CN103866629A - Papermaking processing aid and preparation method thereof - Google Patents
Papermaking processing aid and preparation method thereof Download PDFInfo
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- CN103866629A CN103866629A CN201410070059.8A CN201410070059A CN103866629A CN 103866629 A CN103866629 A CN 103866629A CN 201410070059 A CN201410070059 A CN 201410070059A CN 103866629 A CN103866629 A CN 103866629A
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Abstract
The invention relates to a papermaking processing aid and a preparation method thereof. The papermaking processing aid is prepared from the following components in parts by weight: 13-15 parts of toluene diisocynate, 2-4 parts of C9 petroleum resin, 9-12 parts of octadecyl phenylsulfonic acid potassium, 1-2 parts of potassium oxalate, 4-5 parts of propylene glycol, 4-6 parts of ethyl acetate, and 120-124 parts of deionized water. The preparation method of the papermaking processing aid disclosed by the invention comprises the following steps: heating and mixing the components, mechanically agitating, and cooling. The tensile strength, the ring crush index and the performance parameter of paper can be greatly improved by the prepared papermaking processing aid.
Description
Technical field
The present invention relates to a kind of papermaking processing aid and preparation method thereof, particularly relate to and a kind ofly can promote largely the tensile strength of paper and papermaking processing aid of ring crush index and preparation method thereof.
Background technology
In the process of papermaking, can use a lot of processing aids, as filter aid, dry strength agent, wet strength agent, sizing agent etc.These different auxiliary agents have different functions, and common use can improve the quality of paper product.In the production process of papermaking, the function of certain auxiliary agent is comparatively limited conventionally, can not meet the needs of production completely.
Dry strength agent and wet strength agent are applied in dry strong tensile strength and the wet strong tensile strength that in paper industry, can improve paper, but dry strength agent and wet strength agent can not effectively promote the ring crush intensity of paper, sizing agent can improve the ring crush intensity of paper, but sizing agent can not improve the tensile strength of paper, if the tensile strength that therefore processing aid not only can improve paper can also improve an epoxy intensity for paper, can have and utilize preferably space.
Summary of the invention
The technical problem solving: common processing aid is applied in the production of paper, to the tensile strength of paper with change Compressive Strength and promote less problem.
Technical scheme: in order to promote surface strength and the ring crush index of paper simultaneously, the invention discloses a kind of papermaking processing aid and preparation method thereof, papermaking processing aid is made up of according to weight ratio following composition: toluene di-isocyanate(TDI) is that 13～15 parts, C9 Petropols are that 2～4 parts, octadecyl benzene sulfonic acid potassium are that 9～12 parts, potassium oxalate are that 1～2 part, propylene glycol are that 4～5 parts, ethyl acetate are that 4～6 parts, deionized water are 120～124 parts.
A kind of preparation method of papermaking processing aid, preparation method comprises the steps: that temperature of reaction kettle is adjusted to 70 ℃ by (1), getting toluene di-isocyanate(TDI) and be 13～15 parts, C9 Petropols and be 2～4 parts, octadecyl benzene sulfonic acid potassium is 9～12 parts, toluene di-isocyanate(TDI), C9 Petropols and octadecyl benzene sulfonic acid potassium are dropped in reactor, use mechanical agitation oar to stir, be stirred to evenly; (2) be that 120～124 parts, propylene glycol are 4～5 parts to adding deionized water in reactor again, again carry out mechanical agitation to evenly; (3) finally to add potassium oxalate after be evenly that 1～2 part, ethyl acetate are 4～6 parts to mixed liquor state, is stirred to evenly with mechanical agitation oar, at 70 ℃, protects 3h; (4) be cooled to after room temperature, prepare papermaking processing aid.
Wherein, the toluene di-isocyanate(TDI) adding in the preparation method of papermaking processing aid is preferably 14～15 parts.
Wherein, the C9 Petropols molecular weight adding in the preparation method of papermaking processing aid is preferably 300～3000.
Wherein, the potassium oxalate adding in the preparation method of papermaking processing aid is preferably 2 parts.
Beneficial effect: the papermaking processing aid that the present invention prepares is coated on after paper surface, the dry strong tensile strength of paper is increased to 56.1 to 58.6Nm/g by 25.7Nm/g, wet strong tensile strength is increased to 24.8 to 26.1Nm/g by 12.2Nm/g, the ring crush index of paper is increased to 5.3 Nm/g to 5.6 Nm/g by 2.2 Nm/g, not only improve the tensile strength of paper, also improved the ring crush intensity of paper.
