CN104059440A - Water-based paint with high weatherability - Google Patents
Water-based paint with high weatherability Download PDFInfo
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- CN104059440A CN104059440A CN201410281168.4A CN201410281168A CN104059440A CN 104059440 A CN104059440 A CN 104059440A CN 201410281168 A CN201410281168 A CN 201410281168A CN 104059440 A CN104059440 A CN 104059440A
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- weathering resistance
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 15
- 239000003973 paint Substances 0.000 title abstract description 6
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 23
- 239000006185 dispersion Substances 0.000 claims abstract description 20
- 239000000203 mixture Substances 0.000 claims abstract description 15
- 239000000839 emulsion Substances 0.000 claims abstract description 13
- 229920005553 polystyrene-acrylate Polymers 0.000 claims abstract description 13
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 11
- 239000006096 absorbing agent Substances 0.000 claims abstract description 9
- 229910021538 borax Inorganic materials 0.000 claims abstract description 9
- 239000002994 raw material Substances 0.000 claims abstract description 9
- 239000004328 sodium tetraborate Substances 0.000 claims abstract description 9
- 235000010339 sodium tetraborate Nutrition 0.000 claims abstract description 9
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 8
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 8
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000002156 mixing Methods 0.000 claims abstract description 8
- 239000000049 pigment Substances 0.000 claims abstract description 8
- 238000000576 coating method Methods 0.000 claims description 29
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 18
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims description 12
- 239000013530 defoamer Substances 0.000 claims description 10
- 239000003112 inhibitor Substances 0.000 claims description 9
- 229910052742 iron Inorganic materials 0.000 claims description 9
- 230000003647 oxidation Effects 0.000 claims description 8
- 238000007254 oxidation reaction Methods 0.000 claims description 8
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 7
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims description 7
- 229920002701 Polyoxyl 40 Stearate Polymers 0.000 claims description 5
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 5
- 239000004141 Sodium laurylsulphate Substances 0.000 claims description 5
- 229940099429 polyoxyl 40 stearate Drugs 0.000 claims description 5
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 5
- 239000003223 protective agent Substances 0.000 claims description 4
- 239000003963 antioxidant agent Substances 0.000 abstract description 3
- 230000003078 antioxidant effect Effects 0.000 abstract description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 2
- 230000003712 anti-aging effect Effects 0.000 abstract 2
- 229910021529 ammonia Inorganic materials 0.000 abstract 1
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 239000002270 dispersing agent Substances 0.000 abstract 1
- 150000002505 iron Chemical class 0.000 abstract 1
- 239000004611 light stabiliser Substances 0.000 abstract 1
- 239000004810 polytetrafluoroethylene Substances 0.000 abstract 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 abstract 1
- 229920005749 polyurethane resin Polymers 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 description 8
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 6
- 238000010276 construction Methods 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 238000003756 stirring Methods 0.000 description 4
- -1 Dipentaerythritol diphosphites Chemical class 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- TYUVKZGQQUXSOU-UHFFFAOYSA-N [C].OF Chemical compound [C].OF TYUVKZGQQUXSOU-UHFFFAOYSA-N 0.000 description 2
- 125000005037 alkyl phenyl group Chemical group 0.000 description 2
- 235000006708 antioxidants Nutrition 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 239000012948 isocyanate Substances 0.000 description 2
- 150000002513 isocyanates Chemical class 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- QNAYBMKLOCPYGJ-REOHCLBHSA-N L-alanine Chemical compound C[C@H](N)C(O)=O QNAYBMKLOCPYGJ-REOHCLBHSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 230000006750 UV protection Effects 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 235000004279 alanine Nutrition 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001734 carboxylic acid salts Chemical class 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 1
- SLGWESQGEUXWJQ-UHFFFAOYSA-N formaldehyde;phenol Chemical compound O=C.OC1=CC=CC=C1 SLGWESQGEUXWJQ-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 230000004224 protection Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention relates to a water-based paint with high weatherability. The paint comprises the following raw materials by weight: 40-60 parts of a mixture of polyurethane resin and polystyrene-acrylate copolymer emulsion, 15-25 parts of kaolin, 0.5-3 parts of an iron series pigment, 0.1-0.8 part of borax, 0.5-2 parts of an anti-aging agent, 0.5-2 parts of antioxidant 3010, 0.5-3 parts of a defoaming agent HT6520, 0.1-3 parts of a dispersant, 0.1-1 part of an emulsifier, 0.1-1 part of ammonia, 5- 8 parts of PTFE and 25-50 parts of water; and the anti-aging agent is a mixture of a UV absorber UVP-327 and a light stabilizer 744 in a mixing proportion of 1-2:1. The invention mainly solves the technical problems of weak dispersion and weatherability of water-based paint in the prior art.
