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CN104099008A - Anti-grease aluminium alloy surface treatment agent - Google Patents

Anti-grease aluminium alloy surface treatment agent Download PDF

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Publication number
CN104099008A
CN104099008A CN201410275692.0A CN201410275692A CN104099008A CN 104099008 A CN104099008 A CN 104099008A CN 201410275692 A CN201410275692 A CN 201410275692A CN 104099008 A CN104099008 A CN 104099008A
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CN
China
Prior art keywords
stirring
minute
parts
grease
deionized water
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Pending
Application number
CN201410275692.0A
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Chinese (zh)
Inventor
徐泽军
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Ruizhan Tongling Technologies Co Ltd
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Ruizhan Tongling Technologies Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by Ruizhan Tongling Technologies Co Ltd filed Critical Ruizhan Tongling Technologies Co Ltd
Priority to CN201410275692.0A priority Critical patent/CN104099008A/en
Publication of CN104099008A publication Critical patent/CN104099008A/en
Pending legal-status Critical Current

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Abstract

The invention discloses an anti-grease aluminium alloy surface treatment agent. The anti-grease aluminium alloy surface treatment agent consists of the following raw materials in parts by weight: 0.8-1 part of squalane, 0.5-1 part of ferrous sulfate, 1-2 parts of alum, 0.3-1 part of titanium sulfate, 2-3.1 parts of citric acid, 1.2-2 parts of sodium polyacrylate, 3-5 parts of magnesium chloride, 0.3-1 part of polyvinylpyrrolidone, 0.4-1 part of polysorbate 80, 0.1-0.4 part of diethylenetriamine, 3-4 parts of triethylene glycol, 0.3-1 part of calcium carbonate, 0.1-0.2 part of dibutyltin dilaurate, 3-4 parts of a coalescing agent, 15-20 parts of a silane coupling agent KH560 and 106-130 parts of deionized water. The surface treatment agent provided by the invention is short in treatment time and simple and convenient to control, can form a stable coating film on the aluminium alloy surface, can resist oil, corrosion and impact and improve the adhesive force to the surface of a workpiece and plays a grease-resistant protection role.

