CN103923604A - Cerium based abrasive material - Google Patents
Cerium based abrasive material Download PDFInfo
- Publication number
- CN103923604A CN103923604A CN201310014161.1A CN201310014161A CN103923604A CN 103923604 A CN103923604 A CN 103923604A CN 201310014161 A CN201310014161 A CN 201310014161A CN 103923604 A CN103923604 A CN 103923604A
- Authority
- CN
- China
- Prior art keywords
- abrasive
- abrasive material
- agent
- abrasive substance
- content
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003082 abrasive agent Substances 0.000 title claims abstract description 13
- 229910052684 Cerium Inorganic materials 0.000 title claims abstract description 9
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 title claims abstract description 9
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 30
- 239000002612 dispersion medium Substances 0.000 claims abstract description 8
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910000420 cerium oxide Inorganic materials 0.000 claims abstract description 6
- 239000002609 medium Substances 0.000 claims abstract description 6
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910001404 rare earth metal oxide Inorganic materials 0.000 claims abstract description 6
- 239000000126 substance Substances 0.000 claims description 24
- 239000002245 particle Substances 0.000 claims description 20
- 239000006185 dispersion Substances 0.000 claims description 15
- 239000001913 cellulose Substances 0.000 claims description 6
- 229920002678 cellulose Polymers 0.000 claims description 6
- WSFSSNUMVMOOMR-UHFFFAOYSA-N formaldehyde Natural products O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 6
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims description 6
- 235000019982 sodium hexametaphosphate Nutrition 0.000 claims description 6
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- 239000001488 sodium phosphate Substances 0.000 claims description 4
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 4
- 229910000406 trisodium phosphate Inorganic materials 0.000 claims description 4
- 235000019801 trisodium phosphate Nutrition 0.000 claims description 4
- FUFJGUQYACFECW-UHFFFAOYSA-L calcium hydrogenphosphate Chemical compound [Ca+2].OP([O-])([O-])=O FUFJGUQYACFECW-UHFFFAOYSA-L 0.000 claims description 3
- 239000007859 condensation product Substances 0.000 claims description 3
- YWPOLRBWRRKLMW-UHFFFAOYSA-N sodium;naphthalene-2-sulfonic acid Chemical compound [Na+].C1=CC=CC2=CC(S(=O)(=O)O)=CC=C21 YWPOLRBWRRKLMW-UHFFFAOYSA-N 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 239000002270 dispersing agent Substances 0.000 abstract 2
- 230000002265 prevention Effects 0.000 abstract 2
- 239000013049 sediment Substances 0.000 abstract 2
- 239000011521 glass Substances 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000266 injurious effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Polishing Bodies And Polishing Tools (AREA)
Abstract
The invention discloses a cerium based abrasive material, which contains a curing prevention agent used for softening the sediment of abrasive material grains when the abrasive material is dispersed into a medium and a dispersing agent for making the abrasive material grains disperse in a dispersion medium. Specifically, the content of the curing prevention agent is 0.02%-2.0% (weight ratio), and the content of the dispersing agent is 0.02%-2.0% (weight ratio). In all rare earth oxides, cerium oxide accounts for 40.0%-99.5% (mass ratio), and lanthanum oxide accounts for 0.5%-60.0% (mass ratio). According to the invention, the abrasive material grains have good dispersibility, the grain sediment has reduced hardness, and the abrasive efficiency is stably improved.
Description
Technical field
The present invention relates to a kind of abrasive substance, relate in particular to a kind of cerium based abrasive material.
Background technology
At present, for the abrasive substance that the surface of glass material is processed, conventionally can form being scattered in dispersion medium (such as water) under the state of slurries and use.And in the time that this slurries leave standstill, be easy to separate with dispersion medium as the abrasive substance abrasive particle of dispersion, produce deposited phenomenon.The precipitation separation of this abrasive particle not only can not maintain composition or the concentration of the given concentration slurries during recycling, thereby reduction mill efficiency, also, in the time of the hardening of abrasive particle throw out, glass surface easily adheres to abrasive particle, therefore need to eliminate from glass surface the operation of abrasive particle.In addition, in the time of the hardening of abrasive particle throw out, can cause that pore stops up, and causes being polished the generation of injurious surface mark.