Description
Technical field
The present invention relates to water-borne coatings field, relate in particular to the water-borne coatings that a kind of weathering resistance is high.
Background technology
Along with the enhancing of environmental consciousness, countries in the world have all been worked out limit standard and the rules of volatile organic matter (VOC) discharge in succession.Solvent based coating is the important sources of VOC, and environment is caused to very large pollution, and human body is brought to great harm, has the potential safety hazards such as inflammable, explosive in construction, storage, transportation simultaneously.Water-borne coatings has green, energy-conservation, safety, acts on feature easily, in countries in the world, has obtained developing rapidly.Water-borne coatings, as adding water-reducible clearly pure environmentfriendly products, has the features such as low formaldehyde, low aromatics hydrocarbon polymer compared with traditional solvent reducible coatings, be the high-tech Chaoyang product that belongs to of new generation.In water-borne coatings when construction, directly adds clear water dilution, before construction and both free from environmental pollution after construction, does not damage again HUMAN HEALTH.Water-borne coatings is brand-new generation environmentfriendly products still not, and its property indices is more even better than common paint, has paint film plentiful level and smooth, hardness is moderate, strong adhesion, wear resisting property is excellent, and time of drying is short, enduring quality is good, construction is simple, without brush mark, does not produce the plurality of advantages such as bubble when curing, but its water tolerance, weathering resistance and abrasion resistance are good not, therefore it is only suitable for indoor.
Publication number is that CN102876150A name is called the Chinese invention patent of " anti-graffiti water-borne coatings of a kind of high weather-proof anti-stick subsides and preparation method thereof ", disclosing this coating is two-component coating, the weight ratio of A component and B component is 4: 1, A component is by hydroxyl fluorine carbon emulsion, anti-graffiti resin, defoamer, wetting agent, water forms, described B component is hydrophilic isocyanate curing agent, (3) to hydroxyl fluorine carbon emulsion, add water and anti-graffiti resin, then add defoamer, wetting agent, finally add isocyanate curing agent, obtain the anti-graffiti water-borne coatings of high weather-proof anti-stick subsides.The dispersiveness of this coating is not high enough, and weathering resistance also need to improve.
Summary of the invention
The present invention is intended to solve in prior art, and coating dispersiveness is bad, and the problem that weathering resistance is not high proposes the water-borne coatings that a kind of weathering resistance is high.
In order to realize foregoing invention object, main technical schemes of the present invention is:
The water-borne coatings that a kind of weathering resistance is high, the raw material that comprises following weight part: 40～60 parts, the mixture of urethane resin and Polystyrene-acrylate copolymer emulsion, 15～25 parts of kaolin, 0.5～3 part of iron pigment, 0.1～0.8 part of borax, 0.5～2 part of protective agent, 3,010 0.5～2 parts, oxidation inhibitor, 6,520 0.5～3 parts of defoamer HT, 0.1～3 part of dispersion agent, 0.1～1 part of emulsifying agent, 0.1～1 part of ammoniacal liquor, 25～50 parts, 5～8 parts of tetrafluoroethylene and water; Described protective agent is the mixture of UV light absorber UVP-327 and photostabilizer 744, and its blending ratio is: 1～2:1.
