CN103958213B - A kind of method of printing on wall or floor panel - Google Patents
A kind of method of printing on wall or floor panel Download PDFInfo
- Publication number
- CN103958213B CN103958213B CN201380003952.2A CN201380003952A CN103958213B CN 103958213 B CN103958213 B CN 103958213B CN 201380003952 A CN201380003952 A CN 201380003952A CN 103958213 B CN103958213 B CN 103958213B
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- CN
- China
- Prior art keywords
- methods according
- wearing course
- coating
- carrier
- printing
- Prior art date
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- 238000007639 printing Methods 0.000 title claims abstract description 71
- 238000000576 coating method Methods 0.000 claims abstract description 50
- 239000011248 coating agent Substances 0.000 claims abstract description 49
- 239000000203 mixture Substances 0.000 claims abstract description 35
- 239000003973 paint Substances 0.000 claims abstract description 33
- 230000037452 priming Effects 0.000 claims abstract description 29
- 230000005855 radiation Effects 0.000 claims abstract description 28
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 claims abstract description 17
- 238000007711 solidification Methods 0.000 claims abstract description 11
- 230000008023 solidification Effects 0.000 claims abstract description 11
- 238000005034 decoration Methods 0.000 claims abstract description 7
- 239000007788 liquid Substances 0.000 claims abstract description 4
- 239000000463 material Substances 0.000 claims description 37
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- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 claims description 2
- 229910000365 copper sulfate Inorganic materials 0.000 claims description 2
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims description 2
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- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 claims description 2
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- 239000011155 wood-plastic composite Substances 0.000 claims 14
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims 7
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims 2
- HGWOWDFNMKCVLG-UHFFFAOYSA-N [O--].[O--].[Ti+4].[Ti+4] Chemical compound [O--].[O--].[Ti+4].[Ti+4] HGWOWDFNMKCVLG-UHFFFAOYSA-N 0.000 claims 1
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- 244000028419 Styrax benzoin Species 0.000 description 1
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- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- 235000008411 Sumatra benzointree Nutrition 0.000 description 1
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 description 1
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- JUCDYAGBKUTTBC-UHFFFAOYSA-N [ethyl(phenyl)phosphoryl]-(2,4,6-trimethylphenyl)methanone Chemical compound C=1C=CC=CC=1P(=O)(CC)C(=O)C1=C(C)C=C(C)C=C1C JUCDYAGBKUTTBC-UHFFFAOYSA-N 0.000 description 1
- CSCPPACGZOOCGX-UHFFFAOYSA-N acetone Substances CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 1
- 150000008062 acetophenones Chemical class 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 1
- 125000003647 acryloyl group Chemical group O=C([*])C([H])=C([H])[H] 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 150000004056 anthraquinones Chemical class 0.000 description 1
- RJGDLRCDCYRQOQ-UHFFFAOYSA-N anthrone Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3CC2=C1 RJGDLRCDCYRQOQ-UHFFFAOYSA-N 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 239000002969 artificial stone Substances 0.000 description 1
- 239000011425 bamboo Substances 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- WURBFLDFSFBTLW-UHFFFAOYSA-N benzil Chemical compound C=1C=CC=CC=1C(=O)C(=O)C1=CC=CC=C1 WURBFLDFSFBTLW-UHFFFAOYSA-N 0.000 description 1
- 229960002130 benzoin Drugs 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 238000005842 biochemical reaction Methods 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 description 1
- OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical compound NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- INAHAJYZKVIDIZ-UHFFFAOYSA-N boron carbide Chemical compound B12B3B4C32B41 INAHAJYZKVIDIZ-UHFFFAOYSA-N 0.000 description 1
- GJYLKIZKRHDRER-UHFFFAOYSA-N calcium;sulfuric acid Chemical compound [Ca].OS(O)(=O)=O GJYLKIZKRHDRER-UHFFFAOYSA-N 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 239000011111 cardboard Substances 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000007799 cork Substances 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 238000007766 curtain coating Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- ATVPNOBAMISHNQ-UHFFFAOYSA-N diethylazanium sulfamate Chemical compound S(N)([O-])(=O)=O.C(C)[NH2+]CC ATVPNOBAMISHNQ-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 235000019382 gum benzoic Nutrition 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000007641 inkjet printing Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 239000002650 laminated plastic Substances 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 238000007648 laser printing Methods 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- LNOPIUAQISRISI-UHFFFAOYSA-N n'-hydroxy-2-propan-2-ylsulfonylethanimidamide Chemical compound CC(C)S(=O)(=O)CC(N)=NO LNOPIUAQISRISI-UHFFFAOYSA-N 0.000 description 1
- FTWUXYZHDFCGSV-UHFFFAOYSA-N n,n'-diphenyloxamide Chemical compound C=1C=CC=CC=1NC(=O)C(=O)NC1=CC=CC=C1 FTWUXYZHDFCGSV-UHFFFAOYSA-N 0.000 description 1
- 229910052756 noble gas Inorganic materials 0.000 description 1
- ZDHCZVWCTKTBRY-UHFFFAOYSA-N omega-Hydroxydodecanoic acid Natural products OCCCCCCCCCCCC(O)=O ZDHCZVWCTKTBRY-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 239000011087 paperboard Substances 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- LYXOWKPVTCPORE-UHFFFAOYSA-N phenyl-(4-phenylphenyl)methanone Chemical compound C=1C=C(C=2C=CC=CC=2)C=CC=1C(=O)C1=CC=CC=C1 LYXOWKPVTCPORE-UHFFFAOYSA-N 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 1
- 239000011505 plaster Substances 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000007761 roller coating Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 235000020354 squash Nutrition 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- MDDUHVRJJAFRAU-YZNNVMRBSA-N tert-butyl-[(1r,3s,5z)-3-[tert-butyl(dimethyl)silyl]oxy-5-(2-diphenylphosphorylethylidene)-4-methylidenecyclohexyl]oxy-dimethylsilane Chemical compound C1[C@@H](O[Si](C)(C)C(C)(C)C)C[C@H](O[Si](C)(C)C(C)(C)C)C(=C)\C1=C/CP(=O)(C=1C=CC=CC=1)C1=CC=CC=C1 MDDUHVRJJAFRAU-YZNNVMRBSA-N 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 1
- MTPVUVINMAGMJL-UHFFFAOYSA-N trimethyl(1,1,2,2,2-pentafluoroethyl)silane Chemical compound C[Si](C)(C)C(F)(F)C(F)(F)F MTPVUVINMAGMJL-UHFFFAOYSA-N 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea group Chemical group NC(=O)N XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- AVWRKZWQTYIKIY-UHFFFAOYSA-N urea-1-carboxylic acid Chemical compound NC(=O)NC(O)=O AVWRKZWQTYIKIY-UHFFFAOYSA-N 0.000 description 1
