CN103866306B - A kind of novel, environmental protection macromolecule potteryization liquid and its preparation method - Google Patents
A kind of novel, environmental protection macromolecule potteryization liquid and its preparation method Download PDFInfo
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- CN103866306B CN103866306B CN201210530451.7A CN201210530451A CN103866306B CN 103866306 B CN103866306 B CN 103866306B CN 201210530451 A CN201210530451 A CN 201210530451A CN 103866306 B CN103866306 B CN 103866306B
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- 239000007788 liquid Substances 0.000 title claims abstract description 26
- 230000007613 environmental effect Effects 0.000 title claims description 7
- 229920002521 macromolecule Polymers 0.000 title claims description 5
- 238000002360 preparation method Methods 0.000 title description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 27
- 238000000034 method Methods 0.000 claims abstract description 13
- 150000007524 organic acids Chemical class 0.000 claims abstract description 11
- 239000000203 mixture Substances 0.000 claims abstract description 8
- 239000002994 raw material Substances 0.000 claims abstract description 8
- 229920000642 polymer Polymers 0.000 claims abstract description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 18
- IPCAPQRVQMIMAN-UHFFFAOYSA-L zirconyl chloride Chemical compound Cl[Zr](Cl)=O IPCAPQRVQMIMAN-UHFFFAOYSA-L 0.000 claims description 12
- 239000002253 acid Substances 0.000 claims description 10
- 239000011347 resin Substances 0.000 claims description 10
- 229920005989 resin Polymers 0.000 claims description 10
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 8
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims description 8
- -1 dichloro oxygen titanium Chemical compound 0.000 claims description 8
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 8
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 claims description 7
- 239000004094 surface-active agent Substances 0.000 claims description 7
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 6
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 6
- 229920002125 Sokalan® Polymers 0.000 claims description 6
- 239000011737 fluorine Substances 0.000 claims description 6
- 229910052731 fluorine Inorganic materials 0.000 claims description 6
- 239000004584 polyacrylic acid Substances 0.000 claims description 6
- 229910052700 potassium Inorganic materials 0.000 claims description 6
- 239000011591 potassium Substances 0.000 claims description 6
- ABPJHHHWWYDYFZ-UHFFFAOYSA-N 2-methylidenebutanedioic acid;prop-2-enoic acid Chemical compound OC(=O)C=C.OC(=O)CC(=C)C(O)=O ABPJHHHWWYDYFZ-UHFFFAOYSA-N 0.000 claims description 4
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 4
- LDDQLRUQCUTJBB-UHFFFAOYSA-N ammonium fluoride Chemical compound [NH4+].[F-] LDDQLRUQCUTJBB-UHFFFAOYSA-N 0.000 claims description 4
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 4
- 235000019253 formic acid Nutrition 0.000 claims description 4
- LVHBHZANLOWSRM-UHFFFAOYSA-N itaconic acid Chemical compound OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 claims description 4
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 4
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 4
- NROKBHXJSPEDAR-UHFFFAOYSA-M potassium fluoride Chemical compound [F-].[K+] NROKBHXJSPEDAR-UHFFFAOYSA-M 0.000 claims description 4
- 239000011734 sodium Substances 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- 235000013024 sodium fluoride Nutrition 0.000 claims description 4
- 239000002131 composite material Substances 0.000 claims description 3
- HLJCWGPUCQTHFY-UHFFFAOYSA-H disodium;hexafluorotitanium(2-) Chemical compound [F-].[F-].[Na+].[Na+].F[Ti](F)(F)F HLJCWGPUCQTHFY-UHFFFAOYSA-H 0.000 claims description 3
- 239000011775 sodium fluoride Substances 0.000 claims description 3
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 3
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 2
- 239000004141 Sodium laurylsulphate Substances 0.000 claims description 2
- 235000011054 acetic acid Nutrition 0.000 claims description 2
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 2
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 2
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 2
- 239000000843 powder Substances 0.000 claims description 2
- 235000019260 propionic acid Nutrition 0.000 claims description 2
