CN103963313B - One has electrostatic-proof function glass fiber reinforced plastics product and preparation method - Google Patents
One has electrostatic-proof function glass fiber reinforced plastics product and preparation method Download PDFInfo
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- CN103963313B CN103963313B CN201410157657.9A CN201410157657A CN103963313B CN 103963313 B CN103963313 B CN 103963313B CN 201410157657 A CN201410157657 A CN 201410157657A CN 103963313 B CN103963313 B CN 103963313B
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- glass fibre
- fiber reinforced
- glass fiber
- reinforced plastics
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- 239000011152 fibreglass Substances 0.000 title claims abstract description 47
- 238000002360 preparation method Methods 0.000 title claims abstract description 22
- 238000004519 manufacturing process Methods 0.000 title abstract description 7
- 239000003365 glass fiber Substances 0.000 claims abstract description 65
- 229920005989 resin Polymers 0.000 claims abstract description 36
- 239000011347 resin Substances 0.000 claims abstract description 36
- 238000004544 sputter deposition Methods 0.000 claims abstract description 24
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 16
- 229910052751 metal Inorganic materials 0.000 claims abstract description 11
- 239000002184 metal Substances 0.000 claims abstract description 11
- 239000011256 inorganic filler Substances 0.000 claims abstract description 10
- 229910003475 inorganic filler Inorganic materials 0.000 claims abstract description 10
- 238000000151 deposition Methods 0.000 claims abstract description 7
- 230000008021 deposition Effects 0.000 claims abstract description 7
- 239000011248 coating agent Substances 0.000 claims abstract description 4
- 238000000576 coating method Methods 0.000 claims abstract description 4
- 239000000853 adhesive Substances 0.000 claims description 12
- 230000001070 adhesive effect Effects 0.000 claims description 12
- 239000003292 glue Substances 0.000 claims description 12
- 239000007788 liquid Substances 0.000 claims description 11
- 239000011521 glass Substances 0.000 claims description 9
- 230000001680 brushing effect Effects 0.000 claims description 6
- 238000005516 engineering process Methods 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 5
- 239000010949 copper Substances 0.000 claims description 5
- 229910052802 copper Inorganic materials 0.000 claims description 5
- 239000000758 substrate Substances 0.000 claims description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 2
- 239000003513 alkali Substances 0.000 claims description 2
- 239000004411 aluminium Substances 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
- 238000001354 calcination Methods 0.000 claims description 2
- 230000008020 evaporation Effects 0.000 claims description 2
- 238000001704 evaporation Methods 0.000 claims description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 2
- 229910052737 gold Inorganic materials 0.000 claims description 2
- 239000010931 gold Substances 0.000 claims description 2
- 238000001755 magnetron sputter deposition Methods 0.000 claims description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 2
- 239000010453 quartz Substances 0.000 claims description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 2
- 239000004332 silver Substances 0.000 claims description 2
- 229910052709 silver Inorganic materials 0.000 claims description 2
- 239000000454 talc Substances 0.000 claims description 2
- 229910052623 talc Inorganic materials 0.000 claims description 2
- 235000012222 talc Nutrition 0.000 claims description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 2
- 229920002799 BoPET Polymers 0.000 claims 1
- 239000005041 Mylar™ Substances 0.000 claims 1
- 229910000019 calcium carbonate Inorganic materials 0.000 claims 1
- 229910052742 iron Inorganic materials 0.000 claims 1
- 229940068984 polyvinyl alcohol Drugs 0.000 claims 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 claims 1
- -1 40~80 parts Substances 0.000 abstract description 4
- 238000000034 method Methods 0.000 abstract description 4
- 230000003068 static effect Effects 0.000 abstract description 3
- 238000009825 accumulation Methods 0.000 abstract description 2
- 230000000694 effects Effects 0.000 abstract 1
- 229910000831 Steel Inorganic materials 0.000 description 6
- 239000010959 steel Substances 0.000 description 6
- 229920000049 Carbon (fiber) Polymers 0.000 description 3
- 210000000988 bone and bone Anatomy 0.000 description 3
- 239000004917 carbon fiber Substances 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 3
- WFUGQJXVXHBTEM-UHFFFAOYSA-N 2-hydroperoxy-2-(2-hydroperoxybutan-2-ylperoxy)butane Chemical group CCC(C)(OO)OOC(C)(CC)OO WFUGQJXVXHBTEM-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920002430 Fibre-reinforced plastic Polymers 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000011151 fibre-reinforced plastic Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920006337 unsaturated polyester resin Polymers 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/28—Shaping operations therefor
