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CN103937071A - Polyethylene cable insulation material and preparation method thereof - Google Patents

Polyethylene cable insulation material and preparation method thereof Download PDF

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Publication number
CN103937071A
CN103937071A CN201410116517.7A CN201410116517A CN103937071A CN 103937071 A CN103937071 A CN 103937071A CN 201410116517 A CN201410116517 A CN 201410116517A CN 103937071 A CN103937071 A CN 103937071A
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China
Prior art keywords
parts
density polyethylene
diatomite
polyethylene
agent
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Pending
Application number
CN201410116517.7A
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Chinese (zh)
Inventor
赵兵
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MAANSHAN JIAYUAN ENVIRONMENTAL PROTECTION TECHNOLOGY Co Ltd
Original Assignee
MAANSHAN JIAYUAN ENVIRONMENTAL PROTECTION TECHNOLOGY Co Ltd
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Priority to CN201410116517.7A priority Critical patent/CN103937071A/en
Publication of CN103937071A publication Critical patent/CN103937071A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H01B3/441Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/202Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/06Properties of polyethylene
    • C08L2207/062HDPE

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  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Organic Insulating Materials (AREA)

Abstract

A disclosed polyethylene cable insulation material is characterized by being prepared from the following raw materials in parts by weight: 55-60 parts of high-density polyethylene, 13-16 parts of linear low-density polyethylene, 5-7 parts of PE wax, 16-19 parts of diatomite, 23-26 parts of high-wear-resistance carbon black N330, 1-2 parts of promoter TMTM, 1-2 parts of antiaging agent ODA, 14-16 parts of glyceryl trioleate, 2-3 parts of zinc stearate, 2-3 parts of tricresyl phosphate, 1-2 parts of silane coupling agent KH550, 10-12 parts of epoxidized linseed oil and 6-8 parts of an auxiliary agent. By utilizing high-density resin as a base material, the cable insulation material is smooth in surface and relatively good in fluidity, the production technology is simple, easy and practicable, the production efficiency is high, the cable insulation material is good in effect and capable of replacing imported products, and the cable production cost is reduced also.

