CN103848469A - Method for processing municipal wastewater - Google Patents
Method for processing municipal wastewater Download PDFInfo
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- CN103848469A CN103848469A CN201210496764.5A CN201210496764A CN103848469A CN 103848469 A CN103848469 A CN 103848469A CN 201210496764 A CN201210496764 A CN 201210496764A CN 103848469 A CN103848469 A CN 103848469A
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- China
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- municipal wastewater
- polyacrylamide
- montmorillonite
- processing
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- 238000000034 method Methods 0.000 title claims abstract description 30
- 239000010841 municipal wastewater Substances 0.000 title abstract 5
- 229920002401 polyacrylamide Polymers 0.000 claims abstract description 18
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 17
- 239000011707 mineral Substances 0.000 claims abstract description 17
- 229910052901 montmorillonite Inorganic materials 0.000 claims abstract description 16
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000010865 sewage Substances 0.000 claims abstract description 14
- 239000000203 mixture Substances 0.000 claims abstract description 13
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910052649 zeolite group Inorganic materials 0.000 claims description 14
- 239000000470 constituent Substances 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 5
- 229910052799 carbon Inorganic materials 0.000 abstract description 5
- 239000000126 substance Substances 0.000 abstract description 4
- 239000012535 impurity Substances 0.000 abstract description 3
- 229910021536 Zeolite Inorganic materials 0.000 abstract 1
- 230000007797 corrosion Effects 0.000 abstract 1
- 238000005260 corrosion Methods 0.000 abstract 1
- 231100000956 nontoxicity Toxicity 0.000 abstract 1
- 239000010457 zeolite Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- 238000011282 treatment Methods 0.000 description 8
- 238000001179 sorption measurement Methods 0.000 description 6
- 239000002245 particle Substances 0.000 description 4
- 238000000746 purification Methods 0.000 description 4
- 238000013517 stratification Methods 0.000 description 4
- 238000004065 wastewater treatment Methods 0.000 description 4
- 238000005352 clarification Methods 0.000 description 3
- 239000010840 domestic wastewater Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 239000002351 wastewater Substances 0.000 description 3
- 230000004913 activation Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000002957 persistent organic pollutant Substances 0.000 description 2
- 239000005518 polymer electrolyte Substances 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 238000004062 sedimentation Methods 0.000 description 2
- 241000251468 Actinopterygii Species 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 208000023445 Congenital pulmonary airway malformation Diseases 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 230000000274 adsorptive effect Effects 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 229910052728 basic metal Inorganic materials 0.000 description 1
- 150000003818 basic metals Chemical class 0.000 description 1
- 238000005341 cation exchange Methods 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 230000005591 charge neutralization Effects 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 239000003471 mutagenic agent Substances 0.000 description 1
- 231100000707 mutagenic chemical Toxicity 0.000 description 1
- 230000003505 mutagenic effect Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- -1 silicon (aluminium) oxygen Chemical compound 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 238000009923 sugaring Methods 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
Landscapes
- Water Treatment By Sorption (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
The invention provides a method for processing municipal wastewater, which is characterized in that the municipal wastewater is treated by a composition composed of the following components: active carbon, zeolite mineral, montmorillonite and polyacrylamide. The method for processing municipal wastewater is capable of rapidly absorbing the impurities such as organic substances and inorganic substances in municipal wastewater, and can realize standard discharge of the sewage, and the method has the advantages of low cost, non toxicity and no corrosion.
Description
Technical field
The invention belongs to technical field of waste water processing, be specifically related to a kind of method of processing city domestic sewage.
Background technology
Existing method of wastewater treatment has physical treatment process, method of chemical treatment, biological treatment.
Physical treatment process is the most original water treatment method, is the method that is separated, reclaimed undissolved suspended state pollutent in sewage by modes such as gravity stratification, centrifugal or filtrations.The method is simple, but can only do some simple wastewater treatments, and processing is very incomplete, is difficult to qualified discharge.
Method of chemical treatment is mainly the method with medicament and the pollutent thrown in neutralize, the chemical reaction such as coagulation, redox carries out wastewater treatment.But the method process range is narrow, the wastewater treatment ability many to organism.
