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CN104089988A - Household cereal quality detection device and detection method using the same - Google Patents

Household cereal quality detection device and detection method using the same Download PDF

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Publication number
CN104089988A
CN104089988A CN201310563704.5A CN201310563704A CN104089988A CN 104089988 A CN104089988 A CN 104089988A CN 201310563704 A CN201310563704 A CN 201310563704A CN 104089988 A CN104089988 A CN 104089988A
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gas
signal
microprocessor
grain
detection
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惠国华
赵梦田
杜桂苏
郑海霞
黄洁
王敏敏
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Zhejiang Gongshang University
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Zhejiang Gongshang University
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Abstract

The invention discloses a household cereal quality detection device and a detection method using the same. The household cereal quality detection device comprises a housing and a detection probe arranged on the housing. The detection probe is connected to a miniature air pump. A gas chamber, an operational amplifier, a data acquisition card, a memory and a microprocessor are arranged in the housing. A display screen and multiple control buttons are arranged on the housing. An output end of the operational amplifier is electrically connected to the data acquisition card. The microprocessor is electrically connected respectively to the data acquisition card, the display screen, the memory, the miniature air pump and all the control buttons. One end of the detection probe is connected to the gas chamber. The other end of the detection probe is provided with an air inlet. An insulative circuit board is arranged in the gas chamber. Gas sensitive membranes are arranged on the insulative circuit board. All the gas sensitive membranes are electrically connected respectively to an input end of the operational amplifier. The household cereal quality detection device has the advantages of good economy, small volume, simple detection and fast rate, is suitable for household usage, and can provide reliable guarantee for improvement of safety of household food materials.

Description

家用谷物品质检测装置及检测方法Household grain quality detection device and detection method

技术领域technical field

本发明涉及食品品质检测技术领域,尤其是涉及一种可准确检测家用谷物是否腐败,为确保家用食材的安全性提供可靠保证的家用谷物品质检测装置及检测方法。The invention relates to the technical field of food quality detection, in particular to a household grain quality detection device and detection method that can accurately detect whether household grains are spoiled and provide reliable assurance for the safety of household food materials.

背景技术Background technique

人们每日都要摄取谷物类谷物,谷物质量的好坏,直接关系到人们身体的健康。People take in cereal grains every day, and the quality of cereals is directly related to the health of people.

谷类在贮藏过程中,会因为温度、湿度、氧气、微生物及昆虫等因素的影响,而造成其质量的不良改变。有些变化可以通过视觉及嗅觉发现,而有些细微的变化则是视觉和嗅觉无法发现的,只有质量变化较大时,人们才能感觉到,但是,此前食入的变质谷物食品已经对人体造成了危害。During the storage process of grains, due to the influence of factors such as temperature, humidity, oxygen, microorganisms and insects, it will cause adverse changes in its quality. Some changes can be found by sight and smell, while some subtle changes cannot be found by sight and smell. People can feel it only when the quality changes greatly. However, the spoiled grain food eaten before has caused harm to the human body. .

而通常的谷物品质检测装置往往操作流程比较复杂,使用人员需经过专业培训,才能运用装置配套的软件对检测数据进行分析从而给出分析结果,通常设置于工厂、粮店、仓库、超市、实验室等场所,价格昂贵、体积大,不适合家庭使用。However, the usual grain quality detection device often has a complicated operation process, and the users need professional training before they can use the software supporting the device to analyze the detection data and give the analysis results. They are usually installed in factories, grain stores, warehouses, supermarkets, laboratories, etc. In places such as rooms, the price is expensive and the volume is large, so it is not suitable for home use.

如果有一种适合家庭检测谷物使用的检测装置,将会为提高家用食材的安全性,确保人们的身体健康提供很多帮助。If there is a detection device suitable for family detection of grains, it will provide a lot of help for improving the safety of household food materials and ensuring people's health.

中国专利授权公告号:CN101769889A,授权公告日2010年7月7日,公开了一种农产品品质检测的电子鼻系统,包括一主要完成对低浓度气味收集的气体富集模块,一主要把气味信号转化为电信号的气室气路模块及传感器阵列,一主要对传感器阵列输出信号进行滤波、模数转换、特征提取的传感器调理电路与数据预处理模块,一对信号进行识别和判断、且带有数据存储的嵌入式系统,一显示与结果输出模块;所述的气体富集模块由装填有吸附剂的吸附管、电热丝和温控装置构成。该发明具有功能单一,检测时间长,不适合家用的不足。Chinese patent authorization announcement number: CN101769889A, authorized announcement date July 7, 2010, discloses an electronic nose system for quality inspection of agricultural products, including a gas enrichment module that mainly completes the collection of low-concentration odors, and a main odor signal The gas chamber air circuit module and sensor array that converts electrical signals, a sensor conditioning circuit and data preprocessing module that mainly filter, analog-to-digital conversion, and feature extraction output signals from the sensor array, identify and judge a pair of signals, and bring An embedded system with data storage, a display and result output module; the gas enrichment module is composed of an adsorption tube filled with adsorbent, an electric heating wire and a temperature control device. The invention has the disadvantages of single function, long detection time and being unsuitable for household use.

发明内容Contents of the invention

本发明的发明目的是为了克服现有技术中的检测装置的价格昂贵、体积大,不适合家庭使用的不足,提供了一种可准确检测家用谷物是否腐败,为确保家用食材的安全性提供可靠保证的家用谷物品质检测装置及检测方法。The purpose of the present invention is to overcome the shortcomings of the detection device in the prior art, which are expensive, bulky and unsuitable for home use, to provide a device that can accurately detect whether the household grain is spoiled, and provide a reliable device for ensuring the safety of household ingredients. Guaranteed household grain quality testing device and testing method.

