CN103882439B - A kind of water-soluble metal degreasing derusting rust-proofing liquid and preparation method thereof - Google Patents
A kind of water-soluble metal degreasing derusting rust-proofing liquid and preparation method thereof Download PDFInfo
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- CN103882439B CN103882439B CN201410063881.1A CN201410063881A CN103882439B CN 103882439 B CN103882439 B CN 103882439B CN 201410063881 A CN201410063881 A CN 201410063881A CN 103882439 B CN103882439 B CN 103882439B
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- water
- rust
- soluble metal
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- 239000007788 liquid Substances 0.000 title claims abstract description 17
- 238000005238 degreasing Methods 0.000 title claims abstract description 11
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 11
- 239000002184 metal Substances 0.000 title claims abstract description 11
- 238000002360 preparation method Methods 0.000 title claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 8
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229920013701 VORANOL™ Polymers 0.000 claims abstract description 7
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 claims abstract description 7
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 7
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 claims abstract description 7
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims abstract description 4
- KFFQABQEJATQAT-UHFFFAOYSA-N N,N'-dibutylthiourea Chemical compound CCCCNC(=S)NCCCC KFFQABQEJATQAT-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229940015043 glyoxal Drugs 0.000 claims abstract description 4
- JACMPVXHEARCBO-UHFFFAOYSA-N n-pentylpentan-1-amine Chemical compound CCCCCNCCCCC JACMPVXHEARCBO-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229940095064 tartrate Drugs 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 12
- 239000004160 Ammonium persulphate Substances 0.000 claims description 6
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 6
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 6
- 235000019395 ammonium persulphate Nutrition 0.000 claims description 6
- 239000012467 final product Substances 0.000 claims description 6
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 claims description 6
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 6
- DAJSVUQLFFJUSX-UHFFFAOYSA-M sodium;dodecane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCS([O-])(=O)=O DAJSVUQLFFJUSX-UHFFFAOYSA-M 0.000 claims description 4
- 101710194948 Protein phosphatase PhpP Proteins 0.000 claims description 3
- 235000006040 Prunus persica var persica Nutrition 0.000 claims description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 3
- 229910021538 borax Inorganic materials 0.000 claims description 3
- 239000004202 carbamide Substances 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 3
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 claims description 3
- 239000000244 polyoxyethylene sorbitan monooleate Substances 0.000 claims description 3
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 3
- 229920000053 polysorbate 80 Polymers 0.000 claims description 3
- 235000019353 potassium silicate Nutrition 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 3
- 239000004328 sodium tetraborate Substances 0.000 claims description 3
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 3
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 3
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 claims description 3
- 240000006413 Prunus persica var. persica Species 0.000 claims 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract description 17
- 238000004140 cleaning Methods 0.000 abstract description 5
- 230000002349 favourable effect Effects 0.000 abstract description 2
- 238000002161 passivation Methods 0.000 abstract description 2
- 229920000642 polymer Polymers 0.000 abstract description 2
- 230000003405 preventing effect Effects 0.000 abstract description 2
- 239000003352 sequestering agent Substances 0.000 abstract description 2
- 239000003921 oil Substances 0.000 description 5
- 230000002265 prevention Effects 0.000 description 4
- 230000003449 preventive effect Effects 0.000 description 3
- 244000144730 Amygdalus persica Species 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 235000010288 sodium nitrite Nutrition 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Landscapes
- Preventing Corrosion Or Incrustation Of Metals (AREA)
Abstract
A kind of water-soluble metal degreasing derusting rust-proofing liquid, is made up of the raw material of following weight part: Voranol EP 2001 3-4, sodium laurylsulfonate 1-2,1.3-dibutyl thiourea 2-3, tartrate 1-2, glyoxal ethyline quinoline 0.5-1.1, diamylamine 1-2, epoxy acrylate 30-35,1-Methoxy-2-propyl acetate 5-10, EDETATE SODIUM 1-2, auxiliary agent 4-5, water 300.Rust protection liquid of the present invention can carry out disposable oil removing, rust cleaning, phosphatization, passivation and antirust to metallic surface, by using high molecular polymer and sequestrant, can at metallic surface fast filming, isolated air, favorable rust preventing effect, cleaning is easily, be applicable to pipelining, do not affect next step operation to carry out, and harmless, environmentally safe.
Description
Technical field
The present invention relates to technical field of rust prevention, particularly relate to a kind of water-soluble metal degreasing derusting rust-proofing liquid and preparation method thereof.
