CN1037912C - Emulsion suspending heavy-duty liquid detergent and its preparation method - Google Patents
Emulsion suspending heavy-duty liquid detergent and its preparation method Download PDFInfo
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- CN1037912C CN1037912C CN93101994A CN93101994A CN1037912C CN 1037912 C CN1037912 C CN 1037912C CN 93101994 A CN93101994 A CN 93101994A CN 93101994 A CN93101994 A CN 93101994A CN 1037912 C CN1037912 C CN 1037912C
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- Prior art keywords
- sodium
- alcohol
- emulsive
- acid
- sodium sulfate
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- 239000003599 detergent Substances 0.000 title claims abstract description 23
- 239000007788 liquid Substances 0.000 title claims abstract description 12
- 238000002360 preparation method Methods 0.000 title abstract 2
- 239000000839 emulsion Substances 0.000 title 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 18
- -1 sodium alkyl benzene Chemical class 0.000 claims abstract description 17
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 16
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims abstract description 16
- 239000000194 fatty acid Substances 0.000 claims abstract description 16
- 239000000344 soap Substances 0.000 claims abstract description 16
- 229910052938 sodium sulfate Inorganic materials 0.000 claims abstract description 16
- 235000011152 sodium sulphate Nutrition 0.000 claims abstract description 16
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 15
- 229930195729 fatty acid Natural products 0.000 claims abstract description 15
- 239000002994 raw material Substances 0.000 claims abstract description 15
- 235000019832 sodium triphosphate Nutrition 0.000 claims abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000011734 sodium Substances 0.000 claims abstract description 14
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 14
- 238000005406 washing Methods 0.000 claims abstract description 14
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 10
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 10
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000000654 additive Substances 0.000 claims abstract description 9
- 230000000996 additive effect Effects 0.000 claims abstract description 9
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 9
- 239000000725 suspension Substances 0.000 claims abstract description 9
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 8
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 8
- 239000010457 zeolite Substances 0.000 claims abstract description 8
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 6
- 239000000203 mixture Substances 0.000 claims description 29
- 239000013543 active substance Substances 0.000 claims description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 10
- 239000002253 acid Substances 0.000 claims description 9
- 150000004996 alkyl benzenes Chemical class 0.000 claims description 9
- 235000019353 potassium silicate Nutrition 0.000 claims description 9
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 claims description 9
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 7
- 101710194948 Protein phosphatase PhpP Proteins 0.000 claims description 7
- 239000000975 dye Substances 0.000 claims description 7
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 claims description 7
- 229940072033 potash Drugs 0.000 claims description 7
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 7
- 235000015320 potassium carbonate Nutrition 0.000 claims description 7
- 235000017550 sodium carbonate Nutrition 0.000 claims description 7
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 claims description 7
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 claims description 6
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 6
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 claims description 6
- 125000000217 alkyl group Chemical group 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 239000003352 sequestering agent Substances 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- DPDMMXDBJGCCQC-UHFFFAOYSA-N [Na].[Cl] Chemical compound [Na].[Cl] DPDMMXDBJGCCQC-UHFFFAOYSA-N 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 5
- 150000002632 lipids Chemical class 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- 238000009833 condensation Methods 0.000 claims description 4
- 230000005494 condensation Effects 0.000 claims description 4
- 150000002191 fatty alcohols Chemical class 0.000 claims description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical group NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims 3
- 229910052700 potassium Inorganic materials 0.000 claims 3
- 239000011591 potassium Substances 0.000 claims 3
- 239000004698 Polyethylene Substances 0.000 claims 1
- 150000001335 aliphatic alkanes Chemical class 0.000 claims 1
- 238000012423 maintenance Methods 0.000 claims 1
- 229920000573 polyethylene Polymers 0.000 claims 1
- 238000005202 decontamination Methods 0.000 abstract description 7
- 230000003588 decontaminative effect Effects 0.000 abstract description 7
- 239000003792 electrolyte Substances 0.000 abstract description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 abstract 2
- 239000004115 Sodium Silicate Substances 0.000 abstract 1
- 229940077388 benzenesulfonate Drugs 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 239000006081 fluorescent whitening agent Substances 0.000 abstract 1
- 239000011780 sodium chloride Substances 0.000 abstract 1
- 229910052911 sodium silicate Inorganic materials 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 5
- 230000008014 freezing Effects 0.000 description 4
- 238000007710 freezing Methods 0.000 description 4
- 238000013112 stability test Methods 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
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- Detergent Compositions (AREA)
Abstract
The invention discloses an opacified suspension type heavy-duty liquid detergent and a preparation method thereof. The raw material components comprise a surfactant composed of sodium alkyl benzene sulfonate, fatty alcohol-polyoxyethylene ether sodium sulfate, fatty acid sodium soap, fatty alcohol-polyoxyethylene ether and fatty acid alkylolamide, an electrolyte composed of sodium chloride, sodium sulfate and sodium hydroxide, a builder composed of sodium carbonate, sodium tripolyphosphate, sodium silicate and synthetic zeolite, an effective additive composed of a fluorescent whitening agent and the like, and water. The detergent provided by the invention is an opacified suspension liquid, the pH value is set between 8.0 and 11.0, the decontamination index is between 45 and 50, the performance is stable, and the washing effect on heavy-duty clothes is excellent.
