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CN103876398B - There is metal effect and the slide fastener of laser effect and preparation method - Google Patents

There is metal effect and the slide fastener of laser effect and preparation method Download PDF

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Publication number
CN103876398B
CN103876398B CN201410162219.1A CN201410162219A CN103876398B CN 103876398 B CN103876398 B CN 103876398B CN 201410162219 A CN201410162219 A CN 201410162219A CN 103876398 B CN103876398 B CN 103876398B
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slide fastener
effect
transfer machine
preparation
present
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CN103876398A (en
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郑成敏
连燕峰
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SHENZHEN LIANXING GARMENT ACCESSORIES CO Ltd
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SHENZHEN LIANXING GARMENT ACCESSORIES CO Ltd
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Abstract

The present invention discloses a kind of has metal effect and the slide fastener of laser effect and preparation method, slide fastener base material uses PBT material, doped with toner and Masterbatch in base material, be attached with the gold stamping ply of paper with metal effect and laser effect outside zipper teeth by caloric transfer printing technology, preparation method is for be transferred in heat-transferring printing paper in zipper teeth by heat transfer machine.The present invention uses polar plas PBT to make zipper teeth as base material, then uses thermal transfer equipment to be attached in zipper teeth form according to certain technique by heat transfer film, makes zipper tooth tooth surface have special metal effect, laser effect etc..

Description

There is metal effect and the slide fastener of laser effect and preparation method
Technical field
The open a kind of slide fastener of the present invention, a kind of have metal effect and the slide fastener of laser effect and preparation method.
Background technology
Slide fastener is thing common during people live, and is commonly used in clothes, and current slide fastener is in the majority with plastic fastener, its Slide fastener is made with POM for major ingredient more than in.At present, along with making rapid progress of Garment Industry, it requires that zipper teeth surface has More change, meets the demand of clothes.Owing to POM material is non-polar plastic, due to the restriction of its material self performance, Make zipper teeth surface can not with some special have metallic luster, laser effect heat transfer film bonding.How to find One can be bonding with heat transfer film, can meet again prerequisite Functional Requirement when slide fastener uses on clothes, such as water Wash color fastness, dry-cleaning color fastness and meet the slide fastener preparation method drawing time requirement etc., becoming problem demanding prompt solution in industry.
Summary of the invention
The shortcoming for slide fastener of the prior art mentioned above without metallic luster, laser effect, the present invention carries New there is metal effect and the slide fastener of laser effect and preparation method for a kind of, its use PBT material as base material, by heat The heat transfer film with metal effect and laser effect is attached in zipper teeth by transfer technique, make slide fastener have metal effect and Laser effect.
The present invention solves its technical problem and the technical scheme is that a kind of have drawing of metal effect and laser effect Chain, slide fastener base material uses PBT material, and base material is interior doped with toner and Masterbatch, is attached with by caloric transfer printing technology outside zipper teeth There is the gold stamping ply of paper of metal effect and laser effect.
The preparation method of a kind of slide fastener described above with metal effect and laser effect, this preparation method is by heat Heat-transferring printing paper is transferred in zipper teeth by transfer interpreter.
The present invention solves the technical scheme of its technical problem employing and further comprises:
During described thermal transfer, the temperature setting range of heat transfer machine is 185 DEG C ~ 195 DEG C, the charging rate of heat transfer machine For 0.04m/s ~ 0.05m/s, the pressure limit of heat transfer machine is 3.5 kgf/cm2~5kgf/cm2
The temperature of described heat transfer machine is 190 DEG C.
The speed of described heat transfer machine is 0.05m/s.
The pressure of described heat transfer machine is 5 kgf/ cm2
Described preparation method comprises the steps:
(1), get the raw materials ready: the PBT glue rice of specific polarity is sufficiently mixed with toner, Masterbatch;
(2), row microphone machine device is used to carry out zipper fabrication;
(3), heat transfer machine is used to be transferred in zipper teeth by orange cold foil.
The invention has the beneficial effects as follows: the present invention uses polar plas PBT to make zipper teeth as base material, then uses heat to turn Heat transfer film is attached in zipper teeth form by printing apparatus according to certain technique, makes zipper tooth tooth surface have special metal Effect, laser effect etc..
Detailed description of the invention
The present embodiment is the preferred embodiment for the present invention, and other its principles all are identical with the present embodiment or near with basic structure As, all within scope.