The specific embodiment
Embodiment 1
A kind of preparation method of papermaking processing aid, preparation method comprises the steps: that temperature of reaction kettle is adjusted to 70 ℃ by (1), getting toluene di-isocyanate(TDI) is that 13kg, C9 Petropols are that 3kg, octadecyl benzene sulfonic acid potassium are 9kg, toluene di-isocyanate(TDI), C9 Petropols and octadecyl benzene sulfonic acid potassium are dropped in reactor, use mechanical agitation oar to stir, be stirred to evenly; (2) be that 120kg, propylene glycol are 5kg to adding deionized water in reactor again, again carry out mechanical agitation to evenly; (3) finally to add potassium oxalate after be evenly that 1kg, ethyl acetate are 6kg to mixed liquor state, is stirred to evenly with mechanical agitation oar, at 70 ℃, protects 3h; (4) be cooled to after room temperature, prepare papermaking processing aid.
Embodiment 2
A kind of preparation method of papermaking processing aid, preparation method comprises the steps: that temperature of reaction kettle is adjusted to 70 ℃ by (1), getting toluene di-isocyanate(TDI) is that 15kg, C9 Petropols are that 2kg, octadecyl benzene sulfonic acid potassium are 11kg, toluene di-isocyanate(TDI), C9 Petropols and octadecyl benzene sulfonic acid potassium are dropped in reactor, use mechanical agitation oar to stir, be stirred to evenly; (2) be that 124kg, propylene glycol are 4kg to adding deionized water in reactor again, again carry out mechanical agitation to evenly; (3) finally to add potassium oxalate after be evenly that 1kg, ethyl acetate are 4kg to mixed liquor state, is stirred to evenly with mechanical agitation oar, at 70 ℃, protects 3h; (4) be cooled to after room temperature, prepare papermaking processing aid.
Embodiment 3
A kind of preparation method of papermaking processing aid, preparation method comprises the steps: that temperature of reaction kettle is adjusted to 70 ℃ by (1), getting toluene di-isocyanate(TDI) is that 14kg, C9 Petropols are that 4kg, octadecyl benzene sulfonic acid potassium are 12kg, toluene di-isocyanate(TDI), C9 Petropols and octadecyl benzene sulfonic acid potassium are dropped in reactor, use mechanical agitation oar to stir, be stirred to evenly; (2) be that 122kg, propylene glycol are 5kg to adding deionized water in reactor again, again carry out mechanical agitation to evenly; (3) finally to add potassium oxalate after be evenly that 2kg, ethyl acetate are 5kg to mixed liquor state, is stirred to evenly with mechanical agitation oar, at 70 ℃, protects 3h; (4) be cooled to after room temperature, prepare papermaking processing aid.
Get common string paper, Substance is 55g/m
2, the papermaking processing aid of embodiment 1, embodiment 2, embodiment 3 is diluted with water to after 10wt%, dilution is coated on to paper tow sides, coating weight is 12g/m
2, coating post-drying, has measured the dry strong tensile strength of paper, wet strong tensile strength, ring crush index after oven dry.Carry out blank test, blank test assay method is identical with embodiment simultaneously, the uncoated papermaking processing aid dilution of blank group.
Before and after paper is processed through processing aid of the present invention, the dry strong tensile strength of paper, wet strong tensile strength and ring crush index are all significantly enhanced, and have improved the quality of paper, have expanded the application of paper.
Claims (5)
1. a papermaking processing aid, is characterized in that papermaking processing aid is made up of according to weight ratio following composition: toluene di-isocyanate(TDI) is that 13～15 parts, C9 Petropols are that 2～4 parts, octadecyl benzene sulfonic acid potassium are that 9～12 parts, potassium oxalate are that 1～2 part, propylene glycol are that 4～5 parts, ethyl acetate are that 4～6 parts, deionized water are 120～124 parts.
