CN103834956B - Clean-out system of a kind of household heating system for being made up of various metals material and preparation method thereof - Google Patents
Clean-out system of a kind of household heating system for being made up of various metals material and preparation method thereof Download PDFInfo
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- CN103834956B CN103834956B CN201410122488.5A CN201410122488A CN103834956B CN 103834956 B CN103834956 B CN 103834956B CN 201410122488 A CN201410122488 A CN 201410122488A CN 103834956 B CN103834956 B CN 103834956B
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- clean
- heating system
- household heating
- out system
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- 238000010438 heat treatment Methods 0.000 title claims abstract description 23
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 23
- 239000002184 metal Substances 0.000 title claims abstract description 23
- 239000000463 material Substances 0.000 title claims abstract description 13
- 150000002739 metals Chemical class 0.000 title claims abstract description 13
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims abstract description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000002253 acid Substances 0.000 claims abstract description 13
- 229940120146 EDTMP Drugs 0.000 claims abstract description 10
- NFDRPXJGHKJRLJ-UHFFFAOYSA-N edtmp Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CCN(CP(O)(O)=O)CP(O)(O)=O NFDRPXJGHKJRLJ-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 10
- 239000011734 sodium Substances 0.000 claims abstract description 10
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 7
- 239000012964 benzotriazole Substances 0.000 claims description 7
- TVXXNOYZHKPKGW-UHFFFAOYSA-N sodium molybdate (anhydrous) Chemical compound [Na+].[Na+].[O-][Mo]([O-])(=O)=O TVXXNOYZHKPKGW-UHFFFAOYSA-N 0.000 claims description 5
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 claims description 4
- 239000002994 raw material Substances 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 3
- 230000007797 corrosion Effects 0.000 abstract description 19
- 238000005260 corrosion Methods 0.000 abstract description 19
- 239000002131 composite material Substances 0.000 abstract description 4
- 230000000903 blocking effect Effects 0.000 abstract description 2
- 239000003818 cinder Substances 0.000 abstract description 2
- 239000007769 metal material Substances 0.000 abstract description 2
- 239000000203 mixture Substances 0.000 abstract description 2
- 150000007524 organic acids Chemical class 0.000 abstract description 2
- 238000012546 transfer Methods 0.000 abstract description 2
- 238000003911 water pollution Methods 0.000 abstract description 2
- 238000012360 testing method Methods 0.000 description 10
- 238000004140 cleaning Methods 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 229910000975 Carbon steel Inorganic materials 0.000 description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 5
- 239000004411 aluminium Substances 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- 230000033228 biological regulation Effects 0.000 description 5
- 239000010962 carbon steel Substances 0.000 description 5
- 229910052802 copper Inorganic materials 0.000 description 5
- 239000010949 copper Substances 0.000 description 5
- 238000007689 inspection Methods 0.000 description 5
- 239000010935 stainless steel Substances 0.000 description 5
- 229910001220 stainless steel Inorganic materials 0.000 description 5
- 239000011814 protection agent Substances 0.000 description 3
- 239000003513 alkali Substances 0.000 description 2
- 239000002893 slag Substances 0.000 description 2
- 238000003466 welding Methods 0.000 description 2
- OGSPWJRAVKPPFI-UHFFFAOYSA-N Alendronic Acid Chemical compound NCCCC(O)(P(O)(O)=O)P(O)(O)=O OGSPWJRAVKPPFI-UHFFFAOYSA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 229940062527 alendronate Drugs 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000000116 mitigating effect Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 238000011017 operating method Methods 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- 238000005382 thermal cycling Methods 0.000 description 1
Landscapes
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Detergent Compositions (AREA)
Abstract
The present invention relates to a kind of clean-out system of the household heating system for being made up of various metals material, comprise the component of following weight percent content: propylene glycol 3 ~ 20%, inhibiter 2.5 ~ 10%, thionamic acid 0.1 ~ 5%, ethylene diamine tetra methylene phosphonic acid sodium 5 ~ 25%, all the other are de-mineralized water.Present invention also offers the preparation method of above-mentioned clean-out system.Clean-out system of the present invention utilize organic anti-scale composition and organic acid composite, effectively to peel off, the old dirt dissolved in household heating system equipment, to prevent from generating secondary incrustation scale simultaneously; This clean-out system effectively can not only reduce the corrosion to household heating system equipment metallic substance, effectively can also remove the incrustation scale, anvil cinder etc. of household heating system device interior, prevent the problems such as the low or water cycle blocking of the heat transfer efficiency of the household heating system caused because of fouling, run with making each equipment energy safety economy in whole household heating system, thus reach the object reducing water pollutions and save energy and reduce the cost.
