CN104062703B - A kind of bending resistance refractive power is fine - Google Patents
A kind of bending resistance refractive power is fine Download PDFInfo
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- CN104062703B CN104062703B CN201410323728.8A CN201410323728A CN104062703B CN 104062703 B CN104062703 B CN 104062703B CN 201410323728 A CN201410323728 A CN 201410323728A CN 104062703 B CN104062703 B CN 104062703B
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- 238000005452 bending Methods 0.000 title claims abstract description 120
- 239000013307 optical fiber Substances 0.000 claims abstract description 90
- 239000000835 fiber Substances 0.000 claims abstract description 12
- 239000010410 layer Substances 0.000 claims description 98
- 238000005253 cladding Methods 0.000 claims description 46
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 39
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 39
- 239000007983 Tris buffer Substances 0.000 claims description 32
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 31
- 238000004040 coloring Methods 0.000 claims description 27
- 239000002994 raw material Substances 0.000 claims description 26
- 239000011248 coating agent Substances 0.000 claims description 19
- 238000000576 coating method Methods 0.000 claims description 19
- 239000011247 coating layer Substances 0.000 claims description 15
- XMLYCEVDHLAQEL-UHFFFAOYSA-N 2-hydroxy-2-methyl-1-phenylpropan-1-one Chemical compound CC(C)(O)C(=O)C1=CC=CC=C1 XMLYCEVDHLAQEL-UHFFFAOYSA-N 0.000 claims description 13
- FHAOAWUJYUEJGF-UHFFFAOYSA-N N-[3-[2-aminopropyl(diethoxy)silyl]oxybutyl]prop-2-enamide Chemical compound C(C=C)(=O)NCCC(C)O[Si](OCC)(OCC)CC(C)N FHAOAWUJYUEJGF-UHFFFAOYSA-N 0.000 claims description 13
- 239000003822 epoxy resin Substances 0.000 claims description 13
- JUGMHUQFSYYJTB-UHFFFAOYSA-N n-(3-triethoxysilylpropyl)prop-2-enamide Chemical compound CCO[Si](OCC)(OCC)CCCNC(=O)C=C JUGMHUQFSYYJTB-UHFFFAOYSA-N 0.000 claims description 13
- 229920000647 polyepoxide Polymers 0.000 claims description 13
- 229920005749 polyurethane resin Polymers 0.000 claims description 13
- 229920002050 silicone resin Polymers 0.000 claims description 13
- -1 isopropyl Tris Chemical compound 0.000 claims description 7
- 229910019142 PO4 Inorganic materials 0.000 claims 1
- 125000004423 acyloxy group Chemical group 0.000 claims 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims 1
- 239000010452 phosphate Substances 0.000 claims 1
- 238000010276 construction Methods 0.000 abstract description 12
- 230000009286 beneficial effect Effects 0.000 abstract description 3
- 230000003287 optical effect Effects 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 238000010586 diagram Methods 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000005336 cracking Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/02—Optical fibres with cladding with or without a coating
- G02B6/028—Optical fibres with cladding with or without a coating with core or cladding having graded refractive index
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/02—Optical fibres with cladding with or without a coating
- G02B6/036—Optical fibres with cladding with or without a coating core or cladding comprising multiple layers
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/44—Mechanical structures for providing tensile strength and external protection for fibres, e.g. optical transmission cables
- G02B6/4401—Optical cables
- G02B6/4429—Means specially adapted for strengthening or protecting the cables
- G02B6/443—Protective covering
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- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Optical Fibers, Optical Fiber Cores, And Optical Fiber Bundles (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
Description
技术领域technical field
本发明属于光纤技术领域,尤其是涉及一种耐弯折的光纤。The invention belongs to the field of optical fiber technology, in particular to a bending-resistant optical fiber.
背景技术Background technique
随着光纤到户和光纤到桌面技术的飞速发展,光网络的建设日益加快。目前在光纤接入网中使用最广的是低水峰光纤,其弯曲半径一般推荐为30mm左右。然而,在实际使用中,用户或施工人员对于光纤的弯曲半径常常小于该推荐值,因此,常常会出现光纤的断裂,也就是说光纤的耐弯折性能不理想。With the rapid development of fiber-to-the-home and fiber-to-the-desktop technologies, the construction of optical networks is accelerating. At present, the most widely used in the optical fiber access network is the low water peak optical fiber, and its bending radius is generally recommended to be about 30mm. However, in actual use, the bending radius of the optical fiber by users or construction personnel is often smaller than the recommended value, so the optical fiber often breaks, that is to say, the bending resistance of the optical fiber is not ideal.
发明内容Contents of the invention
为了解决上述问题,本发明的目的是揭示一种耐弯折光纤,它可以在较低的弯曲半径下仍保持良好的光学及机械、环境温度性能,它是采用以下技术方案来实现的。In order to solve the above problems, the object of the present invention is to disclose a bend-resistant optical fiber, which can still maintain good optical, mechanical and ambient temperature performances at a relatively low bending radius, which is realized by the following technical solutions.
