CN103928489A - Organic light-emitting diode display panel and forming method thereof - Google Patents
Organic light-emitting diode display panel and forming method thereof Download PDFInfo
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Abstract
The invention provides an organic light-emitting diode display panel and a forming method thereof. The organic light-emitting diode display panel comprises a substrate base plate and a packaging cover plate which are arranged opposite to each other, an organic light-emitting diode which is located between the substrate base plate and the packaging cover plate, and a light scattering film layer which is located at least one of the inner surface or the outer surface of the packaging cover plate and is capable of conducting scattering on rays emitted by the organic light-emitting diode. Due to the fact that the light scattering film layer can conduct scattering on the rays emitted by the organic light-emitting diode, after the rays are scattered, the scattered rays are emitted from different directions, a looker can see the scattered rays when looking the organic light-emitting diode display panel from different angles, the looker can not see color deviation, and the color-bias phenomenon is eliminated.
Description
Technical field
The present invention relates to demonstration field, particularly relate to a kind of organic LED display panel and forming method thereof.
Background technology
Organic Light Emitting Diode (OLED) display floater is a kind of light-emitting display panel, has the advantages such as short and angular field of view of response time is wide.
The luminescent layer of organic LED display panel is organic luminous layer (organic emitting layer, EML), organic luminous layer is coated with other rete conventionally, so the light that organic luminous layer produces need to just can enter the atmosphere of outside display through other rete.When entering atmosphere through other rete, light can produce refraction, the wavelength of light is longer, refraction angle is less, therefore, the refraction angle of ruddiness is less than blue light refraction angle, thereby the color that causes the being seen color of human eye and organic luminous layer to produce is slightly variant, this difference is called colour cast (color shift).
Organic LED display panel can be divided into top emission type and end emission type.Wherein, in top emission type organic LED display panel, transparent electrode layer is formed on organic luminous layer, and reflection electrode layer is formed under organic luminous layer, and the light that organic luminous layer produces sends from transparency electrode side.Top emission type organic LED display panel has increased the transmission area of light, has improved display brightness, and can support high-res and the large display screen of large aperture ratio and the exploitation of micro-display screen, favored by industry.Yet in top emission type organic LED display panel, reflection electrode layer, organic luminous layer and transparent electrode layer form a kind of micro-cavity structure, cause the generation of microcavity effect.Microcavity effect refers to that light resonates in micro-cavity structure, and the light of specific wavelength is strengthened, and the wavelength difference of resonance occurs each angle.Although microcavity effect is strengthened the light of specific wavelength, improved the luminous intensity of display floater, but in microcavity effect, the resonant wavelength of each angle is different, aggravated the color offset phenomenon of display floater, so the colour cast problem of the different viewing angles of top emission type organic LED display panel is more serious.
For this reason, need a kind of new organic LED display panel and forming method thereof, to solve the colour cast problem of organic LED display panel.
Summary of the invention
The problem that the present invention solves is to provide a kind of organic LED display panel and forming method thereof, to solve colour cast problem.
For addressing the above problem, the invention provides a kind of organic LED display panel, comprising:
The underlay substrate being oppositely arranged and encapsulation cover plate;
Organic Light Emitting Diode, between described underlay substrate and described encapsulation cover plate;
Light scattering rete, be positioned at the inner surface of described encapsulation cover plate or outer surface at least one of them, the light that described light scattering rete can send described Organic Light Emitting Diode carries out scattering.
For addressing the above problem, the present invention also provides a kind of formation method of organic LED display panel, comprising:
Underlay substrate is provided, and described underlay substrate inner surface has Organic Light Emitting Diode;
Encapsulation cover plate is provided;
At least one of them formation light scattering rete at described encapsulation cover plate inner surface or outer surface;
Described encapsulation cover plate and described underlay substrate are fixed together, and the light that described light scattering rete can send described Organic Light Emitting Diode carries out scattering.
Compared with prior art, technical scheme of the present invention has the following advantages:
The invention provides a kind of organic LED display panel and comprise underlay substrate and the encapsulation cover plate being oppositely arranged, Organic Light Emitting Diode between described underlay substrate and described encapsulation cover plate, and light scattering rete, described light scattering rete be positioned at described encapsulation cover plate inner surface or outer surface at least one of them, and the light that can send described Organic Light Emitting Diode carries out scattering, the light that can produce described Organic Light Emitting Diode due to light scattering rete carries out scattering, light is after scattering, from all directions, divide and scatter, when beholder watches described organic LED display panel from all angles, can see the light being scattered, therefore beholder can not see misalignment, eliminated color offset phenomenon.
