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CN103789064B - A kind of nanometer ucon oil and preparation method thereof - Google Patents

A kind of nanometer ucon oil and preparation method thereof Download PDF

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CN103789064B
CN103789064B CN201410061081.6A CN201410061081A CN103789064B CN 103789064 B CN103789064 B CN 103789064B CN 201410061081 A CN201410061081 A CN 201410061081A CN 103789064 B CN103789064 B CN 103789064B
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oil
nanometer
ucon oil
ucon
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CN103789064A (en
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程新明
安鹰泽
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Abstract

The present invention relates to a kind of nanometer ucon oil and preparation method thereof, nanometer ucon oil comprises the raw material of following weight percent: the lubricant base of 60 ~ 90%, the nano material of 0.1 ~ 0.6%, 3 ~ 13% oxidation inhibitor, the dispersion agent of 4 ~ 16%, the viscosity increaser of 1 ~ 5% and 1.9 ~ 5.4% anti-wear agent; Nanometer ucon oil is cut emulsification production line mixing refining by lubricant base, nano material, oxidation inhibitor, dispersion agent, viscosity increaser and anti-wear agent by height and is obtained.Beneficial effect of the present invention is: Ben Na meter ucon oil solves oil engine and the energy-saving and emission-reduction of motor car engine and the integrated technology of environmental protection synergy, the use of this nanometer ucon oil can make user under the prerequisite of a large amount of saving running cost, vehicle is realized in advance the emission reduction targets being better than " state five ", PM2.5 is dropped within high-quality emission standard, and recover and promote engine cylinder pressure to bring to user and like that car power is splashed the Driving of visiing.

