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CN104128979B - A kind of rattan containing Folium Zanthoxyli Bungeani modified soak and using method thereof - Google Patents

A kind of rattan containing Folium Zanthoxyli Bungeani modified soak and using method thereof Download PDF

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Publication number
CN104128979B
CN104128979B CN201410287551.0A CN201410287551A CN104128979B CN 104128979 B CN104128979 B CN 104128979B CN 201410287551 A CN201410287551 A CN 201410287551A CN 104128979 B CN104128979 B CN 104128979B
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rattan
soak
zanthoxyli bungeani
folium zanthoxyli
water
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CN104128979A (en
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李永兴
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Funan Yongxing Crafts Co ltd
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FU'NAN YONGXING ARTS & CRAFTS Co Ltd
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Abstract

本发明涉及编织工艺品用材料改性处理领域,具体涉及一种含花椒叶的藤条用改性浸泡液及其使用方法,其组成原料的重量份为:油酸2-3、十二烷基苯磺酸钠2-4、碳酸钠15-18、硼酸钾6-8、茶多酚0.2-0.3、花椒叶3-4、月桂酰肌氨酸钠4-6、水250-280、助剂4-5;本发明制备的浸泡液不含挥发性毒性有机物成分,不污染使用环境,碳酸钠、硼酸钾、茶多酚等成分渗透入纤维质后,能够有效的软化材质,达到增韧、阻燃、保鲜等功效,花椒叶中生物活性成分有良好的防腐效果,还能防止虫蛀,延长藤条使用寿命,浸泡处理后的藤条更易加工成型,省时高效,得到的产品不易霉腐变质,安全耐热,使用寿命长。The invention relates to the field of material modification treatment for weaving handicrafts, in particular to a modified soaking liquid for rattan containing pepper leaves and a method for using the same. Sodium benzenesulfonate 2-4, sodium carbonate 15-18, potassium borate 6-8, tea polyphenols 0.2-0.3, pepper leaves 3-4, sodium lauroyl sarcosinate 4-6, water 250-280, additives 4-5; The soaking solution prepared by the present invention does not contain volatile toxic organic components, and does not pollute the use environment. After components such as sodium carbonate, potassium borate, and tea polyphenols penetrate into the fiber, they can effectively soften the material, achieving toughness, Flame-retardant, fresh-keeping and other effects, the biologically active ingredients in the pepper leaves have good anti-corrosion effects, can also prevent moths, prolong the life of the rattan, the soaked rattan is easier to process and shape, saves time and high efficiency, and the obtained products are not easy to mold Corrosion, safety and heat resistance, long service life.

Description

一种含花椒叶的藤条用改性浸泡液及其使用方法Modified soaking solution for rattan containing prickly ash leaves and using method thereof

技术领域 technical field

本发明涉及编织工艺品用材料改性处理领域,具体涉及一种含花椒叶的藤条用改性浸泡液及其使用方法。 The invention relates to the field of material modification treatment for weaving handicrafts, in particular to a modified soaking liquid for rattan containing prickly ash leaves and a use method thereof.

背景技术 Background technique

藤条、柳条、竹条、各类秸秆等天然编制材料制作的工艺品具有极高的观赏和实用价值,产品远销国内外,极受消费者喜爱,市场潜力巨大。由于它们的生物特质,存在易燃、易裂、易虫蛀腐烂等缺点,在实际使用过程中需要进行一系列的改性处理,以改善其力学性能和理化性质,使其更易加工和运输储存,提高观赏价值和实用性能,常用的处理手段是采用改性液对材料浸泡处理,因此,改性液的配制尤为重要,理想的改性液需要具备环保无毒、改性效果持久、不影响美观等特点。 Handicrafts made of rattan, wicker, bamboo, various straw and other natural weaving materials have high ornamental and practical value. The products are sold at home and abroad, are very popular with consumers, and have a huge market potential. Due to their biological characteristics, there are disadvantages such as flammability, cracking, and insect-eaten decay. In actual use, a series of modification treatments are required to improve their mechanical properties and physical and chemical properties, making them easier to process, transport and store. , to improve the ornamental value and practical performance, the commonly used treatment method is to use the modified liquid to soak the material. Therefore, the preparation of the modified liquid is particularly important. beautiful features.