The present invention also provides a kind of formation method of organic LED display panel, described formation method first provides underlay substrate, described underlay substrate inner surface has Organic Light Emitting Diode, encapsulation cover plate is provided again, then described encapsulation cover plate inner surface or outer surface at least one of them forms light scattering rete, afterwards described encapsulation cover plate and described underlay substrate are fixed together, the light that described light scattering rete can send described Organic Light Emitting Diode carries out scattering.The organic LED display panel that described formation method forms has described light scattering rete, therefore can eliminate color offset phenomenon, and described formation method processing step is simple, and process costs is low.
Accompanying drawing explanation
Fig. 1 is the schematic diagram of the embodiment of the present invention one organic LED display panel;
Fig. 2 is the encapsulation cover plate schematic perspective view of organic LED display panel shown in Fig. 1;
Fig. 3 is the tangent plane schematic diagram of the encapsulation cover plate broad ways of organic LED display panel shown in Fig. 2;
Fig. 4 is the schematic diagram of the embodiment of the present invention two organic LED display panels.
Embodiment
As described in background, there is colour cast problem in existing organic LED display panel, and the organic LED display panel colour cast problem of top emission type is even more serious.
For this reason, the invention provides a kind of organic LED display panel and forming method thereof, described organic LED display panel the inner surface of encapsulation cover plate or outer surface at least one of them arranges light scattering rete, described light scattering rete can carry out scattering to light, when light enters described light scattering rete from Organic Light Emitting Diode, by the scattering of described light scattering rete, thereby penetrate from different perspectives, therefore beholder is when watching, no matter be from which angle, the light of seeing all there will not be deviation, therefore just there will not be color offset phenomenon.
For above-mentioned purpose of the present invention, feature and advantage can more be become apparent, below in conjunction with accompanying drawing, specific embodiments of the invention are described in detail.
Embodiment mono-
The embodiment of the present invention one provides a kind of organic LED display panel, please refer to Fig. 1.
Described organic LED display panel comprises underlay substrate 1 and the encapsulation cover plate 2 being oppositely arranged.Underlay substrate 1 inner surface includes OLED 10, that is Organic Light Emitting Diode 10 is between underlay substrate 1 and encapsulation cover plate 2.Encapsulation cover plate 2 inner surfaces comprise light scattering rete 20, that is light scattering rete 20 is between encapsulation cover plate 2 and Organic Light Emitting Diode 10.
Organic Light Emitting Diode 10 comprises active electrode part 101, protective layer 102, reflection electrode layer 103, organic luminous layer 104, transparent electrode layer 105, pixel definition portion 106 and sept 107.
Active electrode portion 101 is positioned at underlay substrate 1 inner surface, active electrode portion 101 comprises each structure of dotted line frame institute frame choosing in Fig. 1, concrete, active electrode portion 101 can comprise the structures such as thin-film transistor (not mark) that lead-in wire (not mark) and matrix are arranged.
Protective layer 102 covers active electrode part 101, each structure of protective layer 101 protection active electrode portions 101.
Reflection electrode layer 103 is positioned at protective layer 102 surfaces, and reflection electrode layer 103 some by running through protective layer 102, connect the described lead-in wire of active electrode part 101, thereby reflection electrode layer 103 is electrically connected to active electrode portion 101.The material of reflection electrode layer 103 can be tin indium oxide or silver.
Organic luminous layer 104 is positioned at reflection electrode layer 103 surfaces, is positioned at the pixel definition portion 106 in addition on reflection electrode layer 103 surfaces simultaneously.Pixel definition portion 106 is divided into different pixel cells by organic luminous layer 104.
Transparent electrode layer 105 is positioned at organic luminous layer 104 surfaces, and the material of transparent electrode layer 105 can be magnesium or silver, and the light that organic luminous layer 104 produces spreads out of from transparent electrode layer 105.
Sept 107 is positioned at pixel definition portion 106 surfaces.Sept 107 separates transparent electrode layer 105 and light scattering rete 20, therefore between transparent electrode layer 105 and light scattering rete 20, can form cavity 3.Conventionally cavity 3 need to vacuumize, in case block G&W grades, Organic Light Emitting Diode 10 is caused to harmful effect.
It should be noted that, transparent electrode layer 105 surfaces can also comprise one deck passivation protection layer in other embodiments of the invention.