Description

A kind of nanometer ucon oil and preparation method thereof
Technical field
The present invention relates to a kind of nanometer ucon oil and preparation method thereof.
Background technology
Lubricating oil is mixed by lubricant base and multiple additives.Base oil is divided into three kinds substantially in the market, i.e. mineral oil, semi synthetic base oils and synthetic oil.According to custom, the base oil extracted from oil by physics distillating method is called mineral oil (the non-deep hydrogenation base oil of part also should call mineral oil).Synthetic oil, as the term suggests the base oil (its composition majority is not directly present in oil) obtained by chemosynthesis exactly.Synthetic oil and mineral oil do not define accurately, and this is the saying be commonly called as, so there be saying of semi synthetic base oils.API (API) is divided into five classes to base oil, is usually called synthetic oil to the 3rd class and the 4th class base oil.
Base oil is exactly mineral oil in fact, and so-called semi-synthetic base oil and complete synthesis base oil, with regard to be through the material that constantly adds multiple physics and chemistry composition gradually to improve the wear-resistant, anti-oxidant, corrosion-resistant of lubricating oil and to increase for the purpose of the special efficacy such as glutinous result definition.Common synthetic oil is: PAO class, XHVI class, ester class.In addition VHVI class base oil performance is between synthetic oil and mineral oil, though there is people to be called synthetic oil, its performance (as viscosity-temperature characteristics and oxidation-resistance etc.) comparatively PAO, XHVI and ester class has larger gap.PAO and XHVI is the base oil being widely used as engine oil most, and wherein, XHVI is the synthesis type base oil of shell patented technology, and the synthetic motor oil of Mobil is mainly raw material with PAO, and the synthetic oil of Castrol is mainly with oil based on ester class.XHVI and PAO similar nature, but ester class engine oil performance and first two in oxidation-resistance have certain gap.
The industry of present China is immediately following west new technology, the oil product in a lot of use U.S., Japan, Europe, therefore the standard (as U.S. SAE, Japanese JIS, European Community CCMC, German DIN etc.) quoting these countries is started gradually, China existing lubricating oil standard (SY, SH, GB) is also progressively drawn close to these standards, especially with reference to U.S. SAE standard.Global economic integration is inexorable trend, various countries' lubricating oil industry adopts standard progressively unanimously or to be mutually equal to, China is no exception, first classification and ISO(GB standardization body) consistent: totally ten three major types, main several large class oil product such as I. C. engine oil, gear oil, hydraulic pressure wet goods all have employed the up-to-date criteria classification of GB, go with regard to standard, the level of China is synchronous with GB.
But in actual applications, the lubricating oil of China and developed country's level disparity are obvious, the I. C. engine oil that in lubricating oil, consumption is maximum, and we generally use SE, SG level, and developed country has used SH, SJ level, have differed 2,3 grades (arranging in alphabetical order); China can produce SH, SJ now, even the I. C. engine oil of SM level, but critical materials: oil engine composite additive, or basic dependence on import; The actual gap of Here it is China and international most advanced level.
Under this background, having obvious energy-saving and emission-reduction for producing, increasing efficiency, the high-end nano lubricating oil of health care engine provides chance and market, the lubricating oil processing state of the art of also catching up with and surpassing world advanced person for China scientific research personnel provides wide development space.
Summary of the invention
The object of this invention is to provide a kind of nanometer ucon oil and preparation method thereof, be exactly for the limitation of Lubricating Oil Technique in the market and energy-saving and emission-reduction present situation, by alloy nano-material and synthesis auxiliary material thereof and lube basestocks, cut the shearing of emulsification production line by height and synthesize a kind of high-end nano lubricating oil with energy-saving and emission-reduction, environmental protection synergy, fuel-economizing health care comprehensive energy efficiency, compensate for weak point of the prior art.
The object of the invention is to be achieved through the following technical solutions:
A kind of nanometer ucon oil, comprises the raw material of following weight percent: the lubricant base of 60 ~ 90%, the nano material of 0.1 ~ 0.6%, 3 ~ 13% oxidation inhibitor, the dispersion agent of 4 ~ 16%, the viscosity increaser of 1 ~ 5% and 1.9 ~ 5.4% anti-wear agent.
Described lubricant base adopts I class base oil or II class base oil, and viscosity index is 80 ~ 120.
