CN104087457A - Skin cleaner and preparation method thereof - Google Patents
Skin cleaner and preparation method thereof Download PDFInfo
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- CN104087457A CN104087457A CN201410330336.4A CN201410330336A CN104087457A CN 104087457 A CN104087457 A CN 104087457A CN 201410330336 A CN201410330336 A CN 201410330336A CN 104087457 A CN104087457 A CN 104087457A
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- Prior art keywords
- skin cleaner
- acid
- skin
- perfumed soap
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- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims abstract description 43
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 27
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 claims abstract description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 235000011187 glycerol Nutrition 0.000 claims abstract description 13
- 238000000034 method Methods 0.000 claims abstract description 7
- 239000002253 acid Substances 0.000 claims description 17
- 229940033355 lauric acid Drugs 0.000 claims description 14
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 12
- 239000000194 fatty acid Substances 0.000 claims description 12
- 229930195729 fatty acid Natural products 0.000 claims description 12
- 150000004665 fatty acids Chemical class 0.000 claims description 12
- 235000013162 Cocos nucifera Nutrition 0.000 claims description 11
- 244000060011 Cocos nucifera Species 0.000 claims description 11
- LXAHHHIGZXPRKQ-UHFFFAOYSA-N 5-fluoro-2-methylpyridine Chemical compound CC1=CC=C(F)C=N1 LXAHHHIGZXPRKQ-UHFFFAOYSA-N 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 3
- ZCTXEAQXZGPWFG-UHFFFAOYSA-N imidurea Chemical compound O=C1NC(=O)N(CO)C1NC(=O)NCNC(=O)NC1C(=O)NC(=O)N1CO ZCTXEAQXZGPWFG-UHFFFAOYSA-N 0.000 claims description 3
- 229940113174 imidurea Drugs 0.000 claims description 3
- 238000012423 maintenance Methods 0.000 claims description 3
- 239000000344 soap Substances 0.000 abstract description 36
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract description 2
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 abstract description 2
- QZXSMBBFBXPQHI-UHFFFAOYSA-N N-(dodecanoyl)ethanolamine Chemical compound CCCCCCCCCCCC(=O)NCCO QZXSMBBFBXPQHI-UHFFFAOYSA-N 0.000 abstract description 2
- 238000011010 flushing procedure Methods 0.000 abstract description 2
- 239000006260 foam Substances 0.000 abstract description 2
- BDOYKFSQFYNPKF-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]ethyl-(carboxymethyl)amino]acetic acid;sodium Chemical compound [Na].[Na].OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O BDOYKFSQFYNPKF-UHFFFAOYSA-N 0.000 abstract 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 abstract 1
- 229960001484 edetic acid Drugs 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 16
- 239000007788 liquid Substances 0.000 description 7
- 239000013543 active substance Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 150000002632 lipids Chemical class 0.000 description 4
- 230000003020 moisturizing effect Effects 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000013459 approach Methods 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 230000008719 thickening Effects 0.000 description 2
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- 235000009161 Espostoa lanata Nutrition 0.000 description 1
- 240000001624 Espostoa lanata Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 239000004141 Sodium laurylsulphate Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 239000003974 emollient agent Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- -1 fatty alcohol Vinyl Ether sodium sulfate Chemical class 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 229940051841 polyoxyethylene ether Drugs 0.000 description 1
- 229920000056 polyoxyethylene ether Polymers 0.000 description 1
- 229940072033 potash Drugs 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 1
- 235000015320 potassium carbonate Nutrition 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- 230000001835 salubrious effect Effects 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 239000003009 skin protective agent Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Landscapes
- Cosmetics (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a skin cleaner. The skin cleaner comprises the following components in percentage by weight: 20-50% of glycerin, 10-20% of dodecanoic acid, 6-12% of tetradecanoic acid, 4.5-9.0% of potassium hydroxide, 3-8% of coconut monoethanolamide, 0.5-3% of carbopol 940, 0.1% of EDTA (Ethylene Diamine Tetraacetic Acid)-disodium and the balance of water. The skin cleaner is paste, has the advantages of abundant foam, easiness for smearing and flushing, convenience and sanitation and is particularly suitable for consumers being used to using a perfumed soap. The invention also provides a preparation method of the skin cleaner. After being used, the skin cleaner prepared by using the method is easy to flush like the perfumed soap, has the specific unsmooth feeling of the perfumed soap and is more convenient to use and easier to store and guarantee the quality than the perfumed soap.
Description
Technical field
The present invention relates to a kind of skin cleaner, be specifically related to a kind of skin cleaner of paste.
Background technology
Traditional perfumed soap is solid, and use inconvenience and difficult preservation are put, easily contaminated and rotten, and fragrance is easy to volatilize and disperses in addition.