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 claims description 2
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 2
- DAJSVUQLFFJUSX-UHFFFAOYSA-M sodium;dodecane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCS([O-])(=O)=O DAJSVUQLFFJUSX-UHFFFAOYSA-M 0.000 claims description 2
- 150000003609 titanium compounds Chemical class 0.000 claims 4
- 150000003755 zirconium compounds Chemical class 0.000 claims 4
- PMTRSEDNJGMXLN-UHFFFAOYSA-N titanium zirconium Chemical compound [Ti].[Zr] PMTRSEDNJGMXLN-UHFFFAOYSA-N 0.000 abstract description 8
- 239000003795 chemical substances by application Substances 0.000 abstract description 6
- 239000010936 titanium Substances 0.000 abstract description 6
- 229910052719 titanium Inorganic materials 0.000 abstract description 6
- 229910019142 PO4 Inorganic materials 0.000 abstract description 4
- 229910000831 Steel Inorganic materials 0.000 abstract description 4
- 239000010959 steel Substances 0.000 abstract description 4
- 229910052751 metal Inorganic materials 0.000 abstract description 3
- 239000002184 metal Substances 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract description 2
- 229910052782 aluminium Inorganic materials 0.000 abstract description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract description 2
- 238000007654 immersion Methods 0.000 abstract description 2
- 239000000463 material Substances 0.000 abstract description 2
- 238000005507 spraying Methods 0.000 abstract description 2
- 229910052725 zinc Inorganic materials 0.000 abstract description 2
- 239000011701 zinc Substances 0.000 abstract description 2
- 238000004017 vitrification Methods 0.000 abstract 7
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 abstract 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- 238000013329 compounding Methods 0.000 abstract 1
- 238000009472 formulation Methods 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 229910001385 heavy metal Inorganic materials 0.000 abstract 1
- CMOAHYOGLLEOGO-UHFFFAOYSA-N oxozirconium;dihydrochloride Chemical compound Cl.Cl.[Zr]=O CMOAHYOGLLEOGO-UHFFFAOYSA-N 0.000 abstract 1
- 235000021317 phosphate Nutrition 0.000 abstract 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 abstract 1
- 239000002952 polymeric resin Substances 0.000 abstract 1
- 229920003002 synthetic resin Polymers 0.000 abstract 1
- 239000000080 wetting agent Substances 0.000 abstract 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 4
- 150000001805 chlorine compounds Chemical class 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 150000007513 acids Chemical class 0.000 description 3
- 239000000919 ceramic Substances 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 3
- 239000010410 layer Substances 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 3
- 239000010452 phosphate Substances 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical group OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical class CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 239000006087 Silane Coupling Agent Substances 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000012851 eutrophication Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000002103 nanocoating Substances 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 238000007781 pre-processing Methods 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 230000003405 preventing effect Effects 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- WFSPUOYRSOLZIS-UHFFFAOYSA-N silane zirconium Chemical compound [SiH4].[Zr] WFSPUOYRSOLZIS-UHFFFAOYSA-N 0.000 description 1
- OWEZKDSVCUYVNT-UHFFFAOYSA-I sodium;titanium(4+);pentafluoride Chemical class [F-].[F-].[F-].[F-].[F-].[Na+].[Ti+4] OWEZKDSVCUYVNT-UHFFFAOYSA-I 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000012756 surface treatment agent Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Abstract
