CN103823257B - A kind of anti-blue light optical diffusion - Google Patents
A kind of anti-blue light optical diffusion Download PDFInfo
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- CN103823257B CN103823257B CN201410032899.5A CN201410032899A CN103823257B CN 103823257 B CN103823257 B CN 103823257B CN 201410032899 A CN201410032899 A CN 201410032899A CN 103823257 B CN103823257 B CN 103823257B
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- blue light
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- containing metal
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- 238000009792 diffusion process Methods 0.000 title claims abstract description 51
- 230000003287 optical effect Effects 0.000 title claims abstract description 31
- 150000004696 coordination complex Chemical class 0.000 claims abstract description 25
- 239000000975 dye Substances 0.000 claims abstract description 25
- 239000000463 material Substances 0.000 claims abstract description 22
- 239000011248 coating agent Substances 0.000 claims abstract description 15
- 238000000576 coating method Methods 0.000 claims abstract description 15
- 239000011347 resin Substances 0.000 claims abstract description 15
- 229920005989 resin Polymers 0.000 claims abstract description 15
- 239000011325 microbead Substances 0.000 claims abstract description 6
- 239000012530 fluid Substances 0.000 claims description 13
- -1 polyethylene Polymers 0.000 claims description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- 239000004925 Acrylic resin Substances 0.000 claims description 2
- 229920000178 Acrylic resin Polymers 0.000 claims description 2
- 239000004698 Polyethylene Substances 0.000 claims description 2
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 2
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 claims description 2
- 229920006284 nylon film Polymers 0.000 claims description 2
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 2
- 229920000058 polyacrylate Polymers 0.000 claims description 2
- 229920006289 polycarbonate film Polymers 0.000 claims description 2
- 229920000728 polyester Polymers 0.000 claims description 2
- 229920006267 polyester film Polymers 0.000 claims description 2
- 229920001225 polyester resin Polymers 0.000 claims description 2
- 239000004645 polyester resin Substances 0.000 claims description 2
- 229920000570 polyether Polymers 0.000 claims description 2
- 229920000573 polyethylene Polymers 0.000 claims description 2
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 2
- 229920001296 polysiloxane Polymers 0.000 claims description 2
- 229920005749 polyurethane resin Polymers 0.000 claims description 2
- 239000004800 polyvinyl chloride Substances 0.000 claims description 2
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 2
- 239000004793 Polystyrene Substances 0.000 claims 1
- 238000006116 polymerization reaction Methods 0.000 claims 1
- 229920002223 polystyrene Polymers 0.000 claims 1
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 claims 1
- 230000004888 barrier function Effects 0.000 abstract description 6
- 230000006378 damage Effects 0.000 abstract description 4
- 208000027418 Wounds and injury Diseases 0.000 abstract description 2
- 230000002401 inhibitory effect Effects 0.000 abstract description 2
- 208000014674 injury Diseases 0.000 abstract description 2
- 239000000758 substrate Substances 0.000 abstract 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 8
- 239000005020 polyethylene terephthalate Substances 0.000 description 8
- 238000012360 testing method Methods 0.000 description 6
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- 238000005286 illumination Methods 0.000 description 2
- 239000003595 mist Substances 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 208000020564 Eye injury Diseases 0.000 description 1
- 206010047513 Vision blurred Diseases 0.000 description 1
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- 238000010422 painting Methods 0.000 description 1
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- Optical Elements Other Than Lenses (AREA)
- Optical Filters (AREA)
Abstract
The invention discloses a kind of anti-blue light optical diffusion, it includes base material and anchors at the anti-blue light diffusion layer that base material single face or two surfaces are formed and constitute, anti-blue light diffusion layer be by resin microbeads, resin containing metal complex class dyestuff coating solution set on substrate surface;The present invention is by controlling thickness and the concentration of added metal complex class dyestuff of anti-blue light diffusion layer, change the anti-blue light optical diffusion rejection rate to blue light, this anti-blue light diffusion barrier is made to have the inhibitory action to blue light, the present invention is inhibited to the light of wavelength 380 500 nanometer, greatly reduces the blue light injury to the eyes of people.