本发明的实施实例1中,一种耐弯折光纤,它包含有纤芯1、位于纤芯之外的包层2、位于包层之外的涂覆层3、位于涂覆层之外的着色层5,其特征在于:涂覆层与着色层之间还有一抗弯折外层4;所述包层直径为123~127μm,纤芯/包层同心度误差≤0.6μm,包层不圆度≤1.0%,涂覆层直径为210~230μm,抗弯折外层直径为225~245μm,着色层直径为240~260μm;所述耐弯折光纤以30mm的弯曲半径松绕100圈后,1310nm波长附加衰减≤0.05dB/Km,1383nm波长附加衰减≤0.05dB/Km,1550nm波长附加衰减≤0.1dB/Km,1625nm波长附加衰减≤0.1dB/Km;任取一段长度不小于10cm的耐弯折光纤,将耐弯折光纤两端同时同方向穿过内径为2mm的圆柱形孔后耐弯折光纤不断裂;所述耐弯折光纤中,纤芯的折射率>包层的折射率>涂覆层的折射率>抗弯折外层的折射率;所述抗弯折外层按重量份计,是由以下原料组成的:In Embodiment 1 of the present invention, a bend-resistant optical fiber includes a core 1, a cladding 2 outside the core, a coating 3 outside the cladding, and a coating outside the coating. The coloring layer 5 is characterized in that: there is an anti-bending outer layer 4 between the coating layer and the coloring layer; the diameter of the cladding is 123-127 μm, the core/cladding concentricity error is ≤0.6 μm, and the cladding is not Roundness ≤ 1.0%, the diameter of the coating layer is 210-230 μm, the diameter of the anti-bending outer layer is 225-245 μm, and the diameter of the colored layer is 240-260 μm; the bending-resistant optical fiber is loosely wound 100 times with a bending radius of 30 mm , the additional attenuation of 1310nm wavelength≤0.05dB/Km, the additional attenuation of 1383nm wavelength≤0.05dB/Km, the additional attenuation of 1550nm wavelength≤0.1dB/Km, the additional attenuation of 1625nm wavelength≤0.1dB/Km; Bending the optical fiber, the bending-resistant optical fiber does not break after passing both ends of the bending-resistant optical fiber in the same direction through a cylindrical hole with an inner diameter of 2 mm; in the bending-resistant optical fiber, the refractive index of the core > the refractive index of the cladding >Refractive index of the coating layer>Refractive index of the anti-bending outer layer; the anti-bending outer layer is composed of the following raw materials in parts by weight:
丙烯酰胺基乙基2—氨丙基三乙氧基硅烷或丙烯酰胺基丙基三乙氧基硅烷:15~25份;Acrylamidoethyl 2-aminopropyltriethoxysilane or acrylamidopropyltriethoxysilane: 15-25 parts;
丙烯酸有机硅树脂:15~35份;Acrylic silicone resin: 15-35 parts;
丙烯酸环氧树脂:15~35份;Acrylic epoxy resin: 15-35 parts;
丙烯酸聚氨脂树脂:15~25份;Acrylic polyurethane resin: 15-25 parts;
2—羟基—甲基—苯丙酮:1~2份;2-Hydroxy-methyl-propiophenone: 1 to 2 parts;
异丙基三(二辛基磷酸酰氧基)钛酸酯:2~5份;Isopropyl tris (dioctyl phosphate acyloxy) titanate: 2 to 5 parts;
所述着色层按重量份计,是由以下原料组成的:光纤着色油墨:98~100份;异丙基三(二辛基磷酸酰氧基)钛酸酯:1~2份;异丙基三(二辛基焦磷酸酰氧基)钛酸酯:0.5~1.5份。The colored layer is composed of the following raw materials in parts by weight: optical fiber coloring ink: 98-100 parts; isopropyl tris(dioctyl phosphate acyloxy) titanate: 1-2 parts; isopropyl Tris(dioctylpyrophosphate acyloxy) titanate: 0.5-1.5 parts.
本发明的实施实例2中,一种耐弯折光纤,它包含有纤芯1、位于纤芯之外的包层2、位于包层之外的涂覆层3、位于涂覆层之外的着色层5,其特征在于:纤芯与包层之间还有一抗弯折内层10;所述包层直径为123~127μm,纤芯/包层同心度误差≤0.6μm,包层不圆度≤1.0%,涂覆层直径为235~250μm,抗弯折内层直径为8.5~20μm,着色层直径为240~260μm;所述耐弯折光纤以30mm的弯曲半径松绕100圈后,1310nm波长附加衰减≤0.05dB/Km,1383nm波长附加衰减≤0.05dB/Km,1550nm波长附加衰减≤0.1dB/Km,1625nm波长附加衰减≤0.1dB/Km;任取一段长度不小于10cm的耐弯折光纤,将耐弯折光纤两端同时同方向穿过内径为2mm的圆柱形孔后耐弯折光纤不断裂;所述耐弯折光纤中,纤芯的折射率>抗弯折内层的折射率>包层的折射率>涂覆层的折射率;所述抗弯折内层按重量份计,是由以下原料组成的:In Embodiment 2 of the present invention, a bend-resistant optical fiber includes a core 1, a cladding 2 outside the core, a coating 3 outside the cladding, and a coating outside the coating. The colored layer 5 is characterized in that: there is an anti-bending inner layer 10 between the core and the cladding; the diameter of the cladding is 123-127 μm, the concentricity error of the core/cladding is ≤0.6 μm, and the cladding is not round degree ≤ 1.0%, the diameter of the coating layer is 235-250 μm, the diameter of the anti-bending inner layer is 8.5-20 μm, and the diameter of the colored layer is 240-260 μm; after the bending-resistant optical fiber is loosely wound 100 times with a bending radius of 30 mm, The additional attenuation of 1310nm wavelength≤0.05dB/Km, the additional attenuation of 1383nm wavelength≤0.05dB/Km, the additional attenuation of 1550nm wavelength≤0.1dB/Km, the additional attenuation of 1625nm wavelength≤0.1dB/Km; any length of bending resistance not less than 10cm Bending optical fiber, the bending-resistant optical fiber does not break after passing both ends of the bending-resistant optical fiber in the same direction through a cylindrical hole with an inner diameter of 2 mm; in the bending-resistant optical fiber, the refractive index of the core > the bending-resistant inner layer Refractive index>refractive index of the cladding layer>refractive index of the coating layer; the anti-bending inner layer is composed of the following raw materials in parts by weight:
丙烯酰胺基乙基2—氨丙基三乙氧基硅烷或丙烯酰胺基丙基三乙氧基硅烷:15~25份;Acrylamidoethyl 2-aminopropyltriethoxysilane or acrylamidopropyltriethoxysilane: 15-25 parts;
丙烯酸有机硅树脂:15~35份;Acrylic silicone resin: 15-35 parts;
丙烯酸环氧树脂:15~35份;Acrylic epoxy resin: 15-35 parts;
丙烯酸聚氨脂树脂:15~25份;Acrylic polyurethane resin: 15-25 parts;
2—羟基—甲基—苯丙酮:1~2份;2-Hydroxy-methyl-propiophenone: 1 to 2 parts;
异丙基三(二辛基磷酸酰氧基)钛酸酯:2~5份;Isopropyl tris (dioctyl phosphate acyloxy) titanate: 2 to 5 parts;
所述着色层按重量份计,是由以下原料组成的:光纤着色油墨:98~100份;异丙基三(二辛基磷酸酰氧基)钛酸酯:1~2份;异丙基三(二辛基焦磷酸酰氧基)钛酸酯:0.5~1.5份。The colored layer is composed of the following raw materials in parts by weight: optical fiber coloring ink: 98-100 parts; isopropyl tris(dioctyl phosphate acyloxy) titanate: 1-2 parts; isopropyl Tris(dioctylpyrophosphate acyloxy) titanate: 0.5-1.5 parts.