为了实现上述目的,本发明采用以下技术方案:In order to achieve the above object, the present invention adopts the following technical solutions:

一种家用谷物品质检测装置,包括壳体、设于壳体上的检测探头,检测探头与微型气泵相连接;所述壳体内设有气室、运算放大器、数据采集卡、存储器和微处理器,壳体上设有显示屏和若干个控制按钮;运算放大器的输出端与数据采集卡电连接,所述微处理器分别与数据采集卡、显示屏、存储器、气泵和各个控制按钮电连接;所述检测探头一端与气室相连接,检测探头另一端上设有进气口,进气口上设有过滤网;所述气室内设有绝缘电路板上,绝缘电路板上设有若干个气体敏感膜,各个气体敏感膜分别与运算放大器的输入端电连接。A household grain quality detection device, comprising a housing, a detection probe arranged on the housing, the detection probe is connected with a miniature air pump; the housing is provided with an air chamber, an operational amplifier, a data acquisition card, a memory and a microprocessor , the casing is provided with a display screen and several control buttons; the output terminal of the operational amplifier is electrically connected to the data acquisition card, and the microprocessor is electrically connected to the data acquisition card, display screen, memory, air pump and each control button; One end of the detection probe is connected to the air chamber, the other end of the detection probe is provided with an air inlet, and a filter screen is provided on the air inlet; an insulating circuit board is arranged in the air chamber, and several gas chambers are arranged on the insulating circuit board. Sensitive films, each gas sensitive film is electrically connected to the input end of the operational amplifier.

测量过程中,检测者一只手握住检测探头,将进气口靠近被检测谷物,另外一只手在控制按钮上进行选择操作,谷物品质检测装置开始测量。微处理器对检测的数据进行计算和分析,当判断得出谷物已经腐败,则微处理器控制显示屏显示该种谷物腐败的报警信息。During the measurement process, the inspector holds the detection probe with one hand, closes the air inlet to the grain to be inspected, and performs selection operation on the control button with the other hand, and the grain quality inspection device starts to measure. The microprocessor calculates and analyzes the detected data, and when it is judged that the grain has been spoiled, the microprocessor controls the display to display an alarm message of the spoiled grain.

本发明的家用谷物品质检测装置经济性好、体积小、便于携带、检测简单、快速、适合家庭使用,可为提高家用食材的安全性提供可靠保证。The domestic grain quality detection device of the present invention is economical, small in size, easy to carry, simple and fast in detection, suitable for family use, and can provide a reliable guarantee for improving the safety of household food materials.

作为优选,所述气体敏感膜为7个,分别为用于检测硫化物的第一气体敏感膜,用于检测氢气的第二气体敏感膜,用于检测氨气的第三气体敏感膜,用于检测酒精、甲苯、二甲苯的第四气体敏感膜,用于检测碳氢组分气体的第五气体敏感膜,用于检测甲烷和丙烷的第六气体敏感膜,用于检测氮氧化物的第七气体敏感膜。Preferably, there are seven gas-sensitive films, which are respectively the first gas-sensitive film for detecting sulfide, the second gas-sensitive film for detecting hydrogen, and the third gas-sensitive film for detecting ammonia. The fourth gas sensitive membrane for detecting alcohol, toluene and xylene, the fifth gas sensitive membrane for detecting hydrocarbon gas, the sixth gas sensitive membrane for detecting methane and propane, and the sixth gas sensitive membrane for detecting nitrogen oxides The seventh gas-sensitive film.

作为优选,所述气体敏感膜呈长度为14至16毫米的两端开口中空纺锤体状,气体敏感膜中部直径为3.2毫米至3.6毫米,气体敏感膜两端直径均为1.5至1.6毫米,气体敏感膜的厚度为1毫米至1.25毫米;气体敏感膜的空腔内设有加热电阻丝,加热电阻丝两端分别通过加热引脚与电源电连接,气体敏感膜上设有两个检测引脚和与绝缘电路板相连接的两个固定引脚,两个检测引脚分别与运算放大器的同相输入端和反相输入端电连接。Preferably, the gas-sensitive membrane is in the shape of a hollow spindle with openings at both ends and a length of 14 to 16 mm. The thickness of the sensitive film is 1 mm to 1.25 mm; the cavity of the gas sensitive film is provided with a heating resistance wire, and the two ends of the heating resistance wire are electrically connected to the power supply through heating pins respectively, and two detection pins are arranged on the gas sensitive film and two fixed pins connected to the insulating circuit board, and two detection pins are respectively electrically connected to the non-inverting input terminal and the inverting input terminal of the operational amplifier.

气体敏感膜的空腔内设置的加热电阻丝用于给气体敏感膜加热。本发明的气体敏感膜的结构有助于提高气体检测精度,在工作状态下,气体敏感膜被电阻丝加热至300~480℃,当被测气体被携带至传感器敏感膜表面时,气体分子在高温的作用下被氧化,氧化产物附着在气体敏感膜表面,引起气体敏感膜电阻的变化,依据这个电阻值的变化可以实现气体浓度的表征。本发明的不同气体敏感膜采用不同材料制备,每种气体敏感膜只对特定气体敏感,即气体敏感膜具有特异性。The heating resistance wire arranged in the cavity of the gas sensitive film is used for heating the gas sensitive film. The structure of the gas-sensitive film of the present invention helps to improve the gas detection accuracy. In the working state, the gas-sensitive film is heated to 300-480°C by the resistance wire. When the measured gas is carried to the surface of the sensor sensitive film, the gas molecules are It is oxidized under the action of high temperature, and the oxidation products are attached to the surface of the gas sensitive membrane, causing the change of the resistance of the gas sensitive membrane. According to the change of the resistance value, the gas concentration can be characterized. Different gas-sensitive films of the present invention are made of different materials, and each gas-sensitive film is only sensitive to a specific gas, that is, the gas-sensitive film has specificity.

作为优选,所述气室的宽度为0.8厘米至1.2厘米,长度为1.6至1.9厘米,厚度为0.3厘米至0.5厘米。气室尺寸较小的好处是避免了湍流的存在,检测精度高,需要的进气量小,适合家用。Preferably, the air chamber has a width of 0.8 cm to 1.2 cm, a length of 1.6 cm to 1.9 cm, and a thickness of 0.3 cm to 0.5 cm. The advantage of the small size of the gas chamber is that it avoids the existence of turbulent flow, has high detection accuracy, and requires a small amount of air intake, which is suitable for household use.

作为优选,还包括USIM卡和射频无线收发器电连接;USIM卡和射频无线收发器分别与微处理器电连接。Preferably, the USIM card is electrically connected to the radio frequency wireless transceiver; the USIM card and the radio frequency wireless transceiver are respectively electrically connected to the microprocessor.