Described nano material employing granularity is the ultra-fine multicomponent alloy nanometer powder of 50 ~ 1nm.
Described ultra-fine multicomponent alloy nanometer powder is the ultra-fine multicomponent alloy nanometer powder be made up of platinum, palladium, rhodium, bismuth, antimony, zinc, tin, indium, copper and rich lanthanum.
Described oxidation inhibitor is peroxide decomposer ST-135 or IRGANOX-L135.
Described dispersion agent is non-polymeric succimide.
Described viscosity increaser is hydrogenated styrene-butadiene block polymkeric substance (SEBS) or hydrogenated styrene-polyisoprene block polymers (SEPS).
Described anti-wear agent is dialkyl sulfuric acid zinc salt anti-wear agent.
The preparation method of described nanometer ucon oil, comprises the following steps:
First by following weight percent choose raw material 60 ~ 90% lubricant base, 0.1 ~ 0.6% nano material, 3 ~ 13% oxidation inhibitor, the dispersion agent of 4 ~ 16%, the viscosity increaser of 1 ~ 5% and 1.9 ~ 5.4% anti-wear agent, in above ratio, Lube basic oil material feedstocks is delivered to reactor from raw material tank field by toothed gear pump, deliver to after other raw materials mix according to the above ratio in reactor;
Then, by heating material to 80 DEG C, after various material carries out high-shear stirring and emulsifying 20h emulsification in a kettle., obtain high level nanometer ucon oil product, at the bottom of still, be transported to cooling tank circulating cooling by toothed gear pump be water-cooled to 40 DEG C, the products pot that cooled product is pressed onto tank field stores;
Finally, product is extracted out from products pot, flows automatically to fully automated assembly line quantitative pot and dress up as barreled product nanometer ucon oil after delivering to packing factory building header tank.
Beneficial effect of the present invention is surmount the advanced Lubricating Oil Technique in the American-European world for: comprehensive effect of the nanometer ucon oil obtained by the present invention, is in world lead level.Multicomponent alloy nano material composition in ucon oil is at oil engine, in engine starting operational process, under the high pressure that each parts contact friction produces and hot conditions, be melted in " liquid metal droplet " state, voluntarily at piston, cylinder, bent axle, bearing shell, bearing, gear, cam, tappet, rocking arm, all surface of the works infiltration that the direct contact friction of each parts such as connecting rod runs is clamp-oned to while the abrading sections such as Microscopic pits and micro-lattice gap, premature wear and the boundary wear of each parts of engine is reduced and prevents greatly by brush plating one deck " the mild alloy lubricating protective film of persistence oil-containing " (0.1 μm-200 μm), improve the sealing property of repairing cylinder voluntarily, reduce cylinder leakage tester amount, increase compression pressure without combustion, prevent from machine oil is altered burned, and make the dynamic property of engine, economy and emission behavior are improved voluntarily.Meanwhile, because multicomponent alloy nano material is in gas mixture or fuel oil, the moment of igniting in combustion chamber plays and makes " nontoxic gas that CO, HC, NOX are converted into CO2, H2O and N2 voluntarily " to the catalysis of carbon monoxide (CO) and hydrocarbon polymer (HC) and oxygenizement and to the reductive action of oxynitrides (NOX), thus make engine reach oil-saving discharging-reducing, anti-attrition noise reduction, exempt to tear open and be excused from a college course, and the ideal effect of engine operation life can be extended.Alloy nano lubricating oil obtained by the present invention is used among new car and new engine can be made to be avoided the wearing and tearing of new car parts impurity and to exempt run-in period, early stage and life-time service can allow engine obtain immunizing health effect, exempt from dismounting for a long time, can engine overhaul be removed from.
Embodiment
Below by specific embodiment, nanometer ucon oil of the present invention and preparation method thereof is described in further details.
Embodiment 1
Nanometer ucon oil described in embodiment 1, comprises the raw material of following weight: the dialkyl sulfuric acid zinc salt anti-wear agent of the non-polymeric succimide of peroxide decomposer ST-135,160kg of the I class base oil of 600kg, the ultra-fine multicomponent alloy nanometer powder be made up of platinum, palladium, rhodium, bismuth, antimony, zinc, tin, indium, copper and rich lanthanum of 6kg, 130kg, the hydrogenated styrene-butadiene block polymkeric substance (SEBS) of 50kg and 54kg.
The preparation method of the nanometer ucon oil described in embodiment 1, comprises the following steps:
