating in benzophenone, 2-hydroxy-2-methyl-1-phenyl-acetone, 1-hydroxy cyclohexyl phenylketone or 2,4,6-trimethylbenzoyl-diphenyl phosphine oxide.The ultraviolet ray that light trigger can absorb high voltage mercury lamp radiation forms free radical or positively charged ion, cause acrylic monomer and acrylic resin generation polymerization and crosslinking reaction, in the very short time, solidify to form the high molecular polymer of tridimensional network, the organic matting agent polymkeric substance of this polymkeric substance and gloss oil the inside becomes painting membranaceous, is attached to paper surface, the mute oil of this scratch-resistant UV be coated on paper, have well impermeable, glossiness is high, fullness ratio is good, and sticking power is fine, practical.
Benzophenone belongs to hydrogen-capture-type light initiator, after hydrogen-capture-type light initiator molecular absorption luminous energy, through excite and be between alter and jump to excited triplet state, with the tertiary amine aided initiating generation bimolecular effect as hydrogen donor, through transfer transport, produce living radical, and then cause oligopolymer or reactive thinner crosslinking polymerization.Tertiary amine aided initiating consistency is good, and active high, xanthochromia is low, and smell is low, and pungency is little, and efficiency is high, and can not move.
Wherein, described auxiliary agent is flow agent and defoamer, the silicone antifoam agent of Huo Digao company of defoamer Wei Bike company, the organosilicon flow agent of flow agent Wei Digao company.
The preparation method of the above-mentioned mute oil of scratch-resistant UV for mute film, it comprises following preparation process:
A, acrylic monomer is divided into two portions, by a part of acrylic monomer, matting agent add by weight in agitator kettle, carry out pre-dispersed, mixing and stirring;
B, continue to add by weight epoxy acrylic resin, modified acroleic acid resinoid, another part acrylic monomer, light trigger and auxiliary agent in agitator kettle again, mixing and stirring, makes oil plant;
C, oil plant is filtered with 320 object filter bags, make the mute oil of scratch-resistant UV for mute film.
Wherein, in step a, the rotating speed of stirring is 700-900r/min, and the time of stirring is 25-35min; In step b, the rotating speed of stirring is 700-900r/min, and the time of stirring is 80-100min.
Beneficial effect of the present invention is: the mute oil of scratch-resistant UV for mute film of the present invention is a kind of roller coat printing UV oil polish, main by absorbing UV-light generation polymerization crosslinking reaction formation high molecular polymer, and by adding the organic matting agent that can participate in reaction, a little two key and active methylol that this organic matting agent contains can participate in crosslinked in the process of coating resin film forming, when ultraviolet light polymerization directly with acrylic resin together with monomer crosslinked, the scratch-resistant performance that has greatly improved the mute oil of UV, flatting efficiency is high; In addition, the present invention, by adding modified acroleic acid resinoid, has improved the sticking power of the mute oil of UV greatly.To sum up, the mute oil of scratch-resistant UV of the present invention is printed on the advantage such as have preferably scratch-resistant performance on mute film, feel is fine and smooth, mute degree is low, visual effect is good, sticking power is good, wear resistance is good.
Preparation method of the present invention is simple, and production efficiency is high, is suitable for large-scale production.
Embodiment
Below in conjunction with embodiment, the present invention is further illustrated.
embodiment 1.
The preparation method of the mute oil of scratch-resistant UV for mute film of the present embodiment, comprises following preparation process:
A, by 39 part of 1,6 hexanediyl ester, 15 parts of organic matting agents add in agitator kettle, carry out pre-dispersed, mixing and stirring, the rotating speed of stirring is 700r/min, the time of stirring is 35min;
B, continue to add 5 parts of bisphenol-A epoxy acrylic resins, 35 parts of modified polyurethane acrylic resins, 26 parts of tripropylene glycol diacrylates, 3 parts of benzophenone, 4 parts of tertiary amine aided initiatings, 4 parts of 2-hydroxy-2-methyl-1-phenyl-acetones, 4 parts of 1-hydroxy cyclohexyl phenylketones, 2 parts of organosilicon flow agents, 3 parts of silicone antifoam agents in agitator kettle again, mixing and stirring, the rotating speed stirring is 900r/min, the time of stirring is 80min, makes oil plant;
C, oil plant is filtered with 320 object filter bags, make the mute oil of scratch-resistant UV for mute film.
embodiment 2.
