CN104120263A - High-solid-gas-ratio rotary kiln direct reduction method for nickel iron smelting - Google Patents
High-solid-gas-ratio rotary kiln direct reduction method for nickel iron smelting Download PDFInfo
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- CN104120263A CN104120263A CN201410358031.4A CN201410358031A CN104120263A CN 104120263 A CN104120263 A CN 104120263A CN 201410358031 A CN201410358031 A CN 201410358031A CN 104120263 A CN104120263 A CN 104120263A
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- nickel
- mineral aggregate
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- 238000000034 method Methods 0.000 title claims abstract description 25
- UGKDIUIOSMUOAW-UHFFFAOYSA-N iron nickel Chemical compound [Fe].[Ni] UGKDIUIOSMUOAW-UHFFFAOYSA-N 0.000 title claims abstract description 18
- 238000003723 Smelting Methods 0.000 title claims abstract description 12
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 33
- 239000000203 mixture Substances 0.000 claims abstract description 26
- 239000002893 slag Substances 0.000 claims abstract description 26
- 230000002829 reductive effect Effects 0.000 claims abstract description 21
- 239000003245 coal Substances 0.000 claims abstract description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229910052742 iron Inorganic materials 0.000 claims abstract description 16
- 239000002245 particle Substances 0.000 claims abstract description 16
- 229910001030 Iron–nickel alloy Inorganic materials 0.000 claims abstract description 14
- 230000000694 effects Effects 0.000 claims abstract description 10
- 239000000463 material Substances 0.000 claims abstract description 10
- 238000004945 emulsification Methods 0.000 claims abstract description 4
- 230000005484 gravity Effects 0.000 claims abstract description 4
- 239000007789 gas Substances 0.000 claims description 48
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 45
- 239000011707 mineral Substances 0.000 claims description 45
- 238000002156 mixing Methods 0.000 claims description 27
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 21
- 238000002844 melting Methods 0.000 claims description 18
- 238000006722 reduction reaction Methods 0.000 claims description 17
- 229910000863 Ferronickel Inorganic materials 0.000 claims description 14
- 230000008018 melting Effects 0.000 claims description 12
- 238000010438 heat treatment Methods 0.000 claims description 11
- 238000013467 fragmentation Methods 0.000 claims description 10
- 238000006062 fragmentation reaction Methods 0.000 claims description 10
- 229910052759 nickel Inorganic materials 0.000 claims description 10
- 239000002817 coal dust Substances 0.000 claims description 9
- 150000001875 compounds Chemical class 0.000 claims description 8
- 238000011049 filling Methods 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 239000002918 waste heat Substances 0.000 claims description 6
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 5
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 5
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims description 4
- 230000015572 biosynthetic process Effects 0.000 claims description 4
- 238000000227 grinding Methods 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- ROPGXTOGNYGGRA-UHFFFAOYSA-N [Fe].[Ni].[Ni] Chemical compound [Fe].[Ni].[Ni] ROPGXTOGNYGGRA-UHFFFAOYSA-N 0.000 claims description 3
- 238000005345 coagulation Methods 0.000 claims description 3
- 230000015271 coagulation Effects 0.000 claims description 3
- 239000012535 impurity Substances 0.000 claims description 3
- 239000007791 liquid phase Substances 0.000 claims description 3
- 238000010298 pulverizing process Methods 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 238000005516 engineering process Methods 0.000 abstract description 2
- 239000000843 powder Substances 0.000 abstract description 2
- 235000019738 Limestone Nutrition 0.000 abstract 1
- 238000004220 aggregation Methods 0.000 abstract 1
- 230000002776 aggregation Effects 0.000 abstract 1
- 239000006028 limestone Substances 0.000 abstract 1
- 238000001354 calcination Methods 0.000 description 3