Preferably, the ratio of the mixture of described urethane resin and Polystyrene-acrylate copolymer emulsion is 2～4:1.
Preferably, described dispersion agent is dispersion agent 5040.
Preferably, described emulsifying agent is the mixture of pure Sodium Lauryl Sulphate BP/USP and polyoxyl 40 stearate, and its blending ratio is 1:1～2.
Wherein, oxidation inhibitor 3010 is high-efficiency anti-oxidants of Dipentaerythritol diphosphites spirane structure, has outstanding thermostability and modification of colour.At high temperature antioxidant effect is outstanding, can suppress preferably the discoloration problem that hot oxygen and ultraviolet ray produce, with Hinered phenols antioxidant, UV light absorber, photostabilizer also has optimal process with forming one, ageing resistance, the system of light stability and economy; Red, yellow, brown, black several large classes that iron pigment has, it is except having weathering resistance, chemical resistant properties, nontoxic, cheap advantage, also there is lucid and lively, bright-colored pure, the feature that tinting strength is high of tone, therefore can reach outside adding purpose, can also greatly reduce costs; Borax is cooked inhibitor use, and can effectively prevent affects its decoration and provide protection after external substance is on coating corrosion; Tetrafluoroethylene, with in the present invention, has obvious enhancing coating resistance to elevated temperatures, and has advantages of acidproof, alkaline-resisting.
Beneficial effect: the present invention passes through various raw-material selections and suitable proportioning thereof, between consistency and effect, found a trim point, consistency between material is good, synergy obviously, the water-borne coatings making, compared with prior art, dispersiveness, weathering resistance, corrosion-resistant being significantly improved.Preferred base-material is the mixture of urethane resin and Polystyrene-acrylate copolymer emulsion, and its ratio is 1:1～2, and its urethane resin itself has stronger radiation hardness, the characteristic of ultraviolet resistance, is a kind of outdoor base-material that is suitable for; Polystyrene-acrylate multipolymer is except having the good processibility of polystyrene, also has the weathering resistance of acrylate and good resistance to optical.Both are mixed and used with 1:1～2, and the consumption of Polystyrene-acrylate multipolymer can make the viscosity of mixing solutions best a little more than urethane resin, and result of use doubles, and both have best consistency.In the present invention, preferred dispersion agent is dispersion agent 5040, foaminess is low, can improve the mobility of coating, the excellent properties with stable slurry viscosity, use amount seldom just can reach the effect of good dispersity, use together with other compositions in the present invention, can not reduce the viscosity of mixture, and after finished product is coated on buildings, water tolerance is also improved.Compared with prior art, the present invention has good weathering resistance, erosion resistance.
Embodiment
Embodiment 1
The water-borne coatings that red weathering resistance is high, comprises the raw material of following weight part: 30 parts of urethane resins, 10 parts of Polystyrene-acrylate copolymer emulsions, 15 parts of kaolin, 0.5 part of red iron oxide, 0.1 part of borax, 0.5 part of UV light absorber UVP-327,744 0.5 parts of photostabilizers, 3,010 0.5 parts, oxidation inhibitor, 6,520 1 parts of defoamer HT, 0.1 part of dispersion agent, 0.4 part of emulsifying agent, 0.3 part of ammoniacal liquor, 25 parts, 5 parts of tetrafluoroethylene and water.
Described dispersion agent can be one or more in polyoxyethylene alkyl phenyl ether, dispersion agent 5040, dispersion agent HT-5000.
Described emulsifying agent is a kind of in polyacrylamide, xanthan gum XG, polymerization of carboxylic acid salt polyacrylic acid, alanine type, phenol formaldehyde condensate sulfonate.