- B29C70/30—Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core
- B29C70/34—Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core and shaping or impregnating by compression, i.e. combined with compressing after the lay-up operation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/28—Shaping operations therefor
- B29C70/54—Component parts, details or accessories; Auxiliary operations, e.g. feeding or storage of prepregs or SMC after impregnation or during ageing
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/34—Sputtering
- C23C14/35—Sputtering by application of a magnetic field, e.g. magnetron sputtering
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Composite Materials (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Laminated Bodies (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention relates to one and there is electrostatic-proof function glass fiber reinforced plastics product and preparation method, having electrostatic-proof function glass fiber reinforced plastics product is made up of following component, each component is in mass parts: 60～90 parts of resins, 1～3 part of initator, 2～5 parts of releasing agents, 120～230 parts of inorganic fillers, 40～80 parts, glass fibre; Preparation method: adopt physical sputtering method to obtain electric conductivity glass fibre at fiberglass surfacing deposition one deck conductiving metal coating; The top layer of glass fiber reinforced plastics product is to adopt the glass fibre coated with resins with certain electric conductivity to form. The glass fiber reinforced plastics product with this structure can effectively be eliminated the static charge accumulation in goods use procedure, reaches good anti-static effect.
Description
Technical field
The present invention relates to one and there is electrostatic-proof function glass fiber reinforced plastics product and preparation method, there is this structureGlass fiber reinforced plastics product can effectively eliminate the static charge accumulation in goods use procedure, reach well anti-Electrostatic efficiency.
Background technology
Fiberglass is owing to having the physical property of a lot of excellences, therefore in building materials, electronics, electric power, boatThe fields such as sky and space flight have obtained application more and more widely. As a large amount of in started in power industry productAdopt the good glass steel shell of durability as shell. But glass steel shell easily produces static and stagnantElectrical phenomena, therefore requires these glass steel shell surfaces should have electrostatic-proof function.
At present, the research that preparation has an electrostatic-proof function glass fiber reinforced plastics product mainly concentrates on two aspects:The one, adopt carbon fiber to replace glass fibre and prepare fiberglass, because carbon fiber has electric conductivity, thereforeObtain the lower fiberglass of sheet resistance; The 2nd, the tree that adopts electric conductivity colloid to replace fiberglass to useFat, glass fibre and conductive rubber form fiberglass, and its electric conductivity is obtained by conductive rubber. Above-mentionedThere are following problems in two class methods: one is that carbon fiber is compared with glass fibre, too expensive,Therefore be only applicable to the manufacture of high-end goods; The second conductive rubber using, major part is by carbon dustOr other metal fine powders add in resin and obtain, for obtaining desired electric conductivity, the electric conductivity addingPowder quantity is larger, and this is easy to produce the decline of colloidal property. Meanwhile, above-mentioned two class methods institutesThe product colour great majority of glass fiber reinforced plastics product of preparation are dull black, and this has affected goods greatlyThe scope of application.
Summary of the invention
Problem and defect that object of the present invention exists in order to overcome prior art, provide one to have anti-Electrostatic function glass fiber reinforced plastics product and preparation method, the present invention makes full use of the glass fibers of laying in fiberglassTie up, can form the network structure of a connection, its surface is carried out, after metalized, effectively carryingThe electric conductivity of high fiberglass. Owing to adopting the technological means of sputter coating, fiberglass surfacing shapeBecome thin metal conducting layer, therefore its production cost is very low, simultaneously for the performance of fiberglass itself notCan exert an influence.
Object of the present invention is achieved through the following technical solutions:
One has electrostatic-proof function glass fiber reinforced plastics product, it is characterized in that being made up of following component, eachComponent is in mass parts:
Described resin is unsaturated polyester resin.
Described initator is methyl ethyl ketone peroxide.
Described releasing agent is polyvinyl alcohol.
Described inorganic filler is precipitated calcium carbonate, calcining quartz or talcum
Described glass fibre is alkali-free glass fibre or medium-alkali glass fibre.