The present invention is mainly a kind of slide fastener with metal effect and laser effect, and zipper teeth base material uses PBT(poly-to benzene Dioctyl phthalate butanediol ester, English name polybutylene terephthalate, be called for short PBT, belong to polyester series), mix in PBT Miscellaneous have toner or Masterbatch (toner can use commercially available German LANXESS Energizing Chemistry company to produce The transparent plastic pigment of MACROLEX series, concrete which kind of transparent plastic pigment of selection, can set according to the color of slide fastener finished product Fixed, when needs slide fastener is yellow, can be selected for model is Yellow 3G Gran transparent plastic pigment, when needs slide fastener is blueness Time, can be selected for model is Blue 3R Gran transparent plastic pigment, and when needs slide fastener takes on a red color, can be selected for model is Red A Transparent plastic pigment etc..Masterbatch can use PLA and 123 pearl essences (weight ratio of PLA and 123 pearl essences is 25 ~ 35: 10), so that delrin zippers with pulllers tooth has metallic luster, in the present embodiment, toner and Masterbatch are typically to select an interpolation, its addition Weight ratio for PBT with toner or Masterbatch is 100:3-6, preferably 100:5), thus produce assorted delrin zippers with pulllers, pin Different orange cold foil colors is carried out bottoming process, so makes slide fastener bronzing effect in the case of show-through with zipper head friction Less obvious.
The present invention is in order to make slide fastener have metal effect, laser effect, and heat is turned in zipper teeth by it by heat transfer machine Printing paper is transferred in zipper teeth, and in this city embodiment, heat-transferring printing paper uses special gold stamping turn that model is CFC-186 that the U.S. produces Printing paper, when being embodied as, it would however also be possible to employ the heat-transferring printing paper of other models, and it mainly regulates heat transfer machine Parameter, including speed, pressure and temperature.In the present embodiment, the temperature of the heat transfer machine for producing qualified gold stamping slide fastener sets Determining scope is 185 DEG C ~ 195 DEG C, and wherein selecting optimum temperature is 190 DEG C, for producing the heat transfer machine of qualified gold stamping slide fastener Charging rate (including the charging rate of slide fastener and gold stamping heat-transferring printing paper charging rate) scope be 0.04m/s ~ 0.05m/s, its Middle it is chosen as 0.05m/s according to production requirement optimum speed, for producing the pressure model of the heat transfer machine of qualified gold stamping slide fastener Enclosing is 3.5 kgf/cm2~5kgf/cm2, wherein select optimum pressure to be 5 kgf/ cm according to production requirement2
Below in conjunction with several specific embodiments to being described further in the present invention:
Embodiment one: in the present embodiment, according to slide fastener gold stamping thermal transfer machine speed be 0.05m/s, pressure 5 kgf/ cm2, temperature be 145 DEG C, the slide fastener of production is without obvious bronzing effect.
Embodiment two: in the present embodiment, according to slide fastener gold stamping thermal transfer machine speed be 0.05m/s, pressure 5 kgf/ cm2, temperature be 150 DEG C, the slide fastener of production is without obvious bronzing effect.
Embodiment three: in the present embodiment, according to slide fastener gold stamping thermal transfer machine speed be 0.05m/s, pressure 5 kgf/ cm2, temperature be 155 DEG C, the slide fastener of production is without obvious bronzing effect.
Embodiment four: in the present embodiment, according to slide fastener gold stamping thermal transfer machine speed be 0.05m/s, pressure 5 kgf/ cm2, temperature be 160 DEG C, the slide fastener of production is without obvious bronzing effect.
Embodiment five: in the present embodiment, according to slide fastener gold stamping thermal transfer machine speed be 0.05m/s, pressure 5 kgf/ cm2, temperature be 165 DEG C, the slide fastener bronzing effect of production is unintelligible.
Embodiment six: in the present embodiment, according to slide fastener gold stamping thermal transfer machine speed be 0.05m/s, pressure 5 kgf/ cm2, temperature be 170 DEG C, the slide fastener bronzing effect of production is less clear.
Embodiment seven: in the present embodiment, according to slide fastener gold stamping thermal transfer machine speed be 0.05m/s, pressure 5 kgf/ cm2, temperature be 175 DEG C, the slide fastener bronzing effect of production is clear.