According to statistics, there is such group only to like using perfumed soap, reason to be can allow skin have a kind of distinctive " puckery " dry and comfortable sensation after perfumed soap is washed.Yet general body wash be difficult for to rinse, the residual meeting of its tensio-active agent smooth slipping with it after allowing this class people feel to wash, very uncomfortable.
Directly with soda soap (lipid acid and sodium hydroxide make), adding water or polyvalent alcohol dilution, to dissolve the liquid soap making extremely unstable, easily occurs layering, affects use.
Also just like < < liquid toliet soap > > application number 201310657290.2 of Lin Xiaoli, mention with soft soap and make liquid toliet soap at present; The < < liquid toliet soap > > application number 201110098897.2 that Nantong Hong Lida Knitting Company Ltd mentions, mentions with potash soap (lipid acid and potassium hydroxide make) and makes liquid toliet soap.
The general viscosity of liquid soap is lower, lower than the viscosity (30 ℃, be less than 2000mPaS) of common body wash, uses inconvenient.Because be not suitable for covering bottle dress with general wearing, during use, easily pour out a lot, cause waste.And with the bottle dress with pump head, will increase production cost.
In the patent of above-mentioned two applications, all mention tensio-active agents such as using sodium lauryl sulphate (being ether alcohol sulfate), fatty alcohol-polyoxyethylene ether (being polyethoxylated fatty alcohol) and fatty alcohol-ether sodium sulfate (being fatty alcohol Vinyl Ether sodium sulfate), and large usage quantity, cause detersive power easily to cause too by force the excessive degreasing of skin, injured skin.Meanwhile, these one-tenth branches increase " the sliding sense " after washing, and can not meet perfumed soap " fan's " unique need.Its reason is: the preparation of soft soap or become liquid, or just become to be difficult for to disperse thick, if do not add other compositions, be difficult to be made into easy to apply, easily disperse paste easy to use.
Summary of the invention
The object of the invention is to overcome the weak point that prior art exists and a kind of skin cleaner of paste is provided, the preparation method of described skin cleaner is also provided.
For achieving the above object, the technical scheme of taking: a kind of skin cleaner, described skin cleaner comprises the component of following weight percent: glycerine: 20～50%; Laurostearic acid: 10～20%; TETRADECONIC ACID: 6～12%; Potassium hydroxide: 4.5～9.0%; Coconut Fatty Acid Monoethanolamide: 3～8%; Acritamer 940: 0.5-3%; EDTA-disodium: 0.1%; Surplus is water.
Glycerine of the present invention is glycerol, is good system stabilizers, wetting Agent for Printing Inks, skin-protecting agent.
Laurostearic acid of the present invention has another name called lauric acid, is the main component of soap class tensio-active agent.
TETRADECONIC ACID of the present invention has another name called tetradecanoic acid, is the main component of soap class tensio-active agent.
Potassium hydroxide of the present invention, chemical formula KOH, can with the lipid acid generation saponification reactions such as laurostearic acid, TETRADECONIC ACID, obtain having surface-active fatty acid potassium soap.
Coconut Fatty Acid Monoethanolamide of the present invention, CAS:68140-00-1, good thickening property, froth stability, emollient and stability in hard water etc.Compatibleness is good, and has fabulous synergistic function.
Acritamer 940 of the present invention is a kind of vinylformic acid cross-linked resin, good rheology control agent, the effect that has thickening to suspend.
EDTA-2 sodium of the present invention is a kind of metal chelator, has the effect that strengthens washing effect.
Preferably, described skin cleaner comprises the component of following weight percent: glycerine: 50%; Laurostearic acid: 20%; TETRADECONIC ACID: 12%; Potassium hydroxide: 9%; Coconut Fatty Acid Monoethanolamide: 3%; Acritamer 940: 0.5%; EDTA-disodium: 0.1%; Surplus is water.
Preferably, described skin cleaner also comprises sanitas, and the weight percent of described sanitas in described skin cleaner is 0.1%.Sanitas of the present invention adds when skin cleaner temperature is down to below 50 ℃.
Preferably, described sanitas is Imidurea.Imidurea of the present invention is the gentle sanitas of a kind of used for cosmetic.
Preferably, described skin cleaner is paste.
Preferably, the viscosity of described skin cleaner in the time of 30 ℃ is 3000～30000mPaS.
The present invention also provides the preparation method of skin cleaner described above, said method comprising the steps of:
(1) in agitator, add water, EDTA-disodium, potassium hydroxide, Acritamer 940 and glycerine, heat while stirring;
(2) when temperature rises to 80 ℃, add laurostearic acid and TETRADECONIC ACID, at 80 ℃, after stirring and dissolving, add Coconut Fatty Acid Monoethanolamide, maintenance temperature stops heating after being stirred to dissolving, obtains described skin cleaner.