作为优选,运算放大器为UPC4570低噪运算贴片放大器,数据采集卡为基于MSP430F5438的低功耗嵌入式数据采集卡,微处理器为MSP430F149低功耗嵌入式单片机,显示屏为触摸屏。Preferably, the operational amplifier is a UPC4570 low-noise operational patch amplifier, the data acquisition card is a low-power embedded data acquisition card based on MSP430F5438, the microprocessor is an MSP430F149 low-power embedded single-chip microcomputer, and the display screen is a touch screen.

贴片放大器、基于MSP430F5438的低功耗嵌入式数据采集卡、MSP430F149低功耗嵌入式单片机及触摸屏的设置,使得本发明的检测装置体积小、重量轻、便于携带,更适合家庭使用。SMD amplifier, MSP430F5438-based low-power embedded data acquisition card, MSP430F149 low-power embedded single-chip microcomputer and touch screen settings make the detection device of the present invention small in size, light in weight, easy to carry, and more suitable for home use.

一种家用谷物品质检测装置的检测方法,包括如下步骤:A detection method of a household grain quality detection device, comprising the steps of:

(7-1)存储器中设有级联双稳态随机共振系统模型,所述级联双稳态随机共振系统模型包括一级双稳态随机共振系统模型:和以一级双稳态随机共振系统模型的输出x(t)作为输入信号的二级双稳态随机共振系统模型:其中,V(x)和V(y)为非线性对称势函数,ξ(t)为高斯白噪声,a和b是输入信号强度,f0是调制信号频率,D是噪声强度,为相位,x和y为质点运动位移,t为时间;(7-1) A cascaded bistable stochastic resonance system model is provided in the memory, and the cascaded bistable stochastic resonance system model includes a first-order bistable stochastic resonance system model: and the second-order bistable stochastic resonance system model with the output x(t) of the first-order bistable stochastic resonance system model as the input signal: Among them, V(x) and V(y) are nonlinear symmetric potential functions, ξ(t) is Gaussian white noise, a and b are the input signal strength, f0 is the modulation signal frequency, D is the noise strength, is the phase, x and y are the motion displacement of the particle, and t is the time;

存储器中还设有与谷物种类相对应的单级随机共振系统模型和信噪比计算公式: SNR = 2 [ lim Δω → 0 ∫ Ω - Δω Ω + Δω S ( ω ) dω ] / S N ( Ω ) ;其中ω是信号频率,Ω为角频率,S(ω)是信号频谱密度,SN(Ω)是信号频率范围内的噪声强度;微处理器中设有与谷物种类相对应的霉变阈值N;The memory also has a single-stage stochastic resonance system model corresponding to the grain type and a calculation formula for the signal-to-noise ratio: SNR = 2 [ lim Δω &Right Arrow; 0 ∫ Ω - Δω Ω + Δω S ( ω ) dω ] / S N ( Ω ) ; Wherein ω is the signal frequency, Ω is the angular frequency, S(ω) is the signal spectral density, S N (Ω) is the noise intensity in the signal frequency range; the microprocessor is provided with a mildew threshold corresponding to the grain type N;

(7-2)设定P为任一种被检测谷物,将检测探头的进气口靠近谷物P,检测操作者通过控制按钮将谷物的种类及质量输入到微处理器中,微处理器控制检测探头将谷物散发出的挥发性气体吸入气室中5至20秒,挥发性气体与设于气室内的各个气体敏感膜相接触,各个气体敏感膜分别产生响应信号,微处理器计算各个响应信号的平均信号,得到检测信号I(t);(7-2) Set P as any kind of grain to be detected, put the air inlet of the detection probe close to the grain P, and the detection operator inputs the type and quality of the grain into the microprocessor through the control button, and the microprocessor controls The detection probe inhales the volatile gas emitted by the grain into the air chamber for 5 to 20 seconds. The volatile gas is in contact with each gas-sensitive film installed in the air chamber. Each gas-sensitive film generates a response signal respectively, and the microprocessor calculates each response. The average signal of the signal obtains the detection signal I(t);

(7-3)将I(t)输入级联双稳态随机共振系统模型中,调节a和b的数值,使级联双稳态随机共振系统模型发生共振,微处理器将共振时的a和b值存储在存储器中;(7-3) Input I(t) into the cascaded bistable stochastic resonance system model, adjust the values of a and b, so that the cascaded bistable stochastic resonance system model resonates, and the microprocessor will resonate a and b values are stored in memory;

(7-4)微处理器设定级联双稳态随机共振系统模型中的一组f0和t值,得到一组参数值x1,y1,将a、b和x1,y1代入公式中计算设定检测信号I(t)的恢复信号为将h(t)输入谷物P的单级双稳态随机共振模型中,使单级双稳态随机共振模型发生共振;(7-4) The microprocessor sets a set of f 0 , and t value to get a set of parameter values x 1 , y 1 , and substitute a, b and x 1 , y 1 into the formula Calculated in Set the recovery signal of the detection signal I(t) as Input h(t) into the single-stage bistable stochastic resonance model of grain P to make the single-stage bistable stochastic resonance model resonate;

(7-5)微处理器利用公式计算激励噪声信噪比SNR,微处理器画出随机共振系统模型的信噪比谱图,在信噪比谱图中选取信噪比谱特征值噪声宽度W,并将信噪比谱特征值噪声宽度W与谷物P的霉变阈值N相比较;当|W|≥|N|时,则微处理器控制显示屏显示该种谷物腐败的报警信息。(7-5) Microprocessor utilization formula Calculate the excitation noise signal-to-noise ratio SNR, the microprocessor draws the signal-to-noise ratio spectrum of the stochastic resonance system model, selects the signal-to-noise ratio spectrum eigenvalue noise width W in the signal-to-noise ratio spectrum, and sets the signal-to-noise ratio spectrum eigenvalue The noise width W is compared with the mildew threshold N of the grain P; when |W|≥|N|, the microprocessor controls the display to display the alarm information of the grain corruption.

