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CN103975873A - Method for fixing carbon by utilizing shellfish culture system - Google Patents

Method for fixing carbon by utilizing shellfish culture system Download PDF

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Publication number
CN103975873A
CN103975873A CN201410150466.XA CN201410150466A CN103975873A CN 103975873 A CN103975873 A CN 103975873A CN 201410150466 A CN201410150466 A CN 201410150466A CN 103975873 A CN103975873 A CN 103975873A
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carbon
shellfish
water body
organisms
culture system
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CN103975873B (en
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杨平
赵晟
叶晓春
唐小双
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Zhejiang Ocean University ZJOU
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Zhejiang Ocean University ZJOU
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A40/00Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
    • Y02A40/80Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in fisheries management
    • Y02A40/81Aquaculture, e.g. of fish

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Abstract

本发明公开了一种利用贝类养殖系统固碳的方法,利用贝类的养殖来移除大气中的二氧化碳。本发明使用水产养殖作为碳汇,对于降低温室气体排放产生了良好的环境效益;另外,为水产养殖系统提供了一个自然的净化海水系统,随着越来越多的水产养殖系统的发展,越来越多水域得以净化。The invention discloses a method for sequestering carbon by using a shellfish culture system, which uses the shellfish culture to remove carbon dioxide in the atmosphere. The present invention uses aquaculture as a carbon sink, which produces good environmental benefits for reducing greenhouse gas emissions; in addition, it provides a natural seawater purification system for aquaculture systems. With the development of more and more aquaculture systems, more and more More and more water areas have been purified.

Description

A kind of method of utilizing the solid carbon of shellfish culture system
Technical field
The present invention relates to a kind of solid carbon method and carbon credit quantitative detecting method.
Background technology
Global warming issue current be one of topmost problem in earth environmental protection, and wherein the most outstanding environmental phenomenon is exactly greenhouse effect.
So-called greenhouse effect are mainly the effects due to greenhouse gases, be in specific words, greenhouse gases can absorb the solar radiation of ground return by day, and again launch earthward the radiant energy of holding back daytime night, thereby make the earth cannot normally carry out the circulation of heat as a greenhouse, cannot be to the unnecessary heat of external radiation, and then cause earth surface temperature rise.
Greenhouse gases comprise steam, carbonic acid gas, methane, nitrous oxide and ozone etc.There is no greenhouse gases, the earth does not just have enough warm activities that sustains life, so greenhouse gases are important parts in atmosphere.
By 2011, the content of atmosphere percent of greenhouse gases-carbonic acid gas reached 391ppm(1ppm and has been 1,000,000/), the content of the nitrous oxide content that reached 324ppd (1ppb is part per billion), methane reached 1803ppb.Than whole high by 40%, 20%, 150% before industrialization.Some greenhouse gases are that natural environment produces, and the overwhelming majority is wherein the result of mankind's activity.In air, most of carbonic acid gas is caused by mankind's activity, the burning of for example fossil fuel, running of cement factory etc.
The concentration of some greenhouse gases, along with the time is in continuous increase, now unanimously thinks that the increase of greenhouse gas concentration can cause global warming.
Global warming and then can cause again a series of environmental problem, for example: ice shelf disappears, sea level rise, the change of rainfall pattern and the strength increase of extreme weather and take place frequently etc.
These natural calamities have caused serious economic loss, and in order to make great efforts to reduce these losses, many countries are exploring and reducing the method for air when percent of greenhouse gases.As the main contributions person carbonic acid gas of greenhouse gases, nowadays become global focus in the nature of things.Want to alleviate greenhouse effect, just must must reduce the central carbon dioxide content of atmosphere.
Nowadays there are two kinds of main methods to process the carbonic acid gas in atmosphere.
First method is from all, reduces the discharge of carbonic acid gas.Such as: the burning of restriction fossil fuel.
Another kind method is to make great efforts to absorb or remove the carbonic acid gas in atmosphere.We are called the mechanism that removes carbon from atmosphere " carbon remittance ".