本发明的实施实例3中,一种耐弯折光纤,它包含有纤芯1、位于纤芯之外的包层2、位于包层之外的涂覆层3、位于涂覆层之外的着色层5,其特征在于:涂覆层与着色层之间还有一抗弯折外层4,纤芯与包层之间还有一抗弯折内层10;所述包层直径为123~127μm,纤芯/包层同心度误差≤0.6μm,包层不圆度≤1.0%,涂覆层直径为210~230μm;抗弯折内层直径为8.5~20μm;抗弯折外层直径为225~245μm;着色层直径为240~260μm;所述耐弯折光纤以30mm的弯曲半径松绕100圈后,1310nm波长附加衰减≤0.05dB/Km,1383nm波长附加衰减≤0.05dB/Km,1550nm波长附加衰减≤0.1dB/Km,1625nm波长附加衰减≤0.1dB/Km;任取一段长度不小于10cm的耐弯折光纤,将耐弯折光纤两端同时同方向穿过内径为2mm的圆柱形孔后耐弯折光纤不断裂;所述耐弯折光纤中,纤芯的折射率>抗弯折内层的折射率>包层的折射率>涂覆层的折射率>抗弯折外层的折射率;所述抗弯折内层及抗弯折外层按重量份计,都是由以下原料组成的:In Embodiment 3 of the present invention, a bend-resistant optical fiber includes a core 1, a cladding 2 outside the core, a coating 3 outside the cladding, and a coating outside the coating. The colored layer 5 is characterized in that there is an anti-bending outer layer 4 between the coating layer and the colored layer, and an anti-bending inner layer 10 between the core and the cladding; the diameter of the cladding is 123-127 μm , core/cladding concentricity error≤0.6μm, cladding out-of-roundness≤1.0%, coating layer diameter is 210-230μm; anti-bending inner layer diameter is 8.5-20μm; anti-bending outer layer diameter is 225 ~245μm; the diameter of the colored layer is 240~260μm; after the bend-resistant optical fiber is loosely wound 100 times with a bending radius of 30mm, the additional attenuation of 1310nm wavelength is ≤0.05dB/Km, the additional attenuation of 1383nm wavelength is ≤0.05dB/Km, and the wavelength of 1550nm Additional attenuation ≤ 0.1dB/Km, 1625nm wavelength additional attenuation ≤ 0.1dB/Km; Take any bend-resistant optical fiber with a length of not less than 10cm, and pass both ends of the bend-resistant optical fiber in the same direction through a cylindrical hole with an inner diameter of 2mm Afterwards, the bending-resistant optical fiber does not break; in the bending-resistant optical fiber, the refractive index of the core > the refractive index of the bending-resistant inner layer > the refractive index of the cladding > the refractive index of the coating layer > the refractive index of the bending-resistant outer layer Refractive index; the anti-bending inner layer and the anti-bending outer layer are all composed of the following raw materials in parts by weight:
丙烯酰胺基乙基2—氨丙基三乙氧基硅烷或丙烯酰胺基丙基三乙氧基硅烷:15~25份;Acrylamidoethyl 2-aminopropyltriethoxysilane or acrylamidopropyltriethoxysilane: 15-25 parts;
丙烯酸有机硅树脂:15~35份;Acrylic silicone resin: 15-35 parts;
丙烯酸环氧树脂:15~35份;Acrylic epoxy resin: 15-35 parts;
丙烯酸聚氨脂树脂:15~25份;Acrylic polyurethane resin: 15-25 parts;
2—羟基—甲基—苯丙酮:1~2份;2-Hydroxy-methyl-propiophenone: 1 to 2 parts;
异丙基三(二辛基磷酸酰氧基)钛酸酯:2~5份;Isopropyl tris (dioctyl phosphate acyloxy) titanate: 2 to 5 parts;
所述着色层按重量份计,是由以下原料组成的:光纤着色油墨:98~100份;异丙基三(二辛基磷酸酰氧基)钛酸酯:1~2份;异丙基三(二辛基焦磷酸酰氧基)钛酸酯:0.5~1.5份。The colored layer is composed of the following raw materials in parts by weight: optical fiber coloring ink: 98-100 parts; isopropyl tris(dioctyl phosphate acyloxy) titanate: 1-2 parts; isopropyl Tris(dioctylpyrophosphate acyloxy) titanate: 0.5-1.5 parts.