Description
Technical field
The present invention relates to a kind of for flat panel display screen or illuminating anti-blue light optical diffusion.
Background technology
The effect of optical diffusion is that the light of spot light or line source uniformly diffuses into homogeneous, the face light of high brightness
Source.This optical diffusion is widely used in backlight module and the novel illumination light source of flat-panel monitor, as
TV, computer monitor, notebook computer, mobile phone, digital camera, MP4 player, GPS navigator
And various daily and industrial lighting source etc..
And high energy shortwave blue light is non-to the eye injury of people in the light that these displays or light source send in use
Chang great.Shortwave blue light refers to visible ray medium wavelength light between 380 nanometers to 500 nanometers.
Shortwave blue light has very high energies, it is possible to penetrates crystalline lens and goes directly retina.Blue light illumination retina can produce
Raw free radical, and these free radicals can cause retinal pigment epithelium to become feeble and die, the decline of epithelial cell can be led
Cause photaesthesia cell lacks nutrient thus causes vision impairment, and these damages are irreversible.If irradiated
Time more than 10 seconds, its Main Function of this damaging mechanisms, and be pyrolytic damage several times more than.
Blue light results in the main cause of digital visual fatigue (DEF) just.Luminous ray focuses within the eye
Back focus is different, can form focal length poor between bifocal.This is the main cause forming blurred vision.Long
Time visual fatigue can cause other fatigue symptoms.Injecting of blue light can aggravate focal length difference and the dimness of vision
Degree.Being because blue light after over-focusing, focus does not falls within retina, but falls at retina with crystalline
Between body, increase the focal length that light focuses within the eye poor.
Generally, ordinary optical diffusion barrier is only to complete the diffusion to light, and for electronic curtain
Or the blue light produced during light source luminescent, there is no any safeguard measure, human eye is exposed to high-octane shortwave
In blue light, the eye health of people is constituted very big hidden danger.
So needing a kind of product, there is the effect intercepting blue light, the most do not affect the basic function of diffusion barrier.
Summary of the invention
The present invention, for overcoming the defect of existing product, has the effect of suppression blue light, excellent optics diffusivity
Energy.
For solving above-mentioned technical problem, the technical solution used in the present invention is:
Anti-blue light optical diffusion, it includes base material and is bonded to the anti-blue light diffusion of base material one or two sides
Layer, containing optical diffusant, anti-blue light resin in described anti-blue light diffusion layer.
Described base material is that polyester film, polycarbonate film, nylon film, polyethylene film, polyvinyl chloride are thin
One in film, base material thickness is 18-200 micron.
Described anti-blue light diffusion layer is by being 1:0.2-6 resin microbeads, the painting of anti-blue light resin containing mass ratio
Cloth liquid anchors at formation on the surface of described base material, and the thickness of anti-blue light diffusion layer is 10-50 micron.
Described anti-blue light resin is selected from the acrylic resin containing metal complex class dyestuff, containing metal complex class dye
The polyester resin of material, the polyurethane resin containing metal complex class dyestuff, containing the epoxy of metal complex class dyestuff
Acrylate, containing the ultraviolet curing acrylic resinoid of metal complex class dyestuff, including passing through ultraviolet
The urethane acrylate containing metal complex class dyestuff of photocuring, containing the polyester third of metal complex class dyestuff
Olefin(e) acid ester, containing the polyether acrylate of metal complex class dyestuff, containing the pure acrylic acid of metal complex class dyestuff
Ester, containing the organic siliconresin of metal complex class dyestuff.
Described optical diffusant is resin microbeads, can be polyacrylate, polymethyl methacrylate, polyphenyl
One in ethene or polysiloxanes, average grain diameter is 1-40 micron.
Described anti-blue light optical diffusant is inhibited to the light of wavelength 380-500 nanometer;Make to prevent
Blue light optical diffusion barrier has iris action to blue light, ensures that the optics diffusion of diffusion barrier reaches to use simultaneously
Requirement.
The present invention can be by regulating the thickness of anti-blue light diffusion layer and the dense of added metal complex class dyestuff
Degree, changes the anti-blue light optical diffusion rejection rate to blue light, and excursion is 10~70%.