Embodiment eight: in the present embodiment, according to slide fastener gold stamping thermal transfer machine speed be 0.05m/s, pressure 5 kgf/ cm2, temperature be 180 DEG C, the slide fastener bronzing effect of production is apparent from.
Embodiment nine: in the present embodiment, according to slide fastener gold stamping thermal transfer machine speed be 0.05m/s, pressure 5 kgf/ cm2, temperature be 185 DEG C, the slide fastener bronzing effect of production is the most clear.
Embodiment ten: in the present embodiment, according to slide fastener gold stamping thermal transfer machine speed be 0.05m/s, pressure 5 kgf/ cm2, temperature be 190 DEG C, the slide fastener bronzing effect of production is the most clear.
Embodiment 11: in the present embodiment, according to slide fastener gold stamping thermal transfer machine speed be 0.05m/s, pressure 5 kgf/ cm2, temperature be 195 DEG C, the slide fastener bronzing effect of production is very clear, but orange cold foil somewhat melts, broken trace.
Embodiment 12: in the present embodiment, according to slide fastener gold stamping thermal transfer machine speed be 0.05m/s, pressure 5 kgf/ cm2, temperature be 200 DEG C, the slide fastener bronzing effect of production is very clear, but orange cold foil melts a lot.
Embodiment 13: in the present embodiment, according to slide fastener gold stamping thermal transfer machine speed be 0.05m/s, pressure 5 kgf/ cm2, temperature be 205 DEG C, the slide fastener of production tears to get off with orange cold foil combines.
Embodiment 14: in the present embodiment, is 190 DEG C, pressure 5 kgf/ according to slide fastener gold stamping thermal transfer machine temperature cm2, speed be 0.010m/s, the slide fastener of production tears to get off with orange cold foil combines.
Embodiment 15: in the present embodiment, is 190 DEG C, pressure 5 kgf/ according to slide fastener gold stamping thermal transfer machine temperature cm2, speed be 0.015m/s, the slide fastener of production tears to get off with orange cold foil combines.
Embodiment 16: in the present embodiment, is 190 DEG C, pressure 5 kgf/ according to slide fastener gold stamping thermal transfer machine temperature cm2, speed be 0.020m/s, the slide fastener bronzing effect of production is very clear, but orange cold foil melts a lot.
Embodiment 17: in the present embodiment, is 190 DEG C, pressure 5 kgf/ according to slide fastener gold stamping thermal transfer machine temperature cm2, speed be 0.025m/s, the slide fastener bronzing effect of production is very clear, but orange cold foil melts a lot.
Embodiment 18: in the present embodiment, is 190 DEG C, pressure 5 kgf/ according to slide fastener gold stamping thermal transfer machine temperature cm2, speed be 0.030m/s, the slide fastener bronzing effect of production is very clear, but orange cold foil melts, and has broken trace.
Embodiment 19: in the present embodiment, is 190 DEG C, pressure 5 kgf/ according to slide fastener gold stamping thermal transfer machine temperature cm2, speed be 0.035m/s, the slide fastener bronzing effect of production is very clear, but orange cold foil somewhat melts, and points out trace.
Embodiment 20: in the present embodiment, is 190 DEG C, pressure 5 kgf/ according to slide fastener gold stamping thermal transfer machine temperature cm2, speed be 0.040m/s, the slide fastener bronzing effect of production is the most clear.
Embodiment 21: in the present embodiment, is 190 DEG C, pressure 5 kgf/ according to slide fastener gold stamping thermal transfer machine temperature cm2, speed be 0.045m/s, the slide fastener bronzing effect of production is the most clear.
Embodiment 22: in the present embodiment, is 190 DEG C, pressure 5 kgf/ according to slide fastener gold stamping thermal transfer machine temperature cm2, speed be 0.050m/s, the slide fastener bronzing effect of production is the most clear.
Embodiment 23: in the present embodiment, is 190 DEG C, pressure 5 kgf/ according to slide fastener gold stamping thermal transfer machine temperature cm2, speed be 0.055m/s, the slide fastener bronzing effect of production is apparent from.
Embodiment 24: in the present embodiment, is 190 DEG C, pressure 5 kgf/ according to slide fastener gold stamping thermal transfer machine temperature cm2, speed be 0.055m/s, the slide fastener bronzing effect of production is more visible.