Description
The present invention relates to a kind of emulsive dirt detergent and compound method thereof, belong to washing composition particularly liquid washing agent and formulation art thereof.
Conventional heavy duty liquid laundry detergent uses tensio-active agent, colorant, white dyes and water to be configured to the liquid of homogeneous transparent.Owing to do not contain a large amount of high-efficiency builder for detergent, its detersive power is not strong, and decontamination index generally is no more than 30, and cost is higher.Will be destroyed and serious layering occurs if add products such as the weak zeolite molecular sieve of a large amount of high-efficiency builder for detergent, tripoly phosphate sodium STPP, yellow soda ash, water glass, the washing assistant major part is deposited to the bottom, has a strong impact on quality product and result of use.English Patent 2205852A discloses a kind of liquid washing agent, though its quality product increases, but composition of raw materials complexity, feed composition reaches hundreds of, stability also poor, freezing and be heated after all can destroy the stability of product, make the product layering, influence result of use, its decontamination index only 30.75.Do not reach the purpose of the heavy dirty clothing of washing.
Purpose of the present invention is exactly in order to overcome weak point of the prior art, and a kind of stable performance, decontamination index height, good emulsive dirt detergent and the compound method thereof of result of use are provided.
The objective of the invention is such realization: the feed composition of emulsive dirt detergent is tensio-active agent, ionogen, washing assistant, additive and water.Wherein belonging to the feed composition of tensio-active agent and the weight percent of shared raw material thereof is:
Linear alkylbenzene sulphonic acid 5-15
Fatty acid sodium soap or potash soap 1-5
Polyoxyethylenated alcohol sodium sulfate 2-12
Fatty alcohol-polyoxyethylene ether 1-6
Polyoxyethylene nonylphenol ether 1-5
Fatty acid alkyl alcohol amide 1-5
The per-cent that belongs to the weight of electrolytical feed composition and shared raw material thereof is:
Sodium-chlor 0.5-5
Sodium sulfate 0.2-1
Sodium hydroxide 0.1-1
Belonging to the feed composition of washing assistant and the weight percent of shared raw material thereof is:
Yellow soda ash 3-10
Tripoly phosphate sodium STPP 10-30
Water glass 3-10
Synthetic zeolite 5-20
Belonging to the feed composition of additive and the weight hundred of shared raw material thereof changes than being:
White dyes 0.1-0.5
1-Hydroxy Ethylidene-1,1-Diphosphonic Acid (H501) sequestrant 0.1-0.5
Carboxymethyl cellulose 0.1-1
Essence 0.2-0.5.
Water in the feed composition is the surplus of above-mentioned raw materials component percentage composition.
