CN103933874B - Car light protection hydrophobic oleophobic microporous barrier and manufacture method thereof - Google Patents
Car light protection hydrophobic oleophobic microporous barrier and manufacture method thereof Download PDFInfo
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- CN103933874B CN103933874B CN201410189715.6A CN201410189715A CN103933874B CN 103933874 B CN103933874 B CN 103933874B CN 201410189715 A CN201410189715 A CN 201410189715A CN 103933874 B CN103933874 B CN 103933874B
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- hydrophobic oleophobic
- car light
- finishing agent
- microporous membrane
- microporous
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- 230000002209 hydrophobic effect Effects 0.000 title claims abstract description 58
- 230000004888 barrier function Effects 0.000 title claims abstract description 28
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 16
- 238000000034 method Methods 0.000 title claims abstract description 12
- 239000012982 microporous membrane Substances 0.000 claims abstract description 37
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 35
- 239000011248 coating agent Substances 0.000 claims abstract description 11
- 238000000576 coating method Methods 0.000 claims abstract description 11
- 238000001035 drying Methods 0.000 claims abstract description 10
- 239000002994 raw material Substances 0.000 claims abstract description 10
- 238000010438 heat treatment Methods 0.000 claims abstract description 8
- 238000002360 preparation method Methods 0.000 claims abstract description 8
- 238000005096 rolling process Methods 0.000 claims abstract description 6
- 239000011247 coating layer Substances 0.000 claims abstract description 4
- 238000004806 packaging method and process Methods 0.000 claims abstract description 4
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims description 18
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 11
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 11
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical group [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 10
- 239000003995 emulsifying agent Substances 0.000 claims description 10
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 claims description 5
- YJKHMSPWWGBKTN-UHFFFAOYSA-N 2,2,3,3,4,4,5,5,6,6,7,7-dodecafluoroheptyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)F YJKHMSPWWGBKTN-UHFFFAOYSA-N 0.000 claims description 5
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 claims description 5
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 5
- 239000003344 environmental pollutant Substances 0.000 abstract description 6
- 231100000719 pollutant Toxicity 0.000 abstract description 6
- 238000004140 cleaning Methods 0.000 abstract description 5
- 238000009423 ventilation Methods 0.000 abstract description 5
- 240000002853 Nelumbo nucifera Species 0.000 abstract description 4
- 235000006508 Nelumbo nucifera Nutrition 0.000 abstract description 4
- 235000006510 Nelumbo pentapetala Nutrition 0.000 abstract description 4
- 238000011109 contamination Methods 0.000 abstract description 4
- 239000000428 dust Substances 0.000 abstract description 4
- 239000003921 oil Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 238000005516 engineering process Methods 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- 239000003999 initiator Substances 0.000 description 3
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- 150000001335 aliphatic alkanes Chemical group 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- FMMWHPNWAFZXNH-UHFFFAOYSA-N Benz[a]pyrene Chemical compound C1=C2C3=CC=CC=C3C=C(C=C3)C2=C2C3=CC=CC2=C1 FMMWHPNWAFZXNH-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000035800 maturation Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000013618 particulate matter Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 230000029058 respiratory gaseous exchange Effects 0.000 description 1
- 238000010112 shell-mould casting Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 239000002912 waste gas Substances 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
Abstract
The invention discloses a kind of car light protection hydrophobic oleophobic microporous barrier and manufacture method thereof, this microporous barrier comprises: hydrophobic oleophobic finishing agent and microporous membrane, described microporous membrane is coated with hydrophobic oleophobic finishing agent.Its manufacture method, comprises the following steps: the manufacture of microporous membrane; The preparation of hydrophobic oleophobic finishing agent; The car light protection preparation of hydrophobic oleophobic microporous barrier: hydrophobic oleophobic finishing agent feeds in raw material at coating roller, and regulate coating layer thickness, microporous membrane unreels, with cylinder contact coating, cylinder heating preliminary drying, bakes, rolling, packaging.The present invention has the self-cleaning function of similar lotus leaf surface, the pollutants such as rainwater, profit, dust drop automatically, make in the housing of car light, to reach free of contamination dirt level of confidentiality, automobile exhaust pollution thing can be prevented again to be bonded in microporous membrane surface, be maintained by the function that this microporous barrier cross-ventilation regulates car light humidity for a long time, car light performance is normally played.