Embodiment 25: in the present embodiment, is 190 DEG C, pressure 5 kgf/ according to slide fastener gold stamping thermal transfer machine temperature cm2, speed be 0.060m/s, the slide fastener bronzing effect of production is more visible.
Embodiment 26: in the present embodiment, is 190 DEG C, pressure 5 kgf/ according to slide fastener gold stamping thermal transfer machine temperature cm2, speed be 0.065m/s, the slide fastener bronzing effect of production is more visible.
Embodiment 27: in the present embodiment, is 190 DEG C, pressure 5 kgf/ according to slide fastener gold stamping thermal transfer machine temperature cm2, speed be 0.070m/s, the slide fastener bronzing effect of production is clear.
Embodiment 28: in the present embodiment, is 190 DEG C, pressure 5 kgf/ according to slide fastener gold stamping thermal transfer machine temperature cm2, speed be 0.075m/s, the slide fastener bronzing effect of production is clear.
Embodiment 29: in the present embodiment, is 190 DEG C, pressure 5 kgf/ according to slide fastener gold stamping thermal transfer machine temperature cm2, speed be 0.080m/s, the slide fastener bronzing effect of production is unintelligible.
Embodiment 30: in the present embodiment, is 190 DEG C, pressure 5 kgf/ according to slide fastener gold stamping thermal transfer machine temperature cm2, speed be 0.085m/s, the slide fastener bronzing effect of production is unintelligible.
Embodiment 31: in the present embodiment, is 190 DEG C, pressure 5 kgf/ according to slide fastener gold stamping thermal transfer machine temperature cm2, speed be 0.090m/s, the slide fastener bronzing effect of production is unintelligible.
Embodiment 32: in the present embodiment, is 190 DEG C, pressure 5 kgf/ according to slide fastener gold stamping thermal transfer machine temperature cm2, speed be 0.100m/s, the slide fastener bronzing effect of production is inconspicuous.
Embodiment 33: in the present embodiment, is 190 DEG C, pressure 5 kgf/ according to slide fastener gold stamping thermal transfer machine temperature cm2, speed be 0.105m/s, the slide fastener bronzing effect of production is inconspicuous.
Embodiment 34: in the present embodiment, is 190 DEG C, pressure 5 kgf/ according to slide fastener gold stamping thermal transfer machine temperature cm2, speed be 0.110m/s, the slide fastener bronzing effect of production is inconspicuous.
Embodiment 35: in the present embodiment, is 190 DEG C, pressure 5 kgf/ according to slide fastener gold stamping thermal transfer machine temperature cm2, speed be 0.120m/s, the slide fastener of production is without bronzing effect.
Embodiment 36: in the present embodiment, according to slide fastener gold stamping thermal transfer machine temperature be 190 DEG C, speed be 0.05m/s, pressure 0 kgf/cm2, slide fastener is without walking about.
Embodiment 37: in the present embodiment, according to slide fastener gold stamping thermal transfer machine temperature be 190 DEG C, speed be 0.05m/s, pressure 0.5kgf/cm2, slide fastener is without walking about.
Embodiment 38: in the present embodiment, according to slide fastener gold stamping thermal transfer machine temperature be 190 DEG C, speed be 0.05m/s, pressure 1.0 kgf/cm2, slide fastener is somewhat walked about, but is skidded.
Embodiment 39: in the present embodiment, according to slide fastener gold stamping thermal transfer machine temperature be 190 DEG C, speed be 0.05m/s, pressure 1.5kgf/cm2, the slide fastener bronzing effect of production is inconspicuous.
Embodiment 40: in the present embodiment, according to slide fastener gold stamping thermal transfer machine temperature be 190 DEG C, speed be 0.05m/ S, pressure 2.0kgf/cm2, the slide fastener bronzing effect of production is pure and fresh.
Embodiment 41: in the present embodiment, according to slide fastener gold stamping thermal transfer machine temperature be 190 DEG C, speed be 0.05m/s, pressure 2.5kgf/cm2, the slide fastener bronzing effect of production is more pure and fresh.
Embodiment 42: in the present embodiment, according to slide fastener gold stamping thermal transfer machine temperature be 190 DEG C, speed be 0.05m/s, pressure 3.0kgf/cm2, the slide fastener bronzing effect of production is pure and fresh.
