CN103834431A - Pretreatment device of phenol-containing naphthalene oil fraction washing tower and washing treatment method - Google Patents
Pretreatment device of phenol-containing naphthalene oil fraction washing tower and washing treatment method Download PDFInfo
- Publication number
- CN103834431A CN103834431A CN201410118941.5A CN201410118941A CN103834431A CN 103834431 A CN103834431 A CN 103834431A CN 201410118941 A CN201410118941 A CN 201410118941A CN 103834431 A CN103834431 A CN 103834431A
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- CN
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- Prior art keywords
- naphthalene oil
- phenol fraction
- inner drum
- containing phenol
- body skin
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- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 title claims abstract description 174
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 title claims abstract description 77
- 238000005406 washing Methods 0.000 title claims abstract description 46
- 238000000034 method Methods 0.000 title claims abstract description 13
- 239000003513 alkali Substances 0.000 claims abstract description 38
- 230000009189 diving Effects 0.000 claims abstract description 18
- 238000003756 stirring Methods 0.000 claims abstract description 7
- 239000011259 mixed solution Substances 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 12
- 239000002585 base Substances 0.000 claims description 3
- 238000009792 diffusion process Methods 0.000 claims description 3
- 239000012530 fluid Substances 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 239000007921 spray Substances 0.000 claims description 3
- 239000007788 liquid Substances 0.000 abstract description 3
- 239000011280 coal tar Substances 0.000 description 4
- 150000001299 aldehydes Chemical class 0.000 description 3
- 238000004821 distillation Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000009835 boiling Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
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- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
The invention relates to a pretreatment device of a phenol-containing naphthalene oil fraction washing tower and a washing treatment method. The device comprises a mixer, wherein the outer shell of the mixer is a closed shell which encloses an inner cavity; an inner barrel is located in the inner cavity, and a circular cavity is formed between the inner barrel and the outer shell; an overflow plate is arranged on the top end part of the inner barrel, and a mixed liquid channel is arranged between the overflow plate and the outer shell; a phenol-containing naphthalene oil fraction distributor and an alkali liquor distributor are arranged at the bottom of the inner barrel; the phenol-containing naphthalene oil fraction distributor is connected with a phenol-containing naphthalene oil fraction conveying pump outside the mixer through a phenol-containing naphthalene oil fraction conveying pipeline; the alkali liquor distributor is connected with an alkali liquor conveying pump outside the mixer through an alkali liquor conveying pipeline; a diving stirring device is fixedly located in the inner barrel; a mixed liquid outlet is formed at the bottom of the circular cavity. According to the device and the method, phenol-containing naphthalene oil fraction and alkali liquor are prevented from respectively entering into the power to affect the pressure by fully mixing the phenol-containing naphthalene oil fraction and alkali liquor outside the washing tower, so that the washing tower interface is easy to stabilize.
Description
Technical field
The present invention relates to a kind of containing phenol fraction of naphthalene oil treatment unit and method for washing and processing, specifically washing tower pretreating device and method for washing and processing.
Background technology
Deeply add industry at coal tar, what in coal tar distillation process, coal tar distillation tower produced contains phenol fraction of naphthalene oil, containing phenol amount, generally in about 4.0-4.5%, the boiling point of such boiling point substance and naphthalene is close, very easily sneaks into NAPTHALENE FLAKES. (INDUSTRIAL GRADE） and affect quality product in the time of rectifying deep processing.For improving the quality of NAPTHALENE FLAKES. (INDUSTRIAL GRADE） and extracting these products, before rectifying deep processing, need to carry out alkali cleaning and pickling containing phenol fraction of naphthalene oil, to be reduced in below 0.5% containing phenol content in phenol fraction of naphthalene oil, and wash fraction of naphthalene oil and can be used as producing that NAPTHALENE FLAKES. (INDUSTRIAL GRADE） rectifying produces enters rectifying tower raw materials for production.Coal tar distillation out containing phenol fraction of naphthalene oil go out to exist in advance temperature be 70～80 DEG C containing in phenol naphtalene oil storage tank, then squeeze in washing tower by containing phenol fraction of naphthalene oil pump containing phenol fraction of naphthalene oil, 30% alkali lye joins in washing tower by lye pump, the fraction of naphthalene oil of washing of scrubber overhead discharge has been washed naphtalene oil groove from flowing into, as NAPTHALENE FLAKES. (INDUSTRIAL GRADE） system raw materials for production oil.Wash tower bottoms is discharged alkaline phenates, and alkaline phenates enters the alkaline phenates groove in medial launder district.