Beneficial effect of the present invention is: the skin cleaner that the invention provides a kind of paste, this sanitising agent has advantages of that foam is abundant, easy to apply, easily flushing and convenient and healthy, meet especially the human consumer that custom is used perfumed soap, the present invention also provides the preparation method of described skin cleaner, by easily rinsing as perfumed soap after the skin cleaner use that adopts the method to prepare, there is perfumed soap distinctive " puckery " sense, but more easy to use than perfumed soap, more easy to store and guarantee the quality.
Embodiment
For the object, technical solutions and advantages of the present invention are better described, below in conjunction with specific embodiment, the invention will be further described.
Embodiment 1
A kind of embodiment of skin cleaner of the present invention, described skin cleaner comprises the component of following weight percent: glycerine: 20%; Laurostearic acid: 10%; TETRADECONIC ACID: 6%; Potassium hydroxide: 4.8%; Coconut Fatty Acid Monoethanolamide: 8%; Acritamer 940: 3%; EDTA-disodium: 0.1%; Surplus is water.
The preparation method of skin cleaner described in the present embodiment, said method comprising the steps of:
(1) in agitator, add water, EDTA-disodium, potassium hydroxide, Acritamer 940 and glycerine, heat while stirring;
(2) when temperature rises to 80 ℃, add laurostearic acid and TETRADECONIC ACID, at 80 ℃, after stirring and dissolving, add Coconut Fatty Acid Monoethanolamide, maintenance temperature stops heating after being stirred to dissolving, obtains described skin cleaner.
Embodiment 2
A kind of embodiment of skin cleaner of the present invention, described skin cleaner comprises the component of following weight percent: glycerine: 40%; Laurostearic acid: 15%; TETRADECONIC ACID: 9%; Potassium hydroxide: 7.2%; Coconut Fatty Acid Monoethanolamide: 5%; Acritamer 940: 1.5%; EDTA-disodium: 0.1%; Surplus is water.
The preparation method of skin cleaner described in the present embodiment, described method is with the preparation method of embodiment 1.
Embodiment 3
A kind of embodiment of skin cleaner of the present invention, described skin cleaner comprises the component of following weight percent: glycerine: 50%; Laurostearic acid: 20%; TETRADECONIC ACID: 12%; Potassium hydroxide: 9%; Coconut Fatty Acid Monoethanolamide: 3%; Acritamer 940: 0.5%; EDTA-disodium: 0.1%; Surplus is water.
The preparation method of skin cleaner described in the present embodiment, described method is with the preparation method of embodiment 1.
Embodiment 4
Skin cleaner prepared by embodiment of the present invention 1-3 carries out efficacy test:
1, moisturizing test
Choose 30 experimenters and test, men and women half and half, and the age is from 30-50 year, 38 years old mean age, and to test and within first 2 months, do not use external preparation for skin medicine, skin is without wound.Allow experimenter use respectively tap water, perfumed soap, skin cleaner sample prepared by body wash, embodiment of the present invention 1-3, is divided into 7 days and tests, and only surveys a sample at every turn.Before each test, experimenter is with the clean both hands of clear water, towel, and slow-witted upper 2 hour in 25 ℃, the air-conditioned room of humidity 30rh, and the border circular areas that 4 random positions (each 2 of right-hand men) draw diameter 2cm on the back of the hand is as test zone.With 1g sample, wash one's hands 3 minutes, be over after dabbing off water on hand with cotton balls and start timing.With moisture of skin tester, test respectively in selection area the 5th minute, the 10th minute, the moisture value of skin in the time of the 30th minute, passed judgment on moisturizing degree according to moisture value size.The clear water of usining washing is as blank group.Test data is as table 1
The contrast of table 1 hand skin moisture value
Table 1 test data shows that the moisturizing ability of skin cleaner sample prepared by embodiment of the present invention 1-3 is all strong than perfumed soap and body wash, and can keep in a long time the moisture of skin, while especially using the skin cleaner of embodiment 3 preparations, effect is more outstanding.
2, skinfeel test
Object: checking use skin after product of the present invention whether to perfumed soap, feel similar.
Experimental technique: choose 30 experimenters and test, men and women half and half, the age is from 30-50 year, 38 years old mean age, to test and within first 2 months, do not use external preparation for skin medicine, skin is without wound.The skin cleaner sample that allows experimenter use respectively perfumed soap and embodiment 1-3 to prepare, is divided into 5 days and tests, and only surveys a sample at every turn.Before each test, experimenter is with the clean both hands of clear water, towel, slow-witted in 25 ℃, the air-conditioned room of humidity 30rh on 30min.With 1g sample, wash one's hands 3 minutes, the skinfeel of rinsing well after rear contrast perfumed soap is washed one's hands is marked, score value 1-10, skin wash after with more to approach score value with perfumed soap washing aftersensation higher.Its data are as table 2
The contrast of table 2 skinfeel similarity
| Sample | Embodiment 1 | Embodiment 2 | Embodiment 3 |
| Skinfeel score value | 9.35±0.21 | 9.68±0.15 | 9.89±0.10 |
Table 2 test data shows to use the skinfeel after skin cleaner cleaning skin prepared by embodiment 1-3 similar to perfumed soap, and along with lipid acid (laurostearic acid, TETRADECONIC ACID) content increases, skinfeel after its use just more approaches perfumed soap, while especially using the skin cleaner of embodiment 3 preparations.