Description

A kind of polyethylene cable insulating material and preparation method thereof
Technical field
The present invention relates to polymeric material field, particularly a kind of polyethylene cable insulating material and preparation method thereof.
Background technology
Polyethylene (PE) is a kind of thermoplastic resin that ethene makes through polymerization.Industrial, also comprise the multipolymer of ethene and a small amount of alpha-olefin.Polyethylene odorless, nontoxic, feel ceraceous, has good resistance to low temperature, and chemical stability is good, the erosion of the most of soda acids of ability.Under normal temperature, be insoluble to common solvent, water-absorbent is little, and electrical insulation capability is good.High density polyethylene(HDPE), be commonly called as low pressure polyethylene, compare with LDPE and LLDPE, have higher heatproof, oil-proofness, resistance to vapour permeability and environmental stress crack resistance, in addition electrical insulating property and shock resistance and cold tolerance are fine, are mainly used in the field such as blowing, injection moulding.Generally manufacturing electric wire insulating material of polyethylene, is all after polyethylene starting material and the mixing of various auxiliary agent, to be prepared into by Bitruder extruding pelletization.The weak point such as there will be discharging unstable to disconnect in the ultrafine wire cable course of processing, surface is crude, easily puncture, linear speed is slow, affects quality product and production rate.
Summary of the invention
The object of this invention is to provide a kind of polyethylene cable insulating material and preparation method thereof.
In order to realize object of the present invention, the present invention passes through following scheme implementation:
A kind of polyethylene cable insulating material, is made up of the raw material of following weight part: high density polyethylene(HDPE) 55-60, linear low density polyethylene 13-16, PE wax 5-7, diatomite 16-19, high abrasion furnace carbon black N330 23-26, TM monex TM1-2, anti-aging agent ODA1-2, glycerol glycerinate 14-16, Zinic stearas 2-3, tritolyl phosphate 2-3, Silane coupling agent KH550 1-2, epoxy Toenol 1140 10-12, auxiliary agent 6-8;
Described auxiliary agent is made up of the raw material of following weight part: diatomite 10-12, tri (propylene glycol) diacrylate 2-3, zinc oxide 5-6, jade powder 4-5,3-aminopropyl trimethoxysilane 2-3, linking agent TAC1-2, Zinc Gluconate 1-2, Zinic stearas 1-2, magnesium nitrate 7-9, Syzygium aromaticum stem oil 1-2, Flos Rosae Rugosae quintessence oil 0.1-0.2; Preparation method sends into diatomite in powder in calcining furnace and calcine 3-4 hour at 700-730 DEG C, take out, send in 10-15% hydrochloric acid and soak 1-2 hour, filter to obtain filter residue, wash with clear water, dry, be ground into 200-250 order powder, then the powder of drying is mixed with tri (propylene glycol) diacrylate, zinc oxide, linking agent TAC, grind 1-2 hour, add other remaining component, mixed grinding 1-2 hour, to obtain final product again.
Polyethylene cable insulating material of the present invention, made by following concrete steps:
(1) high density polyethylene(HDPE), linear low density polyethylene, PE wax are heated to molten state, add diatomite, high abrasion furnace carbon black N330, TM monex TM, anti-aging agent ODA, auxiliary agent, stir and mediate 18-25 minute, send into twin screw extruder granulation, obtain A material;
(2) by all the other remaining component heating mixed meltings, stir 8-10 minute, send on twin screw extruder and melt extrude granulation, obtain B material;
(3) after A, B material is mixed, on twin screw extruder, melt extrude granulation, to obtain final product.
Excellent effect of the present invention is: the present invention utilizes high-density resin as base-material, and smooth surface mobility is better, and production technique is simple, and production efficiency is high, respond well, and alternative imported product has also reduced cable production cost.
Embodiment
Below by specific examples, the present invention is described in detail.
A kind of polyethylene cable insulating material, by following weight part (kilogram) raw material make: high density polyethylene(HDPE) 55, linear low density polyethylene 13, PE wax 5, diatomite 16, high abrasion furnace carbon black N330 23, TM monex TM1, anti-aging agent ODA1, glycerol glycerinate 14, Zinic stearas 2, tritolyl phosphate 2, Silane coupling agent KH550 1, epoxy Toenol 1140 10, auxiliary agent 6;
Described auxiliary agent by following weight part (kilogram) raw material make: diatomite 10, tri (propylene glycol) diacrylate 3, zinc oxide 5, jade powder 4,3-aminopropyl trimethoxysilane 2, linking agent TAC2, Zinc Gluconate 1, Zinic stearas 2, magnesium nitrate 9, Syzygium aromaticum stem oil 2, Flos Rosae Rugosae quintessence oil 0.1; Preparation method sends into diatomite in calcining furnace and calcine 3-4 hour at 700-730 DEG C, take out, send in 10-15% hydrochloric acid and soak 1-2 hour, filter to obtain filter residue, wash with clear water, dry, be ground into 200-250 order powder, then the powder of drying is mixed with tri (propylene glycol) diacrylate, zinc oxide, linking agent TAC, grind 1-2 hour, add other remaining component, mixed grinding 1-2 hour, to obtain final product again.
Polyethylene cable insulating material of the present invention, made by following concrete steps:
(1) high density polyethylene(HDPE), linear low density polyethylene, PE wax are heated to molten state, add diatomite, high abrasion furnace carbon black N330, TM monex TM, anti-aging agent ODA, auxiliary agent, stir and mediate 18-25 minute, send into twin screw extruder granulation, obtain A material;
(2) by all the other remaining component heating mixed meltings, stir 8-10 minute, send on twin screw extruder and melt extrude granulation, obtain B material;
(3) after A, B material is mixed, on twin screw extruder, melt extrude granulation, to obtain final product.
Material of the present invention has been carried out to performance test, and main condition are as follows:

Claims (2)

