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CN103834278A - Safety environment-friendly wear-resistant ultraviolet curing coating and preparation method thereof - Google Patents

Safety environment-friendly wear-resistant ultraviolet curing coating and preparation method thereof Download PDF

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Publication number
CN103834278A
CN103834278A CN201410075434.8A CN201410075434A CN103834278A CN 103834278 A CN103834278 A CN 103834278A CN 201410075434 A CN201410075434 A CN 201410075434A CN 103834278 A CN103834278 A CN 103834278A
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China
Prior art keywords
parts
bamboo charcoal
minute
nano
wear
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Granted
Application number
CN201410075434.8A
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Chinese (zh)
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CN103834278B (en
Inventor
汤广顺
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Beijing Qingxin coating Co., Ltd.
Original Assignee
Wuhu Edison Automation Equipment Co Ltd
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Priority to CN201410075434.8A priority Critical patent/CN103834278B/en
Publication of CN103834278A publication Critical patent/CN103834278A/en
Application granted granted Critical
Publication of CN103834278B publication Critical patent/CN103834278B/en
Expired - Fee Related legal-status Critical Current
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency

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Abstract

The invention discloses a safety environment-friendly wear-resistant ultraviolet curing coating which is characterized by being prepared from the following active ingredients in parts by weight: 50-53 parts of polyester acrylate, 10-13 parts of 1,6-hexamethylene diacrylate, 7-9 parts of methoxy polyethylene glycol methacrylate, 3-4 parts of photoinitiator, 13-15 parts of dipentaerythritol hexaacrylate, 9-12 parts of butyl acetate, 1-2 parts of polymethylphenyl silicone, 1-2 parts of antioxidant, 7-9 parts of nano bentonite, 2-3 parts of nanoscale bamboo charcoal, 1-2 parts of IPBC (iodopropynyl butylcarbamate), and 4-5 parts of auxiliaries. Due to the added nano bentonite and nanoscale bamboo charcoal, the dispersion property is good and the mobility is enhanced, and the nanoscale bamboo charcoal powder has excellent electromagnetic shielding action, can release negative ions and far infrared rays, thus being safe and harmless to a human body; due to addition of auxiliaries, the leveling property is good, the coated film is good in adhesion force, large in hardness, wear-resistant and energy-saving and environment-friendly.