The preparation method of the mute oil of scratch-resistant UV for mute film of the present embodiment, comprises following preparation process:
A, by 20 part of 1,6 hexanediyl ester, 12 parts of organic matting agents add in agitator kettle, carry out pre-dispersed, mixing and stirring, the rotating speed of stirring is 750r/min, the time of stirring is 32min;
B, again continue to add in agitator kettle 8 parts of bisphenol-A epoxy acrylic resins, 30 parts of modified polyurethane acrylic resins, 40 parts of tripropylene glycol diacrylates, 2 parts of benzophenone, 5 parts of tertiary amine aided initiatings, 3 parts of 2-hydroxy-2-methyl-1-phenyl-acetones, 4 part 2,4,6-trimethylbenzoyl-diphenyl phosphine oxide, 2 parts of organosilicon flow agents, 2 parts of silicone antifoam agents, mixing and stirring, the rotating speed stirring is 850r/min, the time of stirring is 85min, makes oil plant;
C, oil plant is filtered with 320 object filter bags, make the mute oil of scratch-resistant UV for mute film.
embodiment 3.
The preparation method of the mute oil of scratch-resistant UV for mute film of the present embodiment, comprises following preparation process:
A, by 24 part of 1,6 hexanediyl ester, 10 parts of organic matting agents add in agitator kettle, carry out pre-dispersed, mixing and stirring, the rotating speed of stirring is 800r/min, the time of stirring is 30min;
B, again continue to add in agitator kettle 10 parts of bisphenol-A epoxy acrylic resins, 28 parts of modified polyurethane acrylic resins, 32 parts of tripropylene glycol diacrylates, 3 parts of benzophenone, 3 parts of tertiary amine aided initiatings, 3 parts of 1-hydroxy cyclohexyl phenylketones, 4 part 2,4,6-trimethylbenzoyl-diphenyl phosphine oxide, 1 part of organosilicon flow agent, 2 parts of silicone antifoam agents, mixing and stirring, the rotating speed stirring is 800r/min, the time of stirring is 90min, makes oil plant;
C, oil plant is filtered with 320 object filter bags, make the mute oil of scratch-resistant UV for mute film.
embodiment 4.
The preparation method of the mute oil of scratch-resistant UV for mute film of the present embodiment, comprises following preparation process:
A, by 22 part of 1,6 hexanediyl ester, 22 parts of tripropylene glycol diacrylates, 8 parts of organic matting agents add in agitator kettle, carry out pre-dispersed, mixing and stirring, the rotating speed of stirring is 850r/min, the time of stirring is 28min;
B, again continue to add in agitator kettle 12 parts of bisphenol-A epoxy acrylic resins, 25 parts of modified polyurethane acrylic resins, 11 parts of Viscoat 295s, 2 parts of benzophenone, 3 parts of 2-hydroxy-2-methyl-1-phenyl-acetones, 2 parts of 1-hydroxy cyclohexyl phenylketones, 5 part 2,4,6-trimethylbenzoyl-diphenyl phosphine oxide, 1 part of organosilicon flow agent, 1 part of silicone antifoam agent, mixing and stirring, the rotating speed stirring is 750r/min, the time of stirring is 95min, makes oil plant;
C, oil plant is filtered with 320 object filter bags, make the mute oil of scratch-resistant UV for mute film.
embodiment 5.
The preparation method of the mute oil of scratch-resistant UV for mute film of the present embodiment, comprises following preparation process:
A, by 30 part of 1,6 hexanediyl ester, 10 parts of Viscoat 295s, 5 parts of organic matting agents add in agitator kettle, carry out pre-dispersed, mixing and stirring, the rotating speed of stirring is 900r/min, the time of stirring is 25min;
B, again continue to add in agitator kettle 15 parts of bisphenol-A epoxy acrylic resins, 20 parts of modified polyurethane acrylic resins, 10 parts of tripropylene glycol diacrylates, 2 part 2,4,6-trimethylbenzoyl-diphenyl phosphine oxide, 3 parts of tertiary amine aided initiatings, 2 parts of 2-hydroxy-2-methyl-1-phenyl-acetones, 3 parts of 1-hydroxy cyclohexyl phenylketones, 0.5 part of organosilicon flow agent, 0.5 part of silicone antifoam agent, mixing and stirring, the rotating speed stirring is 700r/min, the time of stirring is 100min, makes oil plant;
C, oil plant is filtered with 320 object filter bags, make the mute oil of scratch-resistant UV for mute film.
