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CN103887350A - Matrix back electrodes for crystalline silicon solar cell - Google Patents

Matrix back electrodes for crystalline silicon solar cell Download PDF

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CN103887350A
CN103887350A CN201410138162.1A CN201410138162A CN103887350A CN 103887350 A CN103887350 A CN 103887350A CN 201410138162 A CN201410138162 A CN 201410138162A CN 103887350 A CN103887350 A CN 103887350A
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back electrode
frame line
row
silicon solar
electrode
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CN103887350B (en
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白海赞
胡中
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Jiangsu Environmental Natural Chemicals (enc) New Material Co Ltd
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    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10FINORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
    • H10F77/00Constructional details of devices covered by this subclass
    • H10F77/20Electrodes
    • H10F77/206Electrodes for devices having potential barriers
    • H10F77/211Electrodes for devices having potential barriers for photovoltaic cells
    • H10F77/219Arrangements for electrodes of back-contact photovoltaic cells
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10FINORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
    • H10F77/00Constructional details of devices covered by this subclass
    • H10F77/20Electrodes
    • H10F77/206Electrodes for devices having potential barriers
    • H10F77/211Electrodes for devices having potential barriers for photovoltaic cells
    • H10F77/215Geometries of grid contacts
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10FINORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
    • H10F10/00Individual photovoltaic cells, e.g. solar cells
    • H10F10/10Individual photovoltaic cells, e.g. solar cells having potential barriers
    • H10F10/14Photovoltaic cells having only PN homojunction potential barriers
    • H10F10/146Back-junction photovoltaic cells, e.g. having interdigitated base-emitter regions on the back side
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy

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Abstract

本发明公开了一种晶体硅太阳能电池矩阵式背电极,所述晶体硅太阳能电池是多晶156电池片,所述背电极具有十五段,且十五段背电极呈五行三列矩阵状排布,一列背电极位于电池片背面中间,其余两列背电极各自距离中间一列背电极52毫米,每段背电极皆是竖条状,且每段背电极的边缘皆连接有若干框线,所述框线呈间隔状均匀布满背电极周边,所述背电极的边缘和所述框线与背电场接触,该晶体硅太阳能电池矩阵式背电极减少了背银的消耗,与背铝接触更好、加大了背场的印刷面积,更好的提高了电流与电压,与此同时也更好的控制了背电极与背电场叠加的问题。

The invention discloses a matrix-type back electrode of a crystalline silicon solar cell. The crystalline silicon solar cell is a polycrystalline 156 battery sheet. The back electrode has fifteen sections, and the back electrodes of the fifteen sections are arranged in a matrix of five rows and three columns. One row of back electrodes is located in the middle of the back of the cell, and the other two rows of back electrodes are each 52 mm away from the middle row of back electrodes. Each section of the back electrode is in the shape of a vertical strip, and the edge of each section of the back electrode is connected with a number of frame lines. The frame lines are evenly distributed around the back electrode at intervals, and the edge of the back electrode and the frame line are in contact with the back electric field. The matrix-type back electrode of the crystalline silicon solar cell reduces the consumption of back silver, and is more in contact with the back aluminum. Well, the printing area of the back field is increased, the current and voltage are better improved, and at the same time, the problem of the superposition of the back electrode and the back electric field is better controlled.

Description

晶体硅太阳能电池矩阵式背电极Crystalline silicon solar cell matrix back electrode

技术领域technical field

本发明属于太阳能电池结构领域,具体涉及一种多晶156电池片的背电极结构。The invention belongs to the field of solar cell structures, and in particular relates to a back electrode structure of polycrystalline 156 cells.

背景技术Background technique

太阳能电池是一种将光能直接转化为电能的器件,由于其清洁、无污染、取之不尽,用之不竭,受到越来越多的关注。A solar cell is a device that directly converts light energy into electrical energy. Due to its cleanliness, pollution-free, inexhaustible and inexhaustible, it has attracted more and more attention.