Description
Technical field
The present invention relates to car light protection field, particularly relate to a kind of car light protection hydrophobic oleophobic microporous barrier and manufacture method thereof.
Background technology
Car light forms cross-ventilation by the upper diverse location air-vent of light fixture, in lamp, steam raises with the temperature in lamp and discharges outside lamp from the air-vent of upper position, the air-vent of upper/lower positions constantly supplements lamp outer air, thus reduce the ambiguous phenomenon generation of the scattering of steam to light, microporous membrane is used in car light protection aspect, though the air in car light can be made to regulate pressure balance by this film convection current, reach free of contamination dirt close, but cannot enter in housing by the steam stoping or reduce in environment when automobile is stopped, be trapped in that wetness in housing is too high will have a strong impact on the performance of the performance of car light.
In many big and medium-sized cities, " overload ", the waste gas of motor vehicle emission causes environmental pollution to the quantity reality of automobile.Vehicle exhaust major pollutants are hydrocarbon, oxynitrides, carbon monoxide, sulfur dioxide, lead-containing compounds, Benzpyrene and solid particulate matter etc., in haze weather and overcast and rainy, these pollutants can stick in the body surface of not water and oil repellant, form dirt, when these oiliness contaminant particles are deposited on the microporous membrane surface of not water and oil repellant, the microporous membrane surface of water and oil repellant does not have self-cleaning ability, with the passing of time the air-locked blanket layer of one deck is defined, the permeability of the microporous membrane of not water and oil repellant is had a strong impact on or airtight, car light convection current of breathing freely is made to regulate the ability of car light humidity greatly to reduce.
Summary of the invention
The technical problem that the present invention mainly solves is to provide a kind of car light protection hydrophobic oleophobic microporous barrier and manufacture method thereof, there is the function that similar lotus leaf surface is self-cleaning, the pollutants such as rainwater, profit, dust drop automatically, automobile exhaust pollution thing can be prevented to be bonded in microporous membrane surface, be maintained by the function that this microporous barrier cross-ventilation regulates car light humidity for a long time, car light performance is normally played.
For solving the problems of the technologies described above, the technical scheme that the present invention adopts is: provide a kind of car light protection hydrophobic oleophobic microporous barrier, comprising: hydrophobic oleophobic finishing agent and microporous membrane, described microporous membrane is coated with hydrophobic oleophobic finishing agent.
In a preferred embodiment of the present invention, described microporous membrane is the microporous membrane of expanded PTFE.
In a preferred embodiment of the present invention, described hydrophobic oleophobic finishing agent is Organic fluoride hydrophobic oleophobic finishing agent, and described Organic fluoride hydrophobic oleophobic finishing agent comprises the raw material of following parts by weight: dodecafluoroheptyl methacrylate 40 ~ 60%, hydroxyethyl methacrylate 1 ~ 3%, emulsifying agent 30 ~ 50% and initator 5 ~ 10%.
In a preferred embodiment of the present invention, described emulsifying agent comprises NPE and neopelex, and described NPE and neopelex weight proportion are 3:2.
In a preferred embodiment of the present invention, described initator is ammonium persulfate.
In a preferred embodiment of the present invention, the coating thickness of described hydrophobic oleophobic finishing agent is 0.005 ~ 0.01mm.
For solving the problems of the technologies described above, another technical solution used in the present invention is: the manufacture method providing a kind of car light protection hydrophobic oleophobic microporous barrier, comprises the following steps:
(1) manufacture of microporous membrane;
(2) preparation of hydrophobic oleophobic finishing agent;
(3) the car light protection preparation of hydrophobic oleophobic microporous barrier: hydrophobic oleophobic finishing agent feeds in raw material at coating roller, and regulate coating layer thickness, microporous membrane unreels, with cylinder contact coating, cylinder heating preliminary drying, bakes, rolling, packaging.
In a preferred embodiment of the present invention, in step (3), the speed that unreels of microporous membrane is 1 ~ 3m/min.