The performance detection data of the mute oil of scratch-resistant UV for mute film that embodiments of the invention 1 ~ embodiment 5 makes is in Table 1.
Table 1
As can be seen from Table 1, the mute oil of scratch-resistant UV for mute film that embodiments of the invention 1 ~ embodiment 5 makes, the advantages such as its wear resistance is good, strong adhesion, mute degree is low, sense of touch is fine and smooth, curing speed is fast, quality product is good, and use properties is good, and marketing degree is high.
Finally should be noted that; above embodiment is only in order to illustrate technical scheme of the present invention; but not limiting the scope of the invention; although the present invention has been done to explain with reference to preferred embodiment; those of ordinary skill in the art is to be understood that; can modify or be equal to replacement technical scheme of the present invention, and not depart from essence and the scope of technical solution of the present invention.
Claims (10)
1. for the mute oil of scratch-resistant UV of mute film, it is characterized in that: it is comprised of the component of following weight part:
Epoxy acrylic resin 5-15 part
Modified acroleic acid resinoid 20-35 part
Acrylic monomer 50-65 part
Light trigger 10-15 part
Matting agent 5-15 part
Auxiliary agent 1-5 part.
2. a kind of mute oil of scratch-resistant UV for mute film according to claim 1, is characterized in that: it is comprised of the component of following weight part:
Epoxy acrylic resin 8-12 part
Modified acroleic acid resinoid 25-30 part
Acrylic monomer 55-60 part
Light trigger 12-14 part
Matting agent 8-12 part
Auxiliary agent 2-4 part.
3. a kind of mute oil of scratch-resistant UV for mute film according to claim 1, is characterized in that: it is comprised of the component of following weight part:
10 parts of epoxy acrylic resins
28 parts of modified acroleic acid resinoids
56 parts of acrylic monomers
13 parts of light triggers
10 parts of matting agents
3 parts of auxiliary agents.
4. a kind of mute oil of scratch-resistant UV for mute film according to claim 1, is characterized in that: described matting agent is the organic matting agent that contains carbon-carbon double bond and active methylol.
5. a kind of mute oil of scratch-resistant UV for mute film according to claim 1, is characterized in that: epoxy acrylic resin is the bisphenol-A epoxy acrylic resin that the model of Dongguan Hong Shi functional materials Science and Technology Ltd. is OG4705K3; Modified acroleic acid resinoid is modified polyurethane acrylic resin.
6. a kind of mute oil of scratch-resistant UV for mute film according to claim 1, it is characterized in that: described acrylic monomer is 1, 6 hexanediyl esters, tripropylene glycol diacrylate, any one in Viscoat 295, or be 1, 6 hexanediyl esters, tripropylene glycol diacrylate, any two kinds of ratios in 1-3:2-4 in Viscoat 295 are mixed the mixture forming, or be 1, 6 hexanediyl esters, tripropylene glycol diacrylate, Viscoat 295 three mixes the mixture forming in the ratio of 2-4:1-3:1-2.
7. a kind of mute oil of scratch-resistant UV for mute film according to claim 1; it is characterized in that: described light trigger is benzophenone, 2-hydroxy-2-methyl-1-phenyl-acetone, 1-hydroxy cyclohexyl phenylketone or 2; the mixture of any one or a few in 4,6-trimethylbenzoyl-diphenyl phosphine oxide and tertiary amine aided initiating.
8. a kind of mute oil of scratch-resistant UV for mute film according to claim 1, is characterized in that: described auxiliary agent is flow agent and defoamer the silicone antifoam agent of Huo Digao company of defoamer Wei Bike company, the organosilicon flow agent of flow agent Wei Digao company.