There is the preparation method of electrostatic-proof function glass fiber reinforced plastics product, it is characterized in that carrying out according to the following steps:
(1) adopt physical sputtering method to obtain at fiberglass surfacing deposition one deck conductiving metal coatingElectric conductivity glass fibre;
(2) at die surface brushing releasing agent, after releasing agent is dry, by the resin of 60-90 part,1-3 part initator, 120-230 part inorganic filler mixing preparation resin glue, be coated with resin adhesive liquidBrush die surface, spread immediately one deck electric conductivity glass fibre, with hairbrush by electric conductivity glass fibreCompacting, makes electric conductivity glass fibre gel content even, discharges bubble;
(3) after ground floor electric conductivity glass fiber resin glue condenses, then in ground floor electric conductivityBrushing resin adhesive liquid on energy glass fibre, proceeds second layer glass fibre and lays, and successively sticks with paste thereafterSystem pastes after 2～3 layers, until desired thickness at every turn; From every layer of later glass used of the second layerFiber is common glass fibre; 48h solidifying and setting at normal temperatures, the demoulding obtains having antistatic meritCan glass fiber reinforced plastics product. Its instructions for use of demoulding backsight, carries out post processing to it, as used polishing machine to itCarry out surface finish etc.
Described physical sputtering method is magnetron sputtering, hot evaporation or laser deposition.
The conducting metal of fiberglass surfacing deposition one deck conductiving metal coating be gold, silver, aluminium, copper orIron.
The concrete technology parameter of described physical sputtering method is as follows: vacuum is less than 1.0 × 10-3Pa，Sputtering pressure Ar=1.0Pa, sputtering power 80W, substrate temperature is 397K, sputtering time 20min.
The present invention makes full use of the glass fibre of laying in fiberglass, can form the network of a connectionStructure, carries out after metalized its surface, will effectively improve the electric conductivity of fiberglass. Owing to adoptingBy the technological means of sputter coating, form thin metal conducting layer at fiberglass surfacing, therefore it is rawProduce cost very low, can not exert an influence for the performance of fiberglass itself simultaneously.
Brief description of the drawings
Fig. 1 is the cross section pie graph of the electrostatic-proof function glass fiber reinforced plastics product prepared of the present invention.
Detailed description of the invention
The present invention's chemical substance used is direct purchase and obtains.
Example 1:
1, carry out the preparation of glass fiber reinforced plastics product according to following formula, each component is in mass parts:
2, adopt copper target to carry out surface magnetic control sputtering to glass fibre, carry out the system of conductive glass fiberStandby, concrete technology parameter is as follows: vacuum is less than 1.0 × 10-3Pa, sputtering pressure Ar=1.0Pa, spattersPenetrate power 80W, substrate temperature is 397K, sputtering time 20min;
3, at die surface brushing releasing agent, after releasing agent bone dry, by resin, initator,Inorganic filler mixing preparation resin glue, is brushed to die surface by deployed resin adhesive liquid, withSpread one deck electric conductivity glass fibre, by the compacting of electric conductivity glass fibre, make electric conductivity with hairbrushGlass fibre gel content is even, discharges bubble;
After ground floor electric conductivity glass fiber resin glue condenses, then at ground floor electric conductivity glassBrushing resin adhesive liquid on glass fiber, proceeds second layer glass fibre and lays, successively pastes thereafter,Paste after 2～3 layers, until desired thickness at every turn; From every layer of later glass fibre used of the second layerBe common glass fibre; 48h solidifying and setting at normal temperatures, the demoulding obtains having electrostatic-proof function glassGlass steel part.
4, obtain according to above-mentioned steps there is electrostatic-proof function glass fiber reinforced plastics product surface specific resistance and be 9 ×107Ω。
Example 2:
Carry out the preparation of glass fiber reinforced plastics product according to following formula, each component is in mass parts:
2, adopt copper target to carry out surface magnetic control sputtering to glass fibre, carry out the system of conductive glass fiberStandby, concrete technology parameter is as follows: vacuum is less than 1.0 × 10-3Pa, sputtering pressure Ar=1.0Pa, spattersPenetrate power 80W, substrate temperature is 397K, sputtering time 20min;
3, at die surface brushing releasing agent, after releasing agent bone dry, by resin, initator,Inorganic filler mixing preparation resin glue, is brushed to die surface by deployed resin adhesive liquid, withSpread one deck electric conductivity glass fibre, by the compacting of electric conductivity glass fibre, make electric conductivity with hairbrushGlass fibre gel content is even, discharges bubble;
After ground floor electric conductivity glass fiber resin glue condenses, then at ground floor electric conductivity glassBrushing resin adhesive liquid on glass fiber, proceeds second layer glass fibre and lays, successively pastes thereafter,Paste after 2～3 layers, until desired thickness at every turn; From every layer of later glass fibre used of the second layerBe common glass fibre; 48h solidifying and setting at normal temperatures, the demoulding obtains having electrostatic-proof function glassGlass steel part.