Background technology
Metallic surface is antirust is important topic in industrial production, and traditional rust protection liquid, slushing oil have advantage also to have shortcoming.Containing a large amount of Sodium Nitrite in common aqueous rust preventive, have carinogenicity, be unfavorable for environmental protection and the person healthy, and adopt wetting Agent for Printing Inks to extend the life-span of aqueous rust preventive, bring again the disadvantage of touching with one's hand, being covered with dust, and can not long-term rust prevention; Although general hard film rust preventive oil is applicable to long-term rust prevention, film forming is also transparent attractive in appearance, and water white resin types is less, and instability is easy oxidation discoloration also, also needs organic solvent dissolution, brings inflammable and explosive danger to be also unfavorable for environmental protection and health; General slushing oil uses mineral oil, difficult degradation, and for the problem of oil removing difficulty also can be brought during short-term rust prevention.Therefore, comprehensive study performance is more excellent, and the antirust product be more applicable to for different occasion research is new direction and trend.
Summary of the invention
The object of the present invention is to provide a kind of water-soluble metal degreasing derusting rust-proofing liquid and preparation method thereof, this rust protection liquid has the feature of rust cleaning, antirust, easy-clear.
Technical scheme of the present invention is as follows:
A kind of water-soluble metal degreasing derusting rust-proofing liquid, is characterized in that being made up of the raw material of following weight part: Voranol EP 2001 3-4, sodium laurylsulfonate 1-2,1.3-dibutyl thiourea 2-3, tartrate 1-2, glyoxal ethyline quinoline 0.5-1.1, diamylamine 1-2, epoxy acrylate 30-35,1-Methoxy-2-propyl acetate 5-10, EDETATE SODIUM 1-2, auxiliary agent 4-5, water 300.Described auxiliary agent is made up of the raw material of following weight part: polyoxyethylene sorbitan monooleate 2-3, nano titanium oxide 0.1-0.2, tripoly phosphate sodium STPP 1-2, water glass 1-2, urotropine 1-2, Resorcinol 1-2, borax 3-4, urea 2-3, ammonium persulphate 1-2, peach gum 2-3, water 20-24; Preparation method be ammonium persulphate is water-soluble after, then add other leftover materials, stir 10-15 minute, be heated to 70-80 DEG C, stirring reaction 1-2 hour, to obtain final product.
The preparation method of described water-soluble metal degreasing derusting rust-proofing liquid, is characterized in that comprising the following steps: heat water to 40-50 DEG C, adds Voranol EP 2001, sodium laurylsulfonate; Continue to be heated to 85-90 DEG C, add epoxy acrylate, 1-Methoxy-2-propyl acetate, EDETATE SODIUM, stir 10-15 minute; Add other remaining components, continue to stir 15-20 minute, to obtain final product.
Beneficial effect of the present invention
Rust protection liquid of the present invention can carry out disposable oil removing, rust cleaning, phosphatization, passivation and antirust to metallic surface, by using high molecular polymer and sequestrant, can at metallic surface fast filming, isolated air, favorable rust preventing effect, cleaning is easily, be applicable to pipelining, do not affect next step operation to carry out, and harmless, environmentally safe.
Embodiment
A kind of water-soluble metal degreasing derusting rust-proofing liquid, is made up of the raw material of following weight part (kilogram): Voranol EP 2001 3.5, sodium laurylsulfonate 1.5,1.3-dibutyl thiourea 2.5, tartrate 1.5, glyoxal ethyline quinoline 0.8, diamylamine 1.5, epoxy acrylate 33,1-Methoxy-2-propyl acetate 7, EDETATE SODIUM 1.5, auxiliary agent 4.5, water 300.Described auxiliary agent is made up of the raw material of following weight part (kilogram): polyoxyethylene sorbitan monooleate 3, nano titanium oxide 0.1, tripoly phosphate sodium STPP 1, water glass 2, urotropine 2, Resorcinol 1, borax 3, urea 3, ammonium persulphate 1, peach gum 2, water 20; Preparation method be ammonium persulphate is water-soluble after, then add other leftover materials, stir 10-15 minute, be heated to 70-80 DEG C, stirring reaction 1-2 hour, to obtain final product.
The preparation method of described water-soluble metal degreasing derusting rust-proofing liquid, comprises the following steps: heat water to 45 DEG C, adds Voranol EP 2001, sodium laurylsulfonate; Continue to be heated to 88 DEG C, add epoxy acrylate, 1-Methoxy-2-propyl acetate, EDETATE SODIUM, stir 13 minutes; Add other remaining components, continue stirring 18 minutes, to obtain final product.
The Water-soluble antirust liquid that this embodiment obtains detects by national standard, and humid heat test * (1) is qualified; Salt water immersion test * (1): qualified; Corrosion test * (2): qualified; Rust removability (secondary) < 6.Prepared Water-soluble antirust liquid is brushed be newly processed into and there is no the steel matrix surface of greasy dirt, be placed in and indoor within 20 days, have no obvious iron mold.