" forest " is that carbon converges and talks about the highest one of frequency in type.The application of trees absorbing carbon dioxide has been studied widely and has been theorized, as patent No. Chinese invention patent " a kind of greenery patches, garden carbon sink detection system based on automatic sampling analysis " that is CN201310060276.4 etc.
Although but carbonic acid gas can absorb by trees, this form could not well be applied, main cause is that Forestry Carbon Mitigation only can store a period of time, and carbonic acid gas can not be sealed up by forest is permanent.Because the burning of trees or rotten situation, carbon will be discharged in atmosphere again; And Forests carbon is consuming time longer, cost is higher is also subject matter.
So sight has been turned to another very important carbon remittance carrier---ocean by we.
The carbon of being sealed up for safekeeping in carbon converges is the basis that obtains " carbon credit ".Discharge transaction plan is used cap-and-trade arrangement conventionally, and government organs arrange limit and provide the discharge permit that represents a certain amount of pollutant emission right for the discharge capacity of license.But how to confirm carbon credit, is converted into carbon credit after needing carbon emission quantitatively to detect, this just concludes the business and has brought the difficulty of essence to carbon credit.Make government be difficult to real fair and reasonable enforcement and assessment.
Summary of the invention
The technical problem to be solved in the present invention is to overcome existing defect, and a kind of method of utilizing the solid carbon of shellfish culture system that solid carbon is effective, cost is low is provided;
Another object of the present invention is to utilize the method that can quantitatively detect carbon credit.
Object of the present invention is carried out specific implementation by the following technical programs:
Utilize a method for the solid carbon of shellfish culture system, utilize the cultivation of shellfish to remove the carbonic acid gas in atmosphere, be specially:
1) taken in and contain the breeding water body that is dissolved with carbonic acid gas in cultivation process of growth by shellfish biology, the carbonic acid gas of absorption is converted into calcium carbonate and is sealed up for safekeeping to form hard shell in body of shellfish;
Wherein, in the breeding process of shellfish biology, in breeding water body, increase the symbiosis of miniature organism, by breeding bait excessive in breeding water body and the dissolved organic carbon that produced by autotroph, be converted into can stable existence inertia dissolved organic carbon, active organic carbon concentration in breeding water body is reduced, the solid carbon ability of autotroph is strengthened;
3) again the shell of the shellfish of sealing calcium carbonate up for safekeeping is recycled, reached long-term carbon admittedly, meanwhile, in breeding water body, the concentration of carbonic acid gas reduces, impel airborne carbon dioxide solubility in water body, the carbon that forms breeding water body converges, thereby atmosphere is produced to optimum impact.
Water body refers to whole breeding water body.Be the culture zone of whole shellfish, the whole region from seawater surface to seabed.Also comprised that people is other microorganism, algae, fish and the excreta thereof etc. in bait and the water body of knocking down in water.
Marine shellfish, in breeding process, can utilize carbon in seawater to form the body, and main component is calcium carbonate, can be expressed as with chemical equation:
The shellfish body is fixed carbon in seawater in process of growth, and the carbonic acid gas of absorption is converted into calcium carbonate and is sealed up for safekeeping to form hard shell in body of shellfish.
As preferred version, in the breeding process of shellfish biology, by reducing the method for input of bait, so that the ratio of the C/N of water body, C/P all reaches more than 2, the ratio of C/N, C/P is 10 o'clock best results.
Further preferred, described shellfish biology refers to shellfish, the shell-fish aquatile of carbon containing shell.
More excellent, described shellfish biology is mussel.In mussel culture process, it is 2% that mussel is controlled at 20 ± 3 DEG C, salinity control in the temperature in seedling stage, and seedling rope adopts atropurpureus coir rope.Before putting in a suitable place to breed, mussel seedling is carried out to the domestication of culture zone water temperature, salinity, current speed.Be conducive to improve the adhesive rate of mussel seedling.Adopt specific seedling rope (atropurpureus coir rope) and wrap seedling processing and can effectively improve the survival rate of mussel in the time putting in a suitable place to breed putting mussel in a suitable place to breed.
