CN103937354A - Preparation method for high-hardness water-based glass baking paint - Google Patents
Preparation method for high-hardness water-based glass baking paint Download PDFInfo
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Abstract
The invention relates to a preparation method for a high-hardness water-based glass baking paint composed of nano water-based acrylic resin, low-methoxylation amino resin, a water-based polyurethane acrylic hybrid, hardening resin, a colorant, a substrate wetting agent, an adhesive agent, an acid catalyst, a film-forming auxiliary agent, a defoaming agent, an anti-scratch flatting agent, a thickening agent, a bactericide, a pH regulator, a cosolvent and water. The prepared water-based glass baking paint has the advantages of low VOC, no pollution to the environment, no poison and harm to operators, strong coating film adhesive force, good flexibility, high hardness, excellent wear resistance, excellent water resistance, excellent alcohol resistance, excellent salt fog resistance, simple construction, and stable storage. A prepared paint film has the hardness reaching 5 H or more, and has anti-scratch and wear-resistance properties of a ceramic glaze film; a prepared glass product achieves effects of blue and white porcelain, enamel colored glaze porcelain, and white glazed porcelain; and the water-based glass baking paint is widely used for surface protection and decoration of wine bottles, perfume bottles, glass products, lamps, woodware, metals, plastics and other products.
Description
Technical field
The present invention relates to a kind of preparation method of aqueous glass paint, relate in particular to a kind of high hardness water baking paint that is applicable to various glass baseplates.
Background technology
The coating protection of glass and glasswork has demand widely with decoration in industry and civil area, as bottle, scent flask, lamp decoration, house ornamentation glasswork and glassware etc. all need to be at surface-coated protective layer and decorative coveringns.At present, the glass paint of domestic application mostly is solvent-borne type product, and along with the raising of people's environmental consciousness and perfecting of environmental law Laws & Regulations, water-borne coatings is subject to great attention in application on glass.In glass substrate, there is the shortcomings such as the poor and hardness of sticking power, alcohol resistance, water tolerance, wear resistant is low in the mono-component aqueous glass lacquer that adopts the acrylic resin of polyurethane aqueous dispersion body, water-soluble polypropylene acid resin, ammonia ester type and modification to prepare.Aqueous dual-component self-vulcanizing glass lacquer can cause certain difficulty to construction too short working life in construction process, also causes that the waste of paint vehicle and working-yard mix a unequal difficult problem simultaneously.
Summary of the invention
The present invention selects self-cross linking type, formaldehydeless core-shell copolymerized nano-water soluble acrylate resin, this nano-scale water acrylate resin is different from the membrane formation mechanism of common ACRYLIC EMULSION micelle flocculate and break emulsion, adopt the film forming mechanism of molecular level, along with evaporation of water, there is physicochemical gathering in the specific functional groups in adjacent polymeric thing, make water-borne acrylic resin system produce the crosslinked of physical property, the critical solid content of this physical crosslinking, the critical solid content of assembling than emulsion particle is much lower, in other words, this crosslinked phenomenon just can occur in the time that water-content is higher, the result that the reinforced effects that system is brought is assembled than common micelle will shift to an earlier date, the surface drying time that is system is faster than general aqueous acrylic emulsion.After nano-resin film forming, in membrane structure, containing nanometer microfacies, hardness, glossiness and the snappiness of film are all improved than ortho-water based acrylic resin.
Solidifying agent is chosen with polymerization high methylol group type part methyl-etherified melamine resin, contains alkoxy methyl and methylol, also has the imino-of minute quantity.Because alkoxy methyl is mainly the group of crosslinking reaction, need comparatively high temps that crosslinking reaction could occur, and the reactive behavior of methylol is greater than alkoxy methyl, the increase of methylol group content in aminoresin, can improve curing reaction speed and reduce storing temperature, the imino-that it contains minute quantity simultaneously, can reduce self-polymeric reaction; The film forming after low methyl-etherified aminoresin solidifies has excellent resistance to ethanol, hardness and gloss.