Summary of the invention
therefore, the object of the present invention is to provide and a kind ofly can make abrasive substance abrasive particle favorable dispersity and make the sedimentary lower hardness of abrasive particle, and can make the stable abrasive substance improving of mill efficiency.
in order to solve the problems of the technologies described above, the present invention adopts following technical scheme:
a kind of cerium based abrasive material, contains and solidifies preventing agent and dispersion agent; Wherein said curing preventing agent for making the throw out deliquescing of this abrasive substance abrasive particle in the time that described abrasive substance is distributed to medium, and described dispersion agent is used for making this abrasive substance abrasive particle to be dispersed in dispersion medium; The content that wherein solidifies preventing agent is 0.02% ~ 2.0%(weight ratio), the content of dispersion agent is 0.02% ~ 2.0%(weight ratio).
preferably, described curing preventing agent is selected from the one in crystalline cellulose, secondary calcium phosphate, sodiumβ-naphthalenesulfonate formaldehyde condensation products, synthetic silica.
preferably, described dispersion agent is selected from the one in Sodium hexametaphosphate 99 and trisodium phosphate.
preferably, all the cerium oxide proportion in rare earth oxide is 40.0% ~ 99.5%(mass ratio), lanthanum trioxide proportion is 0.5% ~ 60.0%(mass ratio).
owing to having adopted technical scheme as above, the present invention has following beneficial effect:
make abrasive substance abrasive particle favorable dispersity; Make the sedimentary lower hardness of abrasive particle; Make the stable raising of mill efficiency.
Embodiment
embodiment 1
a kind of cerium based abrasive material, contains and solidifies preventing agent and dispersion agent; Wherein solidifying preventing agent is crystalline cellulose, and for make the throw out deliquescing of this abrasive substance abrasive particle in the time that described abrasive substance is distributed to medium, dispersion agent is Sodium hexametaphosphate 99, for making this abrasive substance abrasive particle be dispersed in dispersion medium; Wherein the content of crystalline cellulose is 0.02 %(weight ratio), the content of Sodium hexametaphosphate 99 is 0.02 %(weight ratio).Wherein the cerium oxide proportion in whole rare earth oxides is 40 %(mass ratioes), lanthanum trioxide proportion is 0.5 %(mass ratio).
embodiment 2
a kind of cerium based abrasive material, contains and solidifies preventing agent and dispersion agent; Wherein solidifying preventing agent is secondary calcium phosphate, and for make the throw out deliquescing of this abrasive substance abrasive particle in the time that described abrasive substance is distributed to medium, dispersion agent is trisodium phosphate, for making this abrasive substance abrasive particle be dispersed in dispersion medium; Wherein the content of crystalline cellulose is 1.0%(weight ratio), the content of Sodium hexametaphosphate 99 is 1.0%(weight ratio).Wherein the cerium oxide proportion in whole rare earth oxides is 75.0%(mass ratio), lanthanum trioxide proportion is 30%(mass ratio).
embodiment 3
a kind of cerium based abrasive material, contains and solidifies preventing agent and dispersion agent; Wherein solidifying preventing agent is sodiumβ-naphthalenesulfonate formaldehyde condensation products, and for make the throw out deliquescing of this abrasive substance abrasive particle in the time that described abrasive substance is distributed to medium, dispersion agent is trisodium phosphate, for making this abrasive substance abrasive particle be dispersed in dispersion medium; Wherein the content of crystalline cellulose is 2.0%(weight ratio), the content of Sodium hexametaphosphate 99 is 2.0%(weight ratio).Wherein the cerium oxide proportion in whole rare earth oxides is 99.5 % (mass ratioes), and lanthanum trioxide proportion is 60.0 %(mass ratioes).
obviously, the above embodiment of the present invention is only for example of the present invention is clearly described, and is not the restriction to embodiments of the present invention.For those of ordinary skill in the field, can also make on the basis of the above description other multi-form variation and variations.Here cannot give exhaustive to all embodiments.Everyly belong to apparent variation or the still row in protection scope of the present invention of variation that technical scheme of the present invention amplifies out.