发明内容 Contents of the invention

本发明目的在于提供一种含花椒叶的藤条用改性浸泡液及其使用方法,以改善藤条的使用性能,增进实用价值,为了实现上述目的,本发明采用的技术方案如下: The object of the present invention is to provide a modified soaking liquid for rattan containing prickly ash leaves and a method of use thereof, so as to improve the performance of the rattan and increase the practical value. In order to achieve the above object, the technical scheme adopted in the present invention is as follows:

一种含花椒叶的藤条用改性浸泡液及其使用方法,其特征在于,该浸泡液由以下重量份的原料制成:油酸2-3、十二烷基苯磺酸钠2-4、碳酸钠15-18、硼酸钾6-8、茶多酚0.2-0.3、花椒叶3-4、月桂酰肌氨酸钠4-6、水250-280、助剂4-5; A modified soaking solution for rattan containing prickly ash leaves and its use method, characterized in that the soaking solution is made of the following raw materials in parts by weight: oleic acid 2-3, sodium dodecylbenzenesulfonate 2- 4. Sodium carbonate 15-18, potassium borate 6-8, tea polyphenols 0.2-0.3, pepper leaves 3-4, sodium lauroyl sarcosinate 4-6, water 250-280, additives 4-5;

助剂由以下重量份的原料制成:聚甲基丙烯酸8-10、水合硫酸铝4-5、硫酸氧钛1-2、黄酒15-18、杨梅果渣2-4、乙酰化二淀粉磷酸酯6-8,其制备方法为:先将杨梅果渣放入5倍其重量份的水中,煎煮1-1.5h,过滤,所得滤液冷却后加入聚甲基丙烯酸、水合硫酸铝、硫酸氧钛,搅拌,再加入其它剩余物料,继续搅拌溶解分散40-50min,即得助剂。 The auxiliary agent is made of the following raw materials in parts by weight: polymethacrylic acid 8-10, aluminum sulfate hydrate 4-5, titanium oxysulfate 1-2, rice wine 15-18, red bayberry pomace 2-4, acetylated distarch phosphoric acid Esters 6-8, the preparation method of which is as follows: first put red bayberry pomace into water with 5 times its weight part, decoct for 1-1.5h, filter, add polymethacrylic acid, aluminum sulfate hydrate, oxygen sulfate after cooling the obtained filtrate Titanium, stir, then add other remaining materials, continue stirring to dissolve and disperse for 40-50 minutes, and then the additives are obtained.

所述的一种含花椒叶的藤条用改性浸泡液及其使用方法,其制备方法为:先将花椒叶洗净,投入水中,煎煮40-50min,过滤,滤液冷却至50-60℃时,加入十二烷基苯磺酸钠、碳酸钠、硼酸钾、茶多酚,搅拌至混合物料完全溶解后,再加入其它剩余成分,继续搅拌40-50min,即得浸泡液。 The modified soaking liquid for rattan containing Zanthoxylum bungeanum leaves and its use method, the preparation method is: first wash the Zanthoxylum bungeanum leaves, put them into water, decoct for 40-50min, filter, and cool the filtrate to 50-60 At ℃, add sodium dodecylbenzenesulfonate, sodium carbonate, potassium borate, and tea polyphenols, stir until the mixture is completely dissolved, then add other remaining ingredients, and continue stirring for 40-50 minutes to obtain the soaking solution.

所述的一种含花椒叶的藤条用改性浸泡液及其使用方法,其使用方法为:将预处理后的藤条完全没入上述浸泡液中,加热至50-60℃,保温密闭浸泡20-24h,取出清水洗净自然晾干或烘干均可。 The modified soaking solution for rattan containing pepper leaves and its use method are as follows: completely immerse the pretreated rattan into the above soaking solution, heat to 50-60°C, heat-preserve and airtightly soak After 20-24 hours, take out the water and wash it and dry it naturally or dry it.