<b>本发明涉及一种用于金属表面进行陶化处理的陶化剂，特别是该类陶化剂的配方及复配方法。该发明</b><b>公开了一种新型、环保的高分子陶化液，其组成由下述原料复配而成：</b><b>钛锆化合物</b><b>10-20</b><b>份，氟化物</b><b>2-5</b><b>份，水性高分子树脂</b><b>3-10</b><b>份，</b><b>二氯氧化锆（钛）</b><b>1-5</b><b>份，有机酸</b><b>2-5</b><b>份，表面润湿剂</b><b>0-2</b><b>份，</b><b>水</b><b>55-75</b><b>份。</b><b>通过本工艺配置成的陶化液稳定性好、成膜性好，无需用到磷酸盐、重金属等物质，对环境更加环保。该陶化液容易在钢铁、锌和铝材表面形成一层致密的陶化层，适合于常温的喷淋和浸泡处理，无需加热设备，节约能源、易于生产。</b><b>The present invention relates to a vitrification agent for metal surface vitrification treatment, especially the formulation and compounding method of this type of vitrification agent. This invention</b><b>discloses a new type of environment-friendly polymer vitrification solution, which is composed of the following raw materials: </b><b>Titanium-Zirconium Compound</b><b >10-20</b><b>parts, fluoride</b><b>2-5</b><b>parts, water-based polymer resin</b><b>3-10</b><b> b><b>parts,</b><b>zirconium oxychloride (titanium)</b><b>1-5</b><b>parts, organic acid</b><b>2 -5</b><b>parts, surface wetting agent</b><b>0-2</b><b>parts, </b><b>water</b><b>55 -75</b><b>parts. </b><b>The vitrification liquid configured by this process has good stability and good film-forming properties, and does not need to use phosphates, heavy metals and other substances, which is more environmentally friendly. The vitrification solution can easily form a dense vitrification layer on the surface of steel, zinc and aluminum materials, is suitable for spraying and immersion treatment at normal temperature, does not need heating equipment, saves energy, and is easy to produce. </b>
Description
Technical field
The present invention relates to the formula of a kind of vitrified agent, particularly such vitrified agent that carry out potteryization process for metallic surface and preparation method.
Background technology
Iron and steel usually needs to carry out pre-treatment before carrying out application; comprise the technique such as oil removing, rust cleaning; chemical pre-processing method usually also will at surface formation one layer of chemical conversion film of iron and steel; the existing certain antiseptic power of this conversion film; rust is returned in the time that part can be avoided of short duration before spraying; the roughness of piece surface can also be increased, strengthen the bonding force of coating and substrate. What major part adopted at present is phosphating process, and its phosphorization agent added can form one layer of phosphatize phosphate coat in metallic surface. P contained compound conventional in phosphorization agent mostly is phosphoric acid, such as Chinese patent CN1422980A, CN1434150A, CN1401820A, CN1043962A, CN1144278A etc. In these phosphatization liquid, main component (P contained compound) can cause the eutrophication of water, and environment has bigger harm, and therefore its discharge brings very big problem, if directly discharged, will serious environment pollution, organism in water and human lives are produced significant damage. Along with environmental protection constantly advances, novel non-phosphate conversion film (potteryization film) is quietly replacing traditional phosphatize phosphate coat. Novel ceramic liquid is mainly divided into the phosphate-free metal surface treatment agents such as zirconium system, zirconium titanium system, silane system, silane zirconium system, can Some substitute phosphatization liquid. Its main raw material is fluozirconate, silane coupling agent etc. This new conversion film is by amorphous state ZrO
2
Composition, its nano coating formed replaces traditional crystal type phosphatization protective layer, and has good sticking power between metallic surface and paint coating subsequently, fine corrosion resistance. Novel ceramic liquid meets the application requirement of industrialization substantially, but due to formed coating be inorganic nano material, more weak with the bonding force of metallic surface. Therefore, the space being still improved in the bonding force of Novel ceramic liquid in metallic surface, surface filming performance etc.
Summary of the invention
The present invention seeks to the film-forming properties in order to improve potteryization liquid, the bonding force strengthened between coating and metal. Thering is provided a kind of technique simple, potteryization film is fine and close, favorable rust preventing effect, the environment-friendly type potteryization liquid that film-forming properties is strong and its preparation method.
For achieving the above object, the technical solution used in the present invention is:
A kind of novel, polymer potteryization liquid, it forms by following raw material composite and become: titanium zirconium compounds 10-20 part, fluorochemical 2-5 part, aqueous high molecular resin 3-10 part, zirconyl chloride (titanium) 1-5 part, organic acid 2-5 part, surface active agent 0-2 part, water 55-75 part.