In washing tower, contain after phenol fraction of naphthalene oil fully mixes contact with 30% alkali lye of washing use and separate again, generate alkaline phenates containing aldehydes matter and alkaline reaction in phenol fraction of naphthalene oil.Remove and wash fraction of naphthalene oil through NAPTHALENE FLAKES. (INDUSTRIAL GRADE） rectification working process manufacture naphthalene or refined naphthalene product after aldehydes matter.Contacting effect containing phenol fraction of naphthalene oil with the mixing of 30% alkali lye is one of principal element affecting detersive efficiency.Now enter tower containing phenol fraction of naphthalene oil from washing tower middle and lower part, alkali lye enters tower from washing tower middle and upper part, mix through sparger, undercompounding, because two strands of liquid enter the pressure influence of tower, easily cause washing tower interface fluctuation, after processing when serious, washed and in fraction of naphthalene oil, taken more aldehydes matter out of, and then affected NAPTHALENE FLAKES. (INDUSTRIAL GRADE） rectifying product-NAPTHALENE FLAKES. (INDUSTRIAL GRADE） or refined naphthalene quality product.
Summary of the invention
The shortcoming existing in order to overcome above-mentioned prior art, the object of the present invention is to provide a kind of containing phenol fraction of naphthalene oil washing tower pretreating device and method for washing and processing, by mixing outward at washing tower with alkali lye containing phenol fraction of naphthalene oil, mix fully, the pressure influence of having avoided entering respectively containing phenol fraction of naphthalene oil and alkali lye tower, is easy to stablize washing tower interface.
One provided by the invention, containing phenol fraction of naphthalene oil washing tower pretreating device, comprises mixing tank, and described mixing tank comprises body skin, inner drum, diving mixing device; Described body skin is closure casing, surrounds inner chamber; Described inner drum is arranged in the inner chamber that body skin forms, and forms annular chamber between the outside surface of inner drum and the internal surface of body skin; Inner drum top oral area has been disposed radially a circle overflow plate, between the upper surface of overflow plate and the inner top surface of body skin, is spaced apart mixed solution passage; Described inner drum bottom is provided with containing phenol fraction of naphthalene oil sparger, alkaline liquor distributor; Described being connected to containing phenol fraction of naphthalene oil and carrying delivery side of pump through inner drum, body skin extension containing phenol fraction of naphthalene oil transport pipe of connecting containing phenol fraction of naphthalene oil sparger; The alkali lye transport pipe that described alkaline liquor distributor connects extends and is connected to alkali lye conveying delivery side of pump through inner drum, body skin; Described diving mixing device is arranged in inner drum, and diving mixing device is fixedly connected with the top of body skin; The bottom of described annular chamber is provided with mixture export.
Further: on described alkali lye transport pipe, to be provided with alkali lye transfer valve; Be provided with containing phenol fraction of naphthalene oil transfer valve described containing on phenol fraction of naphthalene oil transport pipe.
Further: described mixture export is connected to the entry to mixed solution of washing tower by mixed solution transport pipe.
Further: described diving mixing device is positioned at the top of inner drum.
Further: the base plate of body skin is spherical plate, between the outer bottom of described inner drum and the inner bottom surface of body skin, there is interval.
Further: the end face of described body skin is spherical plate.