Embodiment 43: in the present embodiment, according to slide fastener gold stamping thermal transfer machine temperature be 190 DEG C, speed be 0.05m/s, pressure 3.5kgf/cm2, the slide fastener bronzing effect of production is the most pure and fresh.
Embodiment 44: in the present embodiment, according to slide fastener gold stamping thermal transfer machine temperature be 190 DEG C, speed be 0.05m/s, pressure 4.0kgf/cm2, the slide fastener bronzing effect of production is the most pure and fresh.
Embodiment 45: in the present embodiment, according to slide fastener gold stamping thermal transfer machine temperature be 190 DEG C, speed be 0.05m/s, pressure 4.5kgf/cm2, the slide fastener bronzing effect of production is the most pure and fresh.
Embodiment 46: in the present embodiment, according to slide fastener gold stamping thermal transfer machine temperature be 190 DEG C, speed be 0.05m/s, pressure 5.0kgf/cm2, the slide fastener bronzing effect of production is the most pure and fresh.
Embodiment 47: in the present embodiment, according to slide fastener gold stamping thermal transfer machine temperature be 190 DEG C, speed be 0.05m/s, pressure 5.5kgf/cm2, the slide fastener bronzing effect of production is the most pure and fresh, but somewhat has unconspicuous on zipper cloth belt Gold stamping color and luster.
Embodiment 48: in the present embodiment, according to slide fastener gold stamping thermal transfer machine temperature be 190 DEG C, speed be 0.05m/s, pressure 6.0kgf/cm2, the slide fastener bronzing effect of production is the most pure and fresh, but has obvious gold stamping look on zipper cloth belt Pool.
Embodiment 49: in the present embodiment, according to slide fastener gold stamping thermal transfer machine temperature be 190 DEG C, speed be 0.120m/s, pressure 6.5kgf/cm2, the slide fastener bronzing effect of production is the most pure and fresh, but has on zipper cloth belt and obviously scald Golden pool.
In embodiment one to embodiment 13 in above-described embodiment, to change heat under optimum speed and optimum pressure Realize the difference of thermal transfer effect under conditions of transfer temperature, in embodiment one to embodiment 13, can draw, in the present invention Thermal transfer gilding technology in temperature be not the highest more good, transfer temperature is the lowest can occur thermoprint not go up, and transfer temperature is the highest, then Orange cold foil can be occurred to merge with delrin zippers with pulllers.The present invention, 185-195 DEG C of this scope, can make and meet production The gold stamping slide fastener required, wherein the highest more that beneficially gold stamping slide fastener the produces speed of temperature, so not selecting 185 DEG C in the present invention Following temperature, and when thermal transfer temperature is higher than 195 DEG C, orange cold foil just starts to melt, after thawing, orange cold foil meeting and plastic-steel The glue tooth of slide fastener produces viscosity, is unfavorable for that gold stamping paper membrane is separated with delrin zippers with pulllers tooth, so the most not selecting the transfer less than 195 DEG C Temperature.Again because gilding technology is in production engineering, the reason such as machinery equipment precision, selecting constant temperature 190 DEG C when, heat supply Device is exactly to fluctuate 190 DEG C ± 3 DEG C scopes, so this gilding technology arranges temperature and is preferably 190 DEG C and produces.
In embodiment 10 four to embodiment 35 in above-described embodiment, to change at optimum temperature and optimum pressure Realize the difference of thermal transfer effect under the speed of heating transfer, in embodiment 10 four to embodiment 35, can draw, in temperature Reach that orange cold foil is not ruined bears in atmosphere, and speed of production is to be directly connected to production capacity benefit, when charging rate is too fast, Hot stamping effects is inconspicuous, when charging rate is crossed slow, can produce the phenomenon that orange cold foil melts, so gold stamping speed selects 0.050m/s。
In embodiment 30 six to embodiment 49 in above-described embodiment, with at optimum temperature and optimum speed Changing the difference realizing thermal transfer effect under the pressure of thermal transfer, in test process, pressure is the biggest, gold stamping to produce Slide fastener washing, dry-cleaning and wear-resisting test are obviously improved, in embodiment 30 six to embodiment 49, when pressure is the least Time, slide fastener will not be pulled to feed during the charging of gold stamping material strip, when pressure is excessive, zipper cloth belt be brought on gold stamping color and luster, raw The slide fastener that output is come does not meets customer requirement, so selection pressure is 5.0kgf/cm2
The combination property produced according to slide fastener in above-described embodiment requires higher, is possessing specific production requirement premise Under, maximize benefit with greater need for meeting generation.