4, the product surface obtaining according to above-mentioned steps is 6 × 10 than resistance5Ω。
Example 3:
Carry out the preparation of glass fiber reinforced plastics product according to following formula, each component is in mass parts:
2, adopt copper target to carry out surface magnetic control sputtering to glass fibre, carry out the system of conductive glass fiberStandby, concrete technology parameter is as follows: vacuum is less than 1.0 × 10-3Pa, sputtering pressure Ar=1.0Pa, spattersPenetrate power 80W, substrate temperature is 397K, sputtering time 20min;
3, at die surface brushing releasing agent, after releasing agent bone dry, by resin, initator,Inorganic filler mixing preparation resin glue, is brushed to die surface by deployed resin adhesive liquid, withSpread one deck electric conductivity glass fibre, by the compacting of electric conductivity glass fibre, make electric conductivity with hairbrushGlass fibre gel content is even, discharges bubble;
After ground floor electric conductivity glass fiber resin glue condenses, then at ground floor electric conductivity glassBrushing resin adhesive liquid on glass fiber, proceeds second layer glass fibre and lays, successively pastes thereafter,Paste after 2～3 layers, until desired thickness at every turn; From every layer of later glass fibre used of the second layerBe common glass fibre; 48h solidifying and setting at normal temperatures, the demoulding obtains having electrostatic-proof function glassGlass steel part.
4, the product surface obtaining according to above-mentioned steps is 3 × 10 than resistance7Ω。
Claims (10)
1. have an electrostatic-proof function glass fiber reinforced plastics product, it is characterized in that being made up of following component, each component is with mass partsMeter:
60～90 parts of resins
1～3 part of initator
2～5 parts of releasing agents
120～230 parts of inorganic fillers
40～80 parts, glass fibre;
Having electrostatic-proof function glass fiber reinforced plastics product prepares by following steps: (1) adopts physical sputtering method at glass fibre tableFace deposits one deck conductiving metal coating and obtains electric conductivity glass fibre;
(2) at die surface brushing releasing agent, after releasing agent is dry, by the resin of 60-90 part, 1-3 part initator,120-230 part inorganic filler mixing preparation resin glue, is brushed to die surface by resin adhesive liquid, spreads immediately one deck conductionPerformance glass fibre, by the compacting of electric conductivity glass fibre, makes electric conductivity glass fibre gel content even with hairbrush, discharges gasBubble;
(3) after ground floor electric conductivity glass fiber resin glue condenses, then on ground floor electric conductivity glass fibre, be coated withBrush resin adhesive liquid, proceeds second layer glass fibre and lays, and successively pastes thereafter, pastes after 2～3 layers, until required at every turnThickness; The every layer used glass fibre later from the second layer is common glass fibre; 48h solidifying and setting at normal temperatures,The demoulding obtains having electrostatic-proof function glass fiber reinforced plastics product.
2. according to claim 1 have an electrostatic-proof function glass fiber reinforced plastics product, it is characterized in that: described resin is insatiable hungerAnd mylar.
3. according to claim 1 have an electrostatic-proof function glass fiber reinforced plastics product, it is characterized in that: described initator wasMEKP.
4. according to claim 1 have an electrostatic-proof function glass fiber reinforced plastics product, it is characterized in that: described releasing agent is for poly-Vinyl alcohol.
5. according to claim 1 have an electrostatic-proof function glass fiber reinforced plastics product, it is characterized in that: described inorganic filler isPrecipitated calcium carbonate, calcining quartz or talcum.
6. according to claim 1 have an electrostatic-proof function glass fiber reinforced plastics product, it is characterized in that: described glass fibre isAlkali-free glass fibre or medium-alkali glass fibre.