One provided by the invention contains phenol fraction of naphthalene oil method for washing and processing: alkali lye is entered the inner drum inner bottom part of mixing tank by alkali lye transport pipe, alkaline liquor distributor; Meanwhile, containing phenol fraction of naphthalene oil by containing phenol fraction of naphthalene oil transport pipe, enter the inner drum inner bottom part of mixing tank containing phenol fraction of naphthalene oil sparger;
Diving mixing device work, makes the fluid in inner drum produce certain flow velocity, and sprays diffusion to surrounding at a certain angle in inner drum bottom, phase main flow band circlewise; Because main flow band flow velocity is larger, around it, form regions of turbulent flow, impel the material in whole mixing reactor to stir up and down mixing, increase thing phase-contact surface, reach homogeneous;
The mixed solution stirring flow to annular chamber from the overflow plate at inner drum top; Through mixture export output, send into washing tower washing again.
The invention has the beneficial effects as follows:
(I) mixes outward containing phenol fraction of naphthalene oil and alkali lye process tower, mixes fully containing phenol fraction of naphthalene oil and alkali lye, expands contact area and reaction times containing phenol fraction of naphthalene oil and alkali lye, improves detersive efficiency.
(II) is stable, and washing tower interface is easy to control, and reduces and has washed phenol content in fraction of naphthalene oil, and manipulation is convenient.
(III) makes full use of former technique power, do not increase energy consumption.
Brief description of the drawings
Below in conjunction with drawings and Examples, the present invention is described further:
Fig. 1 is a kind of structural representation containing phenol fraction of naphthalene oil washing tower pretreating device embodiment of the present invention;
Fig. 2 is a kind of structural representation containing mixing tank in phenol fraction of naphthalene oil washing tower pretreating device of the present invention;
In figure: 1 alkali lye transferpump, 2 containing phenol fraction of naphthalene oil transferpump,
3 mixing tanks, 31 body skiies, 32 inner drums, 33 diving mixing devices, 34 annular chambers, 35 overflow plates, 36 mixed solution passages, 37 containing phenol fraction of naphthalene oil sparger, 38 alkaline liquor distributors, 39 containing phenol fraction of naphthalene oil transport pipe, 310,311 alkali lye transport pipes, 312 mixture exports
4 washing towers, 5 alkali lye transfer valves, 6 containing phenol fraction of naphthalene oil transfer valve, 7 mixed solution transport pipes.
Embodiment
As shown in Figure 1, should, containing phenol fraction of naphthalene oil washing tower pretreating device, comprise mixing tank 3,1 alkali lye transferpumps, 2 containing phenol fraction of naphthalene oil transferpump,
As shown in Figure 2, described mixing tank 3 comprises body skin 31, inner drum 32, diving mixing device 33; Described body skin 31 is closure casing, surrounds inner chamber; Described inner drum 32 is arranged in the inner chamber that body skin forms, and forms annular chamber 34 between the outside surface of inner drum 32 and the internal surface of body skin 31; Inner drum 32 top oral areas have been disposed radially a circle overflow plate 35, between the upper surface of overflow plate 35 and the inner top surface of body skin 31, are spaced apart mixed solution passage 36; Described inner drum 32 bottoms are provided with containing phenol fraction of naphthalene oil sparger 37, alkaline liquor distributor 38; The described phenol fraction of naphthalene oil transport pipe 39 that contains connecting containing phenol fraction of naphthalene oil sparger 37 extends through inner drum 32, body skin 31 output terminal being connected to containing phenol fraction of naphthalene oil transferpump 2; The alkali lye transport pipe 311 that described alkaline liquor distributor 38 connects extends through inner drum 32, body skin 31 output terminal that is connected to alkali lye transferpump 2; Described diving mixing device 33 is arranged in inner drum 32, and diving mixing device 33 is fixedly connected with the top of body skin 31; The bottom of described annular chamber 34 is provided with mixture export 312.
Diving mixing device is prior art, can directly obtain.Also be prior art containing phenol fraction of naphthalene oil sparger 37, alkaline liquor distributor 38.Shown in Fig. 2, be positioned at same plane containing phenol fraction of naphthalene oil sparger 37, alkaline liquor distributor 38, in Fig. 2, can not distinguish independent sparger, two spargers are arranged in a crossed manner.
This embodiment adopts further technical measures: on described alkali lye transport pipe 311, be provided with alkali lye transfer valve 5; Be provided with containing phenol fraction of naphthalene oil transfer valve 6 described containing on phenol fraction of naphthalene oil transport pipe 39.