In a preferred embodiment of the present invention, the temperature of step (3) intermediate roll heating preliminary drying is 95 ~ 105 DEG C, and preliminary drying time is 2 ~ 5min, and baking temperature is 140 ~ 160 DEG C, and the time of baking is 3 ~ 8min.
The invention has the beneficial effects as follows: the present invention has the self-cleaning function of similar lotus leaf surface, the pollutants such as rainwater, profit, dust drop automatically, make in the housing of car light, to reach free of contamination dirt level of confidentiality, automobile exhaust pollution thing can be prevented again to be bonded in microporous membrane surface, be maintained by the function that this microporous barrier cross-ventilation regulates car light humidity for a long time, car light performance is normally played.
Accompanying drawing explanation
In order to be illustrated more clearly in the technical scheme in the embodiment of the present invention, below the accompanying drawing used required in describing embodiment is briefly described, apparently, accompanying drawing in the following describes is only some embodiments of the present invention, for those of ordinary skill in the art, under the prerequisite not paying creative work, other accompanying drawing can also be obtained according to these accompanying drawings, wherein:
Fig. 1 is the structural representation of car light protection hydrophobic oleophobic microporous barrier one of the present invention preferred embodiment;
In accompanying drawing, the mark of each parts is as follows: 1, Organic fluoride hydrophobic oleophobic finishing agent, and 2, the microporous membrane of expanded PTFE.
Detailed description of the invention
Be clearly and completely described to the technical scheme in the embodiment of the present invention below, obviously, described embodiment is only a part of embodiment of the present invention, instead of whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art, not making other embodiments all obtained under creative work prerequisite, belong to the scope of protection of the invention.
Refer to Fig. 1:
Embodiment 1
Hydrophobic oleophobic microporous barrier is used in a kind of car light protection, comprising: the microporous membrane 2 of Organic fluoride hydrophobic oleophobic finishing agent 1 and expanded PTFE, the microporous membrane 2 of described expanded PTFE is coated with Organic fluoride hydrophobic oleophobic finishing agent 1.
Described Organic fluoride hydrophobic oleophobic finishing agent 1 comprises the raw material of following parts by weight: dodecafluoroheptyl methacrylate 50%, hydroxyethyl methacrylate 2%, emulsifying agent 40% and ammonium persulfate initiator 8%, wherein, described emulsifying agent comprises NPE and neopelex, and described NPE and neopelex weight proportion are 3:2.
Embodiment 2
Hydrophobic oleophobic microporous barrier is used in a kind of car light protection, comprising: the microporous membrane 2 of Organic fluoride hydrophobic oleophobic finishing agent 1 and expanded PTFE, the microporous membrane 2 of described expanded PTFE is coated with Organic fluoride hydrophobic oleophobic finishing agent 1.
Described Organic fluoride hydrophobic oleophobic finishing agent 1 comprises the raw material of following parts by weight: dodecafluoroheptyl methacrylate 40, hydroxyethyl methacrylate 1%, emulsifying agent 50% and ammonium persulfate initiator 9%, wherein, described emulsifying agent comprises NPE and neopelex, and described NPE and neopelex weight proportion are 3:2.
Embodiment 3
Hydrophobic oleophobic microporous barrier is used in a kind of car light protection, comprising: the microporous membrane 2 of Organic fluoride hydrophobic oleophobic finishing agent 1 and expanded PTFE, the microporous membrane 2 of described expanded PTFE is coated with Organic fluoride hydrophobic oleophobic finishing agent 1.
Described Organic fluoride hydrophobic oleophobic finishing agent 1 comprises the raw material of following parts by weight: dodecafluoroheptyl methacrylate 60%, hydroxyethyl methacrylate 3%, emulsifying agent 30% and ammonium persulfate initiator 7%, wherein, described emulsifying agent comprises NPE and neopelex, and described NPE and neopelex weight proportion are 3:2.