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- 239000000571 coke Substances 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 241000537371 Fraxinus caroliniana Species 0.000 description 1
- 206010058490 Hyperoxia Diseases 0.000 description 1
- 235000010891 Ptelea trifoliata Nutrition 0.000 description 1
- 241001417490 Sillaginidae Species 0.000 description 1
- UCMNWZWXVTUJPF-UHFFFAOYSA-N [C].[P].[S] Chemical compound [C].[P].[S] UCMNWZWXVTUJPF-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 230000000222 hyperoxic effect Effects 0.000 description 1
- 229910001710 laterite Inorganic materials 0.000 description 1
- 239000011504 laterite Substances 0.000 description 1
- 230000035800 maturation Effects 0.000 description 1
- 235000012054 meals Nutrition 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000032258 transport Effects 0.000 description 1
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- Manufacture And Refinement Of Metals (AREA)
Abstract
Disclosed is a high-solid-gas-ratio rotary kiln direct reduction method for nickel iron smelting. The method comprises the steps that josephinite is broken and then dried, the water content is reduced, the josephinite, reduction coal and limestone are put into a blender mixer for being mixed, and are ground to be in a powder shape with the fineness diameter of 0.08 mm, the powdery ore with the diameter of 0.08 mm is fed into a high-solid-gas-ratio preheater for preheating and primary reduction, then the powdery ore enters a rotary kiln for continuous reduction and aggregation, the ore is reduced to the mixture of nickel iron alloy particles and molten slag materials to be discharged out of a kiln head, the discharged mixture passes through a side blown converter to enable the nickel iron alloy particles to be emulsified, under the gravity effect, particles in an iron nickel emulsification body collide with the molten slag materials to enable iron slag to be separated, finished molten nickel iron is obtained, the molten nickel iron is cast into a nickel iron finished product in a specified shape, and therefore the reduction method is completed. The technology is simple, the automation is high, and the production cost is greatly reduced.
Description
Technical field
The present invention relates to a kind of rotary kiln for directly reducing method, be particularly useful for a kind of nickel-iron smelting high solid-gas ratio rotary kiln for directly reducing method.
Background technology
The nickel iron smelting process of existing maturation be rotary kiln-mineral hot furnace technique wherein: first josephinite is transported in toothed roll crusher broken by apron feeder, josephinite after fragmentation enters and in dryer, reduces water content, by the ferronickel after drying with go back raw coal, Wingdale and drop in mixer and mix according to 100:8:2, compound is sent into rotary kiln baking, and temperature is controlled at 800 DEG C.Rotary kiln burner is arranged on kiln hood, compound enters from kiln tail, first be dried, then arrive rotary kiln middle part, start to slough dry ore deposit crystal water, until before discharging, dry ore deposit is by coal and carbon monoxide partial reduction, the nickel finally obtaining in calcining matter exists with metal Ni and two kinds of forms of Ni2+, and the most of iron in dry ore deposit is also reduced to Fe2+; The calcining matter obtaining in rotary kiln is delivered to mineral hot furnace by transmitting device, and calcining matter is in mineral hot furnace, and under 1500 DEG C of conditions, output crude iron slag and slag, after cooling of furnace slag, store up or be recycled.Mine heat furnace smelting, need to be with coke as the energy for better circulation, and its production capacity is little, and energy consumption is high.
Summary of the invention
The object of the invention is to overcome the weak point in prior art, propose a kind of technique simple, be applicable to maximize and produce, less energy consumption, does not use mineral hot furnace, reduces the nickel-iron smelting high solid-gas ratio rotary kiln for directly reducing method that electric energy needs.