9. the preparation method of a kind of mute oil of scratch-resistant UV for mute film described in claim 1-8 any one, is characterized in that: it comprises following preparation process:
A, acrylic monomer is divided into two portions, by a part of acrylic monomer, matting agent add by weight in agitator kettle, carry out pre-dispersed, mixing and stirring;
B, continue to add by weight epoxy acrylic resin, modified acroleic acid resinoid, another part acrylic monomer, light trigger and auxiliary agent in agitator kettle again, mixing and stirring, makes oil plant;
C, oil plant is filtered with 320 object filter bags, make the mute oil of scratch-resistant UV for mute film.
10. the preparation method of a kind of mute oil of scratch-resistant UV for mute film according to claim 9, is characterized in that: in step a, the rotating speed of stirring is 700-900r/min, and the time of stirring is 25-35min; In step b, the rotating speed of stirring is 700-900r/min, and the time of stirring is 80-100min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410372189.7A CN104130675B (en) | 2014-07-31 | 2014-07-31 | A kind of mute oil of scratch-resistant UV for mute film and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410372189.7A CN104130675B (en) | 2014-07-31 | 2014-07-31 | A kind of mute oil of scratch-resistant UV for mute film and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104130675A true CN104130675A (en) | 2014-11-05 |
| CN104130675B CN104130675B (en) | 2016-10-19 |
Family
ID=51803539
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410372189.7A Expired - Fee Related CN104130675B (en) | 2014-07-31 | 2014-07-31 | A kind of mute oil of scratch-resistant UV for mute film and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104130675B (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104442061A (en) * | 2014-12-29 | 2015-03-25 | 东莞市卓艺印刷制品有限公司 | Transfer film with UV (ultraviolet) coating layer |
| CN105176429A (en) * | 2015-07-14 | 2015-12-23 | 潮安新纪源实业有限公司 | Anti-wear matt pre-coating film, preparation method and applications thereof |
| CN110757973A (en) * | 2019-11-11 | 2020-02-07 | 保定永丽印务有限公司 | Kraft paper suitable for low-temperature printing and black card flat screen printing process |
| CN110964250A (en) * | 2019-12-06 | 2020-04-07 | 东莞市美盈森环保科技有限公司 | Wear-resistant matte glue silk-screen UV color box powder falling prevention method |
| CN111205686A (en) * | 2020-03-19 | 2020-05-29 | 上海扬盛印务有限公司 | Low-odor UV matte oil and printing process |
| CN111205699A (en) * | 2020-02-28 | 2020-05-29 | 上海超彩油墨有限公司 | UV matte ink for gloss oil surface and preparation method thereof |
| CN114773932A (en) * | 2022-04-29 | 2022-07-22 | 北京金印联国际供应链管理有限公司 | Environment-friendly water-based matt varnish replacing film laminating process and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101638554A (en) * | 2009-05-06 | 2010-02-03 | 佛山市顺德区希贵光固化材料有限公司 | Ultraviolet curing coating |
| CN102229779A (en) * | 2011-06-20 | 2011-11-02 | 上虞市佑谦特种材料有限公司 | UV (Ultraviolent) deglossing paint and preparation method thereof |
| CN102964969A (en) * | 2012-11-14 | 2013-03-13 | 京东方科技集团股份有限公司 | Ultraviolet curing light oil and preparation method and curing method thereof as well as touch screen |
| CN103555186A (en) * | 2013-09-30 | 2014-02-05 | 上海维凯化学品有限公司 | Matte ultraviolet-curing coating composition used for PET (polyethylene terephthalate) metal-imitating wire drawing film |
-
2014
- 2014-07-31 CN CN201410372189.7A patent/CN104130675B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101638554A (en) * | 2009-05-06 | 2010-02-03 | 佛山市顺德区希贵光固化材料有限公司 | Ultraviolet curing coating |
| CN102229779A (en) * | 2011-06-20 | 2011-11-02 | 上虞市佑谦特种材料有限公司 | UV (Ultraviolent) deglossing paint and preparation method thereof |
| CN102964969A (en) * | 2012-11-14 | 2013-03-13 | 京东方科技集团股份有限公司 | Ultraviolet curing light oil and preparation method and curing method thereof as well as touch screen |