Advantages of the present invention:
The present invention, by controlling concentration and the thickness of coating of the metal complex class dyestuff of interpolation in resin, makes
Obtain this anti-blue light diffusion barrier and there is the inhibitory action to blue light;The present invention light to wavelength 380~500 nanometer
Inhibited, greatly reduce the blue light injury to the eyes of people.
Accompanying drawing explanation
The structural representation of the anti-blue light optical diffusion of Fig. 1 present invention.
1, optical diffusant, 2, anti-blue light resin, 3, base material.
Detailed description of the invention
Below by embodiment, the present invention is described further:
Embodiment 1
The preparation of diffusion layer coating fluid:
Above-mentioned material stirring is mixed, prepares optical diffusion layer coating fluid.
Using polyethylene terephthalate (PET) that thickness is 100 microns, film is as base material, at one
Diffusion layer coating fluid in topcoating, heated-air drying makes its build be about 10 microns.Make anti-blue light optics to expand
Dissipate film, test its performance.
Embodiment 2
The preparation of diffusion layer coating fluid:
Above-mentioned material stirring is mixed, prepares optical diffusion layer coating fluid.
Using polyethylene terephthalate (PET) that thickness is 100 microns, film is as base material, at one
Diffusion layer coating fluid in topcoating, heated-air drying makes its build be about 10 microns.Make anti-blue light optics to expand
Dissipate film, test its performance.
Embodiment 3
The preparation of diffusion layer coating fluid:
Above-mentioned material stirring is mixed, prepares optical diffusion layer coating fluid.
Using polyethylene terephthalate (PET) that thickness is 100 microns, film is as base material, at one
Diffusion layer coating fluid in topcoating, heated-air drying makes its build be about 10 microns, and through 450mj/cm2's
Ultraviolet irradiates, and makes anti-blue light optical diffusion, tests its performance.
Embodiment 4
The preparation of diffusion layer coating fluid:
Above-mentioned material stirring is mixed, prepares optical diffusion layer coating fluid.
Using polyethylene terephthalate (PET) that thickness is 100 microns, film is as base material, at one
Diffusion layer coating fluid in topcoating, heated-air drying makes its build be about 10 microns, and through 450mj/cm2's
Ultraviolet irradiates, and makes anti-blue light optical diffusion, tests its performance.
The method of testing of product resistance blue light performance is as follows:
Use spectrophotometer test 380~500 nano waveband light source transmitance, i.e. blue light rejection rates;
Use photoelectricity mist degree instrument test transmitance and mist degree.
Table 1: product properties table
From table 1 it follows that after using the resin microbeads containing metal complex class dyestuff, anti-blue light optical diffusion
Blue light is had obvious iris action, and does not interferes with the blue color effect of screen color, ensure product light simultaneously
Learn diffusion effect.
Claims (5)
1. an anti-blue light optical diffusion, it is characterised in that: it includes base material and is bonded to the anti-blue light diffusion layer of base material one or two sides, containing optical diffusant, anti-blue light resin in described anti-blue light diffusion layer;
Described anti-blue light diffusion layer is to be anchored at by the coating fluid containing the resin microbeads that mass ratio is 1:0.2-6 Yu anti-blue light resin to be formed on the surface of described base material, and the thickness of anti-blue light diffusion layer is 10-50 micron.
Anti-blue light optical diffusion the most according to claim 1, it is characterised in that described base material is the one in polyester film, polycarbonate film, nylon film, polyethylene film, polyvinyl chloride film, base material thickness is 18-200 micron.
Anti-blue light optical diffusion the most according to claim 1, it is characterized in that, described anti-blue light resin is selected from the acrylic resin containing metal complex class dyestuff, polyester resin containing metal complex class dyestuff, polyurethane resin containing metal complex class dyestuff, epoxy acrylate containing metal complex class dyestuff, ultraviolet curing acrylic resinoid containing metal complex class dyestuff, by the urethane acrylate containing metal complex class dyestuff of ultraviolet light polymerization, polyester acrylate containing metal complex class dyestuff, polyether acrylate containing metal complex class dyestuff, pure acrylate containing metal complex class dyestuff, the one in organic siliconresin containing metal complex class dyestuff.