本发明的家用谷物检测装置体积较小,气室体积较小,采用的微型气泵气体流量有限,检测的时间较短,数据采集卡采集的数据长度有限,通常需要采集1000个以上的数据才能得到准确的检测结果,而数据采集卡中采集的数据只有80至100个,采集的数据个数较低会导致检测准确度的下降。因此,本发明采用独特的数据恢复方法对低采样数据进行无损恢复,将有限个采样数据变成无限个数据,从而保证检测准确性的要求。The household grain detection device of the present invention has small volume, small air chamber volume, limited gas flow rate of the micro air pump adopted, short detection time, and limited data length collected by the data acquisition card, usually more than 1000 data need to be collected to obtain Accurate detection results, while the data collected in the data acquisition card is only 80 to 100, and the low number of collected data will lead to a decline in detection accuracy. Therefore, the present invention adopts a unique data recovery method to perform non-destructive recovery on low-sampled data, and turns limited sampled data into unlimited data, thus ensuring the requirement of detection accuracy.

然后,将h(t)输入谷物P的单级双稳态随机共振中,使单级双稳态随机共振发生共振;微处理器画出随机共振系统模型的信噪比谱图,在信噪比谱图中选取信噪比谱特征值噪声宽度W,并将信噪比谱特征值噪声宽度W与谷物P的霉变阈值N相比较;当|W|≥|N|时,则微处理器控制显示屏显示该种谷物腐败的报警信息。Then, input h(t) into the single-stage bistable stochastic resonance of grain P, so that the single-stage bistable stochastic resonance resonates; the microprocessor draws the signal-to-noise ratio spectrum of the stochastic resonance system model, and the Select the signal-to-noise ratio spectrum eigenvalue noise width W in the ratio spectrum, and compare the signal-to-noise ratio spectrum eigenvalue noise width W with the mildew threshold N of the grain P; when |W|≥|N|, the microprocessing The control display screen of the machine will display the alarm information of the spoilage of this kind of grain.

作为优选,所述还包括USIM卡和射频无线收发器电连接;USIM卡和射频无线收发器分别与微处理器电连接,还包括如下步骤:当W≥N时,则微处理器从USIM卡中读取预先存储在USIM卡中的家庭成员的手机号码,将谷物检测结果作为短信内容,通过射频无线收发器发送给家庭各个成员,并获取短信发送回执信息,并将短信发送回执信息显示在显示屏上。As preferably, it also includes the electrical connection between the USIM card and the radio frequency wireless transceiver; the USIM card and the radio frequency wireless transceiver are respectively electrically connected with the microprocessor, and also includes the following steps: when W≥N, the microprocessor from the USIM card Read the mobile phone numbers of family members pre-stored in the USIM card, send the grain detection results as SMS content to each member of the family through the RF wireless transceiver, and obtain the SMS sending receipt information, and display the SMS sending receipt information on the on the display.

因此,本发明具有如下有益效果:(1)经济性好、体积小、检测简单、快速;(2)适合家庭使用,可为提高家用食材的安全性提供可靠保证。Therefore, the present invention has the following beneficial effects: (1) good economy, small size, simple and rapid detection; (2) suitable for home use, and can provide a reliable guarantee for improving the safety of household ingredients.

附图说明Description of drawings

图1是本发明的一种原理框图;Fig. 1 is a kind of functional block diagram of the present invention;

图2是本发明的实施例的一种流程图;Fig. 2 is a kind of flowchart of the embodiment of the present invention;

图3是本发明检测的燕麦的一种输出信噪比谱图;Fig. 3 is a kind of output SNR spectrogram of the oat that the present invention detects;

图4是本发明的绝缘电路板及气体敏感膜的一种结构示意图。Fig. 4 is a schematic structural view of the insulating circuit board and the gas-sensitive film of the present invention.

图中:壳体1、检测探头2、微型气泵3、气室4、运算放大器5、数据采集卡6、存储器7、微处理器8、控制按钮9、绝缘电路板10、气体敏感膜11、加热引脚12、检测引脚13、固定引脚14、USIM卡15、射频无线收发器16、显示屏17。In the figure: housing 1, detection probe 2, micro air pump 3, air chamber 4, operational amplifier 5, data acquisition card 6, memory 7, microprocessor 8, control button 9, insulating circuit board 10, gas sensitive film 11, Heating pin 12, detection pin 13, fixing pin 14, USIM card 15, radio frequency wireless transceiver 16, display screen 17.

具体实施方式Detailed ways

下面结合附图和具体实施方式对本发明做进一步的描述。The present invention will be further described below in conjunction with the accompanying drawings and specific embodiments.

如图1所示的实施例是一种家用谷物品质检测装置,包括壳体1、设于壳体上的检测探头2,检测探头与微型气泵3相连接;所述壳体内设有气室4、运算放大器5、数据采集卡6、存储器7和微处理器8,壳体上设有显示屏17和测量控制按钮和复位控制按钮9;复位按钮是用于复位重置使用的,用于装置重置过程,防止装置死机失灵。The embodiment shown in Figure 1 is a kind of household grain quality detection device, comprises housing 1, is located at the detection probe 2 on the housing, and detection probe is connected with miniature air pump 3; Described housing is provided with air chamber 4 , operational amplifier 5, data acquisition card 6, memory 7 and microprocessor 8, display screen 17 and measurement control button and reset control button 9 are arranged on the housing; The reset process prevents the device from crashing and malfunctioning.

运算放大器的输出端与数据采集卡电连接,微处理器分别与数据采集卡、显示屏、存储器、气泵和各个控制按钮电连接;所述检测探头一端与气室相连接,检测探头另一端上设有进气口,进气口上设有过滤网;所述气室内设有绝缘电路板10上,绝缘电路板上设有7个气体敏感膜11,各个气体敏感膜分别与运算放大器的输入端电连接。The output terminal of the operational amplifier is electrically connected with the data acquisition card, and the microprocessor is electrically connected with the data acquisition card, display screen, memory, air pump and each control button respectively; one end of the detection probe is connected with the air chamber, and the other end of the detection probe is An air inlet is provided, and a filter screen is provided on the air inlet; an insulating circuit board 10 is arranged in the air chamber, and seven gas-sensitive films 11 are arranged on the insulating circuit board, and each gas-sensitive film is connected to the input terminal of the operational amplifier respectively. electrical connection.