A manufacture method for car light protection hydrophobic oleophobic microporous barrier, comprises the following steps:
(1) manufacture of the microporous membrane 2 of expanded PTFE: polytetrafluoroethyldispersion dispersion resin mixes with liquid extrusion aid and coloring agent, be incubated 32 DEG C of maturations, give and be pressed into cylinder blank, by rolling process, cylinder blank is laminated, slough extrusion aid, simple tension through heating, biaxial tension, thermal finalization, cooling, rolling;
(2) preparation of Organic fluoride hydrophobic oleophobic finishing agent 1: take each raw material according to weight proportion, be uniformly mixed;
(3) the car light protection preparation of hydrophobic oleophobic microporous barrier: Organic fluoride hydrophobic oleophobic finishing agent 1 feeds in raw material at point type coating roller, and regulate coating layer thickness, coating thickness is 0.005 ~ 0.01mm, the microporous membrane 2 of expanded PTFE unreels, and the speed of unreeling is 1 ~ 3m/min, with point type cylinder contact coating, cylinder heating preliminary drying, the temperature of heating preliminary drying is 95 ~ 105 DEG C, and preliminary drying time is 2 ~ 5min, bakes, baking temperature is 140 ~ 160 DEG C, the time of baking is 3 ~ 8min, rolling, packaging.
The present invention uses Organic fluoride hydrophobic oleophobic finishing agent, this finishing agent contains continuously arranged long perfluor alkane chain, due to its special chemical character, its surface tension is very low, not only far below the surface tension of water, also lower than the surface tension of oils, by arranging film surface, Organic fluoride hydrophobic oleophobic finishing agent deposits and is adsorbed in fiber surface, be combined with fiber by polar group, perfluor alkane chain is at the skin of film, form hydrophobic oleophobic rete, microporous fabrics surface is made to be covered with hydro-oleophobicity group, reduce or eliminate the suction-operated of microporous membrane fiber to water or oil, fiber critical surface tension is declined, thus make microporous membrane obtain water and oil repellant performance.
The beneficial effect of car light protection hydrophobic oleophobic microporous barrier of the present invention is:
1, the innovation and application of the present invention in car light protection automobile exhaust pollution, there is the function that similar lotus leaf surface is self-cleaning, the pollutants such as rainwater, profit, dust drop automatically, make in the housing of car light, to reach free of contamination dirt level of confidentiality, automobile exhaust pollution thing can be prevented again to be bonded in microporous membrane surface, be maintained by the function that this microporous barrier cross-ventilation regulates car light humidity for a long time, car light performance is normally played;
2, the defect problem solved in background technology is invented, the performance of this material meets car light completely and other small-sized sophisticated electronics (mobile phone, navigation terminal, microcomputer etc.) dependable performance plays, and meets in comprehensive requirements of protection such as waterproof and dustproof, grease proofing, moisture-inhibiting, anti-oxidant solution corrosion.
3, the present invention can further reduce car light elimination steam and vehicle exhaust to the design and manufacture cost of its performance impact, make shell moulding simplicity, degree of protection reaches IP68.
The foregoing is only embodiments of the invention; not thereby the scope of the claims of the present invention is limited; every utilize description of the present invention to do equivalent structure or equivalent flow process conversion; or be directly or indirectly used in other relevant technical field, be all in like manner included in scope of patent protection of the present invention.
Claims (8)
1. hydrophobic oleophobic microporous barrier is used in a car light protection, it is characterized in that, comprise: hydrophobic oleophobic finishing agent and microporous membrane, described microporous membrane is coated with hydrophobic oleophobic finishing agent, wherein, described hydrophobic oleophobic finishing agent is Organic fluoride hydrophobic oleophobic finishing agent, and described Organic fluoride hydrophobic oleophobic finishing agent comprises the raw material of following parts by weight: dodecafluoroheptyl methacrylate 40 ~ 60%, hydroxyethyl methacrylate 1 ~ 3%, emulsifying agent 30 ~ 50% and initator 5 ~ 10%.
2. car light protection hydrophobic oleophobic microporous barrier according to claim 1, it is characterized in that, described microporous membrane is the microporous membrane of expanded PTFE.
3. car light protection hydrophobic oleophobic microporous barrier according to claim 1, it is characterized in that, described emulsifying agent comprises NPE and neopelex, and described NPE and neopelex weight proportion are 3:2.