Claims (2)
1. a water-soluble metal degreasing derusting rust-proofing liquid, it is characterized in that being made up of the raw material of following weight part: Voranol EP 2001 3-4, sodium laurylsulfonate 1-2,1,3-dibutyl thiourea 2-3, tartrate 1-2, glyoxal ethyline quinoline 0.5-1.1, diamylamine 1-2, epoxy acrylate 30-35,1-Methoxy-2-propyl acetate 5-10, EDETATE SODIUM 1-2, auxiliary agent 4-5, water 300; Described auxiliary agent is made up of the raw material of following weight part: polyoxyethylene sorbitan monooleate 2-3, nano titanium oxide 0.1-0.2, tripoly phosphate sodium STPP 1-2, water glass 1-2, urotropine 1-2, Resorcinol 1-2, borax 3-4, urea 2-3, ammonium persulphate 1-2, peach gum 2-3, water 20-24; The preparation method of described auxiliary agent be ammonium persulphate is water-soluble after, then add other leftover materials, stir 10-15 minute, be heated to 70-80 DEG C, stirring reaction 1-2 hour, to obtain final product.
2. the preparation method of water-soluble metal degreasing derusting rust-proofing liquid according to claim 1, is characterized in that comprising the following steps: heat water to 40-50 DEG C, adds Voranol EP 2001, sodium laurylsulfonate; Continue to be heated to 85-90 DEG C, add epoxy acrylate, 1-Methoxy-2-propyl acetate, EDETATE SODIUM, stir 10-15 minute; Add other remaining components, continue to stir 15-20 minute, to obtain final product.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410063881.1A CN103882439B (en) | 2014-02-25 | 2014-02-25 | A kind of water-soluble metal degreasing derusting rust-proofing liquid and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410063881.1A CN103882439B (en) | 2014-02-25 | 2014-02-25 | A kind of water-soluble metal degreasing derusting rust-proofing liquid and preparation method thereof |
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| Publication Number | Publication Date |
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| CN103882439A CN103882439A (en) | 2014-06-25 |
| CN103882439B true CN103882439B (en) | 2016-03-16 |
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Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104131287A (en) * | 2014-07-01 | 2014-11-05 | 蚌埠天光传感器有限公司 | Antirust chemically mechanical polishing solution and preparation method thereof |
| CN104532256B (en) * | 2014-12-30 | 2017-01-11 | 合肥华清方兴表面技术有限公司 | Steel online waterborne rust inhibitor and preparation method thereof |
| CN106752747A (en) * | 2016-12-19 | 2017-05-31 | 苏州耐思特塑胶有限公司 | A kind of preparation method and application of environmentally friendly metal rust-inhibiting liquid |
| CN106521521A (en) * | 2016-12-29 | 2017-03-22 | 柳州市凯夕贸易有限公司 | Dust remover for copper product and preparation method therefor |
| CN107299354A (en) * | 2017-07-29 | 2017-10-27 | 巢湖鹏远金属焊管有限公司 | A kind of inner wall of metal tube cleaning fluid and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1327324A (en) * | 1970-10-15 | 1973-08-22 | Dow Corning | Process and composition for removing rust |
| US4395365A (en) * | 1980-09-08 | 1983-07-26 | Nissan Motor Co., Ltd. | Metal cleaning composition containing a fatty acid succrose ester and other detergent components |
| KR20120128236A (en) * | 2011-05-17 | 2012-11-27 | 주식회사 삼녹 | Rust Resisting Composition and Method For Rust Resist |
| CN102993877A (en) * | 2012-11-01 | 2013-03-27 | 安徽荣达阀门有限公司 | Metal rust inhibitor containing sodium dodecyl sulfate |
| CN103540241A (en) * | 2013-10-18 | 2014-01-29 | 安徽蓝柯复合材料有限公司 | Ultraviolet-curing primer wood coating and preparation method thereof |
-
2014
- 2014-02-25 CN CN201410063881.1A patent/CN103882439B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1327324A (en) * | 1970-10-15 | 1973-08-22 | Dow Corning | Process and composition for removing rust |
| US4395365A (en) * | 1980-09-08 | 1983-07-26 | Nissan Motor Co., Ltd. | Metal cleaning composition containing a fatty acid succrose ester and other detergent components |
| KR20120128236A (en) * | 2011-05-17 | 2012-11-27 | 주식회사 삼녹 | Rust Resisting Composition and Method For Rust Resist |
| CN102993877A (en) * | 2012-11-01 | 2013-03-27 | 安徽荣达阀门有限公司 | Metal rust inhibitor containing sodium dodecyl sulfate |
| CN103540241A (en) * | 2013-10-18 | 2014-01-29 | 安徽蓝柯复合材料有限公司 | Ultraviolet-curing primer wood coating and preparation method thereof |
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