First the dialkyl sulfuric acid zinc salt anti-wear agent of the I class base oil of raw material 600kg, the ultra-fine multicomponent alloy nanometer powder be made up of platinum, palladium, rhodium, bismuth, antimony, zinc, tin, indium, copper and rich lanthanum of 6kg, the non-polymeric succimide of peroxide decomposer ST-135,160kg of 130kg, the hydrogenated styrene-butadiene block polymkeric substance (SEBS) of 50kg and 54kg is chosen by following weight, the I class base oil of 600kg is delivered to reactor from raw material tank field by toothed gear pump, delivers in reactor after the mixing of other raw materials;
Then, by heating material to 80 DEG C, after various material carries out high-shear stirring and emulsifying 20h emulsification in a kettle., obtain SN level nanometer ucon oil product, at the bottom of still, be transported to cooling tank circulating cooling by toothed gear pump be water-cooled to 40 DEG C, the products pot that cooled product is pressed onto tank field stores;
Finally, product is extracted out from products pot, flows automatically to fully automated assembly line quantitative pot and dress up as barreled product nanometer ucon oil after delivering to packing factory building header tank.
Embodiment 2
Nanometer ucon oil described in embodiment 2, comprises the raw material of following weight: the dialkyl sulfuric acid zinc salt anti-wear agent of the non-polymeric succimide of peroxide decomposer ST-135,40kg of the II class base oil of 900kg, the ultra-fine multicomponent alloy nanometer powder be made up of platinum, palladium, rhodium, bismuth, antimony, zinc, tin, indium, copper and rich lanthanum of 1kg, 30kg, the hydrogenated styrene-polyisoprene block polymers (SEPS) of 10kg and 19kg.
The preparation method of the nanometer ucon oil described in embodiment 2, comprises the following steps:
First the dialkyl sulfuric acid zinc salt anti-wear agent of the II class base oil of raw material 900kg, the ultra-fine multicomponent alloy nanometer powder be made up of platinum, palladium, rhodium, bismuth, antimony, zinc, tin, indium, copper and rich lanthanum of 1kg, the non-polymeric succimide of peroxide decomposer ST-135,40kg of 30kg, the hydrogenated styrene-polyisoprene block polymers (SEPS) of 10kg and 19kg is chosen by following weight, the II class base oil of 900kg is delivered to reactor from raw material tank field by toothed gear pump, delivers in reactor after the mixing of other raw materials;
Then, by heating material to 80 DEG C, after various material carries out high-shear stirring and emulsifying 20h emulsification in a kettle., obtain SJ level nanometer ucon oil product, at the bottom of still, be transported to cooling tank circulating cooling by toothed gear pump be water-cooled to 40 DEG C, the products pot that cooled product is pressed onto tank field stores;
Finally, product is extracted out from products pot, flows automatically to fully automated assembly line quantitative pot and dress up as barreled product nanometer ucon oil after delivering to packing factory building header tank.
Embodiment 3
Nanometer ucon oil described in embodiment 3, comprises the raw material of following weight: the dialkyl sulfuric acid zinc salt anti-wear agent of the non-polymeric succimide of peroxide decomposer IRGANOX-L135,120kg of the I class base oil of 700kg, the ultra-fine multicomponent alloy nanometer powder be made up of platinum, palladium, rhodium, bismuth, antimony, zinc, tin, indium, copper and rich lanthanum of 3kg, 100kg, the hydrogenated styrene-butadiene block polymkeric substance (SEBS) of 40kg and 37kg.
The preparation method of the nanometer ucon oil described in embodiment 3, comprises the following steps:
First the dialkyl sulfuric acid zinc salt anti-wear agent of the I class base oil of raw material 700kg, the ultra-fine multicomponent alloy nanometer powder be made up of platinum, palladium, rhodium, bismuth, antimony, zinc, tin, indium, copper and rich lanthanum of 3kg, the non-polymeric succimide of peroxide decomposer IRGANOX-L135,120kg of 100kg, the hydrogenated styrene-butadiene block polymkeric substance (SEBS) of 40kg and 37kg is chosen by following weight, the I class base oil of 700kg is delivered to reactor from raw material tank field by toothed gear pump, delivers in reactor after the mixing of other raw materials;
Then, by heating material to 80 DEG C, after various material carries out high-shear stirring and emulsifying 20h emulsification in a kettle., obtain SM level nanometer ucon oil product, at the bottom of still, be transported to cooling tank circulating cooling by toothed gear pump be water-cooled to 40 DEG C, the products pot that cooled product is pressed onto tank field stores;
Finally, product is extracted out from products pot, flows automatically to fully automated assembly line quantitative pot and dress up as barreled product nanometer ucon oil after delivering to packing factory building header tank
Above-mentionedly only several specific embodiments in the present invention to be illustrated, but can not protection scope of the present invention to be defined as, every according to the change of the equivalence done by design spirit in the present invention or modify, all should think and fall into protection scope of the present invention.