Anti-blue light optical diffusion the most according to claim 1, it is characterised in that described optical diffusant is resin microbeads, is the one in polyacrylate, polymethyl methacrylate, polystyrene or polysiloxanes, and average grain diameter is 1-40 micron.
Anti-blue light optical diffusion the most according to claim 1, it is characterised in that described anti-blue light optical diffusant is inhibited to the light of wavelength 380-500 nanometer.
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CN201410032899.5A CN103823257B (en) | 2014-01-23 | 2014-01-23 | A kind of anti-blue light optical diffusion |
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CN201410032899.5A CN103823257B (en) | 2014-01-23 | 2014-01-23 | A kind of anti-blue light optical diffusion |
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CN103823257A CN103823257A (en) | 2014-05-28 |
CN103823257B true CN103823257B (en) | 2016-08-17 |
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Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
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CN104570173A (en) * | 2014-12-11 | 2015-04-29 | 太湖金张科技股份有限公司 | Blue-light-proof optical diffusion structures and backlight device |
CN105988231A (en) * | 2015-01-29 | 2016-10-05 | 同昌光学股份有限公司 | Blue light filtering protective lens and manufacturing method thereof |
CN106291777B (en) * | 2015-05-19 | 2018-06-19 | 象山激智新材料有限公司 | The light-transmissive film or plate of a kind of anti-blue light and its application |
CN107976729A (en) * | 2016-10-21 | 2018-05-01 | 苏州今道创业投资有限公司 | A kind of optical diffusion film |
CN107283981B (en) * | 2017-07-05 | 2019-07-05 | 杨建� | A kind of blue light barrier film and preparation method thereof |
CN109553792A (en) * | 2017-09-25 | 2019-04-02 | 安徽屹珹新材料科技有限公司 | A kind of anti-blue light film of double optics coating and preparation method thereof |
CN107561608B (en) * | 2017-09-30 | 2023-07-21 | 凯鑫森(上海)功能性薄膜产业股份有限公司 | Low-blue light optical film for LED lighting device and preparation method thereof |
CN108680980B (en) * | 2018-07-10 | 2024-03-15 | 宁波激智科技股份有限公司 | Blue light prevention optical film and preparation method thereof |
CN111218078A (en) * | 2020-02-29 | 2020-06-02 | 华南理工大学 | Blue-light-proof fluorescent plate, preparation method thereof and blue-light-proof LED lighting lamp structure |
WO2022054933A1 (en) * | 2020-09-11 | 2022-03-17 | 大日本印刷株式会社 | Transparent laminated film, transparent laminated film with protection film, and face shield |
CN114690292B (en) * | 2020-12-28 | 2024-04-12 | 宁波激智科技股份有限公司 | Blue light prevention optical film and preparation method thereof |
CN113736352A (en) * | 2021-09-03 | 2021-12-03 | 宁波东旭成新材料科技有限公司 | Waterborne prevents blue light diffusion membrane |
CN115521523A (en) * | 2022-09-15 | 2022-12-27 | 青岛上雅家居用品股份有限公司 | Hose with blue light prevention function and preparation method thereof |
Family Cites Families (5)
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KR101082898B1 (en) * | 2005-05-25 | 2011-11-11 | 삼성전자주식회사 | Backlight assembly and liquid crystal display apparatus having the same |
JP2009237148A (en) * | 2008-03-26 | 2009-10-15 | Asahi Kasei Corp | Light diffusion sheet and backlight unit |
CN103439804B (en) * | 2013-09-04 | 2016-04-27 | 杏晖光学(厦门)有限公司 | A kind of anti-blue light eyeglass |
CN103465418B (en) * | 2013-09-10 | 2016-04-13 | 上海康耐特光学股份有限公司 | A kind of manufacture method of anti-blue light resin lens and product |
JP5965881B2 (en) * | 2013-10-03 | 2016-08-10 | 恵和株式会社 | Backlight unit for light diffusion sheet and liquid crystal display device |
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