- 150000003673 urethanes Chemical class 0.000 description 1
- 210000001215 vagina Anatomy 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/0011—Pre-treatment or treatment during printing of the recording material, e.g. heating, irradiating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C5/00—Processes for producing special ornamental bodies
- B44C5/04—Ornamental plaques, e.g. decorative panels, decorative veneers
- B44C5/043—Ornamental plaques, e.g. decorative panels, decorative veneers containing wooden elements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M1/00—Inking and printing with a printer's forme
- B41M1/26—Printing on other surfaces than ordinary paper
- B41M1/30—Printing on other surfaces than ordinary paper on organic plastics, horn or similar materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M1/00—Inking and printing with a printer's forme
- B41M1/26—Printing on other surfaces than ordinary paper
- B41M1/38—Printing on other surfaces than ordinary paper on wooden surfaces, leather, or linoleum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/0041—Digital printing on surfaces other than ordinary paper
- B41M5/0064—Digital printing on surfaces other than ordinary paper on plastics, horn, rubber, or other organic polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/0041—Digital printing on surfaces other than ordinary paper
- B41M5/0076—Digital printing on surfaces other than ordinary paper on wooden surfaces, leather, linoleum, skin, or flowers
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Laminated Bodies (AREA)
Abstract
The present invention relates to a kind of method producing decorative wall or floor panel, said method comprising the steps of: a kind of tabular base plate a) is provided；B) on the tabular base plate that will print, priming paint is at least applied；C) decoration coating, by printing at least partly through the surface of prime treatment.The method is characterized in that, the liquid radiation solidification mixture using urethane acrylate as main component is as priming paint.
Description
Technical field
The present invention relates to a kind of decorative wall or method of floor panel (floor panel) of producing, and produce according to this method
Panelling.
Background technology
These decorative panels (plate) are originally as known, and wherein term wallboard also refers to be suitable as ceiling (ceiling
Covering) panelling.They generally carriers or core by solid material are constituted, and such as wood materials, in carrier or core
At least side be also provided with decorative layer and top layer, and optionally other layers, such as the abrasion between decorative layer and top layer
Layer.Decorative layer is usually by the impregnated printing paper of amino resin.Top layer and other layers are made up of amino resins generally equally.
But, in some applications, it is difficult for using tradition laminated panel based on fibrous material, as in constant humid or sky
In the environment of vaporous condition.Such as in outdoor, moist room or some such as specific application area such as shipbuildings when.
In these cases, humidity can cause the expansion of fibrous material, including carrier material based on fiber and the facing paper of use.Cause
This, in the application in these fields, it is necessary to provide corresponding moisture proof and weather proof panelling, such as the panelling being made of plastics.
But, in itself previously known plastics panel shows deficiency in terms of decoration, especially when the imitated natural material of needs, such as wood
Or during natural stone.
Therefore, it is an object of the invention to provide a kind of improved method for producing decorative wall or floor panel.
Summary of the invention
The purpose of the present invention is realized by the method described in claim 1.As for wall or floor panel, this purpose is wanted by right
The panelling described in 14 is asked to realize.
Therefore, the present invention proposes a kind of method producing decorative wall or floor panel, comprises the following steps:
A) one plate-shaped support is provided；
B) on plate-shaped support at least one surface to be printed, (applying) priming paint is applied；
C) decoration coating, by printing at least partially the surface through prime treatment, it is characterised in that
Liquid radiation solidification mixture using urethane acrylate as main component is as priming paint, wherein
The method is before step c), especially, includes a further step after step b):
E) apply a resin combination, including >=5wt.% also≤85wt.%, be preferably >=10wt.% also≤80wt.%
Solid, solid mean diameter d50>=0.1 μm also≤120 μm.
Surprisingly, it has been found that use priming paint with urethane acrylate as main component, can overcome in prior art
The deficiency of the coating decorative layer tack strength known.
Here, urethane acrylate is comprised in primer composition with the form of living oligomer or prepolymer.Term " is lived
Property oligomer " and " prepolymer " represent respectively in background of the present invention and comprise the complex of urethane acrylate unit, should
Urethane acrylate unit, adds activity sticker or reactive diluent alternatively, occurs with urethane acrylate polymer
Radiation induced chemical reaction.
In the context of the present invention, urethane acrylate is complex, substantially by one or more aliphatic structure composition and polyurethane
Group forms.Aliphatic structure composition comprises alkyl group, it is therefore preferred to have 4 to 10 carbon atoms, and cycloalkylidene group, excellent
Selection of land has 6 to 20 carbon atoms.Alkyl group and cycloalkylidene group all can be by C1-C4-alkyl, particularly methyl, monosubstituted
Or polysubstituted, and comprise one or more non-adjacent oxygen atom.This aliphatic structure composition is alternately through level Four or tertiary carbon
Atom, by urea groups, biuret, urea diketone, allophanate, cyanurate, urethanes, ester or amide groups or
Person is mutually bonded by oxygen or amine nitrogen.Additionally, the urethane acrylate under background of the present invention can include that olefinic unsaturation knot is constituted
Point.These are preferably vinyl or pi-allyl, and it also can be by C1-C4-alkyl, particularly methyl, and especially by α, β alkene
Belong to vinyl or pi-allyl that unsaturated carboxylic acid or its amino-compound derive.Particularly preferred olefinic unsaturation construction unit is
Acryloyl group and methylacryloyl, such as acrylamide and Methacrylamide, and especially, acryloxy and methyl
Acryloxy.