本发明的浸泡液优点在于:其采用的原料均为环保成分,不含挥发性毒性有机物成分,不污染使用环境;原料中的碳酸钠、硼酸钾、茶多酚等有效成分经过长时间浸泡渗透入纤维质后,能够有效的软化材质,达到增韧、阻燃、保鲜等功效,花椒叶中生物活性成分有良好的防腐效果,还能防止虫蛀,延长藤条使用寿命,本发明浸泡液制备方法及使用方法简单,化学性能稳定,废液回收处理简单,浸泡处理后的藤条更易加工成型,省时高效,得到的产品不易霉腐变质,安全耐热,使用寿命长。 The soaking solution of the present invention has the advantages that: the raw materials used are all environmentally friendly ingredients, do not contain volatile toxic organic components, and do not pollute the use environment; active ingredients such as sodium carbonate, potassium borate, and tea polyphenols in the raw materials are soaked and infiltrated for a long time After entering the fiber, it can effectively soften the material to achieve the effects of toughening, flame retardancy, and freshness preservation. The biologically active ingredients in the pepper leaves have a good antiseptic effect, can prevent insects, and prolong the service life of the rattan. The soaking solution of the present invention The preparation method and the use method are simple, the chemical properties are stable, the waste liquid recovery and treatment are simple, the rattan after soaking treatment is easier to process and shape, saves time and high efficiency, and the obtained product is not easy to be moldy and deteriorated, safe and heat-resistant, and has a long service life.

具体实施方式 detailed description

实施例 Example

本实施例的浸泡液由以下重量份(公斤)的原料制得:油酸2、十二烷基苯磺酸钠4、碳酸钠18、硼酸钾6、茶多酚0.2、花椒叶4、月桂酰肌氨酸钠6、水280、助剂5;助剂由下列重量份的原料制成:聚甲基丙烯酸8、水合硫酸铝4、硫酸氧钛1、黄酒18、杨梅果渣3、乙酰化二淀粉磷酸酯8,其制备方法为:先将杨梅果渣放入5倍其重量份的水中,煎煮1.5h,过滤,所得滤液冷却后加入聚甲基丙烯酸、水合硫酸铝、硫酸氧钛,搅拌,再加入其它剩余物料,继续搅拌溶解分散50min,即得助剂。 The soaking liquid of this embodiment is prepared from the following raw materials in parts by weight (kg): oleic acid 2, sodium dodecylbenzenesulfonate 4, sodium carbonate 18, potassium borate 6, tea polyphenols 0.2, pepper leaves 4, laurel Acyl sarcosinate sodium 6, water 280, auxiliary agent 5; the auxiliary agent is made of the following raw materials in parts by weight: polymethacrylic acid 8, aluminum sulfate hydrate 4, titanium oxysulfate 1, rice wine 18, red bayberry pomace 3, acetyl Distarch phosphate 8, its preparation method is: put red bayberry pomace into the water of 5 times its weight part first, decoct 1.5h, filter, add polymethacrylic acid, aluminum sulfate hydrate, oxygen sulfate after cooling the obtained filtrate Titanium, stir, then add other remaining materials, continue to stir to dissolve and disperse for 50 minutes, and then the additives are obtained.

本实施例的浸泡液制备方法为:先将花椒叶洗净,投入水中,煎煮50min,过滤,滤液冷却至50-60℃时,加入十二烷基苯磺酸钠、碳酸钠、硼酸钾、茶多酚,搅拌至混合物料完全溶解后,再加入其它剩余成分,继续搅拌50min,即得浸泡液。 The preparation method of the soaking solution in this embodiment is as follows: first wash the pepper leaves, put them into water, decoct for 50 minutes, filter, and when the filtrate is cooled to 50-60°C, add sodium dodecylbenzenesulfonate, sodium carbonate, and potassium borate , tea polyphenols, stir until the mixture is completely dissolved, then add other remaining ingredients, and continue stirring for 50 minutes to obtain the soaking solution.

