CN103819976A - Coating material for diagnosis glass slide and preparation method for coating material - Google Patents
Coating material for diagnosis glass slide and preparation method for coating material Download PDFInfo
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- CN103819976A CN103819976A CN201410074553.1A CN201410074553A CN103819976A CN 103819976 A CN103819976 A CN 103819976A CN 201410074553 A CN201410074553 A CN 201410074553A CN 103819976 A CN103819976 A CN 103819976A
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- 239000000463 material Substances 0.000 title claims abstract description 45
- 239000011248 coating agent Substances 0.000 title claims abstract description 38
- 238000000576 coating method Methods 0.000 title claims abstract description 38
- 239000011521 glass Substances 0.000 title claims abstract description 27
- 238000002360 preparation method Methods 0.000 title abstract description 13
- 238000003745 diagnosis Methods 0.000 title description 10
- 229920005989 resin Polymers 0.000 claims abstract description 19
- 239000011347 resin Substances 0.000 claims abstract description 19
- 239000002245 particle Substances 0.000 claims abstract description 18
- 238000000034 method Methods 0.000 claims abstract description 16
- 239000000203 mixture Substances 0.000 claims abstract description 14
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229920001228 polyisocyanate Polymers 0.000 claims abstract description 9
- 239000005056 polyisocyanate Substances 0.000 claims abstract description 9
- 239000000843 powder Substances 0.000 claims abstract description 7
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 4
- 239000003085 diluting agent Substances 0.000 claims abstract 3
- 239000001023 inorganic pigment Substances 0.000 claims abstract 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical group O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 12
- 239000002994 raw material Substances 0.000 claims description 11
- 229920002545 silicone oil Polymers 0.000 claims description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 9
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims description 8
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 8
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 8
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 8
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 7
- -1 alkyl ethane vinyl ethers Chemical class 0.000 claims description 7
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 6
- 239000004408 titanium dioxide Substances 0.000 claims description 6
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims description 5
- 239000011737 fluorine Substances 0.000 claims description 5
- 229910052731 fluorine Inorganic materials 0.000 claims description 5
- 239000011858 nanopowder Substances 0.000 claims description 5
- 125000001931 aliphatic group Chemical group 0.000 claims description 4
- GBAJYMPPJATTKV-UHFFFAOYSA-N butyl(trifluoro)silane Chemical compound CCCC[Si](F)(F)F GBAJYMPPJATTKV-UHFFFAOYSA-N 0.000 claims description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 4
- 239000012948 isocyanate Substances 0.000 claims description 4
- 150000002513 isocyanates Chemical class 0.000 claims description 4
- 239000000178 monomer Substances 0.000 claims description 4
- 239000000377 silicon dioxide Substances 0.000 claims description 4
- 239000011787 zinc oxide Substances 0.000 claims description 4
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 3
- 235000012239 silicon dioxide Nutrition 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 2
- 125000001153 fluoro group Chemical group F* 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 239000000654 additive Substances 0.000 claims 1
- 150000002148 esters Chemical class 0.000 claims 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 claims 1
- 239000008096 xylene Substances 0.000 claims 1
- 238000007650 screen-printing Methods 0.000 abstract description 3
- 238000005303 weighing Methods 0.000 abstract 1
- 230000003075 superhydrophobic effect Effects 0.000 description 14
- 239000006185 dispersion Substances 0.000 description 8
- 239000000975 dye Substances 0.000 description 7
- 229910052500 inorganic mineral Inorganic materials 0.000 description 7
- 239000011707 mineral Substances 0.000 description 7
- 239000000758 substrate Substances 0.000 description 7
- 239000003054 catalyst Substances 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 4
- 238000005538 encapsulation Methods 0.000 description 4
- 239000003822 epoxy resin Substances 0.000 description 4
- 229920000647 polyepoxide Polymers 0.000 description 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000007334 copolymerization reaction Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 230000002209 hydrophobic effect Effects 0.000 description 3
- 238000003980 solgel method Methods 0.000 description 3
- 238000004528 spin coating Methods 0.000 description 3
- 238000007766 curtain coating Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229960001866 silicon dioxide Drugs 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 239000006087 Silane Coupling Agent Substances 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000003592 biomimetic effect Effects 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000010954 inorganic particle Substances 0.000 description 1