Press weight percent that above-mentioned raw materials component formula range constitutes the feed composition of tensio-active agent and shared raw material thereof preferably:
Linear alkylbenzene sulphonic acid 5-10
Polyoxyethylenated alcohol sodium sulfate 4-8
Fatty alcohol-polyoxyethylene ether 1-4
Polyoxyethylene nonylphenol ether 1-3
And the alkyl chain length in the linear alkylbenzene sulphonic acid is C
10-C
15Fatty acid sodium soap or the potash soap preferably lipid acid in the potash soap are C
12-C
18Long chain acid; Fatty Alcohol(C12-C14 and C12-C18) in the polyoxyethylenated alcohol sodium sulfate generally is C
12-C
18Alcohol, alkyl chain are side chain or straight chain, and 3-5 is counted in the oxyethyl group condensation; Fatty Alcohol(C12-C14 and C12-C18) in the fatty alcohol-polyoxyethylene ether generally is C
12-C
18Alcohol, alkyl chain are side chain or straight chain, and oxyethyl group condensation number is 7-8; Lipid acid is C in the fatty acid alkyl alcohol amide
12-C
18Straight-chain acid, amine are monoethanolamine or diethanolamine.
The water glass that constitutes electrolyte components is that concentration is 45% the aqueous solution, and modulus is 1: 2.44.
Prepare burden after by the above-mentioned raw materials prescription each feed composition being converted into the weight real number, its distribution is: tensio-active agent and water are mixed in a mixing bowl, keep 30-70 ℃ of temperature, under 100-800 rev/min mixing speed, ionogen is added in the cylinder, form the tensio-active agent ball-like structure of 60-70% volume coefficient when tensio-active agent-ionogen-water system, add washing assistant and additive more successively, after fully stirring the homogenizing processing, form stable emulsive suspension type liquid, the pH value is 8.0-11.0.
The present invention compared with prior art has the following advantages:
1. detergency ability is good.Decontamination index is 45-50, and the similar products at home and abroad decontamination index is 30-31.
2. good stability.Prove that through centrifuge test, heat stability test and freezing test product of the present invention is better than similar products at home and abroad greatly.
3. feed composition is few, and compound method is simple.The feed composition of external like product reaches hundreds of, and some component is difficult to solve, and only tens kinds of feed composition of the present invention, raw material sources very easily solve.
Below in conjunction with embodiment in detail the present invention is described in detail:
The feed composition of present embodiment and the per-cent of shared weight thereof see Table 1.(table is seen the literary composition back)
After each percentages of ingredients content is converted into the weight real number in the table 1, prepare burden.Tensio-active agent and water at first will filling a prescription mix in a mixing bowl, and keep 45 ℃ of constant temperature, under 400 rev/mins mixing speed, ionogen is added in a mixing bowl, form the tensio-active agent ball-like structure of 60-70% volume coefficient when tensio-active agent-ionogen-water system, add washing assistant and additive more successively, after fully stirring the homogenizing processing, form stable emulsive suspension type liquid, the pH value is 9.5, promptly obtains the finished product of the present invention.
Milkiness suspension heavy duty liquid laundry detergent of the present invention is compared with the disclosed similar technical products of English Patent 2205852A, and every index all is better than external product, sees Table 2.(table is seen the literary composition back).
Table 1
| Feed composition | Weight percent (%) | |
| Fill a prescription two the prescription three | ||
| Tensio-active agent | Linear alkylbenzene sulphonic acid fatty acid sodium soap or potash soap polyoxyethylenated alcohol sodium sulfate (AES) fatty alcohol-polyoxyethylene ether (AEO 9) pregnant basic phenol polyethenoxy ether Fatty Alcohol(C12-C14 and C12-C18) alkylol amide | ????5???????10??????8.5 ????2.1?????2???????1 ????4.7?????6???????4.5 ????1???????2???????1 ????2???????2.5?????2.5 ????1.2?????1.5?????1.2 |