Comprehensive analysis, skin cleaner of the present invention can allow people use aftersensation salubrious cleaning as used perfumed soap, and it is all good than perfumed soap and body wash to the moisturizing effect of skin and persistence, so the present invention can better meet " only liking using perfumed soap " this class consumer group's demand.
Last institute should be noted that; above embodiment is only in order to illustrate technical scheme of the present invention but not limiting the scope of the invention; although the present invention is explained in detail with reference to preferred embodiment; those of ordinary skill in the art is to be understood that; can modify or be equal to replacement technical scheme of the present invention, and not depart from essence and the scope of technical solution of the present invention.
Claims (7)
1. a skin cleaner, is characterized in that, described skin cleaner comprises the component of following weight percent: glycerine: 20～50%; Laurostearic acid: 10～20%; TETRADECONIC ACID: 6～12%; Potassium hydroxide: 4.5～9.0%; Coconut Fatty Acid Monoethanolamide: 3～8%; Acritamer 940: 0.5-3%; EDTA-disodium: 0.1%; Surplus is water.
2. skin cleaner according to claim 1, is characterized in that, described skin cleaner comprises the component of following weight percent: glycerine: 50%; Laurostearic acid: 20%; TETRADECONIC ACID: 12%; Potassium hydroxide: 9%; Coconut Fatty Acid Monoethanolamide: 3%; Acritamer 940: 0.5%; EDTA-disodium: 0.1%; Surplus is water.
3. skin cleaner according to claim 1, is characterized in that, described skin cleaner also comprises sanitas, and the weight percent of described sanitas in described skin cleaner is 0.1%.
4. skin cleaner according to claim 3, is characterized in that, described sanitas is Imidurea.
5. skin cleaner according to claim 1, is characterized in that, described skin cleaner is paste.
6. skin cleaner according to claim 1, is characterized in that, the viscosity of described skin cleaner in the time of 30 ℃ is 3000～30000mPaS.
7. a preparation method for skin cleaner as claimed in claim 1, is characterized in that, said method comprising the steps of:
(1) in agitator, add water, EDTA-disodium, potassium hydroxide, Acritamer 940 and glycerine, heat while stirring;
(2) when temperature rises to 80 ℃, add laurostearic acid and TETRADECONIC ACID, at 80 ℃, after stirring and dissolving, add Coconut Fatty Acid Monoethanolamide, maintenance temperature stops heating after being stirred to dissolving, obtains described skin cleaner.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410330336.4A CN104087457A (en) | 2014-07-11 | 2014-07-11 | Skin cleaner and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410330336.4A CN104087457A (en) | 2014-07-11 | 2014-07-11 | Skin cleaner and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
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| CN104087457A true CN104087457A (en) | 2014-10-08 |
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| CN201410330336.4A Pending CN104087457A (en) | 2014-07-11 | 2014-07-11 | Skin cleaner and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104449311A (en) * | 2014-11-13 | 2015-03-25 | 山东永泰化工有限公司 | Waterproof insulating paint and preparation method thereof |
| CN106137781A (en) * | 2016-08-26 | 2016-11-23 | 九江天赐高新材料有限公司 | A kind of skin cleansing composition |
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| CN103599021A (en) * | 2013-11-15 | 2014-02-26 | 上海应用技术学院 | Roselle extract as well as preparation method thereof and application thereof in whitening skincare cosmetics |
| WO2014073473A1 (en) * | 2012-11-08 | 2014-05-15 | 花王株式会社 | Cleaning-agent composition |
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2014
- 2014-07-11 CN CN201410330336.4A patent/CN104087457A/en active Pending
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| Publication number | Priority date | Publication date | Assignee | Title |
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| WO2014073473A1 (en) * | 2012-11-08 | 2014-05-15 | 花王株式会社 | Cleaning-agent composition |
| CN103599021A (en) * | 2013-11-15 | 2014-02-26 | 上海应用技术学院 | Roselle extract as well as preparation method thereof and application thereof in whitening skincare cosmetics |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104449311A (en) * | 2014-11-13 | 2015-03-25 | 山东永泰化工有限公司 | Waterproof insulating paint and preparation method thereof |
| CN106137781A (en) * | 2016-08-26 | 2016-11-23 | 九江天赐高新材料有限公司 | A kind of skin cleansing composition |
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Application publication date: 20141008 |