For realizing above-mentioned technical purpose, nickel-iron smelting high solid-gas ratio rotary kiln for directly reducing method of the present invention adopts toothed roll crusher, dryer, high humidity heatproof thin broken machine, sieve apparatus, vertical mill, high solid-gas ratio cyclone preheater, rotary kiln, side-blown converter and liquid filling machine, it is characterized in that comprising the steps:
A. josephinite is transported in toothed roll crusher broken by feeding machine, josephinite after fragmentation is sent into and in dryer, reduced water content, use high-temperature blower that the waste heat tail gas of rotary kiln is imported in dryer by high solid-gas ratio cyclone preheater simultaneously, make the temperature in dryer reach 600 DEG C, the josephinite water content after pulverizing is reduced to 15-18%;
B. the josephinite input high humidity heatproof thin broken machine that water content is reduced to 15%-18% continues broken, josephinite after fragmentation is admitted to sieve apparatus and sieves processing, the josephinite that makes diameter be less than 100mm is separated, diameter is greater than the josephinite of 100mm and delivers to high humidity heatproof thin broken machine continuation fragmentation, by isolated josephinite with go back raw coal, after mixing, Wingdale drops into mixed grinding in vertical mill, obtaining fineness of materials is the mixing mineral aggregate of diameter 0.08mm, 200 objects are mixed to mineral aggregate and be conveyed into high solid-gas ratio cyclone preheater, use high-temperature blower that the waste heat tail gas of rotary kiln is imported to high solid-gas ratio cyclone preheater simultaneously, make to mix mineral aggregate temperature and reach 800 DEG C, tentatively there is reduction reaction in the nickel in mixing mineral aggregate and the oxide compound of iron,
C. will send into rotary kiln from kiln tail through the preliminary mixing mineral aggregate that reduction reaction occurs, be blown into coal dust and air from the kiln hood of rotary kiln to kiln tail direction simultaneously, mixing mineral aggregate in rotary kiln is subject to again obtaining heating with the hot gas flow formation countercurrent movement of kiln hood combusting coal fines generation in rotary kiln heating, by controlling the reducing atmosphere forming in the air capacity being blown in rotary kiln and the coal dust amount control rotary kiln being blown into, mix mineral aggregate slowly moves ahead to kiln hood direction in rotary kiln, and carry out complete reduction reaction, mix mineral aggregate in rotary kiln from the kiln tail electrical path length in 7-8 kiln doubly that moves ahead, time is 20-30 minute, nickel in mixing mineral aggregate and the oxide compound of iron are reduced into nickel gradually, ferrous metal molecule,
D. in the time mixing mineral aggregate and move in the anterior 5-6 times of kiln of rotary kiln electrical path length, the temperature of rotary kiln progressively reaches 1350～1400 DEG C, now mix mineral aggregate and be heated to semi-melting state or molten state, the mixing mineral aggregate of semi-melting state or molten state moves to kiln hood with the running of returning brickkiln, and iron and the nickel iron-nickel alloy particle that Collision coagulation forms in liquid phase environment and the mixture of melting slag charge are exported from kiln hood;
E. the iron-nickel alloy particle transferring out and the mixture of melting slag charge are admitted to side-blown converter, the mixture of iron-nickel alloy particle and melting slag charge continues heating in side-blown converter, make the emulsification of iron-nickel alloy particle, and under the effect of gravity, make particulate and melting slag charge in iron nickel emulsified body mutually collide, after slag iron is separated, obtain ferronickel water, the used heat air that side-blown converter produces is simultaneously introduced rotary kiln from kiln hood under the draft effect of high-temperature blower;
F. ferronickel water is directly sent into liquid filling machine and be cast into the ferronickel finished product of designated shape, and slag charge is got rid of.
The tail gas that described high solid-gas ratio cyclone preheater contains carbon monoxide needs to carry out postreaction burning with coal before discharge, avoids objectionable impurities to enter atmosphere; Described step a～e all carries out under enclosed environment.
Useful technique effect:
1, present method adopts vertical mill that mixture is ground to form to particle diameter 0.08mm powdery mixing mineral aggregate, under the effect of meal wind-force in high solid-gas ratio cyclone preheater, become suspended state and under suspended state, carry out preheating and reduction, delivering to rotary kiln smelts again, because pulverulent material can be realized heat exchange more easily, faster, thereby greatly increase the output that ferronickel reduces;
2, present method therefrom material before entering rotary kiln, first through using the tail gas preheating of rotary kiln in high solid-gas ratio cyclone preheater, do not need again extra consume fuel heat supply, make to mix the temperature increase to 800 of mineral aggregate ° more than C, start preliminary ferronickel reduction reaction by the carbon monoxide in rotary kiln exhaust gas simultaneously, effectively energy-conservation and saved the overall time of ferronickel reduction; Mineral aggregate is entering after rotary kiln, using coal as supplying hot charge and reductive agent, thereby has reduced the use of coke, and inapplicable electric furnace, has saved electric energy; Finally, after mineral aggregate carries out the separation of slag iron by survey blown converter after rotary kiln reduction, direct pouring becomes ferro nickel ingot, has further reduced the consumption of heat energy, and in whole flow process, heat energy recycling has not only been saved the fuel of heating;
3, present method step all completes under enclosed environment, has realized all materials and " has not landed ", and all material is that powdery transports in the pipeline of sealing, is connected closely, cuts down the number of intermediate links, thereby has greatly reduced the pollution of dust to environment;
4, each equipment using in present method is closely connected, thus the generation of having stopped accident; Level of automation is high, has reduced cost of labor.