1. a polyethylene cable insulating material, it is characterized in that, made by the raw material of following weight part: high density polyethylene(HDPE) 55-60, linear low density polyethylene 13-16, PE wax 5-7, diatomite 16-19, high abrasion furnace carbon black N330 23-26, TM monex TM 1-2, anti-aging agent ODA 1-2, glycerol glycerinate 14-16, Zinic stearas 2-3, tritolyl phosphate 2-3, Silane coupling agent KH550 1-2, epoxy Toenol 1140 10-12, auxiliary agent 6-8;
Described auxiliary agent is made up of the raw material of following weight part: diatomite 10-12, tri (propylene glycol) diacrylate 2-3, zinc oxide 5-6, jade powder 4-5,3-aminopropyl trimethoxysilane 2-3, linking agent TAC1-2, Zinc Gluconate 1-2, Zinic stearas 1-2, magnesium nitrate 7-9, Syzygium aromaticum stem oil 1-2, Flos Rosae Rugosae quintessence oil 0.1-0.2; Preparation method sends into diatomite in powder in calcining furnace and calcine 3-4 hour at 700-730 DEG C, take out, send in 10-15% hydrochloric acid and soak 1-2 hour, filter to obtain filter residue, wash with clear water, dry, be ground into 200-250 order powder, then the powder of drying is mixed with tri (propylene glycol) diacrylate, zinc oxide, linking agent TAC, grind 1-2 hour, add other remaining component, mixed grinding 1-2 hour, to obtain final product again.
2. polyethylene cable insulating material according to claim 1, is characterized in that, is made up of following concrete steps:
(1) high density polyethylene(HDPE), linear low density polyethylene, PE wax are heated to molten state, add diatomite, high abrasion furnace carbon black N330, TM monex TM, anti-aging agent ODA, auxiliary agent, stir and mediate 18-25 minute, send into twin screw extruder granulation, obtain A material;
(2) by all the other remaining component heating mixed meltings, stir 8-10 minute, send on twin screw extruder and melt extrude granulation, obtain B material;
(3) after A, B material is mixed, on twin screw extruder, melt extrude granulation, to obtain final product.
CN201410116517.7A 2014-03-26 2014-03-26 Polyethylene cable insulation material and preparation method thereof Pending CN103937071A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410116517.7A CN103937071A (en) 2014-03-26 2014-03-26 Polyethylene cable insulation material and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410116517.7A CN103937071A (en) 2014-03-26 2014-03-26 Polyethylene cable insulation material and preparation method thereof

Publications (1)

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CN103937071A true CN103937071A (en) 2014-07-23

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Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104327350A (en) * 2014-10-17 2015-02-04 苏州市涵信塑业有限公司 Modified high temperature resistant polyethylene plastic particle
CN104829908A (en) * 2015-04-21 2015-08-12 蚌埠天光传感器有限公司 Low smoke bending resistant organosilane crosslinked polyethylene cable material and its production method
CN104829904A (en) * 2015-04-21 2015-08-12 蚌埠天光传感器有限公司 Environmental-friendly silane crosslinked polyethylene cable material and preparation method therefor
CN104829912A (en) * 2015-04-21 2015-08-12 蚌埠天光传感器有限公司 Low odor flame retardant silane crosslinked polyethylene cable material and producing method thereof
CN104829909A (en) * 2015-04-21 2015-08-12 蚌埠天光传感器有限公司 High-temperature-resistant high-strength silane crosslinked polyethylene cable material and preparation method therefor
CN104829911A (en) * 2015-04-21 2015-08-12 蚌埠天光传感器有限公司 Organosilane crosslinked polyethylene power cable material with high cold resistance and preparation method thereof
CN104829906A (en) * 2015-04-21 2015-08-12 蚌埠天光传感器有限公司 Anti-aging high-temperature-resistant silane crosslinked polyethylene cable material and preparation method therefor
CN104829907A (en) * 2015-04-21 2015-08-12 蚌埠天光传感器有限公司 Oil-resistant silane crosslinked polyethylene cable material and preparation method therefor
CN104829910A (en) * 2015-04-21 2015-08-12 蚌埠天光传感器有限公司 Organosilane crosslinked polyethylene power cable material with sound absorption and sound insulation functions and preparation method thereof
CN104829905A (en) * 2015-04-21 2015-08-12 蚌埠天光传感器有限公司 Corrosion-resistant silane crosslinked polyethylene cable material and preparation method therefor
CN104844893A (en) * 2015-04-21 2015-08-19 蚌埠天光传感器有限公司 Wear-resistant organosilane crosslinked polyethylene cable material and manufacturing method thereof
CN115083698A (en) * 2022-08-02 2022-09-20 国网江苏省电力有限公司电力科学研究院 Production device and method for high-conductivity aluminum core insulated wire