Description
Technical field
The present invention relates to a kind of clean-out system, particularly relating to clean-out system of a kind of household heating system for being made up of various metals material and preparation method thereof.
Background technology
The feature of small home heating system is: local temperature is higher, pipeline is comparatively thin in system, easily causes fouling in system, causes the phenomenons such as line clogging.Therefore, for preventing system jams from causing thermal cycling to be obstructed, this system is carried out with cleanings such as front welding slag, residues, and descaling rinsing seems very important termly.
At present, main wash mode has: mechanical descaling, high pressure water cleaning and matting.First two cleaning way much belongs to manual operations, and labour intensity is large, and be a kind of operating method of rough type substantially, suitability is also poor, inapplicable in a lot of technical process; It is wide that matting relates to, and use flexibly, for different systems and different incrustation scale kinds, the cleaning agent formula selected is also different.
The matting of general industry equipment: as boiler, pipeline, petrochemical equipment etc., usually use acid, alkali and some active substances as clean-out system.After the cleaning of this kind of clean-out system, to improve and the fundamental property of restorer, but the bad control of terminal, to have certain danger, and be unsuitable for the household heating system that various metals material forms; In addition, long-term acid, alkaline cleaner make the metallic corrosion of equipment, shorten the life-span of equipment; Further, sour, alkali cleaning operation complex procedures, need after cleaning to carry out neutralizing treatment, then passivation, make equipment cleaning time elongated, affect the normal operation of equipment.
Summary of the invention
The object of the invention is to overcome the defect of prior art and provide a kind of and can run cleaning continuously under not stopped status and be applicable to the neutral cleaners of the household heating system be made up of various metals material.
Another object of the present invention is the preparation method of the clean-out system providing a kind of above-mentioned household heating system for being made up of various metals material
The object of the present invention is achieved like this:
The clean-out system of a kind of household heating system for being made up of various metals material of the present invention, comprise the component of following weight percent content: propylene glycol 3 ~ 20%, inhibiter 2.5 ~ 10%, thionamic acid 0.1 ~ 5%, ethylene diamine tetra methylene phosphonic acid sodium 5 ~ 25%, all the other are de-mineralized water.
The clean-out system of above-mentioned a kind of household heating system for being made up of various metals material, wherein, described inhibiter is at least two kinds in benzotriazole, 1-Hydroxy Ethylidene-1,1-Diphosphonic Acid and Sodium orthomolybdate.
Present invention also offers a kind of preparation method of clean-out system of the above-mentioned household heating system for being made up of various metals material, comprising the following steps:
(1) prepare raw material according to following component and weight percent content: propylene glycol 3 ~ 20%, inhibiter 2.5 ~ 10%, thionamic acid 0.1 ~ 5%, ethylene diamine tetra methylene phosphonic acid sodium 5 ~ 25%, all the other are de-mineralized water;
(2) raw material prepared in step (1) is added successively, stir, namely obtain clean-out system of the present invention.
The present invention compared with prior art has following beneficial effect:
(1) adopt in formula and wash dirt effective thionamic acid and ethylenediamine tetraacetic pitch Alendronate composite, reach dissolvings, peel off the effect of old dirt and removing welding slag, avoid that pipeline is dirty to be blocked up;
(2) utilize multiple inhibiter composite, strengthen the corrosion mitigating effect to various metals material;
(3) this product compares with imported relay agent, shows good inhibition, scale-inhibiting properties.
Clean-out system of the present invention utilize organic anti-scale composition and organic acid composite, effectively to peel off, the old dirt dissolved in household heating system equipment, to prevent from generating secondary incrustation scale simultaneously; This clean-out system effectively can not only reduce the corrosion to household heating system equipment metallic substance, effectively can also remove the incrustation scale, anvil cinder etc. of household heating system device interior, prevent the problems such as the low or water cycle blocking of the heat transfer efficiency of the household heating system caused because of fouling, run with making each equipment energy safety economy in whole household heating system, thus reach the object reducing water pollutions and save energy and reduce the cost.
Embodiment
Below by embodiment, the invention will be further described.
Embodiment 1
In the present embodiment the component of clean-out system and weight percent content as follows: propylene glycol 10%, benzotriazole 1.0%, 1-Hydroxy Ethylidene-1,1-Diphosphonic Acid 1.5%, thionamic acid 2.0%, ethylene diamine tetra methylene phosphonic acid sodium 15%, de-mineralized water surplus.
The component of above-mentioned weight percent content is added respectively, after stirring, obtains finished product.
The present embodiment finished product is brown color or weak yellow liquid, pH(strong solution) be 5.6 ± 0.2, proportion (g/ml, 20 DEG C) is 1.10 ± 0.10.