7个气体敏感膜分别为用于检测硫化物的第一气体敏感膜,用于检测氢气的第二气体敏感膜,用于检测氨气的第三气体敏感膜,用于检测酒精、甲苯、二甲苯的第四气体敏感膜,用于检测碳氢组分气体的第五气体敏感膜,用于检测甲烷和丙烷的第六气体敏感膜,用于检测氮氧化物的第七气体敏感膜。The seven gas sensitive membranes are the first gas sensitive membrane for detecting sulfide, the second gas sensitive membrane for detecting hydrogen, the third gas sensitive membrane for detecting ammonia, and the third gas sensitive membrane for detecting alcohol, toluene, di The fourth gas-sensitive membrane for toluene, the fifth gas-sensitive membrane for detecting hydrocarbon gas, the sixth gas-sensitive membrane for detecting methane and propane, and the seventh gas-sensitive membrane for detecting nitrogen oxides.

如图4所示,气体敏感膜呈长度为15毫米的两端开口中空纺锤体状,气体敏感膜中部直径为3.3毫米,气体敏感膜两端直径均为1.6毫米,气体敏感膜的厚度为1.18毫米;气体敏感膜的空腔内设有加热电阻丝,加热电阻丝两端分别通过加热引脚12与电源电连接,气体敏感膜上设有两个检测引脚13和与绝缘电路板相连接的两个固定引脚14,两个检测引脚分别与运算放大器的同相输入端和反相输入端电连接。As shown in Figure 4, the gas-sensitive membrane is in the shape of a hollow spindle with two ends opening with a length of 15 mm. The diameter of the middle part of the gas-sensitive membrane is 3.3 mm. The cavity of the gas-sensitive film is provided with a heating resistance wire, and the two ends of the heating resistance wire are electrically connected to the power supply through the heating pin 12, and the gas-sensitive film is provided with two detection pins 13 and connected to the insulating circuit board The two fixed pins 14 and the two detection pins are respectively electrically connected to the non-inverting input terminal and the inverting input terminal of the operational amplifier.

气室的宽度为1厘米,长度为1.9厘米,厚度为0.4厘米。还包括USIM卡和射频无线收发器电连接;USIM卡15和射频无线收发器16分别与微处理器电连接。The air chamber has a width of 1 cm, a length of 1.9 cm, and a thickness of 0.4 cm. It also includes the electrical connection between the USIM card and the radio frequency wireless transceiver; the USIM card 15 and the radio frequency wireless transceiver 16 are respectively electrically connected with the microprocessor.

运算放大器为UPC4570低噪运算贴片放大器,数据采集卡为基于MSP430F5438的低功耗嵌入式数据采集卡,微处理器为MSP430F149低功耗嵌入式MCU,显示屏为触摸屏。The operational amplifier is a UPC4570 low-noise operational patch amplifier, the data acquisition card is a low-power embedded data acquisition card based on MSP430F5438, the microprocessor is an MSP430F149 low-power embedded MCU, and the display is a touch screen.

如图2所示的一种家用谷物品质检测装置的检测方法,包括如下步骤:A kind of detection method of household grain quality detection device as shown in Figure 2, comprises the following steps:

存储器中设有级联双稳态随机共振系统模型,所述级联双稳态随机共振系统模型包括一级双稳态随机共振系统模型:和以一级双稳态随机共振系统模型的输出x(t)作为输入信号的二级双稳态随机共振系统模型:其中,V(x)和V(y)为非线性对称势函数,ξ(t)为高斯白噪声,a和b是输入信号强度,f0是调制信号频率,D是噪声强度,为相位,x和y为质点运动位移,t为时间;A cascaded bistable stochastic resonance system model is provided in the memory, and the cascaded bistable stochastic resonance system model includes a first-order bistable stochastic resonance system model: and the second-order bistable stochastic resonance system model with the output x(t) of the first-order bistable stochastic resonance system model as the input signal: Among them, V(x) and V(y) are nonlinear symmetric potential functions, ξ(t) is Gaussian white noise, a and b are the input signal strength, f0 is the modulation signal frequency, D is the noise strength, is the phase, x and y are the motion displacement of the particle, and t is the time;

存储器中还设有与谷物种类相对应的单级随机共振系统模型和信噪比计算公式: SNR = 2 [ lim Δω → 0 ∫ Ω - Δω Ω + Δω S ( ω ) dω ] / S N ( Ω ) ;其中ω是信号频率,Ω为角频率,S(ω)是信号频谱密度,SN(Ω)是信号频率范围内的噪声强度;微处理器中设有与谷物种类相对应的霉变阈值N;The memory also has a single-stage stochastic resonance system model corresponding to the grain type and a calculation formula for the signal-to-noise ratio: SNR = 2 [ lim Δω &Right Arrow; 0 ∫ Ω - Δω Ω + Δω S ( ω ) dω ] / S N ( Ω ) ; Wherein ω is the signal frequency, Ω is the angular frequency, S(ω) is the signal spectral density, S N (Ω) is the noise intensity in the signal frequency range; the microprocessor is provided with a mildew threshold corresponding to the grain type N;

本实施例中,花生的霉变阈值N=-87.5dB,荞麦的霉变阈值N=-79.7dB,大米的霉变阈值N=-68.4dB,燕麦的霉变阈值N=-73.1dB;In this embodiment, the mildew threshold of peanuts N=-87.5dB, the mildew threshold of buckwheat N=-79.7dB, the mildew threshold of rice N=-68.4dB, and the mildew threshold of oats N=-73.1dB;

步骤100,将检测探头的进气口靠近燕麦,检测操作者通过控制按钮将谷物的种类及质量输入到微处理器中,微处理器控制检测探头将燕麦散发出的挥发性气体吸入气室中5至20秒,挥发性气体与设于气室内的各个气体敏感膜相接触,各个气体敏感膜分别产生响应信号,微处理器计算各个响应信号的平均信号,得到检测信号I(t);Step 100, put the air inlet of the detection probe close to the oats, the detection operator inputs the type and quality of the grains into the microprocessor through the control button, and the microprocessor controls the detection probe to inhale the volatile gas emitted by the oats into the air chamber For 5 to 20 seconds, the volatile gas is in contact with each gas-sensitive film arranged in the gas chamber, and each gas-sensitive film generates a response signal respectively, and the microprocessor calculates the average signal of each response signal to obtain the detection signal I(t);