Watersoluble polyurethane acrylic acid hybrid resin has high rigidity, consistency is good, sticking power is excellent, can improve snappiness, tint retention, hardness, wear resistance and the chemical resistant properties of paint film.
Hardening resin is selected aqueous inorganic silicone resin, and after hot setting, film has high hardness, can reach 6～9H, highly stable, and the lower hardness of hot and cold alternately variation is identical.High temperature resistant, can be under 300～600 DEG C of conditions life-time service.Face light, plentiful, wear-resisting, damage resistant, resistance to chemical attack, ultraviolet aging resistance and thermal ageing, water-fast, print resistance.
In order to solve technical problem recited above, the present invention takes following technical scheme: the present invention relates to a kind of high rigidity water-based glass baking varnish, its basic recipe is: nano aqueous acrylic resin 40%～60%, low methyl-etherified aminoresin 7～15%, watersoluble polyurethane acrylic acid hybrid 0～15%, Hardening resin 5～12%, pigment or tinting material 0%～30%, base material wetting agent 0.1%～0.6%, adhesive agent 0.2%～1.5%, acid catalyst 0.2%～1%, film coalescence aid 2%～12%, defoamer 0.1%～0.5%, anti-zoned flow agent 0.1%～0.5%, thickening material 0.2%～1.0%, sterilant 0.1%～0.3%, PH conditioning agent 0.5%～5%, solubility promoter 2%～10%, deionized water 2%～25%.
Wherein, water-borne acrylic resin is selected the self-cross linking type that second-order transition temperature is lower, formaldehydeless core-shell copolymerized nano-water soluble acrylate resin.
Aminoresin is selected polymerization high methylol group type part methyl-etherified melamine resin.
Hardening resin is selected aqueous inorganic silicone resin.
Pigment or tinting material select that consistency is good, high temperature resistant, a kind of or its combination in titanium dioxide, carbon black, pigment dyestuff, dyestuff, transparent pigment, pearly pigment, polygonal effect pigment and the metallic pigment aqueous color paste of ageing resistance, environmental protection, fineness≤15 μ.
Adhesive agent are selected the one of the siloxanes coupling agent that contains amino, two amino, methacrylate based, epoxy group(ing), vinyl, chlorination alkyl etc.
Film coalescence aid is selected a kind of or its combination of ethanol, Virahol, propylene glycol, sec-butyl alcohol, propyl carbinol, propylene glycol monomethyl ether, propandiol butyl ether, alcohol ester-12, propylene glycol phenylate, Diethylene Glycol butyl ether.
Acid catalyst is selected the one of p-methyl benzenesulfonic acid, Witco 1298 Soft Acid, dinonylnaphthalene sulfonic acid, dinonylnaphthalene disulfonic acid.
PH conditioning agent is chosen by ammoniacal liquor, triethylamine, trolamine, N, the one of N-dimethylethanolamine, 2-amino-2-methyl-1-propanol.
The present invention proposes a kind of preparation method of high rigidity water-based glass baking varnish, its preparation technology is as follows: by formulation weight per-cent, deionized water, wetting agent, defoamer mixing and stirring, add water-borne acrylic resin, aminoresin, watersoluble polyurethane acrylic acid hybrid, aqueous inorganic silicone resin, add again film coalescence aid, acid catalyst, flow agent, thickening material, anti-settling agent, PH conditioning agent to stir, add as required pigment or tinting material, moisturizing, froth breaking, be transferred to the viscosity of regulation, make a kind of high rigidity water-based glass baking varnish.
The present invention also provides a kind of coating process of high rigidity water-based glass baking varnish, comprises the following steps: before application, must carry out clean to ground, fill and lead up gap and aperture with putty, after being dried, polish flat; By Water-based glass baking paint brushing, roller coating or spray on the ground of handling well, control build between 8～12 μ m; Place after 5～15min or surface drying in room temperature; Brushing or spraying second water-based stoving paint, control build between 8～12 μ m; As required or the surface appearance of coating film whether determine Pen tri-roads, to control build 10～50 μ m; After surface drying, be placed in the baking oven of 160～180 DEG C and toast 15～25min.