Preferably, described miniature organism refers to small autotroph and difference biology.
More excellent, described miniature organism comprises the unicellular organism of all kinds of autotrophys, heterotrophism, eucaryon, protokaryon and there is no cell structure but have the viroplankton/phage of ecological functions.Be less than the nanoplankton of 20 μ m and/or the individual hekistoplankton that is less than 2 μ m as good taking individuality.
A kind of method that carbon credit quantitatively detects, the carbon that utilizes above-mentioned solid carbon method to form breeding water body converges, the quantity of the carbon that the shell producing by cultivating system is again sealed up for safekeeping obtains the carbon credit that can correspondingly conclude the business, and the total quantity of the shell producing by cultivating system represents certain solid carbon number amount.
Beneficial effect of the present invention:
The present invention utilizes shellfish to absorb the carbonic acid gas in the middle of seawater by relevant biological chemistry action, by biological internalization process, the main component that is shell by the carbon dioxide conversion of absorption---calcium carbonate, thereby reach permanent or semi-permanent " carbon remittance " object, thereby sponge the carbonic acid gas in the middle of atmosphere, atmosphere is formed to desirable influence.
Meanwhile, due to the dissolved organic carbon that remains breeding bait and can be produced by autotroph, the active organic carbon Enrichment in this meeting water body, promotes carbon cycle, and then increases the discharge of carbonic acid gas, is unfavorable for the formation that carbon converges.Be mussel by it, after the excreta in the process of growth is decomposed by microorganism, also can discharge with the form of carbonic acid gas.The present invention, by the control to miniature organism in water body, makes miniature organism in water body, obtain living space and produces inertia dissolved organic carbon, forms miniature organism pump.Inertia dissolved organic carbon can stop decades to more than one thousand years in ocean, no longer enter other biochemical cycles, thereby reach permanent or semi-permanent " carbon remittance " object, improve the seal effect of breeding water body for carbonic acid gas, thereby reach the object that reduces the carbonic acid gas in atmosphere, and then alleviate greenhouse effect.And, can also discharge the nutritive salt such as the necessary N of algal grown, P simultaneously.Throw in the method for bait by minimizing, control water body and form high C/N, C/P ratio, thereby reach the object of the operation that is more conducive to miniature organism pump.
The present invention uses aquaculture to converge as carbon, has produced good environmental benefit for reducing greenhouse gas emission; In addition, for aquaculture system provides a natural purifying sea water system, along with the development of increasing aquaculture system, more and more waters are purified.
Embodiment
Below the preferred embodiments of the present invention are described, should be appreciated that preferred embodiment described herein, only for description and interpretation the present invention, is not intended to limit the present invention.
Embodiment 1:
Utilize a method for the solid carbon of shellfish culture system, utilize the cultivation of shellfish to remove the carbonic acid gas in atmosphere, be specially:
1) taken in and contain the breeding water body that is dissolved with carbonic acid gas in cultivation process of growth by shellfish biology, the carbonic acid gas of absorption is converted into calcium carbonate and is sealed up for safekeeping to form hard shell in body of shellfish;
Wherein, in the breeding process of shellfish biology, in breeding water body, increase the symbiosis of miniature organism, by breeding bait excessive in breeding water body and the dissolved organic carbon that produced by autotroph, be converted into can stable existence inertia dissolved organic carbon, active organic carbon concentration in breeding water body is reduced, the solid carbon ability of autotroph is strengthened;
4) again the shell of the shellfish of sealing calcium carbonate up for safekeeping is recycled, reached long-term carbon admittedly, meanwhile, in breeding water body, the concentration of carbonic acid gas reduces, impel airborne carbon dioxide solubility in water body, the carbon that forms breeding water body converges, thereby atmosphere is produced to optimum impact.
Water body refers to whole breeding water body.Be the culture zone of whole shellfish, the whole region from seawater surface to seabed.Also comprised that people is other microorganism, algae, fish and the excreta thereof etc. in bait and the water body of knocking down in water.