Biological treatment is to make organic pollutant in sewage be converted into the method for stable harmless object by the metabolism of microorganism.But the method treatment scheme is long, facility investment is large, operating cost is high, heavy metal ion is difficult to remove.
Summary of the invention
The present invention aims to provide a kind of method of high-level efficiency, low-cost processes city domestic sewage.
Particularly, the present invention is a kind of method of processing city domestic sewage, it is characterized in that, uses the compositions-treated city domestic sewage of following component: gac, zeolite group mineral, montmorillonite, polyacrylamide.
Wherein, each constituent mass proportion optimization of described composition is: gac 15-25 part, zeolite group mineral 15-20 part, montmorillonite 15-25 part, polyacrylamide 5-10 part, more preferably: gac 20-25 part, zeolite group mineral 18-20 part, montmorillonite 15-18 part, polyacrylamide 5-8 part, be particularly preferably: 22 parts of gacs, 19 parts of zeolite group minerals, 16 parts of montmorillonites, 6 parts of polyacrylamides.
Gac claims again active black, is black powder shape or the granular decolorizing carbon obtaining through charing, activation and aftertreatment with raw materials such as coal, timber and shells.Gac, structurally due to microcrystalline carbon irregular alignment, has pore between cross connection, when activation, can produce carbon tissue defects, and therefore it is a kind of porous carbon, and tap density is low, pore texture prosperity, the large (1500m of specific surface area
2more than/g), high adsorption capacity, be widely used in the deep purifying of tap water, process water and waste water, industrial purification of water quality and Gas Phase Adsorption, as power plant, petrochemical industry, refinery, food-drink, sugaring alcoholic, medicine, electronics, breed fish, the purification of water quality processing of the industry such as sea-freight, free chlorine, phenol, sulphur and other organic pollutant in energy active adsorption water, the particularly precursor of mutagen (THM), the object that reaches purification and impurity removal and remove peculiar smell.
Zeolite group mineral is the manosil AS mineral of a kind of moisture basic metal or alkaline-earth metal, there is the three-dimensional framework being formed by silicon (aluminium) oxygen tetrahedron, in skeleton, there are hole of all sizes and passage, these holes and passage play the effect of strainer and molecular sieve, can optionally adsorb or filtered wastewater in organism or inorganics, be therefore widely used in the aspects such as sewage purification.
Montmorillonite has another name called montmorillonite, is the layer mineral being made up of the superfine hydrous alumino silicates of particle, has very strong adsorptive power and cation exchange property, is widely used in chemical reaction to produce adsorption and cleaning action.In the time that montmorillonite uses together with zeolite group mineral, can make montmorillonite and zeolite group mineral play complementary collaborative effect by micro-porous adsorption and ion-exchange.
Polyacrylamide is that molecular weight has good flocculence by millions of to several macromolecular water-soluble organic polymers of ten million, can reduce the frictional resistance between liquid, forms larger flco and produce thus huge surface adsorption effect between particle.Process and use polyacrylamide to be generally divided into two processes for city domestic sewage: the one, the charge neutralization of polymer electrolyte and particle surface; The 2nd, the long-chain of polymer electrolyte and tiny suspended particles are built bridge and are formed thicker floc sedimentation, and along with the increase of floc sedimentation, settling velocity increases gradually.Domestic representational high polymer polyacrylamide has at present: non-ionic polyacrylamide (is write a Chinese character in simplified form NPAM, molecular weight 800-1500 ten thousand), anion-polyacrylamide (writes a Chinese character in simplified form APAM, molecular weight 800-2000 ten thousand), cationic polyacrylamide (writes a Chinese character in simplified form CPAM, molecular weight 800-1200 ten thousand, ion degree 10%-80%).
The present invention can be adsorbed the impurity such as organism and inorganics in city domestic sewage efficiently, rapidly, realizes the qualified discharge of sewage, and the method cost is low, nontoxic, non-corrosiveness.