本发明中,由于具有了抗弯折内层或抗弯折外层或者兼具了抗弯折内层和抗弯折外层,且抗弯折内层、抗弯折外层具有极高柔韧性,因此,有效地保护了光纤,使光纤在小直径弯折的情况下,也达到了极其理想的耐弯折性能;本发明中的着色层由于其独特的配方,使其着色油墨的固化及延展性更高,在多次反复弯曲/弯折的情况下,也未见有着色层的开裂,为光纤的耐折提供了进一步的保障。In the present invention, due to the anti-bending inner layer or the outer layer of anti-bending or both the inner layer of anti-bending and the outer layer of anti-bending, and the inner layer of anti-bending and the outer layer of anti-bending are extremely flexible Therefore, the optical fiber is effectively protected, so that the optical fiber can achieve an extremely ideal bending resistance when it is bent with a small diameter; And the ductility is higher, and in the case of repeated bending/bending, there is no cracking of the colored layer, which provides a further guarantee for the bending resistance of the optical fiber.
本发明经过测试,除了所有光学指标满足ITU、IEC及国内光纤标准要求外,达到了任取一段长度不小于10cm的耐弯折光纤,将耐弯折光纤两端同时同方向穿过内径为2mm的圆柱形孔后耐弯折光纤不断裂的目标,因此,施工人员不再有施工中光纤易被折断的顾虑,施工更方便;而且,大大地扩大了光纤的应用范围,降低了光纤的使用要求。The invention has been tested, except that all optical indicators meet the requirements of ITU, IEC and domestic optical fiber standards, and it can take any bending-resistant optical fiber with a length of not less than 10cm, and pass both ends of the bending-resistant optical fiber in the same direction at the same time with an inner diameter of 2mm. The aim of the bending-resistant optical fiber behind the cylindrical hole is not to break. Therefore, the construction personnel no longer have to worry about the optical fiber being easily broken during construction, and the construction is more convenient; moreover, the application range of the optical fiber is greatly expanded and the use of the optical fiber is reduced. Require.
因此,本发明具有以下主要有益效果:结构简单、易实现、具有优良的耐折性能、使用范围更广、对于施工时弯曲要求更低。Therefore, the present invention has the following main beneficial effects: simple structure, easy realization, excellent folding resistance, wider application range, and lower bending requirements during construction.
附图说明Description of drawings
图1为本发明实施实例1的横截面结构示意图。Fig. 1 is a schematic diagram of the cross-sectional structure of Embodiment 1 of the present invention.
图2为本发明实施实例2的横截面结构示意图。Fig. 2 is a schematic diagram of the cross-sectional structure of Embodiment 2 of the present invention.
图3为本发明实施实例4的横截面结构示意图。Fig. 3 is a schematic diagram of the cross-sectional structure of Embodiment 4 of the present invention.
具体实施方式detailed description
实施实例1Implementation Example 1
一种耐弯折光纤,它包含有纤芯1、位于纤芯之外的包层2、位于包层之外的涂覆层3、位于涂覆层之外的着色层5,其特征在于:涂覆层与着色层之间还有一抗弯折外层4;所述包层直径为123~127μm,纤芯/包层同心度误差≤0.6μm,包层不圆度≤1.0%,涂覆层直径为210~230μm,抗弯折外层直径为225~245μm,着色层直径为240~260μm;所述耐弯折光纤以30mm的弯曲半径松绕100圈后,1310nm波长附加衰减≤0.05dB/Km,1383nm波长附加衰减≤0.05dB/Km,1550nm波长附加衰减≤0.1dB/Km,1625nm波长附加衰减≤0.1dB/Km;任取一段长度不小于10cm的耐弯折光纤,将耐弯折光纤两端同时同方向穿过内径为2mm的圆柱形孔后耐弯折光纤不断裂;所述耐弯折光纤中,纤芯的折射率>包层的折射率>涂覆层的折射率>抗弯折外层的折射率;所述抗弯折外层按重量份计,是由以下原料组成的:A bend-resistant optical fiber comprising a core 1, a cladding 2 outside the core, a coating 3 outside the cladding, and a colored layer 5 outside the coating, characterized in that: There is an anti-bending outer layer 4 between the coating layer and the colored layer; the cladding diameter is 123-127 μm, the core/cladding concentricity error is ≤0.6 μm, and the cladding out-of-roundness is ≤1.0%. The diameter of the layer is 210-230 μm, the diameter of the anti-bending outer layer is 225-245 μm, and the diameter of the colored layer is 240-260 μm; after the bending-resistant optical fiber is loosely wound 100 times with a bending radius of 30 mm, the additional attenuation of 1310 nm wavelength is ≤0.05 dB /Km, the additional attenuation of 1383nm wavelength≤0.05dB/Km, the additional attenuation of 1550nm wavelength≤0.1dB/Km, the additional attenuation of 1625nm wavelength≤0.1dB/Km; take any bending-resistant optical fiber with a length of not less than 10cm, and the bending-resistant Both ends of the optical fiber pass through a cylindrical hole with an inner diameter of 2 mm at the same time and the bending-resistant optical fiber does not break; in the bending-resistant optical fiber, the refractive index of the core > the refractive index of the cladding > the refractive index of the coating > The refractive index of the anti-bending outer layer; the anti-bending outer layer is composed of the following raw materials in parts by weight:
丙烯酰胺基乙基2—氨丙基三乙氧基硅烷或丙烯酰胺基丙基三乙氧基硅烷:15~25份;Acrylamidoethyl 2-aminopropyltriethoxysilane or acrylamidopropyltriethoxysilane: 15-25 parts;
丙烯酸有机硅树脂:15~35份;Acrylic silicone resin: 15-35 parts;
丙烯酸环氧树脂:15~35份;Acrylic epoxy resin: 15-35 parts;
丙烯酸聚氨脂树脂:15~25份;Acrylic polyurethane resin: 15-25 parts;
2—羟基—甲基—苯丙酮:1~2份;2-Hydroxy-methyl-propiophenone: 1 to 2 parts;
异丙基三(二辛基磷酸酰氧基)钛酸酯:2~5份;Isopropyl tris (dioctyl phosphate acyloxy) titanate: 2 to 5 parts;
所述着色层按重量份计,是由以下原料组成的:光纤着色油墨:98~100份;异丙基三(二辛基磷酸酰氧基)钛酸酯:1~2份;异丙基三(二辛基焦磷酸酰氧基)钛酸酯:0.5~1.5份。The colored layer is composed of the following raw materials in parts by weight: optical fiber coloring ink: 98-100 parts; isopropyl tris(dioctyl phosphate acyloxy) titanate: 1-2 parts; isopropyl Tris(dioctylpyrophosphate acyloxy) titanate: 0.5-1.5 parts.