The low VOC of water-based high rigidity glass baking varnish that the present invention makes, environmentally safe, to operator's toxicological harmless, film adhesive is strong, snappiness good and high rigidity, excellent wear resistance, water tolerance, alcohol resistance and salt fog resistance, construction is simple, shelf-stable.The hardness of paint film that the present invention makes, up to more than 5H, has the scratch resistance wear resisting property of enamel film; The glasswork of making reaches the effect of bule and white porcelain, Franc colored glaze porcelain, white glaze porcelain.The surface protection of doing that is widely used in the goods such as bottle, scent flask, glasswork, light fixture, woodenware, metal, plastics is decorated.
Embodiment
High rigidity water-based glass baking varnish is prepared material according to the component formula of table 1 and is implemented.
Four high rigidity water-based glass baking varnish embodiment component formulas of table 1
Embodiment 1:
Add in Scattered Kettle than deionized water by formulation weight according to the 1 high rigidity water-based white glass baking vanish of example in table 1, under stirring, add sterilant, propylene glycol, wetting agent, adhesive agent, acid catalyst dispersed with stirring 30～40min, add under the low speed water-borne acrylic resin, aminoresin, watersoluble polyurethane acrylic acid hybrid, aqueous inorganic silicone resin stirs, add water-based titanium dioxide slurry, PH conditioning agent, defoamer, then at the uniform velocity add film coalescence aid, flow agent, thickening material, the good viscosity of stirring and adjusting and pH value, make a kind of high rigidity water-based white glass baking vanish.
Embodiment 2:
Embodiment 2 high rigidity water-based black glass baking vanish preparation processes are with reference to embodiment 1.
Embodiment 3:
Embodiment 3 high rigidity water-based aurene baking vanish preparation processes are with reference to embodiment 1.
Embodiment 4:
Embodiment 4 high rigidity water-based transparent glass baking vanish preparation processes are with reference to embodiment 1.
According to relevant national standard, the film performance of high rigidity water-based glass baking varnish of the present invention is detected, detected result is as shown in table 2.
Table 2 Water-based glass baking paint film performance detected result
| Test item | Detected result | Examination criteria |
| Paint film appearance | Smooth, smooth, plentiful | Range estimation |
| Pencil hardness | ≥5H | GB/T6739-2006 |
| Sticking power, draws circle method | 1 grade | GB/T9286-1998 |
| Snappiness | ≤1mm | GB/T1731-1993 |
| Shock-resistance | 50kg·cm | GB/T1732-1993 |
| 60 ° of gloss | ＞96 | GB/T9754-1988 |
| Water tolerance | 168h is without extremely | GB/T1733—1993 |
| Alkali resistance, 0.1%NaOH | 168h is without extremely | GB9274 |
| Resistance to salt water, 3%NaCl | 168h is without extremely | GB/T10834-1989 |
| Salt fog resistance | 96h is without extremely | GB/T1771-1991 |
| Resistance to ethanol, 50%C 2H 5OH | 168 without abnormal | GB/T1763—1979 |
| Wear resistance (back and forth) | > 160 times | GB/T1768—1979 |
Although the present invention has been explained in detail and has quoted as proof embodiment, for those of ordinary skill in the art, various schemes, amendment and the change that obviously can make according to above-mentioned explanation, within all should being included in the scope of claim.
Claims (11)
1. a high rigidity water-based glass baking varnish, it is characterized in that: by weight percentage, comprise following component: nano aqueous acrylic resin 40%～60%, low methyl-etherified aminoresin 7～15%, watersoluble polyurethane acrylic acid hybrid 0～15%, Hardening resin 5～12%, pigment or tinting material 0%～30%, base material wetting agent 0.1%～0.6%, adhesive agent 0.2%～1.5%, acid catalyst 0.2%～1%, film coalescence aid 2%～12%, defoamer 0.1%～0.5%, anti-zoned flow agent 0.1%～0.5%, thickening material 0.2%～1.0%, sterilant 0.1%～0.3%, PH conditioning agent 0.5%～5%, solubility promoter 2%～10%, deionized water 2%～25%.