Description

A kind of anti-grease aluminum alloy surface treatment agent
?
Technical field
The present invention relates generally to field of surface treatment, relates in particular to a kind of anti-grease aluminum alloy surface treatment agent.
Background technology
The surface treatment method of aluminium alloy has a lot, as Physical, chemical method, physico-chemical processes and synthetic method.Conventional method is anonizing now, form conversion film by electrochemical method in aluminum alloy surface, although this method can improve the corrosion resistance nature of aluminium alloy, but the ability that it conforms, transform rete even not, easily come off, wear resisting property does not improve, and although traditional phosphate conversion and chromating process for treating surface can obtain good effect, but contain zinc in the waste liquid of discharging in treating processes, manganese, nickel, the carcinogenic substances such as heavy metal ion and sub-anti-grease such as chromium, environmental pollution is very serious, and metallic surface silanization treatment technology is due to the material of hurm involved environment not, energy consumption in production process is low, technical applications is extensive, being considered to be expected to replace phosphate conversion processes and chromating processing, that recent development direction is protected separately in metallic surface.
Summary of the invention
The object of the invention is just to provide a kind of anti-grease aluminum alloy surface treatment agent.
The present invention is achieved by the following technical solutions:
A kind of anti-grease aluminum alloy surface treatment agent, it is made up of the raw material of following weight parts:
Squalane 0.8-1, ferrous sulfate 0.5-1, alum 1-2, titanium sulfate 0.3-1, citric acid 2-3.1, sodium polyacrylate 1.2-2, magnesium chloride 3-5, polyvinylpyrrolidone 0.3-1, Polysorbate 80 0.4-1, diethylenetriamine 0.1-0.4, triglycol 3-4, calcium carbonate 0.3-1, dibutyl tin laurate 0.1-0.2, film coalescence aid 3-4, silane coupling agent KH560 15-20, deionized water 106-130;
Described film coalescence aid is made up of the raw material of following weight parts:
Protanal Ester SD-LB 20-30, urea 2-3, Sodium Citrate 1-2, octyl group isothiazolinone 0.8-1, clorafin 52 2-3, Span-80 0.5-1, benzyltriethylammoinium chloride 1-2, deionized water 100-120;
Octyl group isothiazolinone is joined in clorafin 52, at 50-60 DEG C, be uniformly mixed 3-4 minute, add 20-30%, the Span-80 of above-mentioned deionized water weight, 100-200 rev/min of dispersed with stirring 6-10 minute;
Urea is mixed with Sodium Citrate, add the 20-30% of above-mentioned deionized water weight, at 25-30 DEG C, be uniformly mixed 3-5 minute, add benzyltriethylammoinium chloride, 100-200 rev/min of dispersed with stirring 5-10 minute;
Protanal Ester SD-LB is joined in remaining deionized water, add above-mentioned each raw material after treatment, 200-300 rev/min of dispersed with stirring 10-20 minute, obtains described film coalescence aid.
A preparation method for anti-grease aluminum alloy surface treatment agent, comprises the following steps:
Alum is mixed with calcium carbonate, after stirring, add diethylenetriamine, be uniformly mixed 3-5 minute at 40-60 DEG C;
Ferrous sulfate is mixed with titanium sulfate, after stirring, join in triglycol, insulated and stirred 6-10 minute at 50-60 DEG C;
Sodium polyacrylate, Polysorbate 80 are mixed, after stirring, join in deionized water, add magnesium chloride, 50-70 rev/min of dispersed with stirring 1-2 minute;
Above-mentioned each raw material after treatment is mixed with the each raw material of residue, and 200-300 rev/min of dispersed with stirring 1-2 hour, obtains described anti-grease aluminum alloy surface treatment agent.
Advantage of the present invention is:
The surface treatment agent treatment time of the present invention is short, controls easyly, can form stable film in aluminum alloy surface, and this film has good oil-proofness, erosion resistance, and shock resistance can improve the sticking power to workpiece surface, plays lipophobic protection effect.
Embodiment
Embodiment 1
A kind of anti-grease aluminum alloy surface treatment agent, it is made up of the raw material of following weight parts:
Squalane 0.8, ferrous sulfate 0.5, alum 1, titanium sulfate 0.3, citric acid 3.1, sodium polyacrylate 1.2, magnesium chloride 3, polyvinylpyrrolidone 0.3, Polysorbate 80 0.4, diethylenetriamine 0.4, triglycol 4, calcium carbonate 0.3, dibutyl tin laurate 0.2, film coalescence aid 4, silane coupling agent KH560 20, deionized water 130;
Described film coalescence aid is made up of the raw material of following weight parts:
Protanal Ester SD-LB 30, urea 3, Sodium Citrate 1, octyl group isothiazolinone 0.8, clorafin 52 3, Span-80 0.5, benzyltriethylammoinium chloride 1, deionized water 120;
Octyl group isothiazolinone is joined in clorafin 52, at 60 DEG C, be uniformly mixed 4 minutes, add 20-30%, the Span-80 of above-mentioned deionized water weight, 200 revs/min of dispersed with stirring 10 minutes;
Urea is mixed with Sodium Citrate, add 30% of above-mentioned deionized water weight, at 25 DEG C, be uniformly mixed 3 minutes, add benzyltriethylammoinium chloride, 200 revs/min of dispersed with stirring 10 minutes;
Protanal Ester SD-LB is joined in remaining deionized water, add above-mentioned each raw material after treatment, 200 revs/min of dispersed with stirring 10-20 minute, obtain described film coalescence aid.
A preparation method for anti-grease aluminum alloy surface treatment agent, comprises the following steps:
Alum is mixed with calcium carbonate, after stirring, add diethylenetriamine, be uniformly mixed 5 minutes at 60 DEG C;
Ferrous sulfate is mixed with titanium sulfate, after stirring, join in triglycol, insulated and stirred 10 minutes at 60 DEG C;
Sodium polyacrylate, Polysorbate 80 are mixed, after stirring, join in deionized water, add magnesium chloride, 70 revs/min of dispersed with stirring 2 minutes;
Above-mentioned each raw material after treatment is mixed with the each raw material of residue, and 2300 revs/min of dispersed with stirring 1 hour, obtain described anti-grease aluminum alloy surface treatment agent.
Using method:
The Al alloy parts carrying out after degreasing, washing is placed in to surface treatment agent of the present invention and floods, working temperature 20-40 DEG C, working hour 0.5-1min.
Performance test:
Getting the aluminum alloy plate materials of surface treatment agent processing of the present invention tests, the specification of this sheet material is 80mm × 100mm × 4mm, by this sheet material lateral dissection, carry out spray test, agents useful for same is that concentration is 5% sodium chloride solution, test period 300 hours, measures the bubbling width forming in line of cut one side, and result bubbling width is 0;
Salt tolerance:
It is in 5% sodium chloride solution that this sheet material is immersed in to concentration, soaks 300 hours, and material surface is substantially unchanged, soaks 300 hours, occurs without rust staining;
Acid resistance:
This sheet material is sprayed to experiment with the 0.05mol/l sulfuric acid that temperature is 23 DEG C, and experimental period 20 hours, cleans with clear water, and indoor placement 2 hours, coating surface was unchanged, and nothing is bubbled, nothing comes off, nothing is damaged;
Stripper-resistance:
The paste that this plate surface is coated with to last layer 2-3mm, being put into temperature is 50 DEG C, and in the watertight chest that relative humidity is 90-96%, experimental period 24 hours, cleans with clear water after taking-up, and coating surface is without bubbling, without coming off, without damaged.