经过申请人的反复试验,发现抗弯折外层按重量份计,由以下原料组成时效果最佳:After repeated tests by the applicant, it is found that the anti-bending outer layer has the best effect when it is composed of the following raw materials in terms of parts by weight:
丙烯酰胺基乙基2—氨丙基三乙氧基硅烷或丙烯酰胺基丙基三乙氧基硅烷:20份;Acrylamidoethyl 2-aminopropyltriethoxysilane or acrylamidopropyltriethoxysilane: 20 parts;
丙烯酸有机硅树脂:30份;Acrylic silicone resin: 30 parts;
丙烯酸环氧树脂:30份;Acrylic epoxy resin: 30 parts;
丙烯酸聚氨脂树脂:20份;Acrylic polyurethane resin: 20 parts;
2—羟基—甲基—苯丙酮:1.5份;2-Hydroxy-methyl-propiophenone: 1.5 parts;
异丙基三(二辛基磷酸酰氧基)钛酸酯:4份;Isopropyl tri(dioctyl phosphate acyloxy) titanate: 4 parts;
所述着色层按重量份计,由以下原料组成时效果最佳:光纤着色油墨:99份;异丙基三(二辛基磷酸酰氧基)钛酸酯:1.5份;异丙基三(二辛基焦磷酸酰氧基)钛酸酯:1份。The coloring layer has the best effect when it is composed of the following raw materials in parts by weight: optical fiber coloring ink: 99 parts; isopropyl tris(dioctyl phosphate acyloxy) titanate: 1.5 parts; isopropyl tris( Dioctyl pyrophosphate acyloxy) titanate: 1 part.
实施实例2Implementation Example 2
一种耐弯折光纤,它包含有纤芯1、位于纤芯之外的包层2、位于包层之外的涂覆层3、位于涂覆层之外的着色层5,其特征在于:纤芯与包层之间还有一抗弯折内层10;所述包层直径为123~127μm,纤芯/包层同心度误差≤0.6μm,包层不圆度≤1.0%,涂覆层直径为235~250μm,抗弯折内层直径为8.5~20μm,着色层直径为240~260μm;所述耐弯折光纤以30mm的弯曲半径松绕100圈后,1310nm波长附加衰减≤0.05dB/Km,1383nm波长附加衰减≤0.05dB/Km,1550nm波长附加衰减≤0.1dB/Km,1625nm波长附加衰减≤0.1dB/Km;任取一段长度不小于10cm的耐弯折光纤,将耐弯折光纤两端同时同方向穿过内径为2mm的圆柱形孔后耐弯折光纤不断裂;所述耐弯折光纤中,纤芯的折射率>抗弯折内层的折射率>包层的折射率>涂覆层的折射率;所述抗弯折内层按重量份计,是由以下原料组成的:A bend-resistant optical fiber comprising a core 1, a cladding 2 outside the core, a coating 3 outside the cladding, and a colored layer 5 outside the coating, characterized in that: There is also a bending-resistant inner layer 10 between the core and the cladding; the diameter of the cladding is 123-127 μm, the concentricity error of the core/cladding is ≤0.6 μm, the out-of-roundness of the cladding is ≤1.0%, and the coating layer The diameter is 235-250 μm, the diameter of the anti-bending inner layer is 8.5-20 μm, and the diameter of the colored layer is 240-260 μm; after the bending-resistant optical fiber is loosely wound 100 times with a bending radius of 30 mm, the additional attenuation of 1310nm wavelength is ≤0.05dB/ Km, 1383nm wavelength additional attenuation ≤ 0.05dB/Km, 1550nm wavelength additional attenuation ≤ 0.1dB/Km, 1625nm wavelength additional attenuation ≤ 0.1dB/Km; any bend-resistant fiber with a length of not less than 10cm is taken, and the bend-resistant fiber The bending-resistant optical fiber does not break after both ends pass through a cylindrical hole with an inner diameter of 2 mm at the same time; in the bending-resistant optical fiber, the refractive index of the core > the refractive index of the anti-bending inner layer > the refractive index of the cladding >The refractive index of the coating layer; the anti-bending inner layer is composed of the following raw materials in parts by weight:
丙烯酰胺基乙基2—氨丙基三乙氧基硅烷或丙烯酰胺基丙基三乙氧基硅烷:15~25份;Acrylamidoethyl 2-aminopropyltriethoxysilane or acrylamidopropyltriethoxysilane: 15-25 parts;
丙烯酸有机硅树脂:15~35份;Acrylic silicone resin: 15-35 parts;
丙烯酸环氧树脂:15~35份;Acrylic epoxy resin: 15-35 parts;
丙烯酸聚氨脂树脂:15~25份;Acrylic polyurethane resin: 15-25 parts;
2—羟基—甲基—苯丙酮:1~2份;2-Hydroxy-methyl-propiophenone: 1 to 2 parts;
异丙基三(二辛基磷酸酰氧基)钛酸酯:2~5份;Isopropyl tris (dioctyl phosphate acyloxy) titanate: 2 to 5 parts;
所述着色层按重量份计,是由以下原料组成的:光纤着色油墨:98~100份;异丙基三(二辛基磷酸酰氧基)钛酸酯:1~2份;异丙基三(二辛基焦磷酸酰氧基)钛酸酯:0.5~1.5份。The colored layer is composed of the following raw materials in parts by weight: optical fiber coloring ink: 98-100 parts; isopropyl tris(dioctyl phosphate acyloxy) titanate: 1-2 parts; isopropyl Tris(dioctylpyrophosphate acyloxy) titanate: 0.5-1.5 parts.