7. according to the preparation method with electrostatic-proof function glass fiber reinforced plastics product one of claim 1-6 Suo Shu, it is characterized in thatCarry out according to the following steps:
(1) adopt physical sputtering method to obtain electric conductivity glass fibers at fiberglass surfacing deposition one deck conductiving metal coatingDimension;
(2) at die surface brushing releasing agent, after releasing agent is dry, by the resin of 60-90 part, 1-3 part initator,120-230 part inorganic filler mixing preparation resin glue, is brushed to die surface by resin adhesive liquid, spreads immediately one deck conductionPerformance glass fibre, by the compacting of electric conductivity glass fibre, makes electric conductivity glass fibre gel content even with hairbrush, discharges gasBubble;
(3) after ground floor electric conductivity glass fiber resin glue condenses, then on ground floor electric conductivity glass fibre, be coated withBrush resin adhesive liquid, proceeds second layer glass fibre and lays, and successively pastes thereafter, pastes after 2～3 layers, until required at every turnThickness; The every layer used glass fibre later from the second layer is common glass fibre; 48h solidifying and setting at normal temperatures,The demoulding obtains having electrostatic-proof function glass fiber reinforced plastics product.
8. the preparation method with electrostatic-proof function glass fiber reinforced plastics product according to claim 7, is characterized in that: describedPhysical sputtering method is magnetron sputtering, hot evaporation or laser deposition.
9. the preparation method with electrostatic-proof function glass fiber reinforced plastics product according to claim 7, is characterized in that: glass fibersThe conducting metal of dimension surface deposition one deck conductiving metal coating is gold, silver, aluminium, copper or iron.
10. the preparation method with electrostatic-proof function glass fiber reinforced plastics product according to claim 7, is characterized in that: described inThe concrete technology parameter of physical sputtering method as follows: vacuum is less than 1.0 × 10-3Pa, sputtering pressure Ar=1.0Pa, sputter meritRate 80W, substrate temperature is 397K, sputtering time 20min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410157657.9A CN103963313B (en) | 2014-04-18 | 2014-04-18 | One has electrostatic-proof function glass fiber reinforced plastics product and preparation method |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410157657.9A CN103963313B (en) | 2014-04-18 | 2014-04-18 | One has electrostatic-proof function glass fiber reinforced plastics product and preparation method |
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| CN103963313A CN103963313A (en) | 2014-08-06 |
| CN103963313B true CN103963313B (en) | 2016-05-18 |
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| CN104669635A (en) * | 2015-01-29 | 2015-06-03 | 柳州市同进汽车零部件制造有限公司 | Preparation method for glass steel product with anti-static function |
| CN108928019A (en) * | 2017-05-24 | 2018-12-04 | 中国石油化工股份有限公司 | A kind of method that fibre glass product manufacture prevents electrostatic induction |
| CN108819298A (en) * | 2018-04-09 | 2018-11-16 | 南通德瑞森复合材料有限公司 | One kind having anti-static function glass fiber reinforced plastics product and preparation method |
| CN109206855B (en) * | 2018-09-30 | 2019-11-08 | 吉林大学 | A kind of resin-based fiber reinforced composite material and preparation method thereof |
| CN113214523B (en) * | 2021-05-14 | 2022-04-01 | 安徽安车新材料有限公司 | Antistatic glass fiber reinforced plastic plate and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JP2011157524A (en) * | 2010-02-03 | 2011-08-18 | Toray Ind Inc | Fiber-reinforced thermoplastic plastic, and method for manufacturing the same |
| CN102952411A (en) * | 2011-08-26 | 2013-03-06 | 亚德化工设备（上海）有限公司 | Glass fiber reinforced plastic material with conductive function and processing method thereof |
| CN102774021B (en) * | 2012-08-10 | 2015-01-14 | 山东金光复合材料股份有限公司 | Production process of light-colored static-conduction glass steel |
| CN102977574B (en) * | 2012-12-04 | 2015-08-19 | 中铁八局集团电务工程有限公司 | Glass reinforced plastic curing agent composition, its glass fiber reinforced plastics composite material made and cable trough |
| CN103483791A (en) * | 2013-09-18 | 2014-01-01 | 常州市华润复合材料有限公司 | UPR composite floor and preparation method thereof |
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