Brief description of the drawings
Fig. 1 is method flow diagram of the present invention.
Embodiment
Below in conjunction with accompanying drawing, enforcement of the present invention is further described.
As shown in Figure 1, nickel-iron smelting high solid-gas ratio rotary kiln for directly reducing method of the present invention, adopt toothed roll crusher, dryer, high humidity heatproof thin broken machine, sieve apparatus, vertical mill, high solid-gas ratio cyclone preheater, rotary kiln, side-blown converter and liquid filling machine, it is characterized in that comprising the steps:
A. josephinite is transported in toothed roll crusher broken by feeding machine, josephinite after fragmentation is sent into and in dryer, reduced water content, use high-temperature blower that the waste heat tail gas of rotary kiln is imported in dryer by high solid-gas ratio cyclone preheater simultaneously, make the temperature in dryer reach 600 DEG C, the josephinite water content after pulverizing is reduced to 15-18%;
B. the josephinite input high humidity heatproof thin broken machine that water content is reduced to 15%-18% continues broken, josephinite after fragmentation is admitted to sieve apparatus and sieves processing, the josephinite that makes diameter be less than 100mm is separated, diameter is greater than the josephinite of 100mm and delivers to high humidity heatproof thin broken machine continuation fragmentation, by isolated josephinite with go back raw coal, after mixing, Wingdale drops into mixed grinding in vertical mill, obtaining fineness of materials is the mixing mineral aggregate of diameter 0.08mm, 200 objects are mixed to mineral aggregate and be conveyed into high solid-gas ratio cyclone preheater, use high-temperature blower that the waste heat tail gas of rotary kiln is imported to high solid-gas ratio cyclone preheater simultaneously, the dust-laden exhaust gas that described vertical mill is discharged enters atmosphere under the effect of exhaust blower after bag dust cleaning,
Described high solid-gas ratio preheater, makes parallel double series air-flow combine with serial material stream, and the solid and gas mass ratio of each heater unit is enhanced about more than once, and makes production hear rate trend towards theoretical hear rate.The system of preheater is set to the plural serial stage of 2-2-2-2-1 built-up type five-stage cyclone preheater, go out the gas of five-stage whirlwind cylinder equably by the bi serie preheaters at different levels that be arranged in parallel, and all powder alternately feeds each preheater step by step from a series to another series, solid-gas ratio in each cyclone preheater is brought up to 2.0 left and right, thereby significantly improve the heat exchange efficiency of pre-heating system, reduce the spent air temperture that preheater.The tail gas that described high solid-gas ratio cyclone preheater contains carbon monoxide needs to carry out postreaction burning with coal before discharge, avoid objectionable impurities to enter atmosphere, coal dust is sprayed into prereduction chamber, at the indoor formation reducing atmosphere of prereduction, there is preliminary reduction reaction in the mineral aggregate mixing, the gas that contains CO that goes out prereduction chamber burns with the high temperature air mixing on high solid-gas ratio top, avoids obnoxious flavour to enter atmosphere.The preheating of process high solid-gas ratio system and preliminary reduction, mix mineral aggregate temperature and reach 800 DEG C, and reduction reaction tentatively occurs for the nickel in mixing mineral aggregate and the oxide compound of iron, and reduction ratio is in 75% left and right;
C. will send into rotary kiln from kiln tail through the preliminary mixing mineral aggregate that reduction reaction occurs, be blown into coal dust and air from the kiln hood of rotary kiln to kiln tail direction simultaneously, mixing mineral aggregate in rotary kiln is subject to again obtaining heating with the hot gas flow formation countercurrent movement of kiln hood combusting coal fines generation in rotary kiln heating, by controlling the reducing atmosphere forming in the air capacity being blown in rotary kiln and the coal dust amount control rotary kiln being blown into, mix mineral aggregate slowly moves ahead to kiln hood direction in rotary kiln, and carry out complete reduction reaction, mix mineral aggregate in rotary kiln from the kiln tail electrical path length in 7-8 kiln doubly that moves ahead, time is 20-30 minute, nickel in mixing mineral aggregate and the oxide compound of iron are reduced into nickel gradually, ferrous metal molecule,