步骤200,将I(t)输入级联双稳态随机共振系统模型中,调节a和b的数值,使级联双稳态随机共振系统模型发生共振,微处理器将共振时的a=12和b=6值存储在存储器中;Step 200, input I(t) into the cascaded bistable stochastic resonance system model, adjust the values of a and b, so that the cascaded bistable stochastic resonance system model resonates, and the microprocessor will resonate when a=12 and b=6 values are stored in memory;

步骤300,微处理器设定级联双稳态随机共振系统模型中的一组f0=6.4、和t=4.5值,得到一组参数值x1=0.96,y1=1.42,将a=12、b=6和x1=0.96,y1=1.42,代入公式中计算得到设定检测信号I(t)的恢复信号为h(t)=-1.7t+t3,将h(t)输入燕麦的单级双稳态随机共振模型中,使单级双稳态随机共振模型发生共振;不同谷物的单级双稳态随机共振模型各不相同;Step 300, the microprocessor sets a set of f 0 =6.4, and t=4.5 value, get a set of parameter values x 1 =0.96, y 1 =1.42, put a=12, b=6 and x 1 =0.96, y 1 =1.42 into the formula Calculated in get Set the recovery signal of the detection signal I(t) as h(t)=-1.7t+t 3 , and input h(t) into the single-stage bistable stochastic resonance model of oats In , the single-stage bistable stochastic resonance model is resonated; the single-stage bistable stochastic resonance models of different grains are different;

步骤400,微处理器利用公式计算激励噪声信噪比SNR,微处理器画出随机共振系统模型的输出信噪比谱图,在输出信噪比谱图中选取信噪比谱特征值噪声宽度W,并将信噪比谱特征值噪声宽度W与谷物P的霉变阈值N相比较;当|W|≥|N|时,则微处理器控制显示屏显示该种谷物腐败的报警信息。Step 400, the microprocessor utilizes the formula Calculate the excitation noise signal-to-noise ratio SNR, the microprocessor draws the output signal-to-noise ratio spectrum diagram of the stochastic resonance system model, selects the signal-to-noise ratio spectrum eigenvalue noise width W in the output signal-to-noise ratio spectrum diagram, and converts the signal-to-noise ratio spectrum The eigenvalue noise width W is compared with the mildew threshold N of the grain P; when |W|≥|N|, the microprocessor controls the display to display the alarm information of the grain spoilage.

当|W|≥|N|时,则微处理器从USIM卡中读取预先存储在USIM卡中的家庭成员的手机号码,将谷物检测结果作为短信内容,通过射频无线收发器发送给家庭各个成员,并获取短信发送回执信息,并将短信发送回执信息显示在显示屏上。When |W|≥|N|, the microprocessor reads the mobile phone number of the family members pre-stored in the USIM card from the USIM card, and sends the grain detection result as a short message to each family member through a radio frequency wireless transceiver. member, and obtain the SMS sending receipt information, and display the SMS sending receipt information on the display screen.

本实施例中,得到被检测的燕麦的如图3所示的输出信噪比谱图,在图3中作一条纵坐标等于-90dB的直线,得到直线与曲线的在峰谷附近的两个交点的横坐标W1=112dB和W2=257dB,W=W2-W1=145dB。In the present embodiment, obtain the output signal-to-noise ratio spectrogram as shown in Figure 3 of the detected oats, in Figure 3 make a straight line whose ordinate is equal to-90dB, obtain the two near peaks and valleys of the straight line and the curve The abscissa of the intersection point W 1 =112dB and W 2 =257dB, W=W 2 -W 1 =145dB.

本实施例中,燕麦的W=145dB,燕麦的霉变阈值N=-73.1dB;因此,燕麦的|W|>|N|,则微处理器控制显示屏显示燕麦腐败的报警信息。In this embodiment, W=145dB of oats, and the mildew threshold N=-73.1dB of oats; therefore, |W|>|N| of oats, and the microprocessor controls the display to display an alarm message of oats corruption.

本实施例中,微处理器从USIM卡中读取预先存储在USIM卡中的家庭成员的手机号码,将燕麦腐败的检测结果作为短信内容,通过射频无线收发器发送给家庭各个成员,并获取短信发送回执信息,并将短信发送回执信息显示在显示屏上。In this embodiment, the microprocessor reads the mobile phone numbers of the family members pre-stored in the USIM card from the USIM card, sends the detection result of oat corruption as a short message to each member of the family through a radio frequency wireless transceiver, and obtains The SMS sending receipt information is displayed on the display screen.

应理解,本实施例仅用于说明本发明而不用于限制本发明的范围。此外应理解,在阅读了本发明讲授的内容之后,本领域技术人员可以对本发明作各种改动或修改,这些等价形式同样落于本申请所附权利要求书所限定的范围。It should be understood that this embodiment is only used to illustrate the present invention but not to limit the scope of the present invention. In addition, it should be understood that after reading the teachings of the present invention, those skilled in the art can make various changes or modifications to the present invention, and these equivalent forms also fall within the scope defined by the appended claims of the present application.

Claims (8)