This embodiment adopts further technical measures: described mixture export 312 is connected to the entry to mixed solution of washing tower 4 by mixed solution transport pipe 7.
This embodiment adopts further technical measures: described diving mixing device 33 is positioned at the top of inner drum 32.
This embodiment adopts further technical measures: the base plate of body skin 31 is spherical plate, between the outer bottom of described inner drum 32 and the inner bottom surface of body skin 31, has interval.
This embodiment adopts further technical measures: the end face of described body skin 31 is spherical plate.
The one of implementing based on said apparatus contains phenol fraction of naphthalene oil method for washing and processing:
Alkali lye is entered inner drum 32 inner bottom parts of mixing tank by alkali lye transport pipe 311, alkaline liquor distributor 38; Meanwhile, containing phenol fraction of naphthalene oil by containing phenol fraction of naphthalene oil transport pipe 39, enter inner drum 32 inner bottom parts of mixing tank containing phenol fraction of naphthalene oil sparger 37;
Diving mixing device 33 is worked, and makes the fluid in inner drum 32 produce certain flow velocity, and sprays diffusion to surrounding at a certain angle in inner drum 32 bottoms, phase main flow band circlewise; Because main flow band flow velocity is larger, around it, form regions of turbulent flow, impel the material in whole mixing reactor to stir up and down mixing, increase thing phase-contact surface, reach homogeneous;
The mixed solution stirring flow to annular chamber 34 from the overflow plate 35 at inner drum 32 tops; Export through mixture export 312 again, send into washing tower 4 and wash.
Claims (7)
1. containing a phenol fraction of naphthalene oil washing tower pretreating device, it is characterized in that: comprise mixing tank, described mixing tank comprises body skin, inner drum, diving mixing device; Described body skin is closure casing, surrounds inner chamber; Described inner drum is arranged in the inner chamber that body skin forms, and forms annular chamber between the outside surface of inner drum and the internal surface of body skin; Inner drum top oral area has been disposed radially a circle overflow plate, between the upper surface of overflow plate and the inner top surface of body skin, is spaced apart mixed solution passage; Described inner drum bottom is provided with containing phenol fraction of naphthalene oil sparger, alkaline liquor distributor; Described being connected to containing phenol fraction of naphthalene oil and carrying delivery side of pump through inner drum, body skin extension containing phenol fraction of naphthalene oil transport pipe of connecting containing phenol fraction of naphthalene oil sparger; The alkali lye transport pipe that described alkaline liquor distributor connects extends and is connected to alkali lye conveying delivery side of pump through inner drum, body skin; Described diving mixing device is arranged in inner drum, and diving mixing device is fixedly connected with the top of body skin; The bottom of described annular chamber is provided with mixture export.
2. one according to claim 1, containing phenol fraction of naphthalene oil washing tower pretreating device, is characterized in that: described mixture export is connected to the entry to mixed solution of washing tower by mixed solution transport pipe.
3. one according to claim 1 and 2, containing phenol fraction of naphthalene oil washing tower pretreating device, is characterized in that: on described alkali lye transport pipe, be provided with alkali lye transfer valve; Be provided with containing phenol fraction of naphthalene oil transfer valve described containing on phenol fraction of naphthalene oil transport pipe.
4. one according to claim 1, containing phenol fraction of naphthalene oil washing tower pretreating device, is characterized in that: described diving mixing device is positioned at the top of inner drum.
5. one according to claim 1, containing phenol fraction of naphthalene oil washing tower pretreating device, is characterized in that: the base plate of body skin is spherical plate having interval between the outer bottom of described inner drum and the inner bottom surface of body skin.
6. a kind of containing phenol fraction of naphthalene oil washing tower pretreating device according to claim 1 or 5, it is characterized in that: the end face of described body skin is spherical plate.