2. a kind of high rigidity water-based glass baking varnish as claimed in claim 1, is characterized in that: described water-borne acrylic resin is selected the self-cross linking type that second-order transition temperature is lower, formaldehydeless core-shell copolymerized nano-water soluble acrylate resin.
3. a kind of high rigidity water-based glass baking varnish as claimed in claim 1, is characterized in that: described aminoresin is selected polymerization high methylol group type part methyl-etherified melamine resin.
4. a kind of high rigidity water-based glass baking varnish as claimed in claim 1, is characterized in that: described Hardening resin is selected aqueous inorganic silicone resin.
5. a kind of high rigidity water-based glass baking varnish as claimed in claim 1, is characterized in that: described pigment or tinting material select that consistency is good, high temperature resistant, a kind of or its combination in titanium dioxide, carbon black, pigment dyestuff, dyestuff, transparent pigment, pearly pigment, polygonal effect pigment and the metallic pigment aqueous color paste of ageing resistance, environmental protection, fineness≤15 μ.
6. a kind of high rigidity water-based glass baking varnish as claimed in claim 1, is characterized in that: described adhesive agent are selected the one of the siloxanes coupling agent that contains amino, two amino, methacrylate based, epoxy group(ing), vinyl, chlorination alkyl etc.
7. a kind of high rigidity water-based glass baking varnish as claimed in claim 1, is characterized in that: described film coalescence aid is selected a kind of or its combination of ethanol, Virahol, propylene glycol, sec-butyl alcohol, propyl carbinol, Trivalin SF, propylene glycol monomethyl ether, propandiol butyl ether, alcohol ester-12, propylene glycol phenylate, Diethylene Glycol butyl ether.
8. a kind of high rigidity water-based glass baking varnish as claimed in claim 1, is characterized in that: described acid catalyst is selected the one of p-methyl benzenesulfonic acid, Witco 1298 Soft Acid, dinonylnaphthalene sulfonic acid, dinonylnaphthalene disulfonic acid.
9. a kind of high rigidity water-based glass baking varnish as claimed in claim 1, is characterized in that: described PH conditioning agent is chosen by ammoniacal liquor, triethylamine, trolamine, N, the one of N-dimethylethanolamine, 2-amino-2-methyl-1-propanol.
10. the preparation method of an a kind of high rigidity water-based glass baking varnish as claimed in claim 1, it is characterized in that: described preparation method, its preparation technology is as follows: by formulation weight per-cent, deionized water, wetting agent, defoamer mixing and stirring, add water-borne acrylic resin, aminoresin, watersoluble polyurethane acrylic acid hybrid, aqueous inorganic silicone resin, add again film coalescence aid, acid catalyst, flow agent, thickening material, anti-settling agent, PH conditioning agent stirs, add as required pigment or tinting material, moisturizing, froth breaking, be transferred to the viscosity of regulation, make a kind of high rigidity water-based glass baking varnish.
The coating process of 11. 1 kinds of a kind of high rigidity water-based glass baking varnish as described in claim 1 or 10, it is characterized in that: described coating process, comprise the following steps: before application, must carry out clean to ground, fill and lead up gap and aperture with putty, after being dried, polish flat; By Water-based glass baking paint brushing, roller coating or spray on the ground of handling well, control build between 8～12 μ m; Place after 5～15min or surface drying in room temperature; Brushing or spraying second water-based stoving paint, control build between 8～12 μ m; As required or the surface appearance of coating film whether determine Pen tri-roads, to control build 10～50 μ m; After surface drying, be placed in the baking oven of 160～180 DEG C and toast 15～25min.
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