The present invention also provides a kind of method preparing above-mentioned pottery liquid, and its step is as follows:
One, various raw material is taken in proportion;
Two, in its 2/3 water requirement, add the titanium zirconium compounds taken, it is stirred to dissolving;
Three, in the solution that step 2 is obtained, add fluorochemical and it is stirred to dissolving;
Four, in the solution that step 3 is obtained, aqueous high molecular resin agitating is added to dissolving;
Five, in the solution that step 4 is obtained, zirconyl chloride (titanium) is added to dissolving;
Six, in the solution that step 5 is obtained, add small molecular organic acid, it is stirred to dissolving;
Seven, in the solution that step 6 is obtained, add surface active agent, it is stirred to dissolving;
Eight, in the solution that step 5 is obtained, add the remaining water yield, it is stirred to and is uniformly dissolved.
Owing to technique scheme is used, the present invention compared with prior art has following advantage: the pottery liquid good stability prepared by this technique, and the pottery layer formed on the surface of iron and steel, zinc and aluminium is more even; Stronger with the binding ability of material surface, the not environmental pollutant such as phosphoric acid salt, environmental protection more. Pottery liquid prepared by this technical scheme is applicable to normal temperature spray and drenches and immersion treatment, and technique is simple, is easy to operation, and cost is lower, is suitable for applying.
Embodiment
A kind of potteryization liquid, its quality group becomes: titanium zirconium compounds 10-20 part, fluorochemical 2-5 part, aqueous high molecular resin 3-10 part, zirconyl chloride (titanium) 1-5 part, small molecular organic acid 2-5 part, water 55-75 part.
The best composition (massfraction) of this pottery liquid is: titanium zirconium compounds 12-16 part, fluorochemical 3-4 part, aqueous high molecular resin 3-5 part, zirconyl chloride (titanium) 1-3 part, small molecular organic acid 3-4 part, nonionogenic tenside 0.1-0.5 part, water 65-75 part. The titanium zirconium compounds that the present invention uses can be: the one in potassium fluozirconate, sodium fluozirconate, fluorine zirconic acid, potassium fluotitanate, titanium sodium fluoride, hydrofluotitanic acid etc., or multiple; Fluorochemical can be one or more in hydrofluoric acid, Sodium Fluoride, Potassium monofluoride, Neutral ammonium fluoride etc.; Aqueous high molecular resin can be: one or more in the multipolymer of vinylformic acid and maleic anhydride, the multipolymer of vinylformic acid methylene-succinic acid, polyacrylic acid, sodium polyacrylate etc.; Small molecular organic acid can be one or more in formic acid, acetic acid, propionic acid, toxilic acid, vinylformic acid, methylene-succinic acid etc.; Surface active agent can be fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, sodium lauryl sulphate, sodium laurylsulfonate, pull open powder etc. in one or more.
The method preparing above-mentioned pottery liquid is as follows:
One, various raw material is taken in proportion;
Two, in its 2/3 water requirement, add the titanium zirconium compounds taken, it is stirred to dissolving;
Three, in the solution that step 2 is obtained, add fluorochemical and it is stirred to dissolving;
Four, in the solution that step 3 is obtained, aqueous high molecular resin agitating is added to dissolving;
Five, in the solution that step 4 is obtained, zirconyl chloride (titanium) is added to dissolving;
Six, in the solution that step 5 is obtained, add small molecular organic acid, it is stirred to dissolving;
Seven, in the solution that step 6 is obtained, add nonionogenic tenside, it is stirred to dissolving;
Eight, in the solution that step 5 is obtained, add the remaining water yield, it is stirred to and is uniformly dissolved.