将预处理后的藤条完全没入上述浸泡液中,保温密闭浸泡22h,取出清水洗净自然晾干或烘干,再进行后续工序。在后续编织过程中,本实施例浸泡液处理后的藤条抗冲击强度较传统方法处理的材料增加20.1%,弯曲强度提高25.4%,燃烧试验表明,改性后的藤条热释放速率降低67.8%,总放热率降低65.5%。处理后的材料编织时更容易,省时省力,产品平均生产时间降低15.2%,产品放置1年以上无变色、腐蛀、裂纹等问题。 Submerge the pretreated rattan completely into the above soaking solution, soak it in a heat-preserving and airtight manner for 22 hours, take out the clean water, wash it and dry it naturally or dry it before proceeding to the follow-up process. In the subsequent weaving process, the impact strength of the rattan treated with the soaking solution in this embodiment increased by 20.1% compared with the material treated by the traditional method, and the bending strength increased by 25.4%. The combustion test showed that the heat release rate of the modified rattan decreased by 67.8%. %, the total heat release rate is reduced by 65.5%. The processed material is easier to weave, saves time and effort, the average production time of the product is reduced by 15.2%, and the product has no discoloration, decay, cracks and other problems after being placed for more than one year.

Claims (3)

1. the rattan containing Folium Zanthoxyli Bungeani is with modifiying soak, it is characterized in that, this soak is made up of the raw material of following weight portion: oleic acid 2-3, dodecylbenzene sodium sulfonate 2-4, sodium carbonate 15-18, potassium borate 6-8, tea polyphenols 0.2-0.3, Folium Zanthoxyli Bungeani 3-4, sodium lauroyl sarcosine 4-6, water 250-280, auxiliary agent 4-5;
Auxiliary agent is made up of the raw material of following weight portion: polymethylacrylic acid 8-10, hydrazine aluminum sulfate 4-5, titanyl sulfate 1-2, yellow wine 15-18, myrica ruba marc 2-4, Ultra Tex 2 6-8; its preparation method is: first put into by myrica ruba marc in the water of 5 times of its weight portions; decoct 1-1.5h; filter; add polymethylacrylic acid, hydrazine aluminum sulfate, titanyl sulfate, stirring after the cooling of gained filtrate, add other leftover materials; continue stirring and dissolving dispersion 40-50min, obtain auxiliary agent。
2. a kind of rattan containing Folium Zanthoxyli Bungeani is used and is modifiied soak as claimed in claim 1, its preparation method is: first cleaned by Folium Zanthoxyli Bungeani, put in water, decoct 40-50min, filter, when filtrate is cooled to 50-60 DEG C, adding dodecylbenzene sodium sulfonate, sodium carbonate, potassium borate, tea polyphenols, stirring adds other residual components after being completely dissolved to mixed material, continue stirring 40-50min, obtain soak。
3. a kind of rattan containing Folium Zanthoxyli Bungeani is used and is modifiied soak as claimed in claim 1, its using method is: submerged completely by pretreated rattan in above-mentioned soak, heating, to 50-60 DEG C, is incubated airtight immersion 20-24h, takes out the clean nature of clear water and dries or dry。
CN201410287551.0A 2014-06-25 2014-06-25 A kind of rattan containing Folium Zanthoxyli Bungeani modified soak and using method thereof Active CN104128979B (en)

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CN104441149A (en) * 2014-11-13 2015-03-25 阜南县富民工艺品有限公司 Whitening and toughening modified soak solution for rattan and using method of whitening and toughening modified soak solution
CN104441165A (en) * 2014-11-13 2015-03-25 阜南县富民工艺品有限公司 Mosquito-repelling health straw modified soak solution and using method thereof
CN104441164A (en) * 2014-11-13 2015-03-25 阜南县富民工艺品有限公司 Straw modification soak solution with function of ultraviolet radiation resistance, and using method of straw modification soak solution
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