- 238000000025 interference lithography Methods 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 238000000608 laser ablation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 230000007170 pathology Effects 0.000 description 1
- 238000001259 photo etching Methods 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 229920013657 polymer matrix composite Polymers 0.000 description 1
- 239000011160 polymer matrix composite Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000001338 self-assembly Methods 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
本发明公开了一种诊断载玻片用涂层材料，该涂层材料的组成及按照重量份数组成为：氟碳树脂15份-20份；封闭型多异氰酸酯5份-10份；稀释剂15份-20份；固化促进剂0.1份-0.5份；助剂5份-10份；无机颜料10份-15份；纳米粉体10份-15份；微米粉体25份-30份。本发明还公开了诊断载玻片用涂层材料的制备方法：称取各组分后，采用分散机高速分散1～2小时；后加入纳米、微米粉体及无机颜料，采用三辊研磨，使涂层材料粒度达到10μm以下。本发明涂层材料用于诊断载玻片适用于丝网印刷，疏水性能优异，与载波片的附着力较好。此外成本较低而且工艺简单，能够满足各种性能要求。The invention discloses a coating material for diagnostic glass slides. The composition of the coating material is as follows: 15-20 parts of fluorocarbon resin; 5-10 parts of blocked polyisocyanate; 15 parts of diluent 0.1-0.5 parts of curing accelerator; 5-10 parts of auxiliary agent; 10-15 parts of inorganic pigment; 10-15 parts of nanometer powder; 25-30 parts of micron powder. The invention also discloses a preparation method of the coating material for diagnostic glass slides: after weighing each component, disperse at high speed for 1 to 2 hours with a disperser; then add nano, micron powder and inorganic pigment, and grind with three rolls. Make the particle size of the coating material below 10 μm. The coating material of the invention is suitable for screen printing when used for diagnostic glass slides, has excellent hydrophobicity and good adhesion to slide slides. In addition, the cost is low and the process is simple, which can meet various performance requirements.
Description
Technical field
The present invention relates to diagnose coating material for glass slide and preparation method thereof, it is specifically related to a kind ofly have the coated material of super-hydrophobic effect and be printed on slide glass, as biological, medical diagnosis analysis.
Background technology
Diagnosis slide glass is widely used in cytodiagnosis, pathology experiment, HPV detection etc., and its profile as shown in Figure 1.Visible, test agent drops in hole, and around coating has super-hydrophobic effect, thereby it is spherical that test agent is formed, and avoids the effect of reagent crossed contamination.Therefore, diagnosis slide glass coated material should have ultra-hydrophobicity, and the contact angle of coating and water should be greater than 150 °, should have good sticking power with slide glass substrate glass, the characteristics such as resistance to each alanysis solvent for use simultaneously.
Large quantity research shows, super-hydrophobic character and surperficial microtexture and lower surface can have very large associated.Super hydrophobic surface has the surface property of a lot of uniquenesses, such as: hydrophobicity, didirtresistance, automatically cleaning etc.Therefore, it has broad application prospects in life and production field.But manually preparing super hydrophobic surface is not to be easy to so.The technology of preparing now super hydrophobic surface exists many deficiencies such as the high and complex process of cost.
Chinese patent [CN200910217946.2] discloses a kind of method that adopts laser ablation and has manufactured super hydrophobic surface.First it is the laser multiple-beam interference system of building, and the then curable or degradable material of spin coating in substrate solidifies curable materials or made degradation material degraded by laser interference lithography, after developing, obtains micro structure array; Then in microstructure, carry out the modification of low-surface-energy material, and then in substrate, obtain the biomimetic colour super-hydrophobic coating that utilizes multi-beam interference photoetching technology to prepare.But this method more complicated is not easy to operate, and cost is higher.
Chinese patent [CN201010164798.5] a kind of polymer matrix composite with super hydrophobic surface and preparation method thereof of openly knowing clearly.Concrete method is: first pre-treatment is carried out in the surface of this matrix material body; Then by resin system brushing its surface and strike off; Be sprayed on resin system surface with metallic oxide nano powder again; Finally be heating and curing, and be placed in the similar solution such as stearic acid ethanolic soln and carry out self-assembly.Same also more complicated of this method, is not easy to operation.Similar patent also comprises Chinese patent [CN200710119670.5], Chinese patent [CN200710065079.6].
Chinese patent [CN200710070728.1] discloses a kind of preparation method of transparent hydrophobic coating.Adopt sol-gel method to carry out film at substrate material surface, and self-assembled modified with coatingsurface being carried out containing the material of hydrophobic chain, and gained contact angle on surface of coating is greater than 150 °.Sol-gel method mainly changes nano inorganic particle by organic precursor into through chemical reaction, but colloidal sol section storage time (being only that several minutes was to several hours).Therefore, this method is unfavorable for large-scale production.