目前广泛采用的是硅太阳能电池,其制造工艺也已经标准化,主要步骤为:化学清洗及表面结构化处理(制绒)-扩散制结-周边刻蚀-沉积减反射膜-丝网印刷-烧结。其中,丝网印刷首先进行背面电极的印刷,浆料为Ag浆,烘干后印刷背面电场,浆料为Al浆,烘干后经过翻转器翻转印刷正面电极,浆料为Ag浆。对于多晶156电池片,背电极一般为三根,边缘两根背电极距电池片边缘的距离均为26mm,中间一根位于电池片中间,亦即距边缘两根的距离均为52mm。背电极的主要作用是为组件部分提供焊接点,有利于光生电流的输出。At present, silicon solar cells are widely used, and its manufacturing process has also been standardized. The main steps are: chemical cleaning and surface structuring (texturing)-diffusion junction-peripheral etching-deposition of anti-reflection film-screen printing-sintering . Among them, the screen printing first prints the back electrode, the paste is Ag paste, the back electric field is printed after drying, the paste is Al paste, and the front electrode is printed after being turned over by a flipper after drying, and the paste is Ag paste. For polycrystalline 156 cells, there are generally three back electrodes, the distance between the two edge electrodes and the edge of the cell is 26mm, and the middle one is located in the middle of the cell, that is, the distance from the two edges is 52mm. The main function of the back electrode is to provide a welding point for the component part, which is beneficial to the output of the photo-generated current.

然而,采用这一方式,背电极Ag浆的单耗太大,目前湿重的控制范围是0.07-0.08g,且由于背电极的区域过大,导致背场的印刷面积较小,不利于电池片的开路电压及短路电流,再者,背电极与背面场的接触及叠加状况不够良好。However, with this method, the unit consumption of the Ag paste for the back electrode is too large, and the current wet weight control range is 0.07-0.08g, and because the area of the back electrode is too large, the printing area of the back field is small, which is not conducive to the battery. The open circuit voltage and short circuit current of the chip, moreover, the contact and superposition of the back electrode and the back field are not good enough.

发明内容Contents of the invention

为了解决上述问题,本发明提供了一种晶体硅太阳能电池矩阵式背电极,该晶体硅太阳能电池矩阵式背电极减少了背银的消耗;与背铝接触更好、加大了背场的印刷面积,更好的提高了电流与电压;与此同时也更好的控制了背电极与背电场叠加的问题。In order to solve the above problems, the present invention provides a matrix-type back electrode of a crystalline silicon solar cell, which reduces the consumption of back silver; has better contact with the back aluminum and increases the printing of the back field The area is better to increase the current and voltage; at the same time, it also better controls the problem of the superposition of the back electrode and the back electric field.

本发明为了解决其技术问题所采用的技术方案是:The technical scheme that the present invention adopts in order to solve its technical problem is:

一种晶体硅太阳能电池矩阵式背电极,所述晶体硅太阳能电池是多晶156电池片,所述背电极具有十五段,且十五段背电极呈五行三列矩阵状排布,一列背电极位于电池片背面中间,其余两列背电极各自距离中间一列背电极52毫米(指每列背电极中心线之间的距离),每段背电极皆是竖条状,且每段背电极的边缘皆连接有若干框线,所述框线呈间隔状均匀布满背电极周边,所述背电极的边缘和所述框线与背电场接触。A matrix-type back electrode of a crystalline silicon solar cell. The crystalline silicon solar cell is a polycrystalline 156 battery sheet. The back electrode has fifteen segments, and the fifteen segments are arranged in a matrix of five rows and three columns. The electrode is located in the middle of the back of the cell, and the other two rows of back electrodes are 52 mm away from the middle row of back electrodes (referring to the distance between the center lines of each row of back electrodes). A number of frame lines are connected to the edges, and the frame lines evenly cover the periphery of the back electrode at intervals, and the edges of the back electrode and the frame lines are in contact with the back electric field.