Description

A kind of safety and environmental protection wear-resistant ultraviolet ray solidified paint and preparation method thereof
Technical field
The present invention relates to a kind of coating and preparation method thereof, particularly a kind of safety and environmental protection wear-resistant ultraviolet ray solidified paint and preparation method thereof.
Background technology
The coating material solidified comparatively proven technique that become of UV, particularly, along with the raising of people's environmental consciousness, production and researchist note the development and application that UV is coating material solidified more.UV is coating material solidified is a kind of environmental type coating, it meets " 4E " principle completely, it is thermofixation 1/5 that general UV solidifies energy consumption, and UV is coating material solidified less containing volatiles, pollute little, attract most researchist and developer to be that UV is coating material solidified can reduce raw materials consumption, be conducive to reduce Financial cost.
Current UV solidify material is various, but still in various degree exist some problems, coating material solidified, the generation string stress large through photocuring post-shrinkage ratio of existing UV, cause that film is crisp, sticking power and the shortcoming such as impact resistance is poor and the snappiness of film is poor and hardness is low, not corrosion-resistant, easy xanthochromia is aging, this series of problems all need to continue improvement for different purposes, reduce production costs, expand purposes.
Summary of the invention
The object of this invention is to provide a kind of safety and environmental protection wear-resistant ultraviolet ray solidified paint and preparation method thereof.
In order to realize object of the present invention, the present invention passes through following scheme implementation:
A kind of safety and environmental protection wear-resistant ultraviolet ray solidified paint, is made up of the raw material of following weight part: polyester acrylate 50-53,1,6-hexanediyl ester 10-13, methoxy polyethylene glycol methacrylate-styrene polymer 7-9, light trigger 2959 3-4, double pentaerythritol methacrylate 13-15, N-BUTYL ACETATE 9-12, PSI 1-2, antioxidant 1010 1-2, nano-bentonite 7-9, nano bamboo carbon powder 2-3, IPBC 1-2, auxiliary agent 4-5;
Described auxiliary agent is made up of the raw material of following weight part: barite 10-13, bamboo charcoal 5-7, nano silicon 5-7, epoxy soybean oil 1-2, lemon quintessence oil 0.1-0.2, lauric acid methacrylic ester 4-6, Hydroxyethyl acrylate 3-5, silane coupling agent KH560 2-3, hydroxyethyl methylacrylate 20-24; Preparation method puts into calcining furnace by barite to calcine 3-4 hour at 520-540 DEG C, takes out, and is ground into 50-100 object mixed powder together with bamboo charcoal, nano silicon; All the other remaining components are mixed, be heated to 50-60 DEG C, stir and add mixed powder after 30-45 minute, 1-1.5 hour is ground in insulation, to obtain final product.
A kind of safety and environmental protection wear-resistant ultraviolet ray solidified paint of the present invention, made by following concrete steps:
(1) polyester acrylate, 1,6-hexanediyl ester, methoxy polyethylene glycol methacrylate-styrene polymer are put into reactor and stirred, be heated to 75-85 DEG C, stir 15-20 minute;
(2) add all the other remaining components except light trigger 2959, continue stirring reaction 30-40 minute, make it to be uniformly dispersed;
(3) be finally cooled to 45-55 DEG C, add light trigger 2959, stirring reaction 20-25 minute, cooling after, grind obtain 20-40 μ m slurry, to obtain final product.
The invention has the beneficial effects as follows: the present invention adds nano-bentonite, nano bamboo carbon powder, good dispersity has increased mobility, and nano bamboo carbon powder has good electromagnetic shielding action, and can anion releasing and far infrared rays, harmless to human-body safety; Add auxiliary agent, good leveling property, film adhesive is good, and hardness is large, wear-resisting, energy-conserving and environment-protective.
Specific embodiments
Below by specific examples, the present invention is described in detail.
A kind of safety and environmental protection wear-resistant ultraviolet ray solidified paint, by following weight part (kilogram) raw material make: polyester acrylate 50,1,6-hexanediyl ester 10, methoxy polyethylene glycol methacrylate-styrene polymer 7, light trigger 2,959 3, double pentaerythritol methacrylate 13, N-BUTYL ACETATE 9, PSI 1, antioxidant 1010 1, nano-bentonite 7, nano bamboo carbon powder 2, IPBC 1, auxiliary agent 4;
Described auxiliary agent by following weight part (kilogram) raw material make: barite 10, bamboo charcoal 5, nano silicon 5, epoxy soybean oil 1, lemon quintessence oil 0.1, lauric acid methacrylic ester 4, Hydroxyethyl acrylate 3, silane coupling agent KH560 2, hydroxyethyl methylacrylate 20; Preparation method puts into calcining furnace by barite to calcine 3-4 hour at 520-540 DEG C, takes out, and is ground into 50-100 object mixed powder together with bamboo charcoal, nano silicon; All the other remaining components are mixed, be heated to 50-60 DEG C, stir and add mixed powder after 30-45 minute, 1-1.5 hour is ground in insulation, to obtain final product.
A kind of safety and environmental protection wear-resistant ultraviolet ray solidified paint of the present invention, made by following concrete steps:
(1) polyester acrylate, 1,6-hexanediyl ester, methoxy polyethylene glycol methacrylate-styrene polymer are put into reactor and stirred, be heated to 75-85 DEG C, stir 15-20 minute;
(2) add all the other remaining components except light trigger 2959, continue stirring reaction 30-40 minute, make it to be uniformly dispersed;
(3) be finally cooled to 45-55 DEG C, add light trigger 2959, stirring reaction 20-25 minute, cooling after, grind obtain 20-40 μ m slurry, to obtain final product.
This coating can adopt the form of construction work of roller coating, showering, spraying to construct.The paint spraying making by above scheme sticking power on plank is all better than secondary, resistance to 75% ethanol is more than 24 hours, alkaline-resisting 24 hours above, acidproof more than 48 hours, the cold cycling that tolerates subzero 40 degree and 40 degree does not ftracture for 10 times, resistance to 15% salt solution is more than 60 hours, hardness can regulate between 3H at 2H, and abrasion resistance index turns above 3700.

Claims (2)

1. a safety and environmental protection wear-resistant ultraviolet ray solidified paint, it is characterized in that, made by the raw material of following weight part: polyester acrylate 50-53,1,6-hexanediyl ester 10-13, methoxy polyethylene glycol methacrylate-styrene polymer 7-9, light trigger 2959 3-4, double pentaerythritol methacrylate 13-15, N-BUTYL ACETATE 9-12, PSI 1-2, antioxidant 1010 1-2, nano-bentonite 7-9, nano bamboo carbon powder 2-3, IPBC 1-2, auxiliary agent 4-5;
Described auxiliary agent is made up of the raw material of following weight part: barite 10-13, bamboo charcoal 5-7, nano silicon 5-7, epoxy soybean oil 1-2, lemon quintessence oil 0.1-0.2, lauric acid methacrylic ester 4-6, Hydroxyethyl acrylate 3-5, silane coupling agent KH560 2-3, hydroxyethyl methylacrylate 20-24; Preparation method puts into calcining furnace by barite to calcine 3-4 hour at 520-540 DEG C, takes out, and is ground into 50-100 object mixed powder together with bamboo charcoal, nano silicon; All the other remaining components are mixed, be heated to 50-60 DEG C, stir and add mixed powder after 30-45 minute, 1-1.5 hour is ground in insulation, to obtain final product.
2. a kind of safety and environmental protection wear-resistant ultraviolet ray solidified paint according to claim 1, is characterized in that, is made up of following concrete steps:
(1) polyester acrylate, 1,6-hexanediyl ester, methoxy polyethylene glycol methacrylate-styrene polymer are put into reactor and stirred, be heated to 75-85 DEG C, stir 15-20 minute;
(2) add all the other remaining components except light trigger 2959, continue stirring reaction 30-40 minute, make it to be uniformly dispersed;
(3) be finally cooled to 45-55 DEG C, add light trigger 2959, stirring reaction 20-25 minute, cooling after, grind obtain 20-40 μ m slurry, to obtain final product.
CN201410075434.8A 2014-03-04 2014-03-04 A kind of safety and environmental protection wear-resistant ultraviolet ray solidified paint and preparation method thereof Expired - Fee Related CN103834278B (en)