7. the one based on device described in claim 1, containing phenol fraction of naphthalene oil method for washing and processing, is characterized in that: alkali lye is entered the inner drum inner bottom part of mixing tank by alkali lye transport pipe, alkaline liquor distributor; Meanwhile, containing phenol fraction of naphthalene oil by containing phenol fraction of naphthalene oil transport pipe, enter the inner drum inner bottom part of mixing tank containing phenol fraction of naphthalene oil sparger;
Diving mixing device work, makes the fluid in inner drum produce certain flow velocity, and sprays diffusion to surrounding at a certain angle in inner drum bottom, phase main flow band circlewise; Because main flow band flow velocity is larger, around it, form regions of turbulent flow, impel the material in whole mixing reactor to stir up and down mixing, increase thing phase-contact surface, reach homogeneous;
The mixed solution stirring flow to annular chamber from the overflow plate at inner drum top; Through mixture export output, send into washing tower washing again.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410118941.5A CN103834431A (en) | 2014-03-27 | 2014-03-27 | Pretreatment device of phenol-containing naphthalene oil fraction washing tower and washing treatment method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410118941.5A CN103834431A (en) | 2014-03-27 | 2014-03-27 | Pretreatment device of phenol-containing naphthalene oil fraction washing tower and washing treatment method |
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| Publication Number | Publication Date |
|---|---|
| CN103834431A true CN103834431A (en) | 2014-06-04 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410118941.5A Pending CN103834431A (en) | 2014-03-27 | 2014-03-27 | Pretreatment device of phenol-containing naphthalene oil fraction washing tower and washing treatment method |
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| CN (1) | CN103834431A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107201627A (en) * | 2016-03-16 | 2017-09-26 | 青岛海尔洗衣机有限公司 | A kind of washing machine inner tub and washing machine |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3544079A (en) * | 1958-02-06 | 1970-12-01 | Saint Gobain Techn Nouvelles | Apparatus for mixing liquids |
| CN1116963A (en) * | 1994-04-19 | 1996-02-21 | 小久夫 | Element of mixing apparatus and making of same |
| CN101402881A (en) * | 2008-07-09 | 2009-04-08 | 彭鸽威 | Method stabilizing color of prime city naphtha |
| CN201268817Y (en) * | 2008-09-18 | 2009-07-08 | 四川正中路面科技有限公司 | Premixing system of rubber asphalt production facility |
| CN101613619A (en) * | 2008-06-25 | 2009-12-30 | 中国石油化工集团公司 | A kind of method that removes phenoxy compounds in the solvent oil |
| CN203768308U (en) * | 2014-03-27 | 2014-08-13 | 济钢集团有限公司 | Pretreating device of phenol-containing naphthalene oil fraction scrubbing tower |
-
2014
- 2014-03-27 CN CN201410118941.5A patent/CN103834431A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3544079A (en) * | 1958-02-06 | 1970-12-01 | Saint Gobain Techn Nouvelles | Apparatus for mixing liquids |
| CN1116963A (en) * | 1994-04-19 | 1996-02-21 | 小久夫 | Element of mixing apparatus and making of same |
| CN101613619A (en) * | 2008-06-25 | 2009-12-30 | 中国石油化工集团公司 | A kind of method that removes phenoxy compounds in the solvent oil |
| CN101402881A (en) * | 2008-07-09 | 2009-04-08 | 彭鸽威 | Method stabilizing color of prime city naphtha |
| CN201268817Y (en) * | 2008-09-18 | 2009-07-08 | 四川正中路面科技有限公司 | Premixing system of rubber asphalt production facility |
| CN203768308U (en) * | 2014-03-27 | 2014-08-13 | 济钢集团有限公司 | Pretreating device of phenol-containing naphthalene oil fraction scrubbing tower |
Non-Patent Citations (1)
| Title |
|---|
| 王曾秀: "提高工业萘一级品率的试验", 《武钢技术》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107201627A (en) * | 2016-03-16 | 2017-09-26 | 青岛海尔洗衣机有限公司 | A kind of washing machine inner tub and washing machine |
| CN107201627B (en) * | 2016-03-16 | 2020-04-21 | 天津海尔洗涤电器有限公司 | A washing machine inner tub and washing machine |
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Application publication date: 20140604 |