Embodiment
Describe the present invention in detail below in conjunction with embodiment; but the following examples are only preferably embodiment of the present invention; protection scope of the present invention is not limited to this; any be familiar with those skilled in the art the present invention disclose technical scope in; be equal to replacement or changed according to technical scheme of the present invention and inventive concept thereof, within all should being encompassed in protection scope of the present invention.
Embodiment 1
Get the composition of following quality proportioning: 15 parts of gacs, 20 parts of zeolite group minerals, 0 part of montmorillonite 2,5 parts of polyacrylamides.Get 5g said composition, join in 1L urban domestic wastewater, stir 15 minutes, stratification, filters, and obtains the water of clarification.Inorganics and organic amount in water before and after processing are measured, and result shows that inorganics and organic clearance have reached respectively more than 85%.
Embodiment 2
Get the composition of following quality proportioning: 22 parts of gacs, 20 parts of zeolite group minerals, 16 parts of montmorillonites, 5 parts of polyacrylamides.Get 6g said composition, join in 1L urban domestic wastewater, stir 12 minutes, stratification, filters, and obtains the water of clarification.Inorganics and organic amount in water before and after processing are measured, and result shows that inorganics and organic clearance have reached respectively more than 82%.
Embodiment 3
Get the composition of following quality proportioning: 22 parts of gacs, 19 parts of zeolite group minerals, 16 parts of montmorillonites, 6 parts of polyacrylamides.Get 4.5g said composition, join in 1L urban domestic wastewater, stir 20 minutes, stratification, filters, and obtains the water of clarification.Inorganics and organic amount in water before and after processing are measured, and result shows that inorganics and organic clearance have reached respectively more than 86%.
Claims (4)
1. a method of processing city domestic sewage, is characterized in that, uses the compositions-treated city domestic sewage of following component: gac, zeolite group mineral, montmorillonite, polyacrylamide.
2. method according to claim 1, is characterized in that, each constituent mass proportioning of described composition is: gac 15-25 part, zeolite group mineral 15-20 part, montmorillonite 15-25 part, polyacrylamide 5-10 part.
3. method according to claim 1, is characterized in that, each constituent mass proportioning of described composition is: gac 20-25 part, zeolite group mineral 18-20 part, montmorillonite 15-18 part, polyacrylamide 5-8 part.
4. method according to claim 1, is characterized in that, each constituent mass proportioning of described composition is: 22 parts of gacs, 19 parts of zeolite group minerals, 16 parts of montmorillonites, 6 parts of polyacrylamides.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201210496764.5A CN103848469A (en) | 2012-11-28 | 2012-11-28 | Method for processing municipal wastewater |
Applications Claiming Priority (1)
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CN201210496764.5A CN103848469A (en) | 2012-11-28 | 2012-11-28 | Method for processing municipal wastewater |
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Publication Number | Publication Date |
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CN103848469A true CN103848469A (en) | 2014-06-11 |
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CN201210496764.5A Pending CN103848469A (en) | 2012-11-28 | 2012-11-28 | Method for processing municipal wastewater |
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Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105236594A (en) * | 2015-11-23 | 2016-01-13 | 济南昊泽环保科技有限公司 | Agent and method for treating waste water of biscuit making enterprise |
CN105254033A (en) * | 2015-11-20 | 2016-01-20 | 济南昊泽环保科技有限公司 | Soy sauce production wastewater treating agent and wastewater treatment method |
CN105254034A (en) * | 2015-11-23 | 2016-01-20 | 济南昊泽环保科技有限公司 | Monosodium glutamate production wastewater treating agent and wastewater treatment method |