Light scattering rete 20 comprises the micro-structural 201 of a plurality of indentations, and micro-structural 201 is orderly matrix and is arranged in encapsulation cover plate 2 inner surfaces.
It should be noted that, in other embodiments of the invention, light scattering rete also can be arranged at the outer surface of encapsulation cover plate, or is arranged on outer surface and the inner surface of encapsulation cover plate simultaneously.
The size of micro-structural 201 is positioned at visible wavelength range, or be positioned near visible wavelength range, thereby the visible light ray that micro-structural 201 can be sent Organic Light Emitting Diode 10 carries out scattering, make described light after micro-structural 201, disperse to propagate, reach the effect that can see from different perspectives described light.Because a plurality of micro-structurals 201 are orderly matrix, be arranged in encapsulation cover plate 2 inner surfaces, so the scattering process of 201 pairs of light of each micro-structural is identical, thereby the light that light scattering rete 20 can be produced Organic Light Emitting Diode 10 carries out scattering equably.Organic Light Emitting Diode 10 can be divided into a plurality of dot structures, the corresponding light of each dot structure through light scattering rete 20 by scattering equably, thereby make display frame there will not be colour cast problem.
In the present embodiment, described organic LED display panel has active electrode portion 101, and active electrode portion 101 comprises the active Drive Structure such as thin-film transistor that matrix is arranged, therefore described organic LED display panel is active matrix type organic light emitting diode display floater.Simultaneously, in described organic LED display panel, organic luminous layer 104 is positioned at reflection electrode layer 103 surfaces, transparent electrode layer 105 is positioned at organic luminous layer 104 surfaces, and the light that light produces from organic luminous layer 104 spreads out of from transparent electrode layer 105, and therefore described organic LED display panel is top emission type organic LED display panel.It should be noted that, in other embodiments of the invention, described organic LED display panel can be only also a kind of in active matrix type organic light emitting diode display floater and top emission type organic LED display panel, or can also be end emission type Organic Light Emitting Diode.
Active matrix type organic light emitting diode display floater provided by the present invention is in procedure for displaying, active electrode portion 101 can be used for controlling the voltage between reflection electrode layer 103 and transparent electrode layer 105, thereby control the light that the organic luminous layer 104 between reflection electrode layer 103 and transparent electrode layer 105 produces, described light spreads out of from transparent electrode layer 105, enter cavity 3, then enter light scattering rete 20 from cavity 3.When light process light scattering rete 20, because above-mentioned analysis is known, light scattering rete 20 can carry out scattering equably to described light, thereby make beholder when all angles are watched described active matrix type organic light emitting diode display floater, can see and be scattered uniform light, therefore beholder can not see misalignment, has eliminated color offset phenomenon.
Please refer to Fig. 2, Fig. 2 is the schematic perspective view of encapsulation cover plate 2 in organic LED display panel shown in Fig. 1.
As can see from Figure 2, light scattering rete 20 is formed on encapsulation cover plate 2 inner surfaces (now encapsulation cover plate 2 inner surfaces upward), the micro-structural 201 that forms light scattering rete 20 is matrix and is arranged on encapsulation cover plate 2 inner surfaces, and each micro-structural 201 is tetrapyamid shape.
Please refer to Fig. 3, Fig. 3 is the tangent plane schematic diagram of the encapsulation cover plate broad ways of organic LED display panel shown in Fig. 2, that is the profile that obtains along A-A dotted line cutting of encapsulation cover plate 2.
For guaranteeing that light scattering rete 20 has good scattering process, the thickness H that light scattering rete 20 is set is greater than or equal to 0.05 μ m, but simultaneously, in order to prevent that light scattering rete 20 is too thick and other structure is impacted, and in order to save process time and cost of manufacture, the thickness H that light scattering rete 20 is set is less than or equal to 2 μ m, and therefore, the scope of the thickness H of described light scattering rete 20 can comprise 0.05 μ m~2 μ m.
Because micro-structural 201 is tetrapyamid shape, therefore in the profile shown in Fig. 3, micro-structural 201 is triangle zigzag, and for making micro-structural 201 can both carry out preferably geometry scattering to all visible rays, it is 0.1 μ m~1 μ m that micro-structural 201 width L scopes are set.Same, the length range that micro-structural 201 is set is also 0.1 μ m~1 μ m.
It should be noted that, in other embodiments of the invention, micro-structural can be also other pyramid-shaped, such as Rhizoma Sparganii taper, pentagonal pyramid shape or hexagonal pyramid shape etc.In addition, micro-structural can also be coniform or prism-frustum-shaped.