Experimental data: record with reference to GB/T25148-2010 " in industrial equipments matting descaling rate and clean rate testing method ", the descaling rate of this clean-out system is 95.2%; With reference to GB/T25147-2010 " in industrial equipments matting rate of metal corrosion and corrosion total amount testing method weighting method " record, this clean-out system to various corrosion of metal rate is: carbon steel: 1.76g/m
2h, stainless steel: 0.81g/m
2h, copper: 0.57g/m
2h, aluminium: 0.90g/m
2h, meets the regulation of GB/T25146 " industrial equipments matting inspection of quality code ".
Embodiment 2
In the present embodiment the component of clean-out system and weight percent content as follows: propylene glycol 10%, benzotriazole 1.5%, Sodium orthomolybdate 1.0%, thionamic acid 1.5%, ethylene diamine tetra methylene phosphonic acid sodium 18%, de-mineralized water surplus.
Its preparation method is with embodiment 1
Experimental data: record with reference to GB/T25148-2010 " in industrial equipments matting descaling rate and clean rate testing method ", the descaling rate of this clean-out system is 96.5%; With reference to GB/T25147-2010 " in industrial equipments matting rate of metal corrosion and corrosion total amount testing method weighting method " record, this clean-out system to various corrosion of metal rate is: carbon steel: 1.62g/m
2h, stainless steel: 0.63g/m
2h, copper: 0.61g/m
2h, aluminium: 0.85g/m
2h, meets the regulation of GB/T25146 " industrial equipments matting inspection of quality code ".
Embodiment 3
In the present embodiment, water quality protection agent contains component and weight percent content is as follows: propylene glycol 10%, benzotriazole 2.0%, 1-Hydroxy Ethylidene-1,1-Diphosphonic Acid 1.5%, thionamic acid 1.5%, ethylene diamine tetra methylene phosphonic acid sodium 15%, de-mineralized water surplus.
Preparation method is with embodiment 1
Experimental data: record with reference to GB/T25148-2010 " in industrial equipments matting descaling rate and clean rate testing method ", the descaling rate of this clean-out system is 97.1; With reference to GB/T25147-2010 " in industrial equipments matting rate of metal corrosion and corrosion total amount testing method weighting method " record, this clean-out system to various corrosion of metal rate is: carbon steel: 1.72g/m
2h, stainless steel: 0.61g/m
2h, copper: 0.54g/m
2h, aluminium: 0.87g/m
2h, meets the regulation of GB/T25146 " industrial equipments matting inspection of quality code ".
Embodiment 4
In the present embodiment, water quality protection agent contains component and weight percent content is as follows: propylene glycol 10%, benzotriazole 2.0%, Sodium orthomolybdate 1.0%, thionamic acid 1.0%, ethylene diamine tetra methylene phosphonic acid sodium 20%, de-mineralized water surplus.
Preparation method is with embodiment 1
Experimental data: record with reference to GB/T25148-2010 " in industrial equipments matting descaling rate and clean rate testing method ", the descaling rate of this clean-out system is 98.4%; With reference to GB/T25147-2010 " in industrial equipments matting rate of metal corrosion and corrosion total amount testing method weighting method " record, this clean-out system to various corrosion of metal rate is: carbon steel: 1.58g/m
2h, stainless steel: 0.63g/m
2h, copper: 0.55g/m
2h, aluminium: 0.76g/m
2h, meets the regulation of GB/T25146 " industrial equipments matting inspection of quality code ".
Embodiment 5
In the present embodiment, water quality protection agent contains component and weight percent content is as follows: propylene glycol 10%, benzotriazole 1.5%, Sodium orthomolybdate 1.5%, thionamic acid 1.0%, ethylene diamine tetra methylene phosphonic acid sodium 20%, de-mineralized water surplus.
Preparation method is with embodiment 1
Experimental data: record with reference to GB/T25148-2010 " in industrial equipments matting descaling rate and clean rate testing method ", the descaling rate of this clean-out system is 97.8%; With reference to GB/T25147-2010 " in industrial equipments matting rate of metal corrosion and corrosion total amount testing method weighting method " record, this clean-out system to various corrosion of metal rate is: carbon steel: 1.60g/m
2h, stainless steel: 0.57g/m
2h, copper: 0.56g/m
2h, aluminium: 0.81g/m
2h, meets the regulation of GB/T25146 " industrial equipments matting inspection of quality code ".
Above embodiment is used for illustrative purposes only, but not limitation of the present invention, person skilled in the relevant technique, without departing from the spirit and scope of the present invention, various conversion or modification can also be made, therefore all equivalent technical schemes also should belong to category of the present invention, should be limited by each claim.