Marine shellfish, in breeding process, can utilize carbon in seawater to form the body, and main component is calcium carbonate, can be expressed as with chemical equation:
The shellfish body is fixed carbon in seawater in process of growth, and the carbonic acid gas of absorption is converted into calcium carbonate and is sealed up for safekeeping to form hard shell in body of shellfish.
In the breeding process of shellfish biology, by reducing the method for input of bait, so that the ratio of the C/N of water body, C/P all reaches more than 2.
Described miniature organism comprises the unicellular organism of all kinds of autotrophys, heterotrophism, eucaryon, protokaryon and there is no cell structure but have the viroplankton/phage of ecological functions.Be less than the nanoplankton of 20 μ m and/or the individual hekistoplankton that is less than 2 μ m as good taking individuality.
The explanation as an example of mussel culture example:
In mussel culture process, it is 2% that mussel is controlled at 20 ± 3 DEG C, salinity control in the temperature in seedling stage, and seedling rope adopts atropurpureus coir rope.Before putting in a suitable place to breed, mussel seedling is carried out to the domestication of culture zone water temperature, salinity, current speed.Be conducive to improve the adhesive rate of mussel seedling.Adopt specific seedling rope (atropurpureus coir rope) and wrap seedling processing and can effectively improve the survival rate of mussel in the time putting in a suitable place to breed putting mussel in a suitable place to breed.By reducing the method for input of bait, so that the ratio of the C/N of water body, C/P all reaches 10, make seedling water be micro-green.
In mussel culture, can take in the seawater that contains dissolved carbon dioxide, these carbonic acid gas transform in mussel body, and add other elements to become calcium carbonate, and it is the main component of mussel shell.In other words, mussel is that calcium carbonate is to form hard shell the carbon dioxide conversion of taking in.
The main component of mussel shell is calcium carbonate, and calcium carbonate can stably be present in breeding water body.Therefore the carbonic acid gas that, mussel absorbs can be stored in shell effectively.The carbon being stored in like this in shell just can remove by results shellfish from breeding water body, and the carbon that has directly formed breeding water body converges.
Shellfish culture has consumed the carbonic acid gas dissolving in seawater, having reduced the gas concentration lwevel in breeding water body declines the partial pressure of carbon dioxide in seawater, airborne carbonic acid gas is more easily dissolved in ocean, in other words, these shells have increased the absorbing capacity of water body to carbonic acid gas, and the carbon that has formed breeding water body converges.
A large amount of cultivation of mussel have produced a large amount of carbon containing shells, its calcium carbonate content is more than 95%, calcium carbonate is highly stable under field conditions (factors), is not easy carbonic acid gas to be discharged back in atmosphere easily, therefore the permanent carbonic acid gas that removes from atmosphere effectively such as mussel again.
Autotroph in mussel culture water body, as algae etc.And the cultivation bait of mussel and the excreta of mussel etc. obviously raise the content of the dissolved organic carbon in breeding water body, dissolved organic carbon can pass through biochemical reaction, then gets back in atmosphere with the form of carbonic acid gas.
This method is converted into inertia dissolved organic carbon by the ecological process of miniature organism by a large amount of dissolved organic carbons, makes it no longer to enter biochemical cycles, no longer discharges back in atmosphere with the form of carbonic acid gas.To guarantee that the carbon that mussel growth produces converges effectively.
In " Kyoto Protocol of UNFCCC ", estimate that industrialized country's carbon dioxide discharge-reduction cost is 150~600 beautiful yuan/ton, to RMB exchange rate (1 dollar=6.08 yuans), amount to 912.5~3648.0 yuan/ton with reference to recent dollar; The same period, China's cost of forestation was 250.0 yuan/t.Consider, can estimate approximately 600.0 yuan/ton of China unit's carbon emission reduction Financial cost.Can estimate accordingly the magnitude of value that shellfish and algae carbon converge: the carbon remittance magnitude of value=carbon sink × unit carbon emission reduction Financial cost.