2. the preparation method of a papermaking processing aid, it is characterized in that preparation method comprises the steps: that temperature of reaction kettle is adjusted to 70 ℃ by (1), getting toluene di-isocyanate(TDI) and be 13～15 parts, C9 Petropols and be 2～4 parts, octadecyl benzene sulfonic acid potassium is 9～12 parts, toluene di-isocyanate(TDI), C9 Petropols and octadecyl benzene sulfonic acid potassium are dropped in reactor, use mechanical agitation oar to stir, be stirred to evenly; (2) be that 120～124 parts, propylene glycol are 4～5 parts to adding deionized water in reactor again, again carry out mechanical agitation to evenly; (3) finally to add potassium oxalate after be evenly that 1～2 part, ethyl acetate are 4～6 parts to mixed liquor state, is stirred to evenly with mechanical agitation oar, at 70 ℃, protects 3h; (4) be cooled to after room temperature, prepare papermaking processing aid.
3. the preparation method of a kind of papermaking processing aid according to claim 2, is characterized in that the toluene di-isocyanate(TDI) adding in preparation process is 14～15 parts.
4. the preparation method of a kind of papermaking processing aid according to claim 2, is characterized in that the C9 Petropols molecular weight adding in preparation process is 300～3000.
5. the preparation method of a kind of papermaking processing aid according to claim 2, is characterized in that the potassium oxalate adding in preparation process is 2 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410070059.8A CN103866629A (en) | 2014-02-28 | 2014-02-28 | Papermaking processing aid and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410070059.8A CN103866629A (en) | 2014-02-28 | 2014-02-28 | Papermaking processing aid and preparation method thereof |
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| CN103866629A true CN103866629A (en) | 2014-06-18 |
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| CN201410070059.8A Pending CN103866629A (en) | 2014-02-28 | 2014-02-28 | Papermaking processing aid and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105862505A (en) * | 2016-04-27 | 2016-08-17 | 商孝霞 | Papermaking auxiliary agent |
| CN105862504A (en) * | 2016-04-27 | 2016-08-17 | 商孝霞 | Papermaking auxiliary agent and production method thereof |
| CN115428976A (en) * | 2022-10-11 | 2022-12-06 | 南通烟滤嘴有限责任公司 | Coconut-flavored heating cigarette sheet and preparation method thereof |
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| JP2002500288A (en) * | 1997-12-31 | 2002-01-08 | キンバリー クラーク ワールドワイド インコーポレイテッド | Method for producing a cellulose web having improved wet tensile strength |
| CN102704338A (en) * | 2012-05-08 | 2012-10-03 | 华南理工大学 | Sizing reinforcing agent and preparation process and application thereof |
| CN102731746A (en) * | 2012-06-29 | 2012-10-17 | 上海东升新材料有限公司 | Enclosed type aqueous polyurethane emulsion papermaking wet strength agent and its preparation method |
| CN103524694A (en) * | 2013-10-16 | 2014-01-22 | 上海东升新材料有限公司 | Preparation method and application of water-based environment-friendly wet strength agent |
| CN103524708A (en) * | 2013-10-16 | 2014-01-22 | 上海东升新材料有限公司 | Preparation method of closed water-based polyurethane modified PAE (polyarylether) wet strength agent |
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2014
- 2014-02-28 CN CN201410070059.8A patent/CN103866629A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| JP2002500288A (en) * | 1997-12-31 | 2002-01-08 | キンバリー クラーク ワールドワイド インコーポレイテッド | Method for producing a cellulose web having improved wet tensile strength |
| CN102704338A (en) * | 2012-05-08 | 2012-10-03 | 华南理工大学 | Sizing reinforcing agent and preparation process and application thereof |
| CN102731746A (en) * | 2012-06-29 | 2012-10-17 | 上海东升新材料有限公司 | Enclosed type aqueous polyurethane emulsion papermaking wet strength agent and its preparation method |
| CN103524694A (en) * | 2013-10-16 | 2014-01-22 | 上海东升新材料有限公司 | Preparation method and application of water-based environment-friendly wet strength agent |
| CN103524708A (en) * | 2013-10-16 | 2014-01-22 | 上海东升新材料有限公司 | Preparation method of closed water-based polyurethane modified PAE (polyarylether) wet strength agent |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105862505A (en) * | 2016-04-27 | 2016-08-17 | 商孝霞 | Papermaking auxiliary agent |
| CN105862504A (en) * | 2016-04-27 | 2016-08-17 | 商孝霞 | Papermaking auxiliary agent and production method thereof |
| CN115428976A (en) * | 2022-10-11 | 2022-12-06 | 南通烟滤嘴有限责任公司 | Coconut-flavored heating cigarette sheet and preparation method thereof |
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Application publication date: 20140618 |