本发明为了解决其技术问题所采用的进一步技术方案是:The further technical scheme that the present invention adopts in order to solve its technical problem is:

进一步地说,每段所述背电极是长为18毫米且宽为2.3毫米的矩形竖条状,且同列背电极之间的间距为12毫米,每列背电极中位于首尾两端的背电极与电池片边缘的间距各自为6毫米。Further, each section of the back electrode is a rectangular vertical strip with a length of 18 mm and a width of 2.3 mm, and the distance between the back electrodes of the same row is 12 mm, and the back electrodes at the first and last ends of each row of back electrodes are connected to the The spacing between the edges of the cells is 6 mm each.

进一步地说,每段所述背电极的左右两侧各自均匀分布有一列所述框线,每列框线皆是由十八个相互间隔为0.5毫米的框线组成,且位于首尾端的框线各自距离背电极的首尾端0.25毫米;每段所述背电极的首尾端各自均匀分布有一行所述框线,每行框线皆是由三个相互间隔为0.4毫米的框线组成,且位于左右端的框线各自与背电极的左右端对齐;所述框线是长为1毫米且宽为0.5毫米的矩形框线。Furthermore, a column of frame lines is evenly distributed on the left and right sides of each section of the back electrode, and each column of frame lines is composed of eighteen frame lines with a mutual interval of 0.5 mm, and the frame lines located at the head and tail ends Each is 0.25 mm away from the head and tail ends of the back electrode; a row of frame lines is evenly distributed at the head and tail ends of each section of the back electrode, and each line of frame lines is composed of three frame lines with a mutual interval of 0.4 mm. The frame lines at the left and right ends are respectively aligned with the left and right ends of the back electrode; the frame lines are rectangular frame lines with a length of 1 mm and a width of 0.5 mm.

本发明的有益效果是:本发明的晶体硅太阳能电池矩阵式背电极主要是将背电极分为十五段,且十五段背电极呈五行三列矩阵状排布,且每段背电极的边缘皆连接有若干框线,背电极的边缘和框线与背电场接触,因此具有如下优点:The beneficial effects of the present invention are: the matrix type back electrode of the crystalline silicon solar cell of the present invention mainly divides the back electrode into fifteen sections, and the back electrodes of the fifteen sections are arranged in a matrix of five rows and three columns, and each section of the back electrode There are several frame lines connected to the edges, and the edges and frame lines of the back electrode are in contact with the back electric field, so it has the following advantages:

1)单耗低:在相同的印刷参数设置下,本发明网版印刷的单耗范围是0.03-0.04g,而现有直线电极的单耗范围是0.06-0.08g,单耗下降约40%;1) Low unit consumption: Under the same printing parameter settings, the unit consumption range of the screen printing of the present invention is 0.03-0.04g, while the unit consumption range of the existing linear electrode is 0.06-0.08g, and the unit consumption is reduced by about 40% ;

2)电池片的开压及电流有所提升:由于矩阵式电极的使用,背电极的印刷面积减少,从而使背电场的钝化面积增大,电池片的开压及电流有所提升;2) The opening voltage and current of the battery are improved: due to the use of matrix electrodes, the printing area of the back electrode is reduced, thereby increasing the passivation area of the back electric field, and the opening voltage and current of the battery are improved;

3)背电极与背电场的接触更好:由于在每段背电极的四周围有一圈密集分布的框线,从而使背电极与背电场的接触更好。3) Better contact between the back electrode and the back electric field: Since there is a circle of densely distributed frame lines around each segment of the back electrode, the contact between the back electrode and the back electric field is better.

附图说明Description of drawings

图1为本发明的结构示意图;Fig. 1 is a structural representation of the present invention;

图2为本发明的每段背电极及其周边框线结构示意图。FIG. 2 is a schematic diagram of the structure of each segment of the back electrode and its surrounding frame lines in the present invention.

具体实施方式Detailed ways

以下通过特定的具体实例说明本发明的具体实施方式,本领域技术人员可由本说明书所揭示的内容轻易地了解本发明的优点及功效。本发明也可以其它不同的方式予以实施,即,在不悖离本发明所揭示的范畴下,能予不同的修饰与改变。The specific implementation of the present invention is described below through specific examples, and those skilled in the art can easily understand the advantages and effects of the present invention from the content disclosed in this specification. The present invention can also be implemented in other different ways, that is, various modifications and changes can be made without departing from the disclosed scope of the present invention.