In the context of the present invention, radiation curing refer to paint base composition at least partly by the electromagnetic radiation induced polymerization of suitable wavelength,
As UV radiates, or electron beam.
Additionally, the radiation curable primer that the present invention uses can include photoinitiator.In this case, photoinitiator can draw
Send out urethane acrylate, or urethane acrylate oligomer or prepolymer, with the radical polymerization of phase emergencing copolymer.Properly
Photoinitiator such as have benzophenone and benzophenone derivates, such as 4-phenyl benzophenone and 4-chlorobenzophenone,
4,4 '-bis-(dimethylamino) benzophenones, anthrone, acetophenone derivative, such as 1-cyclohexyl phenyl ketone-1-alcohol, 2-hydroxyl-2,2-
Dimethyl acetophenone and 2,2-dimethoxy-2-phenyl acetophenone, Benzoinum and benzoin ether, such as methyl, ethyl and fourth
Base benzoin ether, benzil ketals, as benzoin dimethylether, 2-methyl isophthalic acid-[4-(methyl mercapto) benzene]-2-morpholinyl-1-acetone,
Anthraquinone and derivant thereof, such as 2-methylanthraquinone (b-methylanthraquinone) and tert-butyl group anthraquinone, acylphosphine oxide, as
2,4,6-trimethyl benzoyl diphenyl base phosphine oxide, ethyl-2,4,6-trimethylbenzoyl phenyl phosphine oxide and double acyl group oxygen
Change phosphine.Preferably, containing this photoinitiator in primer composition, concentration >=between 0wt.% and≤15wt.%, be preferably >=1wt.
And between≤10wt..
Additionally, as it has been described above, the present invention can primer composition include reactive diluent.The reactive diluent being suitable for such as has,
Simple function or polyfunctional acrylic ester, as 2-hydroxyethyl methylacrylate (HEMA), HPMA (HEPA),
2-(Acryloyloxy)ethanol (HEA), Hydroxypropyl acrylate (HPA), tripropylene glycol double methacrylate (TPGDA), 1,6-hexylene glycol
Diacrylate (HDDA), glycerol propoxylate triacrylate (G3POTA), or pentaerythritol triacrylate (PETIA),
Tri methylol triacrylate (TMPTA), tetramethylol methane tetraacrylate (PETA).In that case it is preferable that priming paint
In composition reactive diluent concentration >=between 1wt.% and≤40wt.%, be preferably >=between 10wt.% and≤30wt..
Additionally, the present invention can primer composition can include further composition, such as UV stabilizer, rheology modifier, such as thickening
Agent, radical scavenger, levelling agent, defoamer, or preservative.The example of UV stabilizer have oxanilide, triazine,
Benzophenone or benzotriazole, it also can be used in combination with radical scavenger, radical scavenger such as sterically hindered amines, such as
2,2,6,6-tetramethyl piperidines, 2,6-di-tert-butyl piperidine or derivatives thereofs, such as, double (2,2,6,6-tetramethyl-4-piperidines
Base) dibutyl sebacate (bis (2,2,6,6-tetramethyl-4-pi-peridyl) sebacinat).
In an embodiment of the present invention, a kind of compositions including pigment or dyestuff is additionally provided, as priming paint.It is preferable, however, that
Ground, the priming paint of employing does not have dyestuff or pigment, or is colourless.In this manner it is possible to prevent due to carrier is irregular,
Priming paint local limit over coating, and cause the stain occurred, affect printed patterns.
According to the preferred embodiment of the inventive method, the primer composition of employing is substantially free of non-polymerizing solvent.Avoiding problems can
Ornament the most to be applied is impacted by the solvent release of energy, such as, and oozing out of color dot.Owing to being substantially free of non-gathering
Bonding solvent, in process of production and from completion after wall or floor panel release solvent will be greatly reduced.
Implement according to one, use radiation curable primer based on urethane acrylate, can be at Primer Layer Coatings and radiation-induced
After solidification, coating decoration immediately, as by digital printing technologies, without there being any restriction.In this article, prime coat is dress
Decorations coating and scribble priming paint carrier surface between good stick together the condition of providing.The advantage of urethane acrylate is as carrier
Material and decorative layer i.e. decorative paint or ink are each provided with good sticking together.This especially can be by occurring such
Polyreaction in polymer is explained, wherein on the one hand, there occurs radiation-induced hydroxyl free radical polymerization, the most logical
Cross NCO and there occurs the rear solidification of polymer.This means after radiation-induced solidification, obtain one immediately without adhesive agent
Surface, for further technique, and the final character of prime coat is also affected by post cure processes based on NCO,
And provide condition for reliably adhering to base material.Additionally, the post cure processes related to can ensure that realizes enough layer stability,
Even if in the less of carrier or non exposed region.Therefore by the carrier of the method for the present invention, particularly preset structure, i.e.
Surface has had the carrier of three dimensional structure, can reliably provide prime coat, so can ensure that the ornament applied subsequently is permissible
Suitably tack strength is bonded on carrier.
The method according to the invention, priming paint preferably utilizes rubber coated pressure bowl to be coated on carrier board.As replacement, can pass through
Casting machine realizes this coating.Similarly, on priming paint carrier board to be sprayed to.According to this application technology, gluing of paint base composition
Degree can be regulated by the amount of reactive diluent in change composition.Apply it is particularly preferred that priming paint may utilize spatula, especially,
Utilize floor trowelling machine.Owing to what carrier may present irregularly can planarize with being optimised, therefore this application technology can realize
Uniform especially surface, thus, available particularly preferred printed patterns.
Preferably, the coating amount of priming paint is at >=1g/m2And≤100g/m2Between, preferably at >=10g/m2And≤50g/m2
Between, it is highly preferred that at >=20g/m2And≤40g/m2Between.After priming paint is coated on carrier surface, with suitably
The radiation source of wavelength performs radiation.