Chinese patent [CN200810061480.7] the invention discloses a kind of preparation method of epoxy resin super-hydrophobic coat.It is characterized in that comprising the steps: the preparation of (1) coating colloidal sol, silicon-dioxide powdery is dissolved in solvent, add silane coupling agent, heated and stirred reaction, adds epoxide resin coating material, hydrophobizing agent, and stirring reaction, makes coating colloidal sol; (2) substrate material surface film, uses the method that lifts film, spin coating, curtain coating film or spraying that the colloidal sol making in step (1) is evenly applied in to substrate surface, set aside for use under room temperature after proposing; (3) process that is heating and curing, puts into baking oven by the base material of film in step (2), and the heating of rising temperature makes epoxy resin cure crosslinked, obtains epoxy resin super-hydrophobic coat after taking-up.Adopt sol-gel method to need low solid content, otherwise can cause that solid separates out.Therefore the super-hydrophobic coating material viscosity that prepared by this method is lower, only can adopt the method that lifts film, spin coating, curtain coating film or spraying to form coating; And for the coating with patterns such as circular holes, adopting silk screen printing more, it requires coated material viscosity to be greater than 10PaS.For this reason, the method that this patent proposes not can be applicable to diagnose slide glass yet.
Meanwhile, comprehensive client both at home and abroad mainly comprises the performance index of diagnosis slide glass coating: 1) can stand enzyme and microwave treatment; 2) can stand long-time storage; 3) HF of massfraction 1% soaks 15 seconds coating performances without impact; 4) HC1 of massfraction 5% soaks 30 minutes performances without impact; 5) more than reaching 5B with substrate glass sticking power.
The present invention, in meeting above-mentioned requirements, has the features such as simple, the with low cost and excellent performance of technique.In addition, the super-hydrophobic coat that the present invention makes, containing poisonous composition, is not suitable for diagnosing slide glass.Inquire about domestic and international patent and have no relevant report.
Summary of the invention
Goal of the invention: the present invention is the super-hydrophobic coating material that preparation is applicable to diagnose slide surface.Meeting outside properties requirement, there is the feature that technique is simple, effect is remarkable and with low cost simultaneously.
The technical solution used in the present invention is: a kind of diagnosis coating material for glass slide, and the composition of this coated material and consisting of according to parts by weight:
As preferably, described fluorocarbon resin is the FEVE fluorocarbon resin of fluorochemical monomer and the copolymerization of alkyl ethane and ethylene ether.
As preferably, described blocked polyisocyanate is aliphatics blocked isocyanate resin.
As preferably, described thinner is one or more mixtures of dihydric acid fat (DBE), pimelinketone, methylethylketone, toluene, dimethylbenzene.
As preferably, described auxiliary agent is fluorine containing silicone oil, preferably trifluoro propyl methyl-silicone oil, 3, two (trifluoromethyl) phenyl silicone oil of 5-.
As preferably, described nano-powder is that particle diameter is titanium dioxide or the silica dioxide granule of 10～500nm.
As preferably, described micro-powder is that particle diameter is one or several mixtures in calcium carbonate, barium sulfate and the zinc oxide of 5-30 μ m.
A preparation method who diagnoses coating material for glass slide, comprises the following steps:
(1) take and account for 15 parts of-20 parts of fluorocarbon resins of raw material gross weight, account for 5 parts of-10 parts of blocked polyisocyanates of raw material gross weight, account for 15 parts of-20 parts of thinners of raw material gross weight, account for 0.1 part of-0.5 part of promotor of raw material gross weight; Account for after 5 parts of-10 parts of auxiliary agents mixing of raw material gross weight, adopt dispersion machine high speed dispersion 60 minutes, rotating speed is 1600r/min
(2) take that to account for raw material gross weight be 10 parts of-15 parts of nano-powders, account for 25 parts of-30 parts of micro-powders of raw material weight and account for 10 parts of-15 parts of mineral dyes of raw material weight and add in compound, adopt three rollers to grind ten times, rear encapsulation is stand-by.
Beneficial effect: coated material of the present invention is used for diagnosing slide glass to be applicable to silk screen printing, hydrophobic performance excellence is better with the sticking power of wave carrier piece.In addition cost is lower and technique is simple, can meet various performance requriementss.
Product performance result is as follows:
Embodiment:
Specific embodiment 1
A kind of diagnosis coating material for glass slide, the composition of this coated material and consisting of according to parts by weight: 15 parts of fluorocarbon resins; 5 parts of blocked polyisocyanates; 15 parts of pimelinketone; 0.1 part of curing catalyst; 5 parts of trifluoro propyl methyl-silicone oils; 10 parts of mineral dyes; Particle diameter is 10 parts of the titanium dioxide of 10nm; Particle diameter is 25 parts, the calcium carbonate of 5 μ m.