Claims (4)
1. a cerium based abrasive material, is characterized in that, contains and solidifies preventing agent and dispersion agent; Wherein said curing preventing agent for making the throw out deliquescing of this abrasive substance abrasive particle in the time that described abrasive substance is distributed to medium, and described dispersion agent is used for making this abrasive substance abrasive particle to be dispersed in dispersion medium; The content that wherein solidifies preventing agent is 0.02% ~ 2.0%(weight ratio), the content of dispersion agent is 0.02% ~ 2.0%(weight ratio).
2.
abrasive substance according to claim 1, is characterized in that: described curing preventing agent is selected from the one in crystalline cellulose, secondary calcium phosphate, sodiumβ-naphthalenesulfonate formaldehyde condensation products, synthetic silica.
3.
abrasive substance according to claim 1, is characterized in that: described dispersion agent is selected from the one in Sodium hexametaphosphate 99 and trisodium phosphate.
4.
abrasive substance according to claim 1, is characterized in that: all the cerium oxide proportion in rare earth oxide is 40.0% ~ 99.5%(mass ratio), lanthanum trioxide proportion is 0.5% ~ 60.0%(mass ratio).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310014161.1A CN103923604A (en) | 2013-01-15 | 2013-01-15 | Cerium based abrasive material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310014161.1A CN103923604A (en) | 2013-01-15 | 2013-01-15 | Cerium based abrasive material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103923604A true CN103923604A (en) | 2014-07-16 |
Family
ID=51142008
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310014161.1A Pending CN103923604A (en) | 2013-01-15 | 2013-01-15 | Cerium based abrasive material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103923604A (en) |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10176164A (en) * | 1996-10-17 | 1998-06-30 | Showa Denko Kk | Abrasive composition for polishing glass and its production |
| CN1186099A (en) * | 1996-12-25 | 1998-07-01 | 清美化学股份有限公司 | Manufacture of cerium group polishing materials |
| US20030051412A1 (en) * | 2000-12-13 | 2003-03-20 | Hidehiko Yamasaki | Cerium based abrasive material and method for evaluating cerium based abrasive material |
| CN1464901A (en) * | 2000-09-20 | 2003-12-31 | 三井金属鉱业株式会社 | Cerium based abrasive material, method of quality examination therefor and method for production thereof |
| CN1543493A (en) * | 2002-03-22 | 2004-11-03 | ���������kҵ��ʽ���� | Cerium-based abrasive material and method for preparation thereof |
| CN1697869A (en) * | 2000-10-06 | 2005-11-16 | 三井金属鉱业株式会社 | Abrasive material |
| CN1701108A (en) * | 2003-04-17 | 2005-11-23 | 三井金属鉱业株式会社 | Cerium-based polishing material |
| WO2012042960A1 (en) * | 2010-09-27 | 2012-04-05 | 三井金属鉱業株式会社 | Cerium-based abrasive |
-
2013
- 2013-01-15 CN CN201310014161.1A patent/CN103923604A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10176164A (en) * | 1996-10-17 | 1998-06-30 | Showa Denko Kk | Abrasive composition for polishing glass and its production |
| CN1186099A (en) * | 1996-12-25 | 1998-07-01 | 清美化学股份有限公司 | Manufacture of cerium group polishing materials |
| CN1464901A (en) * | 2000-09-20 | 2003-12-31 | 三井金属鉱业株式会社 | Cerium based abrasive material, method of quality examination therefor and method for production thereof |
| CN1697869A (en) * | 2000-10-06 | 2005-11-16 | 三井金属鉱业株式会社 | Abrasive material |
| US20030051412A1 (en) * | 2000-12-13 | 2003-03-20 | Hidehiko Yamasaki | Cerium based abrasive material and method for evaluating cerium based abrasive material |
| CN1543493A (en) * | 2002-03-22 | 2004-11-03 | ���������kҵ��ʽ���� | Cerium-based abrasive material and method for preparation thereof |
| CN1701108A (en) * | 2003-04-17 | 2005-11-23 | 三井金属鉱业株式会社 | Cerium-based polishing material |
| WO2012042960A1 (en) * | 2010-09-27 | 2012-04-05 | 三井金属鉱業株式会社 | Cerium-based abrasive |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
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| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20140716 |