Claims (2)

1. an anti-grease aluminum alloy surface treatment agent, is characterized in that what it was made up of the raw material of following weight parts:
Squalane 0.8-1, ferrous sulfate 0.5-1, alum 1-2, titanium sulfate 0.3-1, citric acid 2-3.1, sodium polyacrylate 1.2-2, magnesium chloride 3-5, polyvinylpyrrolidone 0.3-1, Polysorbate 80 0.4-1, diethylenetriamine 0.1-0.4, triglycol 3-4, calcium carbonate 0.3-1, dibutyl tin laurate 0.1-0.2, film coalescence aid 3-4, silane coupling agent KH560 15-20, deionized water 106-130;
Described film coalescence aid is made up of the raw material of following weight parts:
Protanal Ester SD-LB 20-30, urea 2-3, Sodium Citrate 1-2, octyl group isothiazolinone 0.8-1, clorafin 52 2-3, Span-80 0.5-1, benzyltriethylammoinium chloride 1-2, deionized water 100-120;
Octyl group isothiazolinone is joined in clorafin 52, at 50-60 DEG C, be uniformly mixed 3-4 minute, add 20-30%, the Span-80 of above-mentioned deionized water weight, 100-200 rev/min of dispersed with stirring 6-10 minute;
Urea is mixed with Sodium Citrate, add the 20-30% of above-mentioned deionized water weight, at 25-30 DEG C, be uniformly mixed 3-5 minute, add benzyltriethylammoinium chloride, 100-200 rev/min of dispersed with stirring 5-10 minute;
Protanal Ester SD-LB is joined in remaining deionized water, add above-mentioned each raw material after treatment, 200-300 rev/min of dispersed with stirring 10-20 minute, obtains described film coalescence aid.
2. a preparation method for anti-grease aluminum alloy surface treatment agent as claimed in claim 1, is characterized in that comprising the following steps:
Alum is mixed with calcium carbonate, after stirring, add diethylenetriamine, be uniformly mixed 3-5 minute at 40-60 DEG C;
Ferrous sulfate is mixed with titanium sulfate, after stirring, join in triglycol, insulated and stirred 6-10 minute at 50-60 DEG C;
Sodium polyacrylate, Polysorbate 80 are mixed, after stirring, join in deionized water, add magnesium chloride, 50-70 rev/min of dispersed with stirring 1-2 minute;
Above-mentioned each raw material after treatment is mixed with the each raw material of residue, and 200-300 rev/min of dispersed with stirring 1-2 hour, obtains described anti-grease aluminum alloy surface treatment agent.
CN201410275692.0A 2014-06-19 2014-06-19 Anti-grease aluminium alloy surface treatment agent Pending CN104099008A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410275692.0A CN104099008A (en) 2014-06-19 2014-06-19 Anti-grease aluminium alloy surface treatment agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410275692.0A CN104099008A (en) 2014-06-19 2014-06-19 Anti-grease aluminium alloy surface treatment agent

Publications (1)

Publication Number Publication Date
CN104099008A true CN104099008A (en) 2014-10-15

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105040949A (en) * 2015-08-31 2015-11-11 温州泓呈祥科技有限公司 Ceiling with surface coated with oil-resistant corrosion-resistant coating layer

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1786281A (en) * 2005-12-14 2006-06-14 王开平 Metal surface treatment agent
US20090274836A1 (en) * 2008-05-05 2009-11-05 Richard Lionel Bradshaw Systems and methods for protecting a sensitive device from corrosion
CN103087627A (en) * 2012-12-18 2013-05-08 芜湖恒坤汽车部件有限公司 Metal aluminum alloy silane surface treating agent and preparation method thereof
CN103773234A (en) * 2014-01-10 2014-05-07 湖南金裕化工有限公司 Silane surface treating agent and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1786281A (en) * 2005-12-14 2006-06-14 王开平 Metal surface treatment agent
US20090274836A1 (en) * 2008-05-05 2009-11-05 Richard Lionel Bradshaw Systems and methods for protecting a sensitive device from corrosion
CN103087627A (en) * 2012-12-18 2013-05-08 芜湖恒坤汽车部件有限公司 Metal aluminum alloy silane surface treating agent and preparation method thereof
CN103773234A (en) * 2014-01-10 2014-05-07 湖南金裕化工有限公司 Silane surface treating agent and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105040949A (en) * 2015-08-31 2015-11-11 温州泓呈祥科技有限公司 Ceiling with surface coated with oil-resistant corrosion-resistant coating layer

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Application publication date: 20141015

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