| CN103555186A (en) * | 2013-09-30 | 2014-02-05 | 上海维凯化学品有限公司 | Matte ultraviolet-curing coating composition used for PET (polyethylene terephthalate) metal-imitating wire drawing film |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104442061A (en) * | 2014-12-29 | 2015-03-25 | 东莞市卓艺印刷制品有限公司 | Transfer film with UV (ultraviolet) coating layer |
| CN105176429A (en) * | 2015-07-14 | 2015-12-23 | 潮安新纪源实业有限公司 | Anti-wear matt pre-coating film, preparation method and applications thereof |
| CN110757973A (en) * | 2019-11-11 | 2020-02-07 | 保定永丽印务有限公司 | Kraft paper suitable for low-temperature printing and black card flat screen printing process |
| CN110964250A (en) * | 2019-12-06 | 2020-04-07 | 东莞市美盈森环保科技有限公司 | Wear-resistant matte glue silk-screen UV color box powder falling prevention method |
| CN111205699A (en) * | 2020-02-28 | 2020-05-29 | 上海超彩油墨有限公司 | UV matte ink for gloss oil surface and preparation method thereof |
| CN111205686A (en) * | 2020-03-19 | 2020-05-29 | 上海扬盛印务有限公司 | Low-odor UV matte oil and printing process |
| CN114773932A (en) * | 2022-04-29 | 2022-07-22 | 北京金印联国际供应链管理有限公司 | Environment-friendly water-based matt varnish replacing film laminating process and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104130675B (en) | 2016-10-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104130675A (en) | Scraping-resistant UV matt varnish applied to matt membranes and preparation method thereof | |
| CN102964918B (en) | Water-based UV plastic silk-screen printing ink and preparation method thereof | |
| CN106978062A (en) | It is a kind of for skid resistant course of sheet material and preparation method thereof | |
| CN104213465B (en) | Refreshing UV paper gloss oil of release effect, superslide and preparation method thereof is had after a kind of UV ultraviolet light polymerization | |
| CN104179065B (en) | A kind of impermeable UV silk-screen paper gloss oil and preparation method thereof | |
| CN104789039A (en) | Endogenous frosting-effect glass ink and method for producing frosting-effect product by utilizing same | |
| CN104830148A (en) | Environment-friendly UV curing silk screen ink and production method thereof | |
| CN107245299A (en) | A kind of aqueous light diffusion coating and its production and use | |
| CN101591484A (en) | A kind of photocureable coating for pianos | |
| CN104087127A (en) | Ultraviolet curing antique roller coating matt base coat and preparation method thereof | |
| CN104004444B (en) | A kind of unsaturated polyester varnish and using method thereof | |
| CN106634761A (en) | Ultraviolet-light curing composition and master pattern preparation method | |
| CN108384406A (en) | A kind of graphene oxide UV is coating material solidified and preparation method thereof | |
| CN106592327B (en) | Water and mist preventing UV antiseptic varnish composition and its method for preparation | |
| CN104073040A (en) | UV-cured white curtaining paint and preparation method thereof | |
| CN108084900A (en) | Two-dimensional code film and preparation process thereof | |
| CN102964981A (en) | A kind of water-based UV printing iron varnish and preparation method thereof | |
| CN109666384A (en) | A kind of printing reverse droplet formula gloss oil and printing process | |
| CN104017487B (en) | Ultraviolet light cured burnished paint | |
| CN102807814B (en) | Nano silica-modified recoatable ultraviolet (UV) varnish used on plastic and preparation method for varnish | |
| CN108795271B (en) | A kind of UV LED UV-curable waterborne paint of wooden floor and preparation method thereof | |
| CN102146228A (en) | UV (Ultra Voilet) radiation curing coating matched with waterborne primer and production and using methods thereof | |
| CN108003823A (en) | A kind of preparation method that may extend away cured UV-LED cationic curings adhesive | |
| CN106634296A (en) | Special water-based single-component matte white finishing paint for UV white ground and preparation method of special water-based single-component matte white finishing paint | |
| CN107556901B (en) | A kind of release layer formula of size and preparation method thereof for synthetic leather release film |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20161019 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |