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CN103928157A - Thermoplastic ceramic low smoke zero halogen polyolefin low pressure insulation refractory cable - Google Patents

Thermoplastic ceramic low smoke zero halogen polyolefin low pressure insulation refractory cable Download PDF

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Publication number
CN103928157A
CN103928157A CN201410149792.9A CN201410149792A CN103928157A CN 103928157 A CN103928157 A CN 103928157A CN 201410149792 A CN201410149792 A CN 201410149792A CN 103928157 A CN103928157 A CN 103928157A
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layer
conductor
low
thermoplasticity
ceramic
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CN201410149792.9A
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Chinese (zh)
Inventor
刘焱鑫
张照阳
孙建宇
张松松
崔孝叶
杨延军
黄伟
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Zhongli Technology Group Co Ltd
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Zhongli Technology Group Co Ltd
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Priority to CN201410149792.9A priority Critical patent/CN103928157A/en
Publication of CN103928157A publication Critical patent/CN103928157A/en
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Abstract

The invention provides a thermoplastic ceramic low smoke zero halogen polyolefin low pressure insulation refractory cable, and belongs to the technical field of electric wires and cables. The cable comprises a cable core and a sheath layer, wherein the cable core comprises at least two guide lines, a wrapping belt layer outside the guide lines and a stuffing layer which is stuffed outside the guide lines and is located inside the wrapping belt layer, the sheath layer is located outside the wrapping belt layer, and each guide line comprises a conductor and a conductor insulation layer. The thermoplastic ceramic low smoke zero halogen polyolefin low pressure insulation refractory cable is characterized in that each guide line further comprises a thermoplastic refractory layer, the thermoplastic refractory layer is combined outside the conductor, the conductor insulation layer is located outside the thermoplastic refractory layer, the thermoplastic refractory layer is a ceramic thermoplastic refractory material layer, the conductor insulation layer is a silane crosslinked polyethylene insulation layer, the wrapping belt layer is a refractory wrapping tape, the stuffing layer is a refractory stuffing layer, and the sheath layer is a low smoke zero halogen polyolefin sheath layer. The cable is concise in manufacturing technique, high in manufacturing efficiency and free of strict requirements to an extruder; the cable has the advantages that the overall refractory grade is guaranteed, production efficiency is high, and the requirement of industrialization amplification production can be met; poisonous and harmful gas cannot be released in the burning process; light transmittance is good.

Description

Thermoplasticity ceramic low-smoke halogen-free polyolefin low-voltage insulation fire-resisting cable
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Technical field
The invention belongs to technical field of electric wires and cables, be specifically related to a kind of thermoplasticity ceramic low-smoke halogen-free polyolefin low-voltage insulation fire-resisting cable.
Background technology
Above mentioned thermoplasticity ceramic low-smoke halogen-free polyolefin low-voltage insulation fire-resisting cable refers to the low-smoke halogen-free polyolefin low-voltage insulation fire-resisting cable at conductor with ceramic thermoplasticity refractory masses outward.
Low-voltage insulation fire-resisting cable in prior art mainly contains following several: the one, and ceramic silicon rubber low-voltage insulation fire-resisting cable, " a kind of high temperature resistant refractory ceramics silica rubber cable " and " a kind of ceramic silicon rubber insulation fireproof cable " that CN202749140U provides of the open as Granted publication CN202167252U recommendation of the typical document of this type of cable, etc.This cable is owing to needing silicon rubber vulcanization in manufacture process, thereby technique is relatively loaded down with trivial details, and extruder is had to fastidious property (common extruder cannot be suitable for), and the manufacture efficiency of cable is low; The 2nd, the low-voltage insulation fire-resisting cable of wrapped mica tape, open " a kind of mineral insulated cable " introduced as Chinese patent utility model Granted publication CN202736545U of typical document, this patent forms hot-face insulation composite bed by mica tape and glass fiber tape.This type of cable is owing to occurring that in manufacture process the probability of mica tape fracture, bottom pour ladle is higher, thereby fire resistant quality requires to be difficult to control, and easily produces the situation that mica layer comes off in wrapped process, makes cable expose discontinuity fire resistance rating defective, the 3rd, mineral insulation fire-resisting cable, the open core refractory power cable of protective metal shell of mineral insulation as mono-in CN200993894Y(of typical patent documentation of this type of cable), CN200986608Y(insulating protective metal shell of mineral four-in-one refractory optical cable), the fire-resistant branch cable of CN103165231A(mineral insulation), CN102651252A(flexible mineral insulated cable), the self-enclosed mineral insulated cable of CN203026217U(), the fire-resistant branch cable of CN103165235A(mineral insulating flexible), the fire-resistant branch cable of CN103165232A(mineral insulation), CN102800384A(is high temperature resistant mineral insulation flexible cable and manufacture method thereof) and CN103646721A(flexible mineral insulation aluminium core fireproof cable), etc..The shortcoming of mineral insulation fire-resisting cable is because working (machining) efficiency is low, to the having relatively high expectations of equipment, thereby causes the cost of cable high.
In addition, the low-voltage insulation fire-resisting cable of above-mentioned ceramic silicon rubber low-voltage insulation fire-resisting cable and wrapped mica tape is owing to can produce toxic and harmful when burning, easily cause secondary harm, thereby cannot meet the high stability of modern halogen-free cable and harsh environmental requirement, for example cannot meet ROHS and the REACH command request of European Union.
For above-mentioned prior art, very there is improved necessity, the applicant has done repeatedly and useful exploration and design have formed technical scheme described below finally for this reason.
Summary of the invention
Task of the present invention is to provide a kind of thermoplasticity ceramic low-smoke halogen-free polyolefin low-voltage insulation fire-resisting cable, it is loaded down with trivial details that this cable had both contributed to make up ceramic silicon rubber low-voltage insulation fire-resisting cable manufacturing process, extruder is had fastidious property and manufactures inefficient shortcoming and use simplified manufacturing technique and improve extrusion efficiency, be conducive to again overcome the whole poor deficiency of fire resistance rating of low-voltage insulation fire-resisting cable of wrapped mica tape and use the whole fire resistance rating requirement that meets cable, also be of value to and eliminate the drawback that mineral insulation fire-resisting cable working (machining) efficiency is low and cost is high and use and meet industrial amplification production requirement, and then have and be convenient to embody the desirable feature of environmental protection and light transmittance and use and meet ROHS and the REACH command request of promulgating such as European Union.
Task of the present invention completes like this, a kind of thermoplasticity ceramic low-smoke halogen-free polyolefin low-voltage insulation fire-resisting cable, comprise cable core and be positioned at the restrictive coating outside cable core, cable core comprises at least two wires, be positioned at the belting layer outside wire and be filled in packed layer outside wire and that be positioned at belting layer, described restrictive coating is positioned at outside belting layer, described wire comprises conductor and insulating layer of conductor, be characterised in that: described wire also includes thermoplasticity flame retardant coating, this thermoplasticity flame retardant coating is incorporated into outside described conductor, described insulating layer of conductor is positioned at outside thermoplasticity flame retardant coating, wherein: described thermoplasticity flame retardant coating is ceramic thermoplasticity refractory masses, described insulating layer of conductor is organosilane crosslinked polyethylene insulation layer, described belting layer is fire-resistant wrapping tape, described packed layer is fire-resistant packed layer, described restrictive coating is low-smoke halogen-free polyolefin restrictive coating.
In a specific embodiment of the present invention, the cross-sectional area of described conductor is 1.5-500 ㎜ 2.
In another specific embodiment of the present invention, described conductor is single bare copper conductor, single tinned copper conductor, exposed thin copper wire stranded conductor or tin plated wire copper wire twisting conductor
In another specific embodiment of the present invention, described exposed thin copper wire stranded conductor and the outermost layer of described tin plated wire copper stranded conductor are that left-hand is stranded, and direction of lay is between layers contrary.
In another specific embodiment of the present invention, the 10-25 that described stranded twisting pitch is stranded conductor diameter doubly.
Of the present invention, also have in a specific embodiment, the thickness of described insulating layer of conductor is 0.7-2.8 ㎜; The thickness of described restrictive coating 2 is 0.8-3.5 ㎜.
More of the present invention and in a specific embodiment, described fire-resistant wrapping tape is glass fibre belt, mica tape or Halogen band.
In of the present invention and then a specific embodiment, described fire-resistant packed layer is glass fiber rope.
Of the present invention again more and in a specific embodiment, the thickness of described ceramic thermoplasticity refractory masses is 0.3-0.8mm.
In again of the present invention and then a specific embodiment, described ceramic thermoplasticity refractory masses consists of the following raw material of proportioning by weight: 100 parts of ethene-alpha-olefin copolymers, filler A100-300 part, filler B5-30 part, lubricant 0.5-8 part and antioxidant 0.1-1 part; Described filler A is muscovite, sericite or phlogopite; Described filler B is boric anhydride, borax, ammonium borate or Firebrake ZB; Described lubricant is stearic acid, BS, octyl stearate, calcium stearate, zinc stearate, atoleine, solid paraffin, microcrystalline wax, Tissuemat E, viscous silicone fluid or silicone masterbatch; Described antioxidant is antioxidant 1010,1076,168,626,300 or DSTDP.
Technical scheme provided by the invention is because the conductor forming wire is combined with the thermoplasticity flame retardant coating of being filled the post of by ceramic thermoplasticity refractory masses outward, and insulating layer of conductor is adopted to organosilane crosslinked polyethylene insulation layer, belting layer is adopted to fire-resistant wrapping tape, packed layer is adopted to fire-resistant packed layer and restrictive coating is adopted to low-smoke halogen-free polyolefin restrictive coating, thus for the ceramic silicon rubber low-voltage insulation fire-resisting cable in prior art, have manufacturing process terse, manufacture efficiency high and to extruder the strong point without harsh requirement; For the low-voltage insulation fire-resisting cable of the wrapped mica tape in prior art, have advantages of that whole fire resistance rating is ensured; For the mineral insulation fire-resisting cable in prior art, there is production efficiency high and met the feature that industrial amplification production requires; During burning, toxic and harmful can be do not discharged, ROHS and REACH command request can be met; There is good light transmittance.
Accompanying drawing explanation
Fig. 1 is embodiments of the invention schematic diagram.
Embodiment
Embodiment 1:
Refer to Fig. 1, Fig. 1 has provided the shape of cross section of thermoplasticity ceramic low-smoke halogen-free polyolefin low-voltage insulation fire-resisting cable of the present invention, comprise cable core 1 and be positioned at the restrictive coating 2 outside cable core 1, in the present embodiment, cable core comprises five wires 11, is positioned at the belting layer 12 outside wire 11 and is filled in packed layer 13 outside five wires 11 and that be positioned at belting layer 12.As shown in Figure 1, restrictive coating 2 is positioned at outside belting layer 12, specifically adopts the habitual expressing technique of cable industry that restrictive coating 2 is squeezed and is overlying on outside cable core 1, more precisely squeezes and is overlying on outside belting layer 12.Five wires respectively comprise conductor 111 and are coated on the insulating layer of conductor 112 outside conductor 111.
Technical essential as technical scheme provided by the invention: aforesaid wire 11 also includes thermoplasticity flame retardant coating 113, this thermoplasticity flame retardant coating 113 is incorporated into outside conductor 111, and aforesaid insulating layer of conductor 112 is positioned at outside thermoplasticity flame retardant coating 113.And then, ceramic thermoplasticity refractory masses is served as to thermoplasticity flame retardant coating 113, organosilane crosslinked polyethylene insulation layer is served as to insulating layer of conductor 112, fire-resistant wrapping tape is served as to belting layer 12, fire-resistant packed layer is filled to packed layer 13, low-smoke halogen-free polyolefin restrictive coating is served as to restrictive coating 2.
Applicant it should be noted that: although show in the present embodiment the quantity of wire 11, be five, obviously should be subject to this and count quantitative limitation, can comply with and need increase and decrease, but at least need two.
Conductor in the present embodiment is single bare copper conductor, and its sectional area is 1.5 ㎜ 2; The thickness of aforesaid insulating layer of conductor 112 is 0.7 ㎜; The thickness of aforesaid restrictive coating 2 is 1.2 ㎜; Aforesaid fire-resistant wrapping tape layer 12 is glass fibre belt, i.e. glass fiber tape; Aforesaid fire-resistant packed layer is glass fiber rope, i.e. glass cord.
The thickness of the ceramic thermoplasticity refractory masses in the present embodiment is 0.8 ㎜, and this ceramic thermoplasticity refractory masses consists of the following raw material of proportioning by weight: 100 parts of ethene-alpha-olefin copolymers, filler A are that 300 parts of muscovites, filler B are that 20 parts of boraxs, lubricant are 0.5 part of 8 parts of BSs and antioxidant 1010.
Embodiment 2:
Figure slightly, only uses conductor 111 instead single tinned copper conductor, and sectional area changes 100 ㎜ into 2change the thickness of insulating layer of conductor 112 into 1.2 ㎜, change the thickness of restrictive coating 2 into 2 ㎜, use fire-resistant wrapping tape instead mica tape, change the thickness of ceramic thermoplasticity refractory masses into 0.6 ㎜, ceramic thermoplasticity refractory masses is changed into by the following raw material of proportioning by weight and being formed: 100 parts of ethene-alpha-olefin copolymers, filler A are that 100 parts of sericites, filler B are that 5 parts of ammonium borates, lubricant are 0.8 part of 0.5 part of octyl stearate and antioxidant 1076.All the other are all with the description to embodiment 1.
Embodiment 3:
Use conductor 111 instead exposed thin copper wire stranded conductor, cross-sectional area is 500 ㎜ 2, the outermost layer of this exposed thin copper wire stranded conductor is that left-hand is stranded, and direction of lay is between layers contrary, stranded joint square is 25 times of stranded conductor diameter, change the thickness of insulating layer of conductor 112 into 2.8 ㎜, change the thickness of restrictive coating 2 into 3.5 ㎜, use fire-resistant wrapping tape instead Halogen band, change the thickness of ceramic thermoplasticity refractory masses into 0.5 ㎜, ceramic thermoplasticity refractory masses is changed into by the following raw material of proportioning by weight and being formed: 100 parts of ethene-alpha-olefin copolymers, filler A is 200 parts of phlogopite, filler B is 30 parts of Firebrake ZBs, lubricant is 0.4 part of 0.6 part of Tissuemat E and antioxidant DSTDP.All the other are all with the description to embodiment 1.
Embodiment 4:
Use conductor 111 instead zinc-plated thin copper wire stranded conductor, cross-sectional area is 400 ㎜ 2, the outermost layer of zinc-plated thin copper wire stranded conductor is stranded to left-hand, and direction of lay is between layers contrary, twisting pitch is 10 times of stranded conductor diameter, change the thickness of insulating layer of conductor 112 into 2 ㎜, change the thickness of restrictive coating 2 into 0.8 ㎜, change the thickness of ceramic thermoplasticity refractory masses into 0.3 ㎜, and ceramic thermoplasticity refractory masses is changed into by the following raw material of proportioning by weight and being formed: 100 parts of ethene-alpha-olefin copolymers, filler A is 250 parts of phlogopite, filler B is 15 parts of boric anhydrides, lubricant is 0.1 part of 0.7 part of silicone masterbatch and antioxidant 300.All the other are all with the description to embodiment 1.

Claims (10)

1. a thermoplasticity ceramic low-smoke halogen-free polyolefin low-voltage insulation fire-resisting cable, comprise cable core (1) and be positioned at the outer restrictive coating (2) of cable core (1), cable core (1) comprises at least two wires (11), be positioned at the outer belting layer (12) of wire (11) and be filled in wire (11) packed layer (13) outer and that be positioned at belting layer (12), described restrictive coating (2) is positioned at outside belting layer (12), described wire (11) comprises conductor (111) and insulating layer of conductor (112), it is characterized in that: described wire (11) also includes thermoplasticity flame retardant coating (113), this thermoplasticity flame retardant coating (113) is incorporated into outside described conductor (111), described insulating layer of conductor (112) is positioned at outside thermoplasticity flame retardant coating (113), wherein: described thermoplasticity flame retardant coating (113) is ceramic thermoplasticity refractory masses, described insulating layer of conductor (112) is organosilane crosslinked polyethylene insulation layer, described belting layer (12) is fire-resistant wrapping tape, described packed layer (13) is fire-resistant packed layer, described restrictive coating (2) is low-smoke halogen-free polyolefin restrictive coating.
2. thermoplasticity ceramic low-smoke halogen-free polyolefin low-voltage insulation fire-resisting cable according to claim 1, the cross-sectional area that it is characterized in that described conductor (111) is 1.5-500 ㎜ 2.
3. thermoplasticity ceramic low-smoke halogen-free polyolefin low-voltage insulation fire-resisting cable according to claim 1 and 2, is characterized in that described conductor (111) is for single bare copper conductor, single tinned copper conductor, exposed thin copper wire stranded conductor or tin plated wire copper wire twisting conductor.
4. thermoplasticity ceramic low-smoke halogen-free polyolefin low-voltage insulation fire-resisting cable according to claim 3, it is characterized in that described exposed thin copper wire stranded conductor and the outermost layer of described tin plated wire copper stranded conductor are that left-hand is stranded, and direction of lay is between layers contrary.
5. thermoplasticity ceramic low-smoke halogen-free polyolefin low-voltage insulation fire-resisting cable according to claim 4, is characterized in that 10-25 that described stranded twisting pitch is stranded conductor diameter doubly.
6. thermoplasticity ceramic low-smoke halogen-free polyolefin low-voltage insulation fire-resisting cable according to claim 1, the thickness that it is characterized in that described insulating layer of conductor (112) is 0.7-2.8 ㎜; The thickness of described restrictive coating (2) is 0.8-3.5 ㎜.
7. thermoplasticity ceramic low-smoke halogen-free polyolefin low-voltage insulation fire-resisting cable according to claim 1, is characterized in that described fire-resistant wrapping tape is glass fibre belt, mica tape or Halogen band.
8. thermoplasticity ceramic low-smoke halogen-free polyolefin low-voltage insulation fire-resisting cable according to claim 1, is characterized in that described fire-resistant packed layer is glass fiber rope.
9. thermoplasticity ceramic low-smoke halogen-free polyolefin low-voltage insulation fire-resisting cable according to claim 1, the thickness that it is characterized in that described ceramic thermoplasticity refractory masses is 0.3-0.8mm.
10. according to the thermoplasticity ceramic low-smoke halogen-free polyolefin low-voltage insulation fire-resisting cable described in claim 1 or 9, it is characterized in that described ceramic thermoplasticity refractory masses consists of the following raw material of proportioning by weight: 100 parts of ethene-alpha-olefin copolymers, filler A100-300 part, filler B5-30 part, lubricant 0.5-8 part and antioxidant 0.1-1 part; Described filler A is muscovite, sericite or phlogopite; Described filler B is boric anhydride, borax, ammonium borate or Firebrake ZB; Described lubricant is stearic acid, BS, octyl stearate, calcium stearate, zinc stearate, atoleine, solid paraffin, microcrystalline wax, Tissuemat E, viscous silicone fluid or silicone masterbatch; Described antioxidant is antioxidant 1010,1076,168,626,300 or DSTDP.
CN201410149792.9A 2014-04-15 2014-04-15 Thermoplastic ceramic low smoke zero halogen polyolefin low pressure insulation refractory cable Pending CN103928157A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104240832A (en) * 2014-09-26 2014-12-24 中利科技集团股份有限公司 Novel flame-retardant fireproof cable
CN105448388A (en) * 2015-12-03 2016-03-30 成都格瑞思文化传播有限公司 Safe pressure-proof cable
CN106531302A (en) * 2016-12-29 2017-03-22 河南金水电缆集团有限公司 Firewall cable with rated voltage of 450/750V and below

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1447344A (en) * 2002-03-22 2003-10-08 尼克桑斯公司 Insulation compsn. of safety cable
CN1883014A (en) * 2003-09-12 2006-12-20 尼克桑斯公司 Electrically-insulating and heat-resistant composition
WO2010142917A1 (en) * 2009-06-11 2010-12-16 Nexans Electric cable adapted for ensuring the continuity of power distribution in the event of fire
CN202473329U (en) * 2012-01-19 2012-10-03 江苏昌盛电缆集团有限公司 Composite winding type fireproof cable
CN203150216U (en) * 2013-01-28 2013-08-21 安徽龙庵电缆集团有限公司 1500V low-smog halogen-free flame retardation multi-core fireproof photovoltaic cable
CN203773998U (en) * 2014-04-15 2014-08-13 中利科技集团股份有限公司 Thermoplastic ceramic low-smoke halogen-free polyolefin low-voltage insulating fireproof cable

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1447344A (en) * 2002-03-22 2003-10-08 尼克桑斯公司 Insulation compsn. of safety cable
CN1883014A (en) * 2003-09-12 2006-12-20 尼克桑斯公司 Electrically-insulating and heat-resistant composition
WO2010142917A1 (en) * 2009-06-11 2010-12-16 Nexans Electric cable adapted for ensuring the continuity of power distribution in the event of fire
CN202473329U (en) * 2012-01-19 2012-10-03 江苏昌盛电缆集团有限公司 Composite winding type fireproof cable
CN203150216U (en) * 2013-01-28 2013-08-21 安徽龙庵电缆集团有限公司 1500V low-smog halogen-free flame retardation multi-core fireproof photovoltaic cable
CN203773998U (en) * 2014-04-15 2014-08-13 中利科技集团股份有限公司 Thermoplastic ceramic low-smoke halogen-free polyolefin low-voltage insulating fireproof cable

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104240832A (en) * 2014-09-26 2014-12-24 中利科技集团股份有限公司 Novel flame-retardant fireproof cable
CN104240832B (en) * 2014-09-26 2016-07-13 中利科技集团股份有限公司 A kind of fire-retardant fireproof cable
CN105448388A (en) * 2015-12-03 2016-03-30 成都格瑞思文化传播有限公司 Safe pressure-proof cable
CN106531302A (en) * 2016-12-29 2017-03-22 河南金水电缆集团有限公司 Firewall cable with rated voltage of 450/750V and below

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Application publication date: 20140716