According to the preferred embodiment of this method, the radiation-induced solidification of priming paint is performed by radiation, and wavelength is at 100nm to 380nm
Between, it is preferable that between 250nm to 380nm, such as, utilize Hg, Ga, Fe, or metal halide lamp.In this feelings
Under condition, depending on radiant power is according to speed of production and total exposure time, power bracket is at >=50mW/cm2To≤30W/cm2
Between, it is preferable that at >=0.5W/cm2To≤15W/cm2Between.As the replacement of metal halide lamp, there is suitable sending out
The LED-UV lamp of ejected wave length can apply in present invention process.According to radiant power, the scope of time of exposure is at 0.1s and 180s
Between, it is preferable that between 0.5s and 60s.
An embodiment according to the inventive method, by printing technology, ornament is applied directly to radiation-induced at least partly consolidating
The prime coat changed.Here, utilize relief printing process that prime coat is printed, such as aniline printing, hectographic printing, intaglio plate
Printing, or by such as the typography of silk screen printing etc..Especially, ornament printing may utilize digital printing process, such as spray
Ink technique is coated.Here, it is preferable that ornament is applied, independent of use by coating or the ink of radiation curing
Typography.
Under background of the present invention, coating material solidified binding agent and/or the filler of referring to of term radiation, include the combination of pigment simultaneously
Thing, this coating induced by the electromagnetic radiation with suitable wavelength, such as ultraviolet radiation, or electron beam, at least partly can be polymerized.
Under background of the present invention, term radiation cured printing ink refers to be substantially free of filler, and comprises the compositions of pigment, and this ink is had
The electromagnetic radiation induction of suitable wavelength, such as ultraviolet radiation, or electron beam, at least partly can be polymerized.
The method, before step c), especially, also includes a further step after step b):
E) apply a resin combination, including >=5wt.% also≤85wt.%, be preferably >=10wt.% also≤the consolidating of 80wt.%
Body, solid mean diameter d50>=0.1 μm also≤120 μm.
Surprisingly, it has been found that coating has the printing base coat that the resin combination of solids content defined above is constituted,
Such as coating priming paint after, it is provided that good printing surface, it is adaptable to afterwards directly print technique, additionally, also have
The top layer having and apply afterwards or good the sticking together of wearing course, so that the laminate utilizing this form to produce shows the highest steady
Qualitative, there is good printed patterns simultaneously.This can be particularly applied to specific group of above-mentioned prime coat and above-mentioned printing base coat
Close.The specified solids content of this resin combination refers to liquid resin composition.Therefore, the coating of above-mentioned printing base coat
Both particularly preferred printed patterns can have been realized, it is possible to make panelling to be produced have particularly preferred stability.
Here, particularly with the repeatability coating of printing base coat, different compositions can be used.Such as, although
Ground floor can include above-mentioned filler, and does not contains dyestuff and pigment, below in layer can containing have dyestuff and, in particular,
The printing base coat of filler, this dyestuff such as pigment coating.Additionally, these layers are at the filler used and dyestuff, and pigment
Type and amount on can be different.In this way it is possible to apply the adaptability of ornament after Ti Gaoing, such as ornament color.
In the method, the method for application of resin compositions can pass through coating roll, spraying method, blade coating, scraper for coating,
Paint spray, casting coating equipment, squash type coating, heavy curtain coating or other suitable equipments are implemented.Especially, roller can be passed through
It is coated with and above-mentioned resin combination is coated, wherein need to repeat, especially, use roller coating technology twice.Here, resin
Compositions can be coated on another layer of the not resin combination of drying kinetics especially, or preferably, applies it in second time
Before or before each further coating, each corresponding lower floor applied can drying kinetics.In this manner it is possible to obtain
Particularly preferred printed patterns.Such as, resin combination coating total amount can be at >=5g/m2And≤50g/m2Between, preferably exist
≥10g/m2And≤40g/m2Between.
The printing base coat that the present invention provides is also adaptable for aniline printing, hectographic printing, or silk screen printing, and is particularly suitable for numeral
Printing technology, such as ink-jetting process or laser printing.Therefore, it can directly print the surface with printing base coat.With regard to this point
For, it should be noted that printing from the teeth outwards includes directly printing, and also includes indirect printing.It is therefoie, for example, at least
Printing on the surface of part prime treatment can include directly or indirectly printing, as printed another layer from the teeth outwards.In other words, printing
At least partly mean to apply ornament through the surface of prime treatment, priming paint can be directly printed, or alternatively priming paint is printed
Brush base coat.
Additionally, in an embodiment of this method, according to step e), the coating one resin combination containing firming agent, wherein should Firming agent is included in resin combination, such as concentration>=between 0.05wt.% and≤3.0wt.%, be preferably>=0.15wt.% And between≤2.0wt.%, it is further preferred that>=between 0.5wt.% and≤2.0wt.%.Firming agent is added in resin combination Condensation and the curing performance that can make resin combination reach optimum.Here, firming agent for example, organic slat solution.Preferably, Firming agent pH value is acid, it is preferable that>=pH0.5 with<between pH7, preferably,>PH0.5 with<pH6 itBetween.
Such as, a kind of so-called latent curing agent is as firming agent.Latent curing agent is characterised by, is being added into
After resin, on the one hand there is under room temperature environment the enough process time, on the other hand, under treatment environment subsequently,
The shortest hardening time can be realized.This effect of latent curing agent is passivity at normal temperatures due to them, and is sending out
After biochemical reaction or temperature raise, will discharge acidic materials, by this, solidification process will accelerate.Latent curing
Agent example particularly including, alkyl or sulfurous acid alkanol amine salt, sulfamic acid, 3-chlorine-1,2-propylene glycol, p-methyl benzenesulfonic acid,
Quinoline, ammonium sulfate, ammonium chloride, ammonium sulfite, ammonium nitrate, ethanolamine hydrochloric salt, dimethyl ethanol ammonium sulphite or diethyl
Ammonium sulfamate.