1.一种家用谷物品质检测装置,其特征是,包括壳体(1)、设于壳体上的检测探头(2),检测探头与微型气泵(3)相连接;所述壳体内设有气室(4)、运算放大器(5)、数据采集卡(6)、存储器(7)和微处理器(8),壳体上设有显示屏(17)和若干个控制按钮(9);运算放大器的输出端与数据采集卡电连接,所述微处理器分别与数据采集卡、显示屏、存储器、气泵和各个控制按钮电连接;所述检测探头一端与气室相连接,检测探头另一端上设有进气口,进气口上设有过滤网;所述气室内设有绝缘电路板(10)上,绝缘电路板上设有若干个气体敏感膜(11),各个气体敏感膜分别与运算放大器的输入端电连接。1. A household grain quality detection device is characterized in that it comprises a housing (1), a detection probe (2) located on the housing, and the detection probe is connected with a miniature air pump (3); An air chamber (4), an operational amplifier (5), a data acquisition card (6), a memory (7) and a microprocessor (8), and a display screen (17) and several control buttons (9) are arranged on the housing; The output end of the operational amplifier is electrically connected with the data acquisition card, and the microprocessor is electrically connected with the data acquisition card, display screen, memory, air pump and each control button respectively; one end of the detection probe is connected with the air chamber, and the other end of the detection probe is An air inlet is provided on one end, and a filter screen is provided on the air inlet; an insulating circuit board (10) is arranged in the air chamber, and several gas-sensitive films (11) are arranged on the insulating circuit board, and each gas-sensitive film is respectively Electrically connected to the input terminal of the operational amplifier. 2.根据权利要求1所述的家用谷物品质检测装置,其特征是,所述气体敏感膜为7个,分别为用于检测硫化物的第一气体敏感膜,用于检测氢气的第二气体敏感膜,用于检测氨气的第三气体敏感膜,用于检测酒精、甲苯、二甲苯的第四气体敏感膜,用于检测碳氢组分气体的第五气体敏感膜,用于检测甲烷和丙烷的第六气体敏感膜,用于检测氮氧化物的第七气体敏感膜。2. The household grain quality detection device according to claim 1, characterized in that there are seven gas-sensitive membranes, which are respectively the first gas-sensitive membrane for detecting sulfide and the second gas-sensitive membrane for detecting hydrogen Sensitive membrane, the third gas sensitive membrane used to detect ammonia, the fourth gas sensitive membrane used to detect alcohol, toluene, xylene, the fifth gas sensitive membrane used to detect hydrocarbon component gases, used to detect methane And the sixth gas sensitive membrane for propane, the seventh gas sensitive membrane for detecting nitrogen oxides. 3.根据权利要求1所述的家用谷物品质检测装置,其特征是,所述气体敏感膜呈长度为14至16毫米的两端开口中空纺锤体状,气体敏感膜中部直径为3.2毫米至3.6毫米,气体敏感膜两端直径均为1.5至1.6毫米,气体敏感膜的厚度为1毫米至1.25毫米;气体敏感膜的空腔内设有加热电阻丝,加热电阻丝两端分别通过加热引脚(12)与电源电连接,气体敏感膜上设有两个检测引脚(13)和与绝缘电路板相连接的两个固定引脚(14),两个检测引脚分别与运算放大器的同相输入端和反相输入端电连接。3. The household grain quality detection device according to claim 1, characterized in that, the gas-sensitive membrane is in the shape of a hollow spindle with both ends open and the length is 14 to 16 mm, and the diameter of the middle part of the gas-sensitive membrane is 3.2 mm to 3.6 mm. mm, the diameter of both ends of the gas sensitive film is 1.5 to 1.6 mm, the thickness of the gas sensitive film is 1 mm to 1.25 mm; the cavity of the gas sensitive film is equipped with a heating resistance wire, and the two ends of the heating resistance wire pass through the heating pin respectively (12) is electrically connected with the power supply, and the gas sensitive film is provided with two detection pins (13) and two fixed pins (14) connected with the insulating circuit board, and the two detection pins are respectively in phase with the operational amplifier The input terminal is electrically connected to the inverting input terminal. 4.根据权利要求1所述的家用谷物品质检测装置,其特征是,所述气室的宽度为0.8厘米至1.2厘米,长度为1.6至1.9厘米,厚度为0.3厘米至0.5厘米。4 . The household grain quality detection device according to claim 1 , wherein the air chamber has a width of 0.8 cm to 1.2 cm, a length of 1.6 cm to 1.9 cm, and a thickness of 0.3 cm to 0.5 cm. 5.根据权利要求1或2或3或4所述的家用谷物品质检测装置,其特征是,还包括USIM卡(15)和射频无线收发器(16)电连接;USIM卡和射频无线收发器分别与控制器电连接。5. according to claim 1 or 2 or 3 or 4 described household grain quality detecting devices, it is characterized in that, also comprise USIM card (15) and radio frequency wireless transceiver (16) electric connection; USIM card and radio frequency wireless transceiver are respectively electrically connected to the controller. 6.根据权利要求1或2或3或4所述的家用谷物品质检测装置,其特征是,运算放大器为UPC4570低噪运算贴片放大器,数据采集卡为基于MSP430F5438的低功耗嵌入式数据采集卡,控制器为MSP430F149低功耗嵌入式MCU,显示屏为触摸屏。6. according to claim 1 or 2 or 3 or 4 described household grain quality detecting devices, it is characterized in that, operational amplifier is UPC4570 low-noise operational patch amplifier, and data acquisition card is the embedded data acquisition of low power consumption based on MSP430F5438 Card, the controller is MSP430F149 low-power embedded MCU, and the display is a touch screen. 7.一种根据权利要求1所述的家用谷物品质检测装置的检测方法,其特征是,包括如下步骤:7. A detection method of the household grain quality detection device according to claim 1, characterized in that, comprising the steps of: (7-1)存储器中设有级联双稳态随机共振系统模型,所述级联双稳态随机共振系统模型包括一级双稳态随机共振系统模型:和以一级双稳态随机共振系统模型的输出x(t)作为输入信号的二级双稳态随机共振系统模型:其中,V(x)和V(y)为非线性对称势函数,ξ(t)为高斯白噪声,a和b是输入信号强度,f0是调制信号频率,D是噪声强度,为相位,x和y为质点运动位移,t为时间;(7-1) A cascaded bistable stochastic resonance system model is provided in the memory, and the cascaded bistable stochastic resonance system model includes a first-order bistable stochastic resonance system model: and the second-order bistable stochastic resonance system model with the output x(t) of the first-order bistable stochastic resonance system model as the input signal: Among them, V(x) and V(y) are nonlinear symmetric potential functions, ξ(t) is Gaussian white noise, a and b are the input signal strength, f0 is the modulation signal frequency, D is the noise strength, is the phase, x and y are the motion displacement of the particle, and t is the time; 存储器中还设有与谷物种类相对应的单级随机共振系统模型和信噪比计算公式: SNR = 2 [ lim Δω → 0 ∫ Ω - Δω Ω + Δω S ( ω ) dω ] / S N ( Ω ) ;其中ω是信号频率,Ω为角频率,S(ω)是信号频谱密度,SN(Ω)是信号频率范围内的噪声强度;微处理器中设有与谷物种类相对应的霉变阈值N;The memory also has a single-stage stochastic resonance system model corresponding to the grain type and a calculation formula for the signal-to-noise ratio: SNR = 2 [ lim Δω &Right Arrow; 0 ∫ Ω - Δω Ω + Δω S ( ω ) dω ] / S N ( Ω ) ; Wherein ω is the signal frequency, Ω is the angular frequency, S(ω) is the signal spectral density, S N (Ω) is the noise intensity in the signal frequency range; the microprocessor is provided with a mildew threshold corresponding to the grain type N; (7-2)设定P为任一种被检测谷物,将检测探头的进气口靠近谷物P,检测操作者通过控制按钮将谷物的种类及质量输入到微处理器中,微处理器控制检测探头将谷物散发出的挥发性气体吸入气室中5至20秒,挥发性气体与设于气室内的各个气体敏感膜相接触,各个气体敏感膜分别产生响应信号,微处理器计算各个响应信号的平均信号,得到检测信号I(t);(7-2) Set P as any grain to be detected, put the air inlet of the detection probe close to the grain P, and the detection operator inputs the type and quality of the grain into the microprocessor through the control button, and the microprocessor controls The detection probe inhales the volatile gas emitted by the grain into the air chamber for 5 to 20 seconds. The volatile gas is in contact with each gas-sensitive film installed in the air chamber. Each gas-sensitive film generates a response signal respectively, and the microprocessor calculates each response. The average signal of the signal obtains the detection signal I(t); (7-3)将I(t)输入级联双稳态随机共振系统模型中,调节a和b的数值,使级联双稳态随机共振系统模型发生共振,微处理器将共振时的a和b值存储在存储器中;(7-3) Input I(t) into the cascaded bistable stochastic resonance system model, adjust the values of a and b, so that the cascaded bistable stochastic resonance system model resonates, and the microprocessor will resonate a and b values are stored in memory; (7-4)微处理器设定级联双稳态随机共振系统模型中的一组f0和t值,得到一组参数值x1,y1,将a、b和x1,y1代入公式中计算设定检测信号I(t)的恢复信号为将h(t)输入谷物P的单级双稳态随机共振模型中,使单级双稳态随机共振模型发生共振;(7-4) The microprocessor sets a set of f 0 , and t value to get a set of parameter values x 1 , y 1 , and substitute a, b and x 1 , y 1 into the formula Calculated in Set the recovery signal of the detection signal I(t) as Input h(t) into the single-stage bistable stochastic resonance model of grain P to make the single-stage bistable stochastic resonance model resonate; (7-5)微处理器利用公式计算激励噪声信噪比SNR,微处理器画出随机共振系统模型的信噪比谱图,在信噪比谱图中选取信噪比谱特征值噪声宽度W,并将信噪比谱特征值噪声宽度W与谷物P的霉变阈值N相比较;当|W|≥|N|时,则微处理器控制显示屏显示该种谷物腐败的报警信息。(7-5) Microprocessor utilization formula Calculate the excitation noise signal-to-noise ratio SNR, the microprocessor draws the signal-to-noise ratio spectrum of the stochastic resonance system model, selects the signal-to-noise ratio spectrum eigenvalue noise width W in the signal-to-noise ratio spectrum, and sets the signal-to-noise ratio spectrum eigenvalue The noise width W is compared with the mildew threshold N of the grain P; when |W|≥|N|, the microprocessor controls the display to display the alarm information of the grain corruption. 8.根据权利要求7所述的家用谷物品质检测装置的检测方法,所述还包括USIM卡和射频无线收发器电连接;USIM卡和射频无线收发器分别与微处理器电连接,其特征是,还包括如下步骤:当W≥N时,则微处理器从USIM卡中读取预先存储在USIM卡中的家庭成员的手机号码,将谷物检测结果作为短信内容,通过射频无线收发器发送给家庭各个成员,并获取短信发送回执信息,并将短信发送回执信息显示在显示屏上。8. The detection method of the household grain quality detection device according to claim 7, said also comprising USIM card and radio frequency wireless transceiver electrically connected; USIM card and radio frequency wireless transceiver are electrically connected with microprocessor respectively, it is characterized in that , also includes the following steps: when W≥N, the microprocessor reads the mobile phone number of the family member pre-stored in the USIM card from the USIM card, and sends the grain detection result as a text message to the Each member of the family obtains the SMS sending receipt information, and displays the SMS sending receipt information on the display screen.
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104614300A (en) * 2015-02-11 2015-05-13 上海同标质量检测技术有限公司 Unmanned concrete permeability resistance testing system and method
CN109072165A (en) * 2016-01-22 2018-12-21 匡图里有限公司 For controlling the device of natural material fermentation