实施例:一种晶体硅太阳能电池矩阵式背电极,所述晶体硅太阳能电池是多晶156电池片,所述背电极1具有十五段,且十五段背电极呈五行三列矩阵状排布,一列背电极位于电池片背面中间,其余两列背电极各自距离中间一列背电极52毫米(指每列背电极中心线之间的距离),每段背电极皆是竖条状,且每段背电极的边缘皆连接有若干框线2,所述框线呈间隔状均匀布满背电极周边,所述背电极的边缘和所述框线与背电场接触。Embodiment: A matrix-type back electrode of a crystalline silicon solar cell, the crystalline silicon solar cell is a polycrystalline 156 solar cell, the back electrode 1 has fifteen segments, and the fifteen segment back electrodes are arranged in a matrix of five rows and three columns One row of back electrodes is located in the middle of the back of the cell, and the other two rows of back electrodes are each 52 mm away from the middle row of back electrodes (referring to the distance between the center lines of each row of back electrodes). A plurality of frame lines 2 are connected to the edges of the segment back electrodes, and the frame lines are evenly distributed around the back electrode at intervals, and the edges of the back electrodes and the frame lines are in contact with the back electric field.

每段所述背电极是长为18毫米且宽为2.3毫米的矩形竖条状,且同列背电极之间的间距为12毫米,每列背电极中位于首尾两端的背电极与电池片边缘的间距各自为6毫米。The back electrodes in each segment are rectangular vertical strips with a length of 18 mm and a width of 2.3 mm, and the distance between the back electrodes of the same row is 12 mm, and the back electrodes at the first and last ends of each row of back electrodes are connected to the edge of the cell The pitches are each 6 mm.

每段所述背电极的左右两侧各自均匀分布有一列所述框线,每列框线皆是由十八个相互间隔为0.5毫米的框线组成,且位于首尾端的框线各自距离背电极的首尾端0.25毫米;每段所述背电极的首尾端各自均匀分布有一行所述框线,每行框线皆是由三个相互间隔为0.4毫米的框线组成,且位于左右端的框线各自与背电极的左右端对齐;所述框线是长为1毫米且宽为0.5毫米的矩形框线。A column of frame lines is evenly distributed on the left and right sides of each section of the back electrode, and each column of frame lines is composed of eighteen frame lines with a mutual interval of 0.5 mm, and the frame lines at the head and tail ends are respectively separated from the back electrode The first and last ends of each section of the back electrode are 0.25 mm; each row of the frame lines is evenly distributed at the head and tail ends of each section of the back electrode, and each line of frame lines is composed of three frame lines with an interval of 0.4 mm, and the frame lines at the left and right ends Each is aligned with the left and right ends of the back electrode; the frame lines are rectangular frame lines with a length of 1 mm and a width of 0.5 mm.

实验选取同一硅锭的硅片200件,分别用矩阵式背电极网版及现有直线背电极网版印刷100件,比较单耗及电性能数据。In the experiment, 200 pieces of silicon wafers from the same silicon ingot were selected, and 100 pieces were printed with the matrix back electrode screen and the existing linear back electrode screen respectively, and the unit consumption and electrical performance data were compared.

实验例:本发明的矩阵式背电极Experimental example: matrix back electrode of the present invention

将网版装入印刷机,装上刮刀、回墨刀,并加浆料,调节好印刷参数,保证印刷的背电极图形良好,称测湿重,结果如下:Put the screen plate into the printing machine, install the scraper, ink return knife, and add slurry, adjust the printing parameters to ensure that the printed back electrode pattern is good, measure the wet weight, and the results are as follows:

抽样sampling 11 22 33 44 55 平均值average value 湿重(g)wet weight (g) 0.0330.033 0.0350.035 0.0370.037 0.0360.036 0.0340.034 0.0350.035