Especially, firming agent is aqueous phase solution, it is preferable that non-ionic solution.Suitably an example of firming agent is MH-180B
(Melatec AG, Switzerland).
According to another embodiment of method in step e), coatable resin combination is for comprising titanium dioxide, barium sulfate, oxidation
Barium, barium chromate, zirconium oxide (IV), silicon dioxide, aluminium hydroxide, aluminium oxide, ferrum oxide, ferric ferricyanide (III), chromium oxide,
Aska-Rid., cadmium sulfide, Monohydrated selenium dioxide cadmium, cobalt oxide, C.I. Pigment Violet 14, cobalt aluminate, vanadium oxide, bismuth vanadium oxide compound, stannum oxide, copper oxygen
Compound, copper sulfate, curpic carbonate, lead antimonate, plumbous chromate, lead oxide, ceruse, calcium carbonate, calcium sulfate, sulphuric acid calcium aluminate,
The solid of at least one compound in zinc oxide, zinc sulfide, arsenic sulfide, cinnabar, white carbon black, graphite or its mixture.Utilize
These solids, can provide colorful printing secondary priming paint in detail, and its Color Scheme has the feature supporting decorating printing.
Such as, in an Art Design, it is desirable to present the effect of dark-coloured wood, then the printing the of brown or brown keynote can be used
Two priming paint, and in another Art Design, it is desirable to present light color wood or the effect of light color stone, then can use yellow or
Printing second priming paint of white color tone.
According to another embodiment of method in step e), coatable resin combination can be to include melamine resin, first
Urea formaldehyde, Lauxite, phenolic resin, epoxy resin, unsaturated polyester resin, diallyl phthalate or its mixing
At least one compound in thing is as resin Composition.It was unexpected that when the solids knot of corresponding resin Composition with resin combination
During conjunction, just obtain printing the second priming paint, its top layer that can significantly improve last coating and/or the adhesion of wearing course, and then
Improve the stability of laminate.This resin combination, such as, the resin content contained >=between 15wt.% and≤95wt.%,
Be preferably >=between 20wt.% and≤90wt.%, it is further preferred that >=between 25wt.% and≤65wt.%.
According to the preferred embodiment of this method, the viscosity also specially requiring resin combination in step e) meets when employing standard sticks
Degree cup time, flowing time >=between 7s and≤60s.This concentration is according to DIN53211 standard, and using aperture is 4mm's
Viscosity cup measures.
In step e) after application of resin compositions, preferably to implement a drying steps, surface to be printed is wanted
At least partly drying kinetics.In order to reach this purpose, in the surface of application of resin compositions, such as, especially prime coat table
Face, the surface temperature of generation, between >=75 DEG C and≤125 DEG C, is preferably between >=80 DEG C and≤110 DEG C, especially,
Between >=90 DEG C and≤100 DEG C.Such as IR emitter, NIR emitter, jet drier or similar means are applicable to
Produce respective surfaces temperature.Described surface temperature is held time between preferably adjustment >=1s and≤600s, be preferably >=5s with
Between≤400s, it is further preferred that >=between 10s and≤300s.
The resin combination that step e) uses, in addition to the above components, also includes other components or additive, as rheology modifier is used
In regulation viscosity, water, flow improving agent, preservative, surfactant, defoamer, like this.
In order to be dried printing secondary priming paint, simultaneously in order to be dried priming paint, it is preferable that emitter to be used, especially such as UV lamp.
It is for instance possible to use four emitters.Thus can realize complete unified surface to be dried to cover, and further can be real
Show dry run that is the most particularly flexible and that apply guiding in like fashion.
According to the embodiment that the present invention is further preferred, can be by wearing course and/or top coated to this decorative layer.At this
In particularly preferably, the formation of wearing course and/or top layer need also exist for apply radiation-curable composition, such as radiation curing
Varnish.Here, wearing course can include hard material, such as titanium nitride, titanium carbide, silicon nitride, carborundum, boron carbide, carbon
Changing tungsten, ramet, aluminium oxide (corundum), zirconium oxide or its mixture, to increase the wearability of this layer.Here, this hard material
Material amount in wearing course composition is between 5wt.% and 40wt.%, between preferably 15wt.% and 25wt.%.Here,
This hard material preferably mean diameter is between 10 μm and 250 μm, it is preferable that between 10 μm and 100 μm.Therefore,
It is useful that wearing course compositions forms stable dispersion, can avoid decomposition or the deposition of hard material in wearing course.
In an embodiment of the present invention, in order to form corresponding wearing course, radiation-curable composition contains the content of hard material
For 10g/m2To 250g/m2, it is therefore preferable to 25g/m2To 100g/m2.In this case, this coating can pass through such as roller,
Such as rubber coated pressure bowl, or implemented by pouring device.
According in another embodiment of the inventive method, when applying wearing course compositions, in composition and do not contain hard material,
But it is scattered in the form of granules on the wearing course compositions of coating, and subsequently by radiation-induced solidification.
According to the method one embodiment, carrier board is molded of plastic material, especially, by thermoplastic, elasticity or thermosetting
Plastic material, Paper or cardboard are constituted.Additionally, mineral board, as nature and artificial stone's plate, concrete slab, plaster board,
So-called WPC plate (is mixed by plastics and timber), and natural raw material plate, as cork and wood can be as the present invention
Carrier.The panel being even made up of biomass also apply be applicable to the present invention, described biomass such as straw, corn straw, bamboo,
Leaf, Sargassum extract, Fructus Cannabis, oil palm fibre.Additionally, from the material of described material recovery also the inventive method scope it
In.
Carrier board material according to production board being expected physical attribute can be the most intensive, or have more or less big
Cavity, such as, cystose or have cavity, its size is similar to plate size.The multiple structure that multiple above-mentioned material is constituted is also
Can use, such as plasterboard or wood-plastic laminates.