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CN201410075434.8A CN103834278B (en) 2014-03-04 2014-03-04 A kind of safety and environmental protection wear-resistant ultraviolet ray solidified paint and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201410075434.8A CN103834278B (en) 2014-03-04 2014-03-04 A kind of safety and environmental protection wear-resistant ultraviolet ray solidified paint and preparation method thereof

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CN103834278A true CN103834278A (en) 2014-06-04
CN103834278B CN103834278B (en) 2016-05-25

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105368108A (en) * 2015-12-15 2016-03-02 湖州大周高分子材料有限公司 Anion photocureable coating
CN105678748A (en) * 2015-12-30 2016-06-15 清华大学 Interactive calibration method and apparatus based on three dimensional reconstruction in three dimensional monitoring system
CN106519755A (en) * 2016-11-16 2017-03-22 成都市创斯德机电设备有限公司 Wear-resistant ultraviolet-cured coating for optical fiber and preparation method thereof
CN109485886A (en) * 2018-09-29 2019-03-19 江苏芯力特电子科技有限公司 A kind of UV solidifies the preparation method of electric thin

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002040292A1 (en) * 2000-11-14 2002-05-23 Sung Soo Park The composition of uv-smelling in all sorts of cards
CN101921511A (en) * 2010-09-16 2010-12-22 珠海保税区天然宝杰数码科技材料有限公司 Ink composition for ink-jet printing
CN102220070A (en) * 2011-05-10 2011-10-19 上海富臣化工有限公司 Ultraviolet solidified yellowing resistant and glossy woodenware paint and application technology thereof
CN102533063A (en) * 2012-02-27 2012-07-04 江苏利田科技股份有限公司 Ultraviolet ray-curable low-gloss flow-coating paint and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002040292A1 (en) * 2000-11-14 2002-05-23 Sung Soo Park The composition of uv-smelling in all sorts of cards
CN101921511A (en) * 2010-09-16 2010-12-22 珠海保税区天然宝杰数码科技材料有限公司 Ink composition for ink-jet printing
CN102220070A (en) * 2011-05-10 2011-10-19 上海富臣化工有限公司 Ultraviolet solidified yellowing resistant and glossy woodenware paint and application technology thereof
CN102533063A (en) * 2012-02-27 2012-07-04 江苏利田科技股份有限公司 Ultraviolet ray-curable low-gloss flow-coating paint and preparation method thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105368108A (en) * 2015-12-15 2016-03-02 湖州大周高分子材料有限公司 Anion photocureable coating
CN105678748A (en) * 2015-12-30 2016-06-15 清华大学 Interactive calibration method and apparatus based on three dimensional reconstruction in three dimensional monitoring system
CN105678748B (en) * 2015-12-30 2019-01-15 清华大学 Interactive calibration method and device in three-dimension monitoring system based on three-dimensionalreconstruction
CN106519755A (en) * 2016-11-16 2017-03-22 成都市创斯德机电设备有限公司 Wear-resistant ultraviolet-cured coating for optical fiber and preparation method thereof
CN109485886A (en) * 2018-09-29 2019-03-19 江苏芯力特电子科技有限公司 A kind of UV solidifies the preparation method of electric thin

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Publication number Publication date
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Inventor after: Tian Yaguang

Inventor before: Tang Guangshun

COR Change of bibliographic data
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Effective date of registration: 20170113

Address after: 100000 Beijing city Changping District Xiaotangshan town Lai Ma Village South

Patentee after: Beijing Qingxin coating Co., Ltd.

Address before: 241200 Anhui city of Wuhu province Fanchang Sunshine City Garden Building 406 room 3

Patentee before: Wuhu Edison Automation Equipment Co., Ltd.

CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20160525

Termination date: 20180304