For the ease of being familiar with the preparation of such potteryization liquid, now describe the present invention in conjunction with the embodiments:
Embodiment 1
A preparation method for pottery liquid, its step is as follows:
1) fluorine zirconic acid 7 parts is taken, sodium fluozirconate 9 parts, Potassium monofluoride 4 parts, polyacrylic acid 6 parts, zirconyl chloride 3 parts, 2 parts, formic acid, 1 part, vinylformic acid, ethoxylated dodecyl alcohol 0.2 part, 67.8 parts, water;
2) in 40 parts of water, add 7 parts of fluorine zirconic acids and it is stirred to abundant dissolving;
3) add 9 parts of sodium fluozirconates in step 2 and it is stirred to abundant dissolving;
4) add 4 parts of Potassium monofluorides in step 3 and it is stirred to abundant dissolving;
5) add 2 parts of formic acid in step 4,1 part of vinylformic acid be stirred to dissolving;
6) add 6 parts of polyacrylic acid in steps of 5 and it is stirred to abundant dissolving;
7) add 3 parts of zirconyl chlorides in step 6 and it is stirred to abundant dissolving;
8) ethoxylated dodecyl alcohol adding 0.2 part in step 7 is stirred to dissolving;
9) add 27.8 parts of water in step 8 to be stirred to and mix.
Embodiment 2
A preparation method for pottery liquid, its step is as follows:
1) hydrofluotitanic acid 5 parts is taken, potassium fluotitanate 10 parts, Sodium Fluoride 4 parts, polyacrylic acid 7 parts, zirconyl chloride 2 parts, acetic acid 3 parts, 69 parts, water;
2) in 40 parts of water, add 5 parts of hydrofluotitanic acids and it is stirred to abundant dissolving;
3) add 10 parts of potassium fluotitanates in step 2 and it is stirred to abundant dissolving;
4) add 4 parts of Sodium Fluorides in step 3 and it is stirred to abundant dissolving;
5) add 3 parts of acetic acid in step 4 and it is stirred to dissolving;
6) add 7 parts of polyacrylic acid in steps of 5 and it is stirred to abundant dissolving;
7) add 2 parts of zirconyl chlorides in step 6 and it is stirred to abundant dissolving;
8) add 29 parts of water in step 7 to be stirred to and mix.
Embodiment 3
A preparation method for pottery liquid, its step is as follows:
1) fluorine zirconic acid 12 parts is taken, Neutral ammonium fluoride 4 parts, the multipolymer of vinylformic acid methylene-succinic acid 6 parts, zirconyl chloride 3 parts, alkylphenol polyoxyethylene 0.2 part, 74.8 parts, water;
2) in 45 parts of water, add 12 parts of fluorine zirconic acids and it is stirred to abundant dissolving;
3) add 4 parts of Neutral ammonium fluorides in step 2 and it is stirred to abundant dissolving;
4) multipolymer adding 6 parts of vinylformic acid methylene-succinic acids in step 3 is stirred to abundant dissolving;
5) add 3 parts of zirconyl chlorides in step 4 and it is stirred to abundant dissolving;
6) add 0.2 part of alkylphenol polyoxyethylene in steps of 5 and it is stirred to abundant dissolving
7) add 29.8 parts of water in step 6 to be stirred to and mix.
Embodiment 4
A preparation method for pottery liquid, its step is as follows:
1) titanium sodium fluoride 15 parts is taken, 3 parts, hydrofluoric acid, sodium polyacrylate 7 parts, zirconyl chloride 2 parts, toxilic acid 1 part, acetic acid 2 parts, 2 parts, vinylformic acid, 68 parts, water;
2) 40 parts of water add 3 parts of hydrofluoric acid and it is stirred to abundant dissolving;
3) add 15 parts of titanium sodium fluorides in step 2 and it is stirred to abundant dissolving;
4) add 1 part of toxilic acid in step 3,2 parts of acetic acid, 2 parts of vinylformic acid be stirred to dissolving;
5) add 7 parts of sodium polyacrylates in step 4 and it is stirred to abundant dissolving;
6) add 2 parts of zirconyl chlorides in steps of 5 and it is stirred to abundant dissolving;
7) add 28 parts of water in step 6 to be stirred to and mix.