Its preparation method is: take respectively after required various raw materials, urethane resin and Polystyrene-acrylate copolymer emulsion are added in agitator and under the rotating speed with 1300r/min, stir after 3 minutes, add defoamer to continue to stir 25min, then by other auxiliary agents: kaolin, borax, UV light absorber UVP-327, photostabilizer, oxidation inhibitor 3010, defoamer HT 6520, after dispersion agent adds together, with 1000r/min rotating speed, stir after 10min, add pigment, continue to stir more than 5 minutes, color even, finally add ammoniacal liquor, regulate PH to 5～7.
Embodiment 2
The water-borne coatings that weathering resistance is high, comprises the raw material of following weight part: 30 parts of urethane resins, 15 parts of Polystyrene-acrylate copolymer emulsions, 20 parts of kaolin, 0.8 part of iron pigment, 0.3 part of borax, 1 part of UV light absorber UVP-327,744 0.5 parts of photostabilizers, 3,010 0.8 parts, oxidation inhibitor, 6,520 0.5 parts of defoamer HT, 5,040 0.18 parts of dispersion agents, 0.6 part of emulsifying agent, 0.7 part of ammoniacal liquor, 35 parts, 6 parts of tetrafluoroethylene and water.
Described emulsifying agent is the mixture of pure Sodium Lauryl Sulphate BP/USP and polyoxyl 40 stearate, and its blending ratio is 1:2.
Its preparation method is with embodiment 1.
Embodiment 3
The water-borne coatings that yellow weathering resistance is high, comprises the raw material of following weight part: 45 parts of urethane resins, 15 parts of Polystyrene-acrylate copolymer emulsions, 25 parts of kaolin, 3 parts of iron oxide yellow, 0.8 part of borax, 1 part of UV light absorber UVP-327,744 1 parts of photostabilizers, 3,010 2 parts, oxidation inhibitor, 6,520 2 parts of defoamer HT, 2.5 parts of dispersion agents, 1 part of emulsifying agent, 1 part of ammoniacal liquor, 45 parts, tetrafluoroethylene 57 and water.
Described dispersion agent can be one or more in polyoxyethylene alkyl phenyl ether, dispersion agent 5040, dispersion agent HT-5000.
Described emulsifying agent is the mixture of pure Sodium Lauryl Sulphate BP/USP and polyoxyl 40 stearate, and its blending ratio is 1:1.
Its preparation method is with embodiment 1.
Embodiment 4
The water-borne coatings that a kind of weathering resistance is high, the raw material that comprises following weight part: 30 parts of urethane resins, 15 parts of Polystyrene-acrylate copolymer emulsions, 20 parts of kaolin, 1.2 parts of iron pigments, 0.5 part of borax, 0.5 part of UV light absorber UVP-327,744 0.5 parts of photostabilizers, 3,010 1 parts, oxidation inhibitor, 6,520 0.9 parts of defoamer HT, 5,040 0.6 parts of dispersion agents, 0.4 part of pure Sodium Lauryl Sulphate BP/USP, 0.4 part of polyoxyl 40 stearate, 0.5 part of ammoniacal liquor, 40 parts, 7 parts of tetrafluoroethylene and water.
Described iron pigment can select that iron oxide red, iron oxide yellow, iron oxide black, iron are blue, iron is green, iron is purple and cologne earth etc.
Its preparation method is with embodiment 1.
Claims (4)
1. the water-borne coatings that weathering resistance is high, it is characterized in that: the raw material that comprises following weight part: 40～60 parts, the mixture of urethane resin and Polystyrene-acrylate copolymer emulsion, 15～25 parts of kaolin, 0.5～3 part of iron pigment, 0.1～0.8 part of borax, 0.5～2 part of protective agent, 3,010 0.5～2 parts, oxidation inhibitor, 6,520 0.5～3 parts of defoamer HT, 0.1～3 part of dispersion agent, 0.1～1 part of emulsifying agent, 0.1～1 part of ammoniacal liquor, 25～50 parts, 5～8 parts of tetrafluoroethylene and water; Described protective agent is the mixture of UV light absorber UVP-327 and photostabilizer 744, and its blending ratio is: 1～2:1.