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09288076A (en) * 1996-04-09 1997-11-04 Lg Electron Inc Meat freshness measuring device using gas sensor, its measuring method and gas sensor manufacturing method
US5731510A (en) * 1995-06-24 1998-03-24 Sun Electric U.K. Limited Multi-gas sensor systems for automotive emissions measurement
CN101825624A (en) * 2009-03-02 2010-09-08 中国科学院化学研究所 Miniaturized total analysis device formed by six-channel microfluidic chip and quartz crystal microbalance
CN102297878A (en) * 2011-05-19 2011-12-28 浙江清华长三角研究院 Electronic nose system for rapid detection of pollution of volatile chlorinated hydrocarbons
CN102590288A (en) * 2012-01-17 2012-07-18 浙江工商大学 Food quality detection system and detection method based on electronic nose

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5731510A (en) * 1995-06-24 1998-03-24 Sun Electric U.K. Limited Multi-gas sensor systems for automotive emissions measurement
JPH09288076A (en) * 1996-04-09 1997-11-04 Lg Electron Inc Meat freshness measuring device using gas sensor, its measuring method and gas sensor manufacturing method
CN101825624A (en) * 2009-03-02 2010-09-08 中国科学院化学研究所 Miniaturized total analysis device formed by six-channel microfluidic chip and quartz crystal microbalance
CN102297878A (en) * 2011-05-19 2011-12-28 浙江清华长三角研究院 Electronic nose system for rapid detection of pollution of volatile chlorinated hydrocarbons
CN102590288A (en) * 2012-01-17 2012-07-18 浙江工商大学 Food quality detection system and detection method based on electronic nose

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104614300A (en) * 2015-02-11 2015-05-13 上海同标质量检测技术有限公司 Unmanned concrete permeability resistance testing system and method
CN109072165A (en) * 2016-01-22 2018-12-21 匡图里有限公司 For controlling the device of natural material fermentation

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