CN105254036A (en) * | 2015-11-24 | 2016-01-20 | 济南昊泽环保科技有限公司 | Hot-pickled mustard tuber production wastewater treating agent and wastewater treating method |
CN105271507A (en) * | 2015-11-19 | 2016-01-27 | 济南昊泽环保科技有限公司 | Bean product production wastewater treating agent and wastewater treating method |
CN105293721A (en) * | 2015-11-23 | 2016-02-03 | 济南昊泽环保科技有限公司 | Pastry factory production wastewater treatment agent and wastewater treatment method |
CN105293722A (en) * | 2015-11-23 | 2016-02-03 | 济南昊泽环保科技有限公司 | Treatment agent for wastewater from food coloring production and wastewater treatment method |
CN105347510A (en) * | 2015-11-20 | 2016-02-24 | 济南昊泽环保科技有限公司 | Pickled vegetable production wastewater treatment agent and wastewater treatment method |
CN105347509A (en) * | 2015-11-20 | 2016-02-24 | 济南昊泽环保科技有限公司 | Pectin production wastewater treatment agent and wastewater treatment method |
CN105597670A (en) * | 2015-10-30 | 2016-05-25 | 王立鑫 | Novel active carbon composite material and preparation method thereof |
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WO2003022745A1 (en) * | 2001-09-10 | 2003-03-20 | Aquaest International B.V. | Self contained water filter having zeolites, filtration membranes and water flow rate control means |
CN101654290A (en) * | 2009-09-01 | 2010-02-24 | 苏州市甘泉自动化环保设备厂 | Chemical film wastewater treatment method and device thereof |
CN201578930U (en) * | 2009-09-01 | 2010-09-15 | 苏州市甘泉自动化环保设备厂 | Filter membrane for waste water treatment and waste water treatment device |
CN102399042A (en) * | 2010-09-08 | 2012-04-04 | 四川冶金环能工程有限责任公司 | Method for treating wastewater by combining adsorbent with magnetic disk separation technology and application thereof |
-
2012
- 2012-11-28 CN CN201210496764.5A patent/CN103848469A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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WO2003022745A1 (en) * | 2001-09-10 | 2003-03-20 | Aquaest International B.V. | Self contained water filter having zeolites, filtration membranes and water flow rate control means |
CN101654290A (en) * | 2009-09-01 | 2010-02-24 | 苏州市甘泉自动化环保设备厂 | Chemical film wastewater treatment method and device thereof |
CN201578930U (en) * | 2009-09-01 | 2010-09-15 | 苏州市甘泉自动化环保设备厂 | Filter membrane for waste water treatment and waste water treatment device |
CN102399042A (en) * | 2010-09-08 | 2012-04-04 | 四川冶金环能工程有限责任公司 | Method for treating wastewater by combining adsorbent with magnetic disk separation technology and application thereof |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105597670A (en) * | 2015-10-30 | 2016-05-25 | 王立鑫 | Novel active carbon composite material and preparation method thereof |
CN105271507A (en) * | 2015-11-19 | 2016-01-27 | 济南昊泽环保科技有限公司 | Bean product production wastewater treating agent and wastewater treating method |
CN105254033A (en) * | 2015-11-20 | 2016-01-20 | 济南昊泽环保科技有限公司 | Soy sauce production wastewater treating agent and wastewater treatment method |
CN105347510A (en) * | 2015-11-20 | 2016-02-24 | 济南昊泽环保科技有限公司 | Pickled vegetable production wastewater treatment agent and wastewater treatment method |
CN105347509A (en) * | 2015-11-20 | 2016-02-24 | 济南昊泽环保科技有限公司 | Pectin production wastewater treatment agent and wastewater treatment method |
CN105236594A (en) * | 2015-11-23 | 2016-01-13 | 济南昊泽环保科技有限公司 | Agent and method for treating waste water of biscuit making enterprise |
CN105254034A (en) * | 2015-11-23 | 2016-01-20 | 济南昊泽环保科技有限公司 | Monosodium glutamate production wastewater treating agent and wastewater treatment method |
CN105293721A (en) * | 2015-11-23 | 2016-02-03 | 济南昊泽环保科技有限公司 | Pastry factory production wastewater treatment agent and wastewater treatment method |
CN105293722A (en) * | 2015-11-23 | 2016-02-03 | 济南昊泽环保科技有限公司 | Treatment agent for wastewater from food coloring production and wastewater treatment method |
CN105254036A (en) * | 2015-11-24 | 2016-01-20 | 济南昊泽环保科技有限公司 | Hot-pickled mustard tuber production wastewater treating agent and wastewater treating method |
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Application publication date: 20140611 |