2. the high water-borne coatings of a kind of weathering resistance according to claim 1, is characterized in that: the ratio of the mixture of described urethane resin and Polystyrene-acrylate copolymer emulsion is 2～4:1.
3. the high water-borne coatings of a kind of weathering resistance according to claim 1, is characterized in that: described dispersion agent is dispersion agent 5040.
4. the high water-borne coatings of a kind of weathering resistance according to claim 1, is characterized in that: described emulsifying agent is the mixture of pure Sodium Lauryl Sulphate BP/USP and polyoxyl 40 stearate, and its blending ratio is 1:1～2.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410281168.4A CN104059440B (en) | 2014-06-23 | 2014-06-23 | The water-borne coatings that a kind of weathering resistance is high |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410281168.4A CN104059440B (en) | 2014-06-23 | 2014-06-23 | The water-borne coatings that a kind of weathering resistance is high |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104059440A true CN104059440A (en) | 2014-09-24 |
| CN104059440B CN104059440B (en) | 2016-03-16 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201410281168.4A Expired - Fee Related CN104059440B (en) | 2014-06-23 | 2014-06-23 | The water-borne coatings that a kind of weathering resistance is high |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104449094A (en) * | 2014-09-25 | 2015-03-25 | 阜南县永盛工艺品有限公司 | Wicker coating |
| CN104962160A (en) * | 2015-07-24 | 2015-10-07 | 苏州荣昌复合材料有限公司 | Ultraviolet-resistant paint composition for plastics |
| CN108017988A (en) * | 2017-12-06 | 2018-05-11 | 苏州铂邦胶业有限公司 | The water paint of good weatherability |
| CN108978024A (en) * | 2018-06-28 | 2018-12-11 | 安徽原野滤材有限公司 | A kind of grease proofing antistatic dust-removal cloth-bag material of water repellent |
| CN113698826A (en) * | 2021-09-01 | 2021-11-26 | 浙江浩博新材料有限公司 | Weather-resistant water-based acrylic coating |
| CN116676020A (en) * | 2023-07-03 | 2023-09-01 | 无锡市昊彩光学科技有限公司 | A weather-resistant self-healing coating and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101481443A (en) * | 2009-01-23 | 2009-07-15 | 华南理工大学 | Polyurethane-polyacrylacid ester interpenetrating network polymer, preparation and use thereof |
| CN101481584A (en) * | 2009-01-23 | 2009-07-15 | 华南理工大学 | Dry powder latex paint for inner wall and preparation thereof |
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2014
- 2014-06-23 CN CN201410281168.4A patent/CN104059440B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101481443A (en) * | 2009-01-23 | 2009-07-15 | 华南理工大学 | Polyurethane-polyacrylacid ester interpenetrating network polymer, preparation and use thereof |
| CN101481584A (en) * | 2009-01-23 | 2009-07-15 | 华南理工大学 | Dry powder latex paint for inner wall and preparation thereof |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104449094A (en) * | 2014-09-25 | 2015-03-25 | 阜南县永盛工艺品有限公司 | Wicker coating |
| CN104962160A (en) * | 2015-07-24 | 2015-10-07 | 苏州荣昌复合材料有限公司 | Ultraviolet-resistant paint composition for plastics |
| CN108017988A (en) * | 2017-12-06 | 2018-05-11 | 苏州铂邦胶业有限公司 | The water paint of good weatherability |
| CN108978024A (en) * | 2018-06-28 | 2018-12-11 | 安徽原野滤材有限公司 | A kind of grease proofing antistatic dust-removal cloth-bag material of water repellent |
| CN113698826A (en) * | 2021-09-01 | 2021-11-26 | 浙江浩博新材料有限公司 | Weather-resistant water-based acrylic coating |
| CN116676020A (en) * | 2023-07-03 | 2023-09-01 | 无锡市昊彩光学科技有限公司 | A weather-resistant self-healing coating and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104059440B (en) | 2016-03-16 |
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