| Dielectric medium | Sodium-chlor sodium sulfate sodium hydroxide | ????2.2?????0.8?????1.5 ????0.0?????0.5?????0.8 ????0.2?????0.2?????0.2 |
| Washing assistant | Tripoly phosphate sodium STPP synthetic zeolite yellow soda ash water glass | ????15??????10??????20 ????5???????5???????5 ????5???????5???????3 ????6???????4???????5 |
| Additive | White dyes 1-Hydroxy Ethylidene-1,1-Diphosphonic Acid (H501) sequestrant carboxymethyl cellulose (CMC) essence | ????0.2?????0.2?????0.2 ????0.1?????0.1?????0.1 ????1???????1???????1 ????0.2?????0.2?????0.2 |
| Water | ????48.3????49.0????49.3 | |
Table 2 technical indicator product external product of the present invention
Decontamination index 47 30.75 centrifuge test 2000RPM were regardless of 50 ℃ of 30 minutes layer by layer branch heat stability tests in 120 minutes, not stratified layering heat stability test was 70 ℃ in 30 hours, not stratified laminated freezing test in 80 hours: melting chilling test at room temperature again after-10--20 ℃ of not stratified layering stores 24 hours :-10--20 ℃ of storage at room temperature melted after 24 hours, and then it is freezing, not stratified layering is melted again, three times totally 72 hours
Claims (12)
1. an emulsive dirt detergent comprises tensio-active agent, ionogen, washing assistant, additive, water, it is characterized in that:
The feed composition of a, tensio-active agent (weight %) is:
Linear alkylbenzene sulphonic acid 5-15
Fatty acid sodium soap or potash soap 1-5
Polyoxyethylenated alcohol sodium sulfate 2-12
Fatty alcohol-polyoxyethylene ether 1-6
Polyoxyethylene nonylphenol ether 1-5
Fatty acid alkyl alcohol amide 1-5
B, electrolytical raw material are formed (weight %) and are:
Sodium-chlor 0.5-5
Sodium sulfate 0.2-1
Sodium hydroxide 0.1-1
The feed composition of c, washing assistant (weight %) is:
Yellow soda ash 3-10
Tripoly phosphate sodium STPP 10-30
Water glass 3-10
Synthetic zeolite 5-20
The feed composition of d, additive (weight %) is:
White dyes 0.1-0.5
1-Hydroxy Ethylidene-1,1-Diphosphonic Acid (H501) sequestrant 0.1-0.5
Carboxymethyl cellulose 0.1-1
Essence 0.2-0.5.
2. emulsive dirt detergent according to claim 1 is characterized in that the alkyl chain length C10-C15 in the linear alkylbenzene sulphonic acid.
3. according to the emulsive suspension type dirt detergent agent of claim 1, it is characterized in that fatty acid sodium soap or potash soap are that lipid acid in the potash soap is the C12-C18 long chain acid.
4. emulsive dirt detergent according to claim 1 is characterized in that the Fatty Alcohol(C12-C14 and C12-C18) in the fat alcohol polyethylene ether sodium sulfate is a C12-C18 alcohol, and alkyl chain is side chain or straight chain, and oxyethyl group condensation number is 3-5.
5. emulsive dirt detergent according to claim 1 is characterized in that the Fatty Alcohol(C12-C14 and C12-C18) in the fatty alcohol-polyoxyethylene ether is a C12-C18 alcohol, and alkyl chain is side chain or straight chain, and oxyethyl group condensation number is 7-9.
6. the suspension type heavy duty liquid laundry detergent of milkiness according to claim 1 is characterized in that lipid acid is the C12-C18 straight-chain acid in the fatty acid alkyl alcohol amide, and amine is monoethanolamine or diethanolamine.
7. emulsive dirt detergent according to claim 1 is characterized in that water glass is that concentration is 45% water-soluble degree, modulus 1: 2.44.
8. emulsive dirt detergent according to claim 1 is characterized in that composition of raw materials (weight %) is:
Linear alkylbenzene sulphonic acid 5
Fatty acid potassium soap 2.1
Polyoxyethylenated alcohol sodium sulfate (AES) 4.7
Fatty alcohol-polyoxyethylene ether (AEO
9) 1
Polyoxyethylene nonylphenol ether 2
Fatty acid alkyl alcohol amide 1.2
Sodium-chlor 2.2
Sodium sulfate 0.8
Sodium hydroxide 0.2
Tripoly phosphate sodium STPP 15
Synthetic zeolite 5
Yellow soda ash 5
Water glass 6
White dyes 0.2
1-Hydroxy Ethylidene-1,1-Diphosphonic Acid (H501) sequestrant 0.1
Carboxymethyl cellulose (CMC) 1
Essence 0.2
Water 48.3.