Preferably panel material has thermoplastic such as polrvinyl chloride, polyolefin (such as polyethylene (PE), polypropylene (PP)), gathers
Amide (PA), polyurethane (PU), polystyrene (PS), acrylonitrile butadient styrene (ABS), polymethyl
Acid methyl ester (PMMA), Merlon (PC), polyethylene terephthalate (PET), polyether-ether-ketone (PEEK) or its mix
Compound or copolymer.Plastic material can comprise traditional filler, such as calcium carbonate (Chalk), aluminium oxide, silica gel, silica flour, wood
Powder, Gypsum Fibrosum.It addition, they can colour in a known manner.Especially, planking stuff includes fire retardant.
Especially, thermoplastic also has an advantage, it product produced easily reclaims.Come additionally, can use from other
Source recycled materials.Because so, making reduction production cost be provided with probability.
According to this method one preferred embodiment, use structured supports plate.Here, this carrier board will carry out decorating
At least partly having three-D grain on surface, such as, the surface texture of imitated natural material, such as wood.Here, Ke Yi
Being introduced directly into texture during producing carrier board, such as, directly extruding forms texture, or in step subsequently, it is suitable to utilize
Instrument, as texture roller or texture mould make carrier board produce texture, wherein veining can be implemented after extruding processing immediately.
It is particularly preferred that the decoration implemented is consistent with the texture of carrier board, to copy natural material truly as far as possible.Here,
The texture of carrier board can be implemented by suitable two-phonon process, the detection to be relied on of aliging relative to each other of printing equipment and carrier board
The texture arrived is implemented.In this case, for carrier board and printing equipment aliging relative to each other, printing equipment and carrier board
Relative to each other in order to align and relative movement can be affected because of carrier or the skew of printing equipment necessarily.
According in another embodiment of this method, after coating top layer and/or wearing course, wall or floor panel implement texture
Change.In order to reach this purpose, it is preferable that top layer and/or wearing course coating radiation-curable composition, and radiated by enforcement
The solidification process radiation of induction, only carries out partially cured to top layer and/or wearing course.Utilize suitable tools, such as hard metal stricture of vagina
Reason roller or mould, the superficial makings needed for the most partially cured lamination print.Here, the enforcement of moulding process
Preferably consistent with the ornament being coated to prime coat.In order to ensure that texture to be produced and ornament have enough concordance,
Carrier board wants respective relative movement to align with the other side with coining tool.Expectation in partially cured top layer and/or wearing course
After texture is made, the top layer of veining and/or wearing course to be implemented further to solidify, and especially, utilize electromagnetism spoke
Penetrate or electron beam radiates this layer further.
According to another embodiment of this method, in method, at least part of step is implemented in an inert atmosphere.Particularly, it is coated with
Apply ornament step to implement in an inert atmosphere.Here, suitable noble gas such as have nitrogen, carbon dioxide,
Rare gas or its mixture.
Additionally, the present invention relates to wall or floor panel, including plate-shaped support, prime coat, alternatively printing secondary priming paint and
Decorative layer, wherein prime coat includes urethane acrylate.
According to wall of the present invention or an embodiment of floor panel, prime coat thickness is between >=50 μm and≤1mm, it is preferable that
Between >=100 μm and≤800 μm.
According to another embodiment of wall of the present invention or floor panel, decorative layer is formed by radiation-induced coating or ink substantially.?
Here, decorative layer thickness is such as between >=50 μm and≤1mm, it is preferable that between >=100 μm and≤800 μm.
Top layer or wearing course are coatable on decorative layer.Here, especially, top layer or wearing course are by radiation-induced varnish shape
Become.Top layer or wearing course thickness are such as between >=100 μm and≤5mm, it is preferable that >=between 0.5mm and≤2.5mm.
Accompanying drawing explanation
Below in conjunction with accompanying drawing and an exemplary embodiment, the present invention is illustrated.
Fig. 1 very diagrammatically show the structure of the wall according to the present invention or floor panel.
Detailed description of the invention
Fig. 1 is wall of the present invention or the structural representation of floor panel 100 1 embodiment.This panelling includes a plate-shaped support 110.
Carrier 110 is made up of extruding plastic material, as polyethylene (PE), polypropylene (PP), polyamide fat (PA), polyurethane (PU),
Polystyrene (PS), acrylonitrile butadiene styrene polymer (ABS), polymethyl methacrylate (PMMA), Merlon
(PC), polyethylene terephthalate (PET), polyether-ether-ketone (PEEK) or its mixture or copolymer.Superficial makings
111 copy natural wood materials, utilize suitable instrument to make in carrier 110.The polyurethane propylene of radiation curing will be included
The prime coat 120 of acid esters is coated on plate-shaped support 110.Alternatively, printing base coat 160 is combined by application of resin
Thing is on prime coat 120, and resin combination includes >=between 5wt.% and≤85wt.%, be preferably >=10wt.% and≤80wt.%
Between solid, solid mean diameter d50Meet >=0.1 μm also≤120 μm, as shown in Figure 2.At prime coat 120 top, and
Alternatively at printing base coat 160 top, by suitable typography, such as digital printed, aniline printing or graph
Brush, applies decorative layer 130.In order to increase wearability, top layer 140 and/or wearing course 150 containing hard material apply
On decorative layer 130, wherein this top layer and/or wearing course 140,150 are formed by radiation curable lacquers layer especially.
Example 1
Priming paint synthetic containing aliphatic urethane acrylate prepolymer is with 20-35g/m2Amount to be coated to tabular, surface veined
On carrier, wherein carrier is made up of polyurethane material, and by mercury vapor lamp with about 3W/cm2The time of exposure of power, about 10s
Radiation curing.Utilizing ink-jet technology and use UV cured printing ink, decorative layer is coated to primer layer, and with the texture of carrier board
Consistent.After application UV cured printing ink, decorative layer is radiated by the UV lamp source with suitable wavelength immediately.At decorative layer spoke
Penetrate with enough solidifications after, need before carrying out next process counter plate carry out destacking (destacking), with prevent coating dress
The bleeding of jewelry or defile.Subsequently, top layer and/or wearing course are coated on decorative carrier plate, and it is by radiation curable coating
Layer is formed, and wherein has corundum in granules.