4. car light protection hydrophobic oleophobic microporous barrier according to claim 1, it is characterized in that, described initator is ammonium persulfate.
5. car light protection hydrophobic oleophobic microporous barrier according to claim 1, is characterized in that, the coating thickness of described hydrophobic oleophobic finishing agent is 0.005 ~ 0.01mm.
6. the manufacture method of car light protection hydrophobic oleophobic microporous barrier according to claim 1, is characterized in that, comprise the following steps:
(1) manufacture of microporous membrane;
(2) preparation of hydrophobic oleophobic finishing agent;
(3) the car light protection preparation of hydrophobic oleophobic microporous barrier: hydrophobic oleophobic finishing agent feeds in raw material at coating roller, and regulate coating layer thickness, microporous membrane unreels, with cylinder contact coating, cylinder heating preliminary drying, bakes, rolling, packaging.
7. manufacture method according to claim 6, is characterized in that, in step (3), the speed that unreels of microporous membrane is 1 ~ 3m/min.
8. manufacture method according to claim 6, is characterized in that, the temperature of step (3) intermediate roll heating preliminary drying is 95 ~ 105 DEG C, and preliminary drying time is 2 ~ 5min, and baking temperature is 140 ~ 160 DEG C, and the time of baking is 3 ~ 8min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410189715.6A CN103933874B (en) | 2014-05-07 | 2014-05-07 | Car light protection hydrophobic oleophobic microporous barrier and manufacture method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410189715.6A CN103933874B (en) | 2014-05-07 | 2014-05-07 | Car light protection hydrophobic oleophobic microporous barrier and manufacture method thereof |
Publications (2)
| Publication Number | Publication Date |
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| CN103933874A CN103933874A (en) | 2014-07-23 |
| CN103933874B true CN103933874B (en) | 2015-12-09 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201410189715.6A Active CN103933874B (en) | 2014-05-07 | 2014-05-07 | Car light protection hydrophobic oleophobic microporous barrier and manufacture method thereof |
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Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108654324A (en) * | 2018-06-05 | 2018-10-16 | 江苏泛亚微透科技股份有限公司 | Absorb the component and its manufacturing method, lamp rear cover of sustainable unidirectional discharge moisture in small micro- space |
| CN108583225A (en) * | 2018-06-05 | 2018-09-28 | 江苏泛亚微透科技股份有限公司 | Absorb component of the sustainable unidirectional quickly heating discharge moisture of moisture in small micro- space and preparation method thereof, lamp rear cover |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5539072A (en) * | 1993-03-26 | 1996-07-23 | W. L. Gore & Associates, Inc. | Fabric laminates |
| CN101218013A (en) * | 2005-05-25 | 2008-07-09 | 戈尔企业控股股份有限公司 | Multi-functional coatings on microporous substrates |
-
2014
- 2014-05-07 CN CN201410189715.6A patent/CN103933874B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5539072A (en) * | 1993-03-26 | 1996-07-23 | W. L. Gore & Associates, Inc. | Fabric laminates |
| CN101218013A (en) * | 2005-05-25 | 2008-07-09 | 戈尔企业控股股份有限公司 | Multi-functional coatings on microporous substrates |
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Effective date of registration: 20190107 Address after: 213165 28-8 Liban Road, Bangshang Village, Lijia Town, Wujin District, Changzhou City, Jiangsu Province Patentee after: JIANGSU PAN ASIAN MICROVENT TECHNOLOGY CO., LTD. Address before: 213165 No. 28-8, Li ban Road, Lijia Town, Wujin District, Changzhou, Jiangsu. Patentee before: Pan-Asian Automotive Garnishry (Changzhou) Co., Ltd. |
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Address after: 213000 No.8 Qiancao Road, Lijia Town, Wujin District, Changzhou City, Jiangsu Province Patentee after: JIANGSU PAN ASIAN MICROVENT TECHNOLOGY CO., LTD. Address before: 213165, No. 28-8, Sakamoto Road, Sakamoto village, Lijia Town, Wujin District, Jiangsu, Changzhou Patentee before: JIANGSU PAN ASIAN MICROVENT TECHNOLOGY CO., LTD. |
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