经过申请人的反复试验,发现抗弯折内层按重量份计,由以下原料组成时效果最佳:After repeated tests by the applicant, it is found that the anti-bending inner layer is best when it is composed of the following raw materials in parts by weight:
丙烯酰胺基乙基2—氨丙基三乙氧基硅烷或丙烯酰胺基丙基三乙氧基硅烷:20份;Acrylamidoethyl 2-aminopropyltriethoxysilane or acrylamidopropyltriethoxysilane: 20 parts;
丙烯酸有机硅树脂:30份;Acrylic silicone resin: 30 parts;
丙烯酸环氧树脂:30份;Acrylic epoxy resin: 30 parts;
丙烯酸聚氨脂树脂:20份;Acrylic polyurethane resin: 20 parts;
2—羟基—甲基—苯丙酮:1.5份;2-Hydroxy-methyl-propiophenone: 1.5 parts;
异丙基三(二辛基磷酸酰氧基)钛酸酯:4份;Isopropyl tri(dioctyl phosphate acyloxy) titanate: 4 parts;
所述着色层按重量份计,由以下原料组成时效果最佳:光纤着色油墨:99份;异丙基三(二辛基磷酸酰氧基)钛酸酯:1.5份;异丙基三(二辛基焦磷酸酰氧基)钛酸酯:1份。The coloring layer has the best effect when it is composed of the following raw materials in parts by weight: optical fiber coloring ink: 99 parts; isopropyl tris(dioctyl phosphate acyloxy) titanate: 1.5 parts; isopropyl tris( Dioctyl pyrophosphate acyloxy) titanate: 1 part.
实施实例3Implementation Example 3
一种耐弯折光纤,它包含有纤芯1、位于纤芯之外的包层2、位于包层之外的涂覆层3、位于涂覆层之外的着色层5,其特征在于:涂覆层与着色层之间还有一抗弯折外层4,纤芯与包层之间还有一抗弯折内层10;所述包层直径为123~127μm,纤芯/包层同心度误差≤0.6μm,包层不圆度≤1.0%,涂覆层直径为210~230μm;抗弯折内层直径为8.5~20μm;抗弯折外层直径为225~245μm;着色层直径为240~260μm;所述耐弯折光纤以30mm的弯曲半径松绕100圈后,1310nm波长附加衰减≤0.05dB/Km,1383nm波长附加衰减≤0.05dB/Km,1550nm波长附加衰减≤0.1dB/Km,1625nm波长附加衰减≤0.1dB/Km;任取一段长度不小于10cm的耐弯折光纤,将耐弯折光纤两端同时同方向穿过内径为2mm的圆柱形孔后耐弯折光纤不断裂;所述耐弯折光纤中,纤芯的折射率>抗弯折内层的折射率>包层的折射率>涂覆层的折射率>抗弯折外层的折射率;所述抗弯折内层及抗弯折外层按重量份计,都是由以下原料组成的:A bend-resistant optical fiber comprising a core 1, a cladding 2 outside the core, a coating 3 outside the cladding, and a colored layer 5 outside the coating, characterized in that: There is an anti-bending outer layer 4 between the coating layer and the colored layer, and an anti-bending inner layer 10 between the core and the cladding; the diameter of the cladding is 123-127 μm, and the core/cladding concentricity Error ≤ 0.6 μm, cladding out of roundness ≤ 1.0%, coating layer diameter is 210-230 μm; anti-bending inner layer diameter is 8.5-20 μm; anti-bending outer layer diameter is 225-245 μm; coloring layer diameter is 240 ~260μm; after the bend-resistant optical fiber is loosely wound 100 times with a bending radius of 30mm, the additional attenuation of 1310nm wavelength is ≤0.05dB/Km, the additional attenuation of 1383nm wavelength is ≤0.05dB/Km, and the additional attenuation of 1550nm wavelength is ≤0.1dB/Km, 1625nm wavelength additional attenuation ≤ 0.1dB/Km; Take any bend-resistant optical fiber with a length of not less than 10cm, and pass both ends of the bend-resistant optical fiber in the same direction at the same time through a cylindrical hole with an inner diameter of 2mm, and the bend-resistant optical fiber will not break; In the bending-resistant optical fiber, the refractive index of the core>the refractive index of the bending-resistant inner layer>the refractive index of the cladding>the refractive index of the coating layer>the refractive index of the bending-resistant outer layer; The inner layer and the anti-bending outer layer are composed of the following raw materials in parts by weight:
丙烯酰胺基乙基2—氨丙基三乙氧基硅烷或丙烯酰胺基丙基三乙氧基硅烷:15~25份;Acrylamidoethyl 2-aminopropyltriethoxysilane or acrylamidopropyltriethoxysilane: 15-25 parts;
丙烯酸有机硅树脂:15~35份;Acrylic silicone resin: 15-35 parts;
丙烯酸环氧树脂:15~35份;Acrylic epoxy resin: 15-35 parts;
丙烯酸聚氨脂树脂:15~25份;Acrylic polyurethane resin: 15-25 parts;
2—羟基—甲基—苯丙酮:1~2份;2-Hydroxy-methyl-propiophenone: 1 to 2 parts;
异丙基三(二辛基磷酸酰氧基)钛酸酯:2~5份;Isopropyl tris (dioctyl phosphate acyloxy) titanate: 2 to 5 parts;
所述着色层按重量份计,是由以下原料组成的:光纤着色油墨:98~100份;异丙基三(二辛基磷酸酰氧基)钛酸酯:1~2份;异丙基三(二辛基焦磷酸酰氧基)钛酸酯:0.5~1.5份。The colored layer is composed of the following raw materials in parts by weight: optical fiber coloring ink: 98-100 parts; isopropyl tris(dioctyl phosphate acyloxy) titanate: 1-2 parts; isopropyl Tris(dioctylpyrophosphate acyloxy) titanate: 0.5-1.5 parts.