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101570610A (en) * 2009-06-04 2009-11-04 上海凯波特种电缆料厂有限公司 Fire-retardant polyethylene cable material with mould-proof function and preparation method thereof
CN102140197A (en) * 2011-03-30 2011-08-03 曲阜市东宏实业有限公司 Antistatic agent, antistatic flame-retarding plastics and production methods thereof
CN103319763A (en) * 2012-03-21 2013-09-25 上海盈致橡塑制品有限公司 HDPE-LLDPE-blended cable plastic
CN103351506A (en) * 2013-06-19 2013-10-16 安徽天星光纤通信设备有限公司 Insulated cable material and preparation method thereof
CN103571005A (en) * 2012-07-22 2014-02-12 上海利隆化工化纤有限公司 HDPE-LLDPE blended cable plastic and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101570610A (en) * 2009-06-04 2009-11-04 上海凯波特种电缆料厂有限公司 Fire-retardant polyethylene cable material with mould-proof function and preparation method thereof
CN102140197A (en) * 2011-03-30 2011-08-03 曲阜市东宏实业有限公司 Antistatic agent, antistatic flame-retarding plastics and production methods thereof
CN103319763A (en) * 2012-03-21 2013-09-25 上海盈致橡塑制品有限公司 HDPE-LLDPE-blended cable plastic
CN103571005A (en) * 2012-07-22 2014-02-12 上海利隆化工化纤有限公司 HDPE-LLDPE blended cable plastic and preparation method thereof
CN103351506A (en) * 2013-06-19 2013-10-16 安徽天星光纤通信设备有限公司 Insulated cable material and preparation method thereof

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104327350A (en) * 2014-10-17 2015-02-04 苏州市涵信塑业有限公司 Modified high temperature resistant polyethylene plastic particle
CN104829908A (en) * 2015-04-21 2015-08-12 蚌埠天光传感器有限公司 Low smoke bending resistant organosilane crosslinked polyethylene cable material and its production method
CN104829904A (en) * 2015-04-21 2015-08-12 蚌埠天光传感器有限公司 Environmental-friendly silane crosslinked polyethylene cable material and preparation method therefor
CN104829912A (en) * 2015-04-21 2015-08-12 蚌埠天光传感器有限公司 Low odor flame retardant silane crosslinked polyethylene cable material and producing method thereof
CN104829909A (en) * 2015-04-21 2015-08-12 蚌埠天光传感器有限公司 High-temperature-resistant high-strength silane crosslinked polyethylene cable material and preparation method therefor
CN104829911A (en) * 2015-04-21 2015-08-12 蚌埠天光传感器有限公司 Organosilane crosslinked polyethylene power cable material with high cold resistance and preparation method thereof
CN104829906A (en) * 2015-04-21 2015-08-12 蚌埠天光传感器有限公司 Anti-aging high-temperature-resistant silane crosslinked polyethylene cable material and preparation method therefor
CN104829907A (en) * 2015-04-21 2015-08-12 蚌埠天光传感器有限公司 Oil-resistant silane crosslinked polyethylene cable material and preparation method therefor
CN104829910A (en) * 2015-04-21 2015-08-12 蚌埠天光传感器有限公司 Organosilane crosslinked polyethylene power cable material with sound absorption and sound insulation functions and preparation method thereof
CN104829905A (en) * 2015-04-21 2015-08-12 蚌埠天光传感器有限公司 Corrosion-resistant silane crosslinked polyethylene cable material and preparation method therefor
CN104844893A (en) * 2015-04-21 2015-08-19 蚌埠天光传感器有限公司 Wear-resistant organosilane crosslinked polyethylene cable material and manufacturing method thereof
CN115083698A (en) * 2022-08-02 2022-09-20 国网江苏省电力有限公司电力科学研究院 Production device and method for high-conductivity aluminum core insulated wire

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Application publication date: 20140723

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