Claims (49)
1. for the method producing decorative wall or floor panel, including step:
A) one plate-shaped support is provided；
B) on plate-shaped support surface to be printed, priming paint is at least applied；
C) decoration coating, by printing at least partially the surface through prime treatment:
It is characterized in that
Liquid radiation solidification mixture using urethane acrylate as main component is as priming paint, and wherein the method is in step
C) before, including a further step:
E) apply a resin combination, including >=5wt.% also≤solid of 85wt.%, solid mean diameter d50≥0.1μm
And≤120 μm.
Method the most according to claim 1, wherein according to step e), the coating one resin combination containing firming agent,
Wherein this firming agent is included in resin combination, concentration >=between 0.05wt.% and≤2.0wt.%.
Method the most according to claim 1 and 2, wherein according to step e), the resin combination of coating comprises titanium dioxide
Titanium, barium sulfate, Barium monoxide, barium chromate, zirconium oxide (IV), silicon dioxide, aluminium hydroxide, aluminium oxide, ferrum oxide,
Ferric ferricyanide (III), chromium oxide, Aska-Rid., cadmium sulfide, Monohydrated selenium dioxide cadmium, cobalt oxide, C.I. Pigment Violet 14, cobalt aluminate,
Vanadium oxide, bismuth vanadium oxide compound, stannum oxide, Cu oxide, copper sulfate, curpic carbonate, lead antimonate, plumbous chromate, lead oxide,
Ceruse, calcium carbonate, calcium sulfate, aluminium calcium sulfate, zinc oxide, zinc sulfide, arsenic sulfide, cinnabar, white carbon black, stone
The solid of at least one compound in ink or its mixture.
4., according to method according to any one of claim 1-2, wherein according to step e), the resin combination of coating includes three
Melamine-formaldehyde resin, formaldehyde resin, Lauxite, phenolic resin, epoxy resin, unsaturated polyester resin, neighbour
At least one compound in dially phthalate or its mixture is as resin Composition.
The most according to claim 3, method, wherein according to step e), the resin combination of coating includes melamino-formaldehyde
Resin, formaldehyde resin, Lauxite, phenolic resin, epoxy resin, unsaturated polyester resin, phthalic acid two
At least one compound in allyl ester or its mixture is as resin Composition.
6. according to the method according to any one of claim 1,2 and 5, including step
D) by wearing course and/or top coated on printing surface.
Method the most according to claim 3, including step
D) by wearing course and/or top coated on printing surface.
Method the most according to claim 4, including step
D) by wearing course and/or top coated on printing surface.
9., according to the method according to any one of claim 1,2,5,7 and 8, wherein this printing process is by digital printed
Realize.
Method the most according to claim 3, wherein this printing process is by digital printed realization.
11. methods according to claim 4, wherein this printing process is by digital printed realization.
12. methods according to claim 6, wherein this printing process is by digital printed realization.
13. according to the method according to any one of claim 1,2,5,7,8 and 10-12, and wherein this printing process passes through spoke
Penetrate coating material solidified and/or ink realization.
14. methods according to claim 3, wherein this printing process is realized by radiation curable coating and/or ink.
15. methods according to claim 4, wherein this printing process is realized by radiation curable coating and/or ink.
16. methods according to claim 6, wherein this printing process is realized by radiation curable coating and/or ink.
17. methods according to claim 9, wherein this printing process is realized by radiation curable coating and/or ink.
18. according to claim 7,8, method according to any one of 10-12 and 14-17, wherein apply varnish, as abrasion
Layer, this varnish comprises hard material and/or has thermosetting.
19. methods according to claim 6, wherein apply varnish, as wearing course, this varnish comprise hard material and
/ or there is thermosetting.
20. methods according to claim 9, wherein apply varnish, as wearing course, this varnish comprise hard material and
/ or there is thermosetting.
21. methods according to claim 13, wherein apply varnish, and as wearing course, this varnish comprises hard material also
And/or person has thermosetting.
22. according to claim 1,2,5,7,8, method according to any one of 10-12,14-17 and 19-21, Qi Zhongti
Confession one is the carrier as main component with thermoplastic or wood-plastic composite (WPC).
23. methods according to claim 3, wherein provide a kind of with thermoplastic or wood-plastic composite (WPC)
Carrier for main component.
24. methods according to claim 4, wherein provide a kind of with thermoplastic or wood-plastic composite (WPC)
Carrier for main component.
25. methods according to claim 6, wherein provide a kind of with thermoplastic or wood-plastic composite (WPC)
Carrier for main component.
26. methods according to claim 9, wherein provide a kind of with thermoplastic or wood-plastic composite (WPC)
Carrier for main component.
27. methods according to claim 13, wherein provide a kind of with thermoplastic or wood-plastic composite (WPC)
Carrier for main component.
28. methods according to claim 18, wherein provide a kind of with thermoplastic or wood-plastic composite (WPC)
Carrier for main component.
29. according to claim 1,2,5,7,8, method according to any one of 10-12,14-17,19-21 and 23-28,
Wherein provide a veining board-like material as carrier.
30. methods according to claim 3, wherein provide a veining board-like material as carrier.
31. methods according to claim 4, wherein provide a veining board-like material as carrier.
32. methods according to claim 6, wherein provide a veining board-like material as carrier.
33. methods according to claim 9, wherein provide a veining board-like material as carrier.
34. methods according to claim 13, wherein provide a veining board-like material as carrier.
35. methods according to claim 18, wherein provide a veining board-like material as carrier.
36. methods according to claim 22, wherein provide a veining board-like material as carrier.
37. methods according to claim 29, wherein the enforcement of printing process and the texture of carrier material are consistent.
38. according to the method according to any one of claim 30-36, wherein the enforcement of printing process and the texture one of carrier material
Cause.
39. according to claim 7,8, method according to any one of 10-12,14-17,19-21,23-28 and 30-37,
Including step d) by wearing course and/or top coated on printing surface, the most after coating, these abrasion
Layer and/or top layer are textured.
40. methods according to claim 6, including step d) by wearing course and/or top coated in printing surface
On, the most after coating, this wearing course and/or top layer are textured.