经过申请人的反复试验,发现抗弯折内层及抗弯折外层按重量份计,都由以下原料组成时效果最佳:After repeated tests by the applicant, it is found that the bending-resistant inner layer and the bending-resistant outer layer are the best when they are composed of the following raw materials in parts by weight:
丙烯酰胺基乙基2—氨丙基三乙氧基硅烷或丙烯酰胺基丙基三乙氧基硅烷:20份;Acrylamidoethyl 2-aminopropyltriethoxysilane or acrylamidopropyltriethoxysilane: 20 parts;
丙烯酸有机硅树脂:30份;Acrylic silicone resin: 30 parts;
丙烯酸环氧树脂:30份;Acrylic epoxy resin: 30 parts;
丙烯酸聚氨脂树脂:20份;Acrylic polyurethane resin: 20 parts;
2—羟基—甲基—苯丙酮:1.5份;2-Hydroxy-methyl-propiophenone: 1.5 parts;
异丙基三(二辛基磷酸酰氧基)钛酸酯:4份;Isopropyl tri(dioctyl phosphate acyloxy) titanate: 4 parts;
所述着色层按重量份计,由以下原料组成时效果最佳:光纤着色油墨:99份;异丙基三(二辛基磷酸酰氧基)钛酸酯:1.5份;异丙基三(二辛基焦磷酸酰氧基)钛酸酯:1份。The coloring layer has the best effect when it is composed of the following raw materials in parts by weight: optical fiber coloring ink: 99 parts; isopropyl tris(dioctyl phosphate acyloxy) titanate: 1.5 parts; isopropyl tris( Dioctyl pyrophosphate acyloxy) titanate: 1 part.
此外,申请人发现,以下配方也是比较理想的配方:In addition, the applicant found that the following formulations are also ideal formulations:
配方1:抗弯折内层及抗弯折外层按重量份计,都由以下原料组成:丙烯酰胺基乙基2—氨丙基三乙氧基硅烷或丙烯酰胺基丙基三乙氧基硅烷:15份;Formula 1: The anti-bending inner layer and the anti-bending outer layer are composed of the following raw materials in parts by weight: acrylamidoethyl 2-aminopropyltriethoxysilane or acrylamidopropyltriethoxy Silane: 15 parts;
丙烯酸有机硅树脂:15份;Acrylic silicone resin: 15 parts;
丙烯酸环氧树脂:15份;Acrylic epoxy resin: 15 parts;
丙烯酸聚氨脂树脂:15份;Acrylic polyurethane resin: 15 parts;
2—羟基—甲基—苯丙酮:1份;2-Hydroxy-methyl-propiophenone: 1 part;
异丙基三(二辛基磷酸酰氧基)钛酸酯:2份;Isopropyl tri(dioctyl phosphate acyloxy) titanate: 2 parts;
所述着色层按重量份计,是由以下原料组成的:光纤着色油墨:98~100份;异丙基三(二辛基磷酸酰氧基)钛酸酯:1份;异丙基三(二辛基焦磷酸酰氧基)钛酸酯:0.5份。The colored layer is composed of the following raw materials in parts by weight: optical fiber coloring ink: 98-100 parts; isopropyl tris(dioctyl phosphate acyloxy) titanate: 1 part; isopropyl tris( Dioctyl pyrophosphate acyloxy) titanate: 0.5 parts.
配方2:抗弯折内层及抗弯折外层按重量份计,都由以下原料组成:丙烯酰胺基乙基2—氨丙基三乙氧基硅烷或丙烯酰胺基丙基三乙氧基硅烷:25份;Formula 2: The anti-bending inner layer and the anti-bending outer layer are composed of the following raw materials in parts by weight: acrylamidoethyl 2-aminopropyltriethoxysilane or acrylamidopropyltriethoxy Silane: 25 parts;
丙烯酸有机硅树脂:35份;Acrylic silicone resin: 35 parts;
丙烯酸环氧树脂:35份;Acrylic epoxy resin: 35 parts;
丙烯酸聚氨脂树脂:25份;Acrylic polyurethane resin: 25 parts;
2—羟基—甲基—苯丙酮:2份;2-Hydroxy-methyl-propiophenone: 2 parts;
异丙基三(二辛基磷酸酰氧基)钛酸酯:5份;Isopropyl tri(dioctyl phosphate acyloxy) titanate: 5 parts;
所述着色层按重量份计,是由以下原料组成的:光纤着色油墨:98~100份;异丙基三(二辛基磷酸酰氧基)钛酸酯:2份;异丙基三(二辛基焦磷酸酰氧基)钛酸酯:1.5份。The colored layer is composed of the following raw materials in parts by weight: optical fiber coloring ink: 98-100 parts; isopropyl tris(dioctyl phosphate acyloxy) titanate: 2 parts; isopropyl tris( Dioctyl pyrophosphate acyloxy) titanate: 1.5 parts.