Claims (2)
1. the clean-out system of household heating system for being made up of various metals material, it is characterized in that, it comprises the component of following weight percent content: propylene glycol 3 ~ 20%, inhibiter 2.5 ~ 10%, thionamic acid 0.1 ~ 5%, ethylene diamine tetra methylene phosphonic acid sodium 5 ~ 25%, all the other are de-mineralized water
Described inhibiter is at least two kinds in benzotriazole, 1-Hydroxy Ethylidene-1,1-Diphosphonic Acid and Sodium orthomolybdate.
2. a preparation method for the clean-out system of the household heating system for being made up of various metals material as claimed in claim 1, is characterized in that, comprise the following steps:
(1) prepare raw material according to following component and weight percent content: propylene glycol 3 ~ 20%, inhibiter 2.5 ~ 10%, thionamic acid 0.1 ~ 5%, ethylene diamine tetra methylene phosphonic acid sodium 5 ~ 25%, all the other are de-mineralized water;
(2) raw material prepared in step (1) is added successively, stir, namely obtain clean-out system of the present invention.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410122488.5A CN103834956B (en) | 2014-03-28 | 2014-03-28 | Clean-out system of a kind of household heating system for being made up of various metals material and preparation method thereof |
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| CN201410122488.5A CN103834956B (en) | 2014-03-28 | 2014-03-28 | Clean-out system of a kind of household heating system for being made up of various metals material and preparation method thereof |
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| CN103834956A CN103834956A (en) | 2014-06-04 |
| CN103834956B true CN103834956B (en) | 2016-02-03 |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104402126B (en) * | 2014-12-02 | 2016-03-23 | 天津开广工业水处理有限公司 | A kind of oil field special sterilizing inhibiter |
| CN109534520A (en) * | 2018-11-12 | 2019-03-29 | 深圳大学 | A kind of dish-washing machine Special scale remover and preparation method thereof |
| CN112978945A (en) * | 2020-12-31 | 2021-06-18 | 湖南伟方环保技术股份有限公司 | Special scale inhibitor for papermaking black liquor and preparation method thereof |
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| KR20040012135A (en) * | 2002-08-01 | 2004-02-11 | 에스케이케미칼주식회사 | Water treatmrnt composition, preparation method of the same and water treatment method using the same |
| CN101086065A (en) * | 2007-06-13 | 2007-12-12 | 长沙市永峰水质处理服务有限公司 | Descaling agent for cleaning central air conditioner main machine |
| CN101982542A (en) * | 2010-09-16 | 2011-03-02 | 吴龙生 | Special cleaning agent for three-way catalyst of vehicle |
| CN102358875A (en) * | 2011-09-29 | 2012-02-22 | 广东环凯微生物科技有限公司 | Novel acidic detergent for container of food industry |
| CN102633373A (en) * | 2012-04-19 | 2012-08-15 | 上海工业锅炉研究所 | Composite-type water quality protective agent for household heating system |
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2014
- 2014-03-28 CN CN201410122488.5A patent/CN103834956B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20040012135A (en) * | 2002-08-01 | 2004-02-11 | 에스케이케미칼주식회사 | Water treatmrnt composition, preparation method of the same and water treatment method using the same |
| CN101086065A (en) * | 2007-06-13 | 2007-12-12 | 长沙市永峰水质处理服务有限公司 | Descaling agent for cleaning central air conditioner main machine |
| CN101982542A (en) * | 2010-09-16 | 2011-03-02 | 吴龙生 | Special cleaning agent for three-way catalyst of vehicle |
| CN102358875A (en) * | 2011-09-29 | 2012-02-22 | 广东环凯微生物科技有限公司 | Novel acidic detergent for container of food industry |
| CN102633373A (en) * | 2012-04-19 | 2012-08-15 | 上海工业锅炉研究所 | Composite-type water quality protective agent for household heating system |
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Address after: Room 101 and 201, building 4, No. 138, xinjunhuan Road, Fengxian District, Shanghai, 201114 Patentee after: SHANGHAI INDUSTRIAL BOILER RESEARCH INSTITUTE Co.,Ltd. Address before: 200071 Shanghai city Zhabei District Baochang Road No. 297 Patentee before: SHANGHAI INDUSTRIAL BOILER Research Institute |
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Address after: 201114 Room 101 and 201, 4 building, 138 new Chun Ring Road, Minhang District, Shanghai. Patentee after: SHANGHAI INDUSTRIAL BOILER RESEARCH INSTITUTE Co.,Ltd. Address before: Room 101 and 201, building 4, No. 138, xinjunhuan Road, Fengxian District, Shanghai, 201114 Patentee before: SHANGHAI INDUSTRIAL BOILER RESEARCH INSTITUTE Co.,Ltd. |