Claims (3)
1. novel, an environmental protection macromolecule potteryization liquid, its composition is composite and become by following raw material: titanium compound/zirconium compounds 10-20 part, fluorochemical 2-5 part, aqueous high molecular resin 3-10 part, zirconyl chloride/dichloro oxygen titanium 1-5 part, small molecular organic acid 2-5 part, surface active agent 0-2 part, water 55-75 part; Wherein, titanium compound/zirconium compounds is one or more in potassium fluozirconate, sodium fluozirconate, fluorine zirconic acid, potassium fluotitanate, titanium sodium fluoride, hydrofluotitanic acid, and fluorochemical is one or more in hydrofluoric acid, Sodium Fluoride, Potassium monofluoride, Neutral ammonium fluoride; Aqueous high molecular resin is one or more in the multipolymer of vinylformic acid and maleic anhydride, the multipolymer of vinylformic acid methylene-succinic acid, polyacrylic acid, sodium polyacrylate; Small molecular organic acid is one or more in formic acid, acetic acid, propionic acid, toxilic acid, vinylformic acid, methylene-succinic acid; Surface active agent be fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, sodium lauryl sulphate, sodium laurylsulfonate, pull open in powder one or more.
2. novel, environmental protection macromolecule potteryization liquid as claimed in claim 1, it is characterized in that, described novel high polymer potteryization liquid is composite and become by following raw material: titanium compound/zirconium compounds 12-16 part, fluorochemical 3-4 part, aqueous high molecular resin 3-5 part, zirconyl chloride/dichloro oxygen titanium 1-3 part, small molecular organic acid 3-4 part, surface active agent 0.1-0.5 part, water 65-75 part.
3. preparing a method novel described in claim 1, environmental protection macromolecule potteryization liquid, its step is as follows:
One, various raw material is taken in proportion;
Two, in its 2/3 water requirement, add the titanium compound/zirconium compounds taken, it is stirred to dissolving;
Three, in the solution that step 2 is obtained, add fluorochemical and it is stirred to dissolving;
Four, in the solution that step 3 is obtained, aqueous high molecular resin agitating is added to dissolving;
Five, in the solution that step 4 is obtained, zirconyl chloride/dichloro oxygen titanium is added to dissolving;
Six, in the solution that step 5 is obtained, add small molecular organic acid, it is stirred to dissolving;
Seven, in the solution that step 6 is obtained, add surface active agent, it is stirred to dissolving;
Eight, in the solution that step 5 is obtained, add the remaining water yield, it is stirred to and is uniformly dissolved.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1572913A (en) * | 2003-06-09 | 2005-02-02 | 日本油漆株式会社 | Aluminium base material surface treatment method and surface treated base material |
| CN101137766A (en) * | 2005-03-07 | 2008-03-05 | 日本油漆株式会社 | Chemical Conversion Treatments and Surface Treatments for Metals |
| CN101611170A (en) * | 2006-12-04 | 2009-12-23 | 汉高股份及两合公司 | Stable thin-film organic passivates |
| CN101629286A (en) * | 2009-07-29 | 2010-01-20 | 岑添祥 | Vitrified agent and preparation method thereof |
| CN102066612A (en) * | 2008-03-17 | 2011-05-18 | 汉高两合股份公司 | Optimized passivation on Ti-/Zr-basis for metal surfaces |
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| CN1572913A (en) * | 2003-06-09 | 2005-02-02 | 日本油漆株式会社 | Aluminium base material surface treatment method and surface treated base material |
| CN101137766A (en) * | 2005-03-07 | 2008-03-05 | 日本油漆株式会社 | Chemical Conversion Treatments and Surface Treatments for Metals |
| CN101611170A (en) * | 2006-12-04 | 2009-12-23 | 汉高股份及两合公司 | Stable thin-film organic passivates |
| CN102066612A (en) * | 2008-03-17 | 2011-05-18 | 汉高两合股份公司 | Optimized passivation on Ti-/Zr-basis for metal surfaces |
| CN101629286A (en) * | 2009-07-29 | 2010-01-20 | 岑添祥 | Vitrified agent and preparation method thereof |
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