配方1及配方2也达到了理想的耐弯折效果。Formula 1 and formula 2 also achieved ideal bending resistance.
申请人将本发明上述实施实例中的光纤与现有技术中的光纤的耐折性能作了对比,每个实施实例及现有技术中的光纤都取了500个作为样品试验,下表未标范围的是平均值,为叙述方便,将实施实例1—3分别标为1#—3#,现有技术中的G.652B为4#、G.652D为5#、G657A2为6#、G657B3为7#,测试结果如下,其中“√”表示光纤未断裂,“X”表示光纤断裂;断裂与否,能过光时域反射仪(OTDR)及可见光功率仪进行测试。The applicant compared the folding resistance of the optical fiber in the above-mentioned implementation example of the present invention with that of the optical fiber in the prior art, and 500 optical fibers in each implementation example and the prior art were taken as sample tests, and the following table is not marked The range is the average value. For the convenience of description, the implementation examples 1-3 are respectively marked as 1#-3#, G.652B in the prior art is 4#, G.652D is 5#, G657A2 is 6#, G657B3 It is 7#, and the test results are as follows, where "√" means that the fiber is not broken, and "X" means that the fiber is broken; whether it is broken or not, it can be tested by optical time domain reflectometer (OTDR) and visible light power meter.
因此,很显然,本发明的光纤具有优良的抗弯折性能。Therefore, it is apparent that the optical fiber of the present invention has excellent bending resistance.
此外,申请人还采用现有技术中的着色油墨进行着色,形成着色层,与采用本发明中的着色层的配方进行着色的耐折光纤进行了耐折对比,得到了以下数据,其中,采用现有技术的着色油墨及本发明中的三个实施例着色层都着了200盘25.2公里的光纤;为叙述方便,将实施实例1—3分别标为1#—3#,三个实施实例对应的现有技术着色油置着的光纤分别标为11#—33#;对于每个实施实例中每个样品各穿10次;及在负重10N的情况下,进行100圈弯曲试验;光纤断裂采用OTDR或可见光功率仪测试。In addition, the applicant also used the coloring ink in the prior art for coloring to form a coloring layer, and compared the folding resistance of the folding-resistant optical fiber coloring with the coloring layer formula in the present invention, and obtained the following data. The coloring ink of prior art and three embodiment coloring layers in the present invention all had the optical fiber of 200 disks 25.2 kilometers; Corresponding optical fibers placed with coloring oil in the prior art are respectively marked as 11#-33#; each sample is worn 10 times in each implementation example; and under the condition of a load of 10N, a 100-turn bending test is carried out; the optical fiber breaks Use OTDR or visible light power meter to test.
因此,本申请中,着色层的配方对于光纤的耐折性能也起到了贡献作用。Therefore, in this application, the formulation of the colored layer also contributes to the folding performance of the optical fiber.
本发明中,由于具有了抗弯折内层或抗弯折外层或者兼具了抗弯折内层和抗弯折外层,且抗弯折内层、抗弯折外层具有极高柔韧性,因此,有效地保护了光纤,使光纤在小直径弯折的情况下,也达到了极其理想的耐弯折性能;本发明中的着色层由于其独特的配方,使其着色油墨的固化及延展性更高,在多次反复弯曲/弯折的情况下,也未见有着色层的开裂,为光纤的耐折提供了进一步的保障。In the present invention, due to the anti-bending inner layer or the outer layer of anti-bending or both the inner layer of anti-bending and the outer layer of anti-bending, and the inner layer of anti-bending and the outer layer of anti-bending are extremely flexible Therefore, the optical fiber is effectively protected, so that the optical fiber can achieve an extremely ideal bending resistance when it is bent with a small diameter; And the ductility is higher, and in the case of repeated bending/bending, there is no cracking of the colored layer, which provides a further guarantee for the bending resistance of the optical fiber.
本发明经过测试,除了所有光学指标满足ITU、IEC及国内光纤标准要求外,达到了任取一段长度不小于10cm的耐弯折光纤,将耐弯折光纤两端同时同方向穿过内径为2mm的圆柱形孔后耐弯折光纤不断裂的目标,因此,施工人员不再有施工中光纤易被折断的顾虑,施工更方便;而且,大大地扩大了光纤的应用范围,降低了光纤的使用要求。The invention has been tested, except that all optical indicators meet the requirements of ITU, IEC and domestic optical fiber standards, and it can take any bending-resistant optical fiber with a length of not less than 10cm, and pass both ends of the bending-resistant optical fiber in the same direction at the same time with an inner diameter of 2mm. The aim of the bending-resistant optical fiber behind the cylindrical hole is not to break. Therefore, the construction personnel no longer have to worry about the optical fiber being easily broken during construction, and the construction is more convenient; moreover, the application range of the optical fiber is greatly expanded and the use of the optical fiber is reduced. Require.
因此,本发明具有以下主要有益效果:结构简单、易实现、具有优良的耐折性能、使用范围更广、对于施工时弯曲要求更低。Therefore, the present invention has the following main beneficial effects: simple structure, easy realization, excellent folding resistance, wider application range, and lower bending requirements during construction.
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CN109385187A (en) * | 2018-11-05 | 2019-02-26 | 上海铎奇线缆科技有限公司 | Coating composition and preparation method thereof and bending resistance optical fiber and preparation method thereof |
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