According to the data of " China Fisheries yearbook ", the aquaculture gross yield of China in 2010 is 1.25 × 10 10ton, wherein the output of shellfish is 1.11 × 10 9ton.Because filter-feeding shellfish shell phosphorus content is 11.44%~12.01%.The carbon removing from ocean by the results of cultivated shellfish has 1.29 × 10 8ton, is equivalent to 3.84 × 10 8ton carbonic acid gas.Amount to into RMB, within 2010, China is 22.96 hundred million yuan by the available carbon remittance of cultivated shellfish income.
Embodiment 2:
A kind of method that carbon credit quantitatively detects, the carbon that utilizes above-mentioned solid carbon method to form breeding water body converges, the quantity of the carbon that the shell producing by cultivating system is again sealed up for safekeeping obtains the carbon credit that can correspondingly conclude the business, and the total quantity of the shell producing by cultivating system represents certain solid carbon number amount.
The explanation as an example of mussel culture example:
Can obtain the carbon credit that can conclude the business according to the quantity of the carbon of sealing up for safekeeping in mussel shell, the total quantity of the shell producing by cultivating system represents certain solid carbon number amount, and the amount of the carbonic acid gas of sealing up for safekeeping can be measured for obtaining carbon credit.
The foregoing is only the preferred embodiments of the present invention, be not limited to the present invention, although the present invention is had been described in detail with reference to previous embodiment, for a person skilled in the art, its technical scheme that still can record aforementioned each embodiment is modified, or part technical characterictic is wherein equal to replacement.Within the spirit and principles in the present invention all, any amendment of doing, be equal to replacement, improvement etc., within all should being included in protection scope of the present invention.

Claims (9)

1.一种利用贝类养殖系统固碳的方法,其特征在于:利用贝类的养殖来移除大气中的二氧化碳,具体为:1. A method for utilizing shellfish culture system to fix carbon is characterized in that: the cultivation of shellfish is utilized to remove carbon dioxide in the atmosphere, specifically: 1)通过贝类生物在养殖生长过程中摄入含有溶解有二氧化碳的养殖水体,摄入的二氧化碳在贝类体内转化为碳酸钙以形成坚硬的外壳被封存;1) The ingested carbon dioxide is converted into calcium carbonate in the body of the shellfish to form a hard shell and be sealed through the ingestion of the cultured water body containing dissolved carbon dioxide during the growth of the shellfish; 其中,在贝类生物的养殖过程中,在养殖水体中增加微型生物的共生,将养殖水体中过量的养殖饵料和由自养生物所产生的溶解性有机碳,转化为能够稳定存在的惰性溶解性有机碳,使养殖水体中的活性有机碳浓度降低,使自养生物的固碳能力加强;Among them, in the cultivation process of shellfish organisms, the symbiosis of micro organisms is increased in the cultivation water body, and the excessive cultivation bait in the cultivation water body and the dissolved organic carbon produced by the autotrophic organisms are converted into inert dissolved organic carbon that can exist stably. Organic carbon, which reduces the concentration of active organic carbon in the aquaculture water body, and strengthens the carbon fixation capacity of autotrophic organisms; 2)再将封存有碳酸钙的贝类的外壳回收利用,达到长期固碳,与此同时,养殖水体中二氧化碳的浓度降低,促使空气中的二氧化碳溶解于水体中,形成养殖水体的碳汇,从而对大气产生良性的影响。2) Recycle the shells of shellfish sealed with calcium carbonate to achieve long-term carbon sequestration. At the same time, the concentration of carbon dioxide in the aquaculture water body is reduced, which promotes the dissolution of carbon dioxide in the air in the water body, forming a carbon sink for the aquaculture water body. Thereby having a benign impact on the atmosphere. 