9, emulsive dirt detergent according to claim 1 is characterized in that composition of raw materials (weight %) is:
Linear alkylbenzene sulphonic acid 10
Fatty acid potassium soap 2
Polyoxyethylenated alcohol sodium sulfate (AES) 6
Fatty alcohol-polyoxyethylene ether (AEO
9) 2
Polyoxyethylene nonylphenol ether 2.5
Lipid acid alkane is at alcohol amide 1.5
Sodium-chlor 0.8
Sodium sulfate 0.5
Sodium hydroxide 0.2
Tripoly phosphate sodium STPP 10
Synthetic zeolite 5
Yellow soda ash 5
Water glass 4
White dyes 0.2
1-Hydroxy Ethylidene-1,1-Diphosphonic Acid (H501) sequestrant 0.1
Carboxymethyl cellulose (CMC) 1
Essence 0.2
Water 10.0.
10, emulsive dirt detergent according to claim 1 is characterized in that composition of raw materials (weight %) is:
Linear alkylbenzene sulphonic acid 8.5
Fatty acid potassium soap 1
Polyoxyethylenated alcohol sodium sulfate (AES) 4.5
Fat and polyoxyethylenated alcohol (AEO
9) 1
Polyoxyethylene nonylphenol ether 2.5
Fatty acid alkyl alcohol amide 1.2
Sodium-chlor 1.5
Sodium sulfate 0.8
Sodium hydroxide 0.2
Tripoly phosphate sodium STPP 20
Synthetic zeolite 5
Yellow soda ash 3
Water glass 5
White dyes 0.2
1-Hydroxy Ethylidene-1,1-Diphosphonic Acid (H501) sequestrant 0.1
Carboxymethyl cellulose (CMC) 1
Essence 0.2
Water 49.3.
11. the compound method of the described emulsive dirt detergent of claim 1, it is characterized in that tensio-active agent and water mix in a mixing bowl, and 30-70 ℃ of temperature of maintenance, under 100-800 rev/min stirring velocity, add ionogen, form the surfactivity ball-like structure of 60-70% volume coefficient up to tensio-active agent-ionogen-water system, add high-efficiency builder for detergent and effective additive more successively, form stable emulsive suspension type liquid after stirring processing, pH is 8.0-11.0.
12. the compound method of the heavy dirty body washing composition of emulsive suspension type according to claim 11, it is characterized in that stirring cylinder temperature is 45 ℃, and stirring velocity is 400 rev/mins.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN93101994A CN1037912C (en) | 1993-03-01 | 1993-03-01 | Emulsion suspending heavy-duty liquid detergent and its preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN93101994A CN1037912C (en) | 1993-03-01 | 1993-03-01 | Emulsion suspending heavy-duty liquid detergent and its preparation method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1091771A CN1091771A (en) | 1994-09-07 |
| CN1037912C true CN1037912C (en) | 1998-04-01 |
Family
ID=4983896
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN93101994A Expired - Fee Related CN1037912C (en) | 1993-03-01 | 1993-03-01 | Emulsion suspending heavy-duty liquid detergent and its preparation method |
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|---|---|
| CN (1) | CN1037912C (en) |
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|---|---|---|---|---|
| EP0015887A1 (en) * | 1979-02-28 | 1980-09-17 | THE PROCTER & GAMBLE COMPANY | Improved laundering method |
| US4332692A (en) * | 1979-02-28 | 1982-06-01 | The Procter & Gamble Company | Laundering with a nonionic detergent system at a temperature between the cloud point and the phase coalescence temperatures |
| CN88103546A (en) * | 1987-06-10 | 1988-12-28 | 阿尔布赖特-威尔逊公司 | Liquid detergent compositions |
-
1993
- 1993-03-01 CN CN93101994A patent/CN1037912C/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0015887A1 (en) * | 1979-02-28 | 1980-09-17 | THE PROCTER & GAMBLE COMPANY | Improved laundering method |
| US4332692A (en) * | 1979-02-28 | 1982-06-01 | The Procter & Gamble Company | Laundering with a nonionic detergent system at a temperature between the cloud point and the phase coalescence temperatures |
| CN88103546A (en) * | 1987-06-10 | 1988-12-28 | 阿尔布赖特-威尔逊公司 | Liquid detergent compositions |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1091771A (en) | 1994-09-07 |
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