在AM1.5、光强1000W,25℃条件下测量其电性能参数的情况为:The situation of measuring its electrical performance parameters under the conditions of AM1.5, light intensity 1000W, and 25°C is:

Voc(开路电压)Voc (open circuit voltage) Isc(短路电流)Isc (short circuit current) FF(填充因子)FF (fill factor) Eff(光电转换效率)Eff (photoelectric conversion efficiency) 0.6260.626 8.568.56 78.478.4 17.26%17.26%

比较例:印刷参数不变,更换现有直线电极网版印刷制成现有直线式电极,称测湿重,结果如下:Comparative example: The printing parameters remain unchanged, and the existing linear electrode is replaced by screen printing to make the existing linear electrode, and the wet weight is measured. The results are as follows:

抽样sampling 11 22 33 44 55 平均值average value 湿重(g)wet weight (g) 0.0620.062 0.0620.062 0.0610.061 0.0630.063 0.0630.063 0.0620.062

在AM1.5、光强1000W,25℃条件下测量其电性能参数的情况为:The situation of measuring its electrical performance parameters under the conditions of AM1.5, light intensity 1000W, and 25°C is:

Voc(开路电压)Voc (open circuit voltage) Isc(短路电流)Isc (short circuit current) FF(填充因子)FF (fill factor) Eff(光电转换效率)Eff (photoelectric conversion efficiency) 0.6250.625 8.558.55 78.578.5 17.24%17.24%

从上述实验可以看出,本发明单耗约降低40%,电性能参数上开路电压Uoc及短路电流Isc均有小幅提升,效率上略高0.02%。可见,此发明不仅大幅降低了电池片生产过程的成本,也在一定程度上提升了太阳能电池片的转换效率。It can be seen from the above experiments that the unit consumption of the present invention is reduced by about 40%, the open-circuit voltage Uoc and the short-circuit current Isc are slightly improved in terms of electrical performance parameters, and the efficiency is slightly higher by 0.02%. It can be seen that this invention not only greatly reduces the cost of the production process of solar cells, but also improves the conversion efficiency of solar cells to a certain extent.

Claims (3)

1. a crystal silicon solar energy battery matrix form back electrode, described crystal silicon solar energy battery is polycrystalline 156 cell pieces, it is characterized in that: described back electrode (1) has 15 sections, and 15 sections of back electrodes are the five-element's three column matrix shapes and arrange, one row back electrode is positioned in the middle of the cell piece back side, all the other two row back electrodes are separately apart from 52 millimeters of middle row back electrodes, every section of back electrode is all vertical bar shape, and the edge of every section of back electrode is all connected with some frame lines (2), the interruption-like back electrode periphery that is evenly covered with of described frame line, the edge of described back electrode contacts with back of the body electric field with described frame line.
2. crystal silicon solar energy battery matrix form back electrode as claimed in claim 1, it is characterized in that: every section of described back electrode be length be 18 millimeters and wide be the rectangle vertical bar shape of 2.3 millimeters, and the spacing between same column back electrode is 12 millimeters, in every row back electrode, is positioned at the head and the tail back electrode at two ends and the spacing at cell piece edge and does for oneself 6 millimeters.
3. crystal silicon solar energy battery matrix form back electrode as claimed in claim 2, it is characterized in that: the left and right sides of every section of described back electrode is evenly distributed with the described frame line of row separately, the frame line that every row frame line is all 0.5 millimeter by 18 spaces forms, and the frame line that is positioned at two ends is separately apart from 0.25 millimeter of the two ends of back electrode; The two ends of every section of described back electrode are evenly distributed with frame line described in a line separately, and the frame line that every row frame line is all 0.4 millimeter by three spaces forms, and the frame line that is positioned at left and right end separately with the left right-hand justified of back electrode; Described frame line be length be 1 millimeter and wide be the rectangle frame line of 0.5 millimeter.
CN201410138162.1A 2014-04-08 2014-04-08 Crystal silicon solar energy battery matrix form back electrode Expired - Fee Related CN103887350B (en)

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