2.根据权利要求1所述的利用贝类养殖系统固碳的方法,其特征在于:在贝类生物的养殖过程中,通过减少饵料的投放的方法,以使水体的C/N、C/P的比均达到2以上。2. The method of utilizing the shellfish culture system for carbon sequestration according to claim 1, characterized in that: in the culture process of shellfish organisms, by reducing the method of putting in bait, the C/N, C/ The ratio of P reached 2 or more in all cases. 3.根据权利要求2所述的利用贝类养殖系统固碳的方法,其特征在于:在贝类生物的养殖过程中,通过减少饵料的投放的方法,以使水体的C/N、C/P的比均为10。3. The method for utilizing the shellfish culture system to fix carbon according to claim 2, characterized in that: in the culture process of shellfish organisms, by reducing the method of putting in bait, the C/N, C/ The ratios of P are all 10. 4.根据权利要求1至3任一项所述的利用贝类养殖系统固碳的方法,其特征在于:所述贝类生物是指含碳壳的贝类、甲壳类水生生物。4. The method for sequestering carbon in a shellfish culture system according to any one of claims 1 to 3, wherein the shellfish organisms refer to shellfish and crustacean aquatic organisms containing carbon shells. 5.根据权利要求4所述的利用贝类养殖系统固碳的方法,其特征在于:所述贝类生物为贻贝。5 . The method for sequestering carbon in a shellfish culture system according to claim 4 , wherein the shellfish organisms are mussels. 6 . 6.根据权利要求5所述的利用贝类养殖系统固碳的方法,其特征在于:在贻贝养殖过程中,贻贝在苗期的温度控制在20±3℃、盐度控制为2%,苗绳采用紫黑色棕绳。6. The method for sequestering carbon by using the shellfish culture system according to claim 5, characterized in that: during the mussel culture process, the temperature of the mussels at the seedling stage is controlled at 20±3°C, and the salinity is controlled at 2% , The seedling rope is made of purple-black brown rope. 7.根据权利要求1至3任一项所述的利用贝类养殖系统固碳的方法,其特征在于:所述微型生物包括各类自养、异养、真核、原核的单细胞生物以及没有细胞结构但有生态功能的浮游病毒/噬菌体。7. according to the method for utilizing shellfish culture system carbon fixation according to any one of claims 1 to 3, it is characterized in that: described microbiology comprises various autotrophic, heterotrophic, eukaryotic, prokaryotic unicellular organisms and Ecologically functional planktonic viruses/phages without cellular structures. 8.根据权利要求7所述的利用贝类养殖系统固碳的方法,其特征在于:所述微型生物为个体小于20μm的微型浮游生物和/或个体小于2μm的超微型浮游生物。8 . The method for sequestering carbon by shellfish culture system according to claim 7 , characterized in that: the micro-organisms are micro-plankton whose individual size is smaller than 20 μm and/or micro-plankton whose individual size is smaller than 2 μm. 9.一种检测碳信用的方法,其特征在于:利用权利要求1至8任一项所述的固碳方法形成养殖水体的碳汇,再通过养殖系统产生的外壳封存的碳的数量获得相应的能够进行交易的碳信用,即通过养殖系统产生的外壳的总数量代表一定的固碳数量。9. A method for detecting carbon credits, characterized in that: using the carbon fixation method described in any one of claims 1 to 8 to form a carbon sink for aquaculture water, and then obtain the corresponding amount of carbon sequestered by the shell produced by the aquaculture system. The carbon credits that can be traded, i.e. the total amount of shells produced by the farming system represent a certain amount of carbon sequestered.
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CN106990231A (en) * 2017-04-06 2017-07-28 中国水产科学研究院东海水产研究所 A kind of metering method of Filter feeding bivalves carbon sequestration
CN107202867A (en) * 2017-06-16 2017-09-26 中国水产科学研究院东海水产研究所 A kind of method for determining shellfish carbon sequestration
CN111903581A (en) * 2020-09-10 2020-11-10 张雪涛 Working pile for mussel pile insertion cultivation
CN118483201A (en) * 2024-05-11 2024-08-13 河北农业大学 A method for quantifying inert components in dissolved organic carbon of tidal shellfish and its application

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