D. in the time mixing mineral aggregate and move in the anterior 5-6 times of kiln of rotary kiln electrical path length, the temperature of rotary kiln progressively reaches 1350～1400 DEG C, now mix mineral aggregate and be heated to semi-melting state or molten state, the mixing mineral aggregate of semi-melting state or molten state moves to kiln hood with the running of returning brickkiln, and iron and the nickel iron-nickel alloy particle that Collision coagulation forms in liquid phase environment and the mixture of melting slag charge are exported from kiln hood;
E. the iron-nickel alloy particle transferring out and the mixture of melting slag charge are admitted to side-blown converter, the mixture of iron-nickel alloy particle and melting slag charge continues heating in side-blown converter, make the emulsification of iron-nickel alloy particle, and under the effect of gravity, make particulate and melting slag charge in iron nickel emulsified body mutually collide, thereby after slag iron is separated, discharge slag charge and obtain ferronickel water, the used heat air that simultaneously side-blown converter produces is introduced rotary kiln from kiln hood under the draft effect of high-temperature blower, and described side-blown converter is not less than by importing oxygen level the heat that 85% hyperoxia gas and coal dust firing produce;
F. ferronickel water is directly sent into liquid filling machine and be cast into the ferronickel finished product of designated shape, and slag charge is got rid of.
Above-mentioned coal dust is raw coal, and through air swept mill, grinding obtains; Above-mentioned steps a～e all automatically carries out under enclosed environment.
The composition of the josephinite that uses in described method of reducing, coal, Wingdale is as follows:
Josephinite:
| Title | Ni | ΣFe | H 2O | SiO 2 | MgO | P | CaO |
| Laterite | ～1.7 | 18～19% | ～35 | 35～45 | ＜30 | ＜0.01 | ＜3.0 |
Coal composition:
| Project | Total moisture | Interior water | Ash content | Fugitive constituent | Fixed carbon | Phosphorus | Sulphur | Calorific value |
| Also raw coal | 26.2 | —— | 12.0 | 2.0 | 84.8 | 0.004 | 0.50 | 6920 |
| Bunker coal | 11.0 | 4.3 | 15.6 | 39.1 | 41.0 | 0.007 | 1.5 | 6310 |
Wingdale composition:
| Scaling loss | SiO 2 | Fe 2O 3 | Al 2O 3 | CaO | MgO | P | S |
| 43.63 | 0.29 | 0.10 | 0.15 | 55.08 | 0.37 | 0.004 | 0.007 |
Claims (3)
1. a nickel-iron smelting high solid-gas ratio rotary kiln for directly reducing method, adopt toothed roll crusher, dryer, high humidity heatproof thin broken machine, sieve apparatus, vertical mill, high solid-gas ratio cyclone preheater, rotary kiln, side-blown converter and liquid filling machine, it is characterized in that comprising the steps:
A. josephinite is transported in toothed roll crusher broken by feeding machine, josephinite after fragmentation is sent into and in dryer, reduced water content, use high-temperature blower that the waste heat tail gas of rotary kiln is imported in dryer by high solid-gas ratio cyclone preheater simultaneously, make the temperature in dryer reach 600 DEG C, the josephinite water content after pulverizing is reduced to 15-18%;
B. the josephinite input high humidity heatproof thin broken machine that water content is reduced to 15%-18% continues broken, josephinite after fragmentation is admitted to sieve apparatus and sieves processing, the josephinite that makes diameter be less than 100mm is separated, diameter is greater than the josephinite of 100mm and delivers to high humidity heatproof thin broken machine continuation fragmentation, by isolated josephinite with go back raw coal, after mixing, Wingdale drops into mixed grinding in vertical mill, obtaining fineness of materials is the mixing mineral aggregate of diameter 0.08mm, 200 objects are mixed to mineral aggregate and be conveyed into high solid-gas ratio cyclone preheater, use high-temperature blower that the waste heat tail gas of rotary kiln is imported to high solid-gas ratio cyclone preheater simultaneously, make to mix mineral aggregate temperature and reach 800 DEG C, tentatively there is reduction reaction in the nickel in mixing mineral aggregate and the oxide compound of iron,