Present invention simultaneously provides a kind of technique using above-mentioned raw materials to produce slide fastener, concrete technology comprises the steps:
1, get the raw materials ready: by polarity PBT glue rice (in the present embodiment, the particle diameter of glue rice is generally 0.2 ~ 0.3cm) and toner or look Master batch mixes, and produces assorted delrin zippers with pulllers, carries out bottoming process for different orange cold foil colors, so make the gold stamping effect of slide fastener Fruit is less obvious in the case of show-through with zipper head friction;
2, the model using Long Hui Machinery Manufacturing Co., Ltd. of Wenzhou City to produce is that LH123S row microphone machine device carries out slide fastener system Making, machine parameter during manufacture sets as shown in the table:
The slide fastener that the present invention produces has metal effect, laser effect, at the same time it can also be meet each side of slide fastener Can, there are wide market prospects, meet development and the environmental requirement of zipper industry.

Claims (5)

1. having a preparation method for the slide fastener of metal effect and laser effect, described slide fastener base material uses PBT material, base Doped with toner and Masterbatch in material, it is attached with by caloric transfer printing technology outside zipper teeth and there is the boiling hot of metal effect and laser effect Gold ply of paper, is characterized in that: described preparation method is for be transferred in heat-transferring printing paper in zipper teeth by heat transfer machine, during thermal transfer The temperature setting range of heat transfer machine is 185 DEG C ~ 195 DEG C, and the charging rate of heat transfer machine is 0.04m/s ~ 0.05m/s, and heat turns The pressure limit of print machine is 3.5 kgf/cm2~5kgf/cm2
The preparation method of the slide fastener with metal effect and laser effect the most according to claim 1, is characterized in that: described The temperature of heat transfer machine be 190 DEG C.
The preparation method of the slide fastener with metal effect and laser effect the most according to claim 1, is characterized in that: described The speed of heat transfer machine be 0.05m/s.
The preparation method of the slide fastener with metal effect and laser effect the most according to claim 1, is characterized in that: described The pressure of heat transfer machine be 5 kgf/ cm2
The preparation method of the slide fastener with metal effect and laser effect the most as claimed in any of claims 1 to 4, It is characterized in that: described preparation method comprises the steps:
(1), get the raw materials ready: the PBT glue rice of specific polarity is sufficiently mixed with toner, Masterbatch;
(2), row microphone machine device is used to carry out zipper fabrication;
(3), heat transfer machine is used to be transferred in zipper teeth by orange cold foil.
CN201410162219.1A 2014-04-22 2014-04-22 There is metal effect and the slide fastener of laser effect and preparation method Expired - Fee Related CN103876398B (en)

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CN104783412A (en) * 2015-04-30 2015-07-22 深圳市联星服装辅料有限公司 Resin fastener with reflecting colorful effect and manufacturing method
CN106476460A (en) * 2015-09-02 2017-03-08 吉田拉链(深圳)有限公司 Zipper tooth surface treatment method and the zipper tooth using the method coloring, slide fastener and clothes
CN105690990A (en) * 2016-01-25 2016-06-22 温州市江湾机械有限公司 Zipper hot stamping machine
CN105520284A (en) * 2016-01-25 2016-04-27 温州市江湾机械有限公司 Processing technology of zipper and zipper product obtained by adopting same
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CN107348628A (en) * 2017-08-21 2017-11-17 深圳市联星服装辅料有限公司 A kind of waterproof lettering slide fastener and preparation method thereof
CN107880498B (en) * 2017-10-30 2020-08-04 中广核俊尔新材料有限公司 Polybutylene terephthalate alloy material and preparation method and application thereof
CN109527723A (en) * 2018-11-29 2019-03-29 深圳市联星服装辅料有限公司 A kind of production method of double-colored metal zip fastener
CN110667245B (en) * 2019-11-14 2021-07-13 深圳市联星服装辅料有限公司 Method for manufacturing metallic zipper
CN111925632B (en) * 2020-08-17 2022-08-02 浙江伟星实业发展股份有限公司 Injection molding zipper and preparation method thereof

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