In the present embodiment, the ranges of indices of refraction of light scattering rete 20 can comprise 1~2, and in this ranges of indices of refraction, light scattering rete 20 can either guarantee the scattering process to light, can guarantee again the light emission rate effect of light.In the present embodiment, the material of light scattering rete 20 can be epoxy resin or polyimides, and can regulate by corresponding manufacture craft the refractive index of light scattering rete 20.
But the ranges of indices of refraction that the present embodiment also can further be chosen light scattering rete 20 is 1.1~2.This be because, in above-mentioned analytic process, mention, the light that organic luminous layer 104 produces spreads out of from transparent electrode layer 105, enters cavity 3, then enters light scattering rete 20 from cavity 3.And cavity 3 is evacuated conventionally, its refractive index is close to 1, therefore suitably improve the refractive index of light scattering rete 20, can make cavity 3 relatively become a kind of optically thinner medium, and light scattering rete 20 becomes a kind of optically denser medium relatively, and then making light when entering into light scattering rete 20 from cavity 3, the reflex of light is reduced.From optical reflection principle, the refractive index difference of cavity 3 and light scattering rete 20 is larger, between the interface of cavity 3 and light scattering rete 20, reflex to occur less for light, and the refractive index that therefore improves light scattering rete 20 is conducive to light and imports light scattering rete 20 into from cavity 3.But the material of encapsulation cover plate 2 is generally plastics or glass, its ranges of indices of refraction is conventionally 1.7~1.8, if the refractive index of light scattering rete 20 is too high, can there is stronger reflex in light between light scattering rete 20 and the interface of encapsulation cover plate 2, cause light transmition decrease in efficiency, therefore, the present embodiment considers above-mentioned factor, the ranges of indices of refraction of light scattering rete 20 is further set 1.7~2, thereby make light from organic luminous layer 104, be transmitted to organic LED display panel outside as best one can, improve and light effect.
Embodiment bis-
The embodiment of the present invention two provides another organic LED display panel, please refer to Fig. 4.
Described Organic Light Emitting Diode comprises underlay substrate 4 and the encapsulation cover plate 5 being oppositely arranged.Underlay substrate 4 inner surfaces include OLED 40, and encapsulation cover plate 5 inner surfaces comprise light scattering rete 50.Organic Light Emitting Diode 40 comprises the reflection electrode layer 401 that is positioned at underlay substrate 4 inner surfaces; be positioned at the organic luminous layer 402 on reflection electrode layer 401 surfaces; be positioned at the transparent electrode layer 403 on organic luminous layer 402 surfaces; and the passivation protection layer 404 that is positioned at transparent electrode layer 403 surfaces; the light that wherein organic luminous layer 402 produces spreads out of through transparent electrode layer 403 and passivation protection layer 404, so the organic LED display panel that the present embodiment provides is top emission type organic LED display panel.Light scattering rete 50 comprises a plurality of micro-structurals 501 that matrix distribution is arranged in encapsulation cover plate 5 inner surfaces that are, and light scattering rete 50 can carry out scattering to the light importing into light scattering rete 50 from passivation protection layer 404.Above-mentioned each structure of the present embodiment and character thereof can reference example one corresponding contents.
Different from embodiment mono-, in the organic LED display panel that the present embodiment provides, micro-structural 501 is convex tip shaped, in profile as shown in Figure 4, and the depression forming between adjacent two micro-structurals 501 (not mark) semicircular in shape.
Identical with embodiment mono-, the thickness range of light scattering rete 50 can comprise 0.5 μ m~2 μ m, and the width of micro-structural 501 and length range all can comprise 0.1 μ m~1 μ m.The micro-structural 501 of the present embodiment convex tip shaped can be carried out scattering to light better.
It should be noted that, in other embodiments of the invention, described micro-structural can be to be also round convex or other shape, and light scattering rete also can be positioned at encapsulation cover plate outer surface, or light scattering rete is positioned at encapsulation cover plate inner surface and outer surface simultaneously, and the present invention is not construed as limiting this.
Implement three
The invention process three provides a kind of formation method of organic LED display panel.
First described formation method provides underlay substrate, and described underlay substrate inner surface has Organic Light Emitting Diode.Wherein said Organic Light Emitting Diode can be top emission type or end emission type Organic Light Emitting Diode, and described Organic Light Emitting Diode can also be active matrix type organic light emitting diode.