41. methods according to claim 9, including step d) by wearing course and/or top coated in printing surface
On, the most after coating, this wearing course and/or top layer are textured.
42. methods according to claim 13, including step d) by wearing course and/or top coated in printing surface
On, the most after coating, this wearing course and/or top layer are textured.
43. methods according to claim 18, including step d) by wearing course and/or top coated in printing surface
On, the most after coating, this wearing course and/or top layer are textured.
44. methods according to claim 22, including step d) by wearing course and/or top coated in printing surface
On, the most after coating, this wearing course and/or top layer are textured.
45. methods according to claim 29, including step d) by wearing course and/or top coated in printing surface
On, the most after coating, this wearing course and/or top layer are textured.
46. according to the method described in claim 38, including step d) by wearing course and/or top coated in printing surface
On, the most after coating, this wearing course and/or top layer are textured.
47. according to the method described in claim 39, and wherein wearing course and/or top layer are partially cured before veining.
48. according to the method according to any one of claim 40-46, and wherein wearing course and/or top layer are before veining
Partially cured.
49. walls or floor panel (100), including a plate-shaped support (110), a prime coat (120), printing base coat (160),
And a decorative layer (130), be characterised by this prime coat (120) containing urethane acrylate,
Wherein print base coat (160) to be made up of a resin combination, described resin combination includes >=5wt.% also≤
The solid of 85wt.%, solid mean diameter d50>=0.1 μm also≤120 μm.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP12181696.1 | 2012-08-24 | ||
| EP12181696.1A EP2700508A1 (en) | 2012-08-24 | 2012-08-24 | Method for printing a wall or floor panel |
| PCT/EP2013/067586 WO2014029887A1 (en) | 2012-08-24 | 2013-08-23 | Method for printing on a wall or floor panel |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103958213A CN103958213A (en) | 2014-07-30 |
| CN103958213B true CN103958213B (en) | 2016-10-26 |
Family
ID=47010213
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201380003952.2A Active CN103958213B (en) | 2012-08-24 | 2013-08-23 | A kind of method of printing on wall or floor panel |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP2700508A1 (en) |
| KR (1) | KR20140097505A (en) |
| CN (1) | CN103958213B (en) |
| WO (1) | WO2014029887A1 (en) |
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| EP3326835A1 (en) * | 2016-11-25 | 2018-05-30 | Akzenta Paneele + Profile GmbH | Substrate for a decorated wall or floor panel |
| PL3348419T3 (en) * | 2017-01-13 | 2021-06-14 | Akzenta Paneele + Profile Gmbh | Decorated surface structured wall or floor panel based on fibre cement board |
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| DE102018119766B4 (en) | 2018-08-14 | 2023-03-23 | Akzenta Paneele + Profile Gmbh | Multilaminar plastic carrier material, method for its production and decorative panel |
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| PL3686029T3 (en) * | 2019-01-23 | 2022-09-12 | Flooring Technologies Ltd. | Method for producing an abrasion-resistant and waterproof multilayer panel |
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| CN114165010B (en) * | 2021-11-19 | 2023-07-18 | 诺森（常州）建筑产业有限公司 | 3D flat-plate printing decorative plate based on electron beam curing technology and application thereof |
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| US4581255A (en) * | 1983-08-30 | 1986-04-08 | Abitibi-Price Corporation | Method of making simulated ceramic tile |
| JP4184516B2 (en) * | 1998-12-21 | 2008-11-19 | 大日本印刷株式会社 | Blow molding simultaneous decorating sheet and decorative blow molded product |
| SE516696C2 (en) * | 1999-12-23 | 2002-02-12 | Perstorp Flooring Ab | Process for producing surface elements comprising an upper decorative layer as well as surface elements produced according to the method |
| JP5011635B2 (en) * | 2004-08-18 | 2012-08-29 | 大日本印刷株式会社 | Cosmetic material |
| GB0507904D0 (en) * | 2005-04-19 | 2005-05-25 | Sun Chemical Bv | A method and apparatus for ink jet printing |
| WO2007042258A1 (en) * | 2005-10-10 | 2007-04-19 | Kronospan Technical Co. Ltd. | Abrasion-resistant slabs having a decorative surface |
| WO2007091614A1 (en) * | 2006-02-07 | 2007-08-16 | Dai Nippon Printing Co., Ltd. | Flooring material |
| JP4957319B2 (en) * | 2006-03-27 | 2012-06-20 | 大日本印刷株式会社 | Decorative sheet for steel plate and decorative steel plate using the same |
| JP4903618B2 (en) * | 2006-09-25 | 2012-03-28 | 富士フイルム株式会社 | Inkjet recording method and inkjet recording apparatus |
| KR101456731B1 (en) * | 2006-12-22 | 2014-10-31 | 다이니폰 인사츠 가부시키가이샤 | Make-up sheets and veneers using them |
| CN101545312A (en) * | 2008-07-04 | 2009-09-30 | 广东盈然木业有限公司 | Decorative floor and manufacturing method thereof |
| EP2236313B1 (en) * | 2009-03-31 | 2012-07-11 | Flooring Technologies Ltd. | Method for manufacturing panels and panels manufactured according to this method |
| CN102021990B (en) * | 2010-11-17 | 2012-06-06 | 四川奥菲克斯建设工程有限公司 | Automatic production method for heat insulation decorative board with wood grain texture patterns |
-
2012
- 2012-08-24 EP EP12181696.1A patent/EP2700508A1/en not_active Withdrawn
-
2013
- 2013-08-23 KR KR1020147017871A patent/KR20140097505A/en not_active Ceased
- 2013-08-23 CN CN201380003952.2A patent/CN103958213B/en active Active
- 2013-08-23 WO PCT/EP2013/067586 patent/WO2014029887A1/en active Application Filing
Also Published As
| Publication number | Publication date |
|---|---|
| EP2700508A1 (en) | 2014-02-26 |
| CN103958213A (en) | 2014-07-30 |
| WO2014029887A1 (en) | 2014-02-27 |
| KR20140097505A (en) | 2014-08-06 |
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