C. will send into rotary kiln from kiln tail through the preliminary mixing mineral aggregate that reduction reaction occurs, be blown into coal dust and air from the kiln hood of rotary kiln to kiln tail direction simultaneously, mixing mineral aggregate in rotary kiln is subject to again obtaining heating with the hot gas flow formation countercurrent movement of kiln hood combusting coal fines generation in rotary kiln heating, by controlling the reducing atmosphere forming in the air capacity being blown in rotary kiln and the coal dust amount control rotary kiln being blown into, mix mineral aggregate slowly moves ahead to kiln hood direction in rotary kiln, and carry out complete reduction reaction, mix mineral aggregate in rotary kiln from the kiln tail electrical path length in 7-8 kiln doubly that moves ahead, time is 20-30 minute, nickel in mixing mineral aggregate and the oxide compound of iron are reduced into nickel gradually, ferrous metal molecule,
D. in the time mixing mineral aggregate and move in the anterior 5-6 times of kiln of rotary kiln electrical path length, the temperature of rotary kiln progressively reaches 1350～1400 DEG C, now mix mineral aggregate and be heated to semi-melting state or molten state, the mixing mineral aggregate of semi-melting state or molten state moves to kiln hood with the running of returning brickkiln, and iron and the nickel iron-nickel alloy particle that Collision coagulation forms in liquid phase environment and the mixture of melting slag charge are exported from kiln hood;
E. the iron-nickel alloy particle transferring out and the mixture of melting slag charge are admitted to side-blown converter, the mixture of iron-nickel alloy particle and melting slag charge continues heating in side-blown converter, make the emulsification of iron-nickel alloy particle, and under the effect of gravity, make particulate and melting slag charge in iron nickel emulsified body mutually collide, after slag iron is separated, obtain ferronickel water, the used heat air that side-blown converter produces is simultaneously introduced rotary kiln from kiln hood under the draft effect of high-temperature blower;
F. ferronickel water is directly sent into liquid filling machine and be cast into the ferronickel finished product of designated shape, and slag charge is sent.
2. nickel-iron smelting high solid-gas ratio rotary kiln for directly reducing method according to claim 1, it is characterized in that: the tail gas that described high solid-gas ratio cyclone preheater contains carbon monoxide needs to carry out postreaction burning with coal before discharge, avoids objectionable impurities to enter atmosphere.
3. nickel-iron smelting solid-gas ratio rotary kiln for directly reducing method according to claim 1, is characterized in that: described step a～e all carries out under enclosed environment.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105463214A (en) * | 2015-07-27 | 2016-04-06 | 潘料庭 | Method for producing high-nickel iron by adopting low-grade laterite-nickel ores |
| CN110637101A (en) * | 2017-05-24 | 2019-12-31 | 住友金属矿山株式会社 | Method for smelting oxide ore |
| CN112138862A (en) * | 2020-08-13 | 2020-12-29 | 中国矿业大学 | A method for improving magnetic composition of coal preparation medium |
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| (加拿大)J.R.小博尔德 等: "《镍(提取冶金)》", 30 September 1977, article "日本冶金工业公司", pages: 198-201 * |
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| CN105463214A (en) * | 2015-07-27 | 2016-04-06 | 潘料庭 | Method for producing high-nickel iron by adopting low-grade laterite-nickel ores |
| CN105463214B (en) * | 2015-07-27 | 2018-05-25 | 潘料庭 | A kind of method that high ferronickel is produced using low poor grade lateritic nickel ore |
| CN110637101A (en) * | 2017-05-24 | 2019-12-31 | 住友金属矿山株式会社 | Method for smelting oxide ore |
| CN110637101B (en) * | 2017-05-24 | 2021-07-20 | 住友金属矿山株式会社 | Method for smelting oxide ore |
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