Encapsulation cover plate is provided.The material of described encapsulation cover plate can be plastics or glass, can certainly be other applicable material, and can form described encapsulation cover plate according to the correspondence formation method of different materials.
At described encapsulation cover plate inner surface, form light scattering rete.Concrete, at described encapsulation cover plate inner surface, form described light scattering rete and comprise following process: at least one technique that described light-scattering material layer is rubbed in (rubbing) technique, dry etch process and wet-etching technology, until form a plurality of micro-structurals that orderly matrix is arranged that are, described micro-structural forms described light scattering rete.The technology of friction process, dry etch process and wet-etching technology is ripe, therefore can improve the efficiency of described formation method, and reduce costs.
The material of described light-scattering material layer can be epoxy resin or polyimides, and the thickness range that forms described light scattering rete can comprise 0.05 μ m~2 μ m.The width of described micro-structural and length range all can be set to 0.1 μ m~1 μ m.The ranges of indices of refraction of described light-scattering material layer can comprise 1~2, for improving, light effect, and the refractive index that can described light-scattering material layer be further set is 1.7~2.
It should be noted that, in other embodiments of the invention, also can form light scattering rete at encapsulation cover plate outer surface, or also can at encapsulation cover plate inner surface and outer surface, form light scattering rete simultaneously.
Described encapsulation cover plate and described underlay substrate are fixed together, and the light that described light scattering rete can send described Organic Light Emitting Diode carries out scattering.
The formation method that the present embodiment provides can be produced the organic LED display panel with described light scattering rete, the light that described light scattering rete can send described Organic Light Emitting Diode carries out scattering, the organic LED display panel that therefore described formation method forms has been eliminated color offset phenomenon, and described formation method processing step is simple, and process costs is low.
Although the present invention discloses as above, the present invention is not defined in this.Any those skilled in the art, without departing from the spirit and scope of the present invention, all can make various changes or modifications, so protection scope of the present invention should be as the criterion with claim limited range.
Claims (10)
1. an organic LED display panel, is characterized in that, comprising:
The underlay substrate being oppositely arranged and encapsulation cover plate;
Organic Light Emitting Diode, between described underlay substrate and described encapsulation cover plate;
Light scattering rete, be positioned at the inner surface of described encapsulation cover plate or outer surface at least one of them, the light that described light scattering rete can send described Organic Light Emitting Diode carries out scattering.
2. organic LED display panel as claimed in claim 1, is characterized in that, described light scattering rete comprises a plurality of micro-structurals, and described micro-structural is orderly matrix and is arranged in described encapsulation cover plate inner surface.
3. organic LED display panel as claimed in claim 2, is characterized in that, the thickness range of described light scattering rete comprises 0.05 μ m~2 μ m; The width range of described micro-structural and length range include 0.1 μ m~1 μ m.
4. organic LED display panel as claimed in claim 2, is characterized in that, that described micro-structural is is coniform, pyramid-shaped, prism-frustum-shaped, convex tip shaped or round convex.
5. the organic LED display panel as described in claim 1 to 4 any one, is characterized in that, the ranges of indices of refraction of described light scattering rete is 1~2.
6. organic LED display panel as claimed in claim 5, is characterized in that, the ranges of indices of refraction of described light scattering rete is 1.7~2.
7. the organic LED display panel as described in claim 1 to 4 any one, is characterized in that, the material of described light scattering rete comprises epoxy resin or polyimides.
8. the organic LED display panel as described in claim 1 to 4 any one, is characterized in that, described Organic Light Emitting Diode comprises at least one of active matrix type organic light emitting diode and top emission type Organic Light Emitting Diode.
9. a formation method for organic LED display panel, is characterized in that, comprising:
Underlay substrate is provided, and described underlay substrate inner surface has Organic Light Emitting Diode;
Encapsulation cover plate is provided;
At least one of them formation light scattering rete at described encapsulation cover plate inner surface or outer surface;
Described encapsulation cover plate and described underlay substrate are fixed together, and the light that described light scattering rete can send described Organic Light Emitting Diode carries out scattering.
10. the formation method of organic LED display panel as claimed in claim 9, is characterized in that, described encapsulation cover plate inner surface or outer surface at least one of them forms described light scattering rete and comprises:
At least one of them formation light-scattering material layer at described encapsulation cover plate inner surface or outer surface;
Described light-scattering material layer is carried out at least one technique in polish-brush technique, dry etch process and wet-etching technology, until form a plurality of micro-structurals that orderly matrix is arranged that are.
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