A preparation method who diagnoses coating material for glass slide, comprises the following steps:
(1) after taking and accounting for and consist of 15 parts of fluorocarbon resins, 5 parts of blocked polyisocyanates, 15 parts of pimelinketone, 0.1 part of curing catalyst, 5 parts of trifluoro propyl methyl-silicone oils and mix according to parts by weight, adopt dispersion machine high speed dispersion 60 minutes, rotating speed is 1600r/min.
(2) take to account for and consist of according to parts by weight calcium carbonate and the 10 parts of mineral dyes that titanium dioxide that 10 parts of particle diameters are 10nm, 25 parts of particle diameters are 5 μ m and add in compound, adopt three rollers to grind ten times, rear encapsulation is stand-by.
Specific embodiment 2
A kind of diagnosis wave carrier piece coated material, the composition of this material and consisting of according to parts by weight: 20 parts of fluorocarbon resins; 10 parts of aliphatics blocked isocyanate resins; 20 parts of methylethylketones; 0.5 part of curing catalyst; 10 parts of two (trifluoromethyl) phenyl silicone oil of 3,5-; 15 parts of mineral dyes; Particle diameter is 5 parts of the silica 1s of 500nm; Particle diameter is 30 parts, the barium sulfate of 30 μ m.
A preparation method who diagnoses coating material for glass slide, comprises the following steps:
(1) take account for according to parts by weight consist of 20 parts of fluorocarbon resins, 10 parts of aliphatics blocked isocyanate resins, 20 parts of methylethylketones, 0.5 part of curing catalyst, 10 part 3, after two (trifluoromethyl) phenyl silicone oil of 5-are mixed, adopt dispersion machine high speed dispersion 60 minutes, rotating speed is 1600r/min;
(2) take to account for and consist of according to parts by weight barium sulfate and the 15 parts of mineral dyes that silicon-dioxide that 15 parts of particle diameters are 500nm, 30 parts of particle diameters are 30 μ m and add in compound, adopt three rollers to grind ten times, rear encapsulation is stand-by.
Specific embodiment 3
A kind of diagnosis coating material for glass slide, the composition of this coated material and consisting of according to parts by weight: 18 parts of the FEVE fluorocarbon resins of fluorochemical monomer and the copolymerization of alkyl ethane and ethylene ether; 7 parts of blocked polyisocyanates; 16 parts of dimethylbenzene; 0.3 part of curing catalyst; 9 parts of fluorine containing silicone oils; 13 parts of mineral dyes; Particle diameter is 12 parts of the titanium dioxide of 300nm; Particle diameter is 28 parts, the zinc oxide of 17 μ m.
A preparation method who diagnoses coating material for glass slide, comprises the following steps:
(1) after taking and accounting for and consist of 18 parts of fluorochemical monomers and mix with the FEVE fluorocarbon resin of alkyl ethane and ethylene ether copolymerization, 7 parts of blocked polyisocyanates, 16 parts of dimethylbenzene, 0.3 part of curing catalyst, 9 parts of fluorine containing silicone oils according to parts by weight, adopt dispersion machine high speed dispersion 60 minutes, rotating speed is 1600r/min;
(2) take to account for and consist of 13 parts of 12 parts of titanium dioxide that particle diameter is 300nm, 28 parts, zinc oxide that particle diameter is 17 μ m and mineral dyes according to parts by weight and add in compound, adopt three rollers to grind ten times, rear encapsulation is stand-by.
Claims (8)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201410074553.1A CN103819976A (en) | 2014-02-27 | 2014-02-27 | Coating material for diagnosis glass slide and preparation method for coating material |
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| CN201410074553.1A CN103819976A (en) | 2014-02-27 | 2014-02-27 | Coating material for diagnosis glass slide and preparation method for coating material |
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| CN201410074553.1A Pending CN103819976A (en) | 2014-02-27 | 2014-02-27 | Coating material for diagnosis glass slide and preparation method for coating material |
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| CN108102541A (en) * | 2017-12-22 | 2018-06-01 | 肇庆欧迪斯实业有限公司 | Efficient hydrophobing agent and preparation method thereof |
| CN114937874A (en) * | 2022-06-06 | 2022-08-23 | 西安工程大学 | A kind of preparation method of FeSiAl/Al2O3/resin composite wave absorbing coating |
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