Claims (3)

1. a SJ level nanometer ucon oil, it is characterized in that, comprise the raw material of following weight percent: the II class base oil of 90%, the ultra-fine multicomponent alloy nanometer powder be made up of platinum, palladium, rhodium, bismuth, antimony, zinc, tin, indium, copper and rich lanthanum of 0.1%, 3% peroxide decomposer ST-135, the non-polymeric succimide of 4%, the hydrogenated styrene-polyisoprene block polymers of 1% and 1.9% dialkyl sulfuric acid zinc salt anti-wear agent;
The preparation method of described SJ level nanometer ucon oil, comprises the following steps:
First by following weight percent choose raw material 90% II class base oil, 0.1% the ultra-fine multicomponent alloy nanometer powder be made up of platinum, palladium, rhodium, bismuth, antimony, zinc, tin, indium, copper and rich lanthanum, 3% peroxide decomposer ST-135, the non-polymeric succimide of 4%, the hydrogenated styrene-polyisoprene block polymers of 1% and 1.9% dialkyl sulfuric acid zinc salt anti-wear agent, II class base oil is delivered to reactor from raw material tank field by toothed gear pump, delivers in reactor after the mixing of other raw material;
Then, by heating material to 80 DEG C, various material carries out high-shear stirring and emulsifying in a kettle., after emulsification 20h, obtain SJ level nanometer ucon oil product, at the bottom of still, be transported to cooling tank by toothed gear pump, be water-cooled to 40 DEG C by circulating cooling, the products pot that cooled product is pressed onto tank field stores;
Finally, product is extracted out from products pot, flows automatically to fully automated assembly line quantitative pot and dress up as barreled product SJ level nanometer ucon oil after delivering to packing factory building header tank.
2. SJ level nanometer ucon oil according to claim 1, is characterized in that: the viscosity index of described II class base oil is 80 ~ 120.
3. SJ level nanometer ucon oil according to claim 1, is characterized in that: the granularity of described ultra-fine multicomponent alloy nanometer powder is 50 ~ 1nm.
CN201410061081.6A 2014-02-24 2014-02-24 A kind of nanometer ucon oil and preparation method thereof Active CN103789064B (en)

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CN105886080A (en) * 2016-04-21 2016-08-24 上海润立得材料科技有限公司 Modified nano material lubricating oil
CN107418650A (en) * 2017-05-28 2017-12-01 张进忠 A kind of discovery and preparation method containing super lubriation material lubricating oil
CN107557112A (en) * 2017-09-18 2018-01-09 吴江华威特种油有限公司 A kind of new mist of oil lubricating oil and preparation method thereof
CN108559583A (en) * 2018-04-28 2018-09-21 山东源根化学技术研发有限公司 Antiwear and antifriction antioxidant additive and containing the additive energy-saving hydraulic oil
CN109022101A (en) * 2018-07-09 2018-12-18 北方民族大学 A kind of anti-attrition antiwear additive and its application in Reclaimed Base Oil
CN109536244A (en) * 2018-07-10 2019-03-29 江苏机擎恒安节能环保科技有限公司 A kind of engine chamber targeting recovery technique
CN109233958A (en) * 2018-10-18 2019-01-18 上海加美实业有限公司 A kind of automobile oil
CN110157515A (en) * 2019-06-19 2019-08-23 泉州市迈辉化工贸易有限公司 A kind of cleaning lubricating oil and production technology based on nanotechnology
CN110699162A (en) * 2019-11-25 2020-01-17 秦引 Lubricating oil for automobile detection

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CN1560206A (en) * 2004-02-24 2005-01-05 安鹰泽 Additive of Nano alloy lubricating oil special for internal combustion engine and its making method
CN102942982A (en) * 2012-12-03 2013-02-27 季立忠 Lubricating oil for natural gas engine and preparation method thereof

Patent Citations (2)

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Publication number Priority date Publication date Assignee Title
CN1560206A (en) * 2004-02-24 2005-01-05 安鹰泽 Additive of Nano alloy lubricating oil special for internal combustion engine and its making method
CN102942982A (en) * 2012-12-03 2013-02-27 季立忠 Lubricating oil for natural gas engine and preparation method thereof

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