CN103774422B - A kind of environmental protection carbon fiber modifying agent for fishing rod carbon fiber - Google Patents
A kind of environmental protection carbon fiber modifying agent for fishing rod carbon fiber Download PDFInfo
- Publication number
- CN103774422B CN103774422B CN201410011153.6A CN201410011153A CN103774422B CN 103774422 B CN103774422 B CN 103774422B CN 201410011153 A CN201410011153 A CN 201410011153A CN 103774422 B CN103774422 B CN 103774422B
- Authority
- CN
- China
- Prior art keywords
- carbon fiber
- fishing rod
- environmental protection
- modifying agent
- raw material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a kind of environmental protection carbon fiber modifying agent for fishing rod carbon fiber, obtained after being mixed at 22-26 DEG C by the raw material of following weight parts: tri (propylene glycol) diacrylate 3-4, CNT 1-2, double pentaerythritol methacrylate 4-5, antioxidant NBC? 1-2, anilinomethyl triethoxysilane 2-3, auxiliary agent 4-5; The present invention is easy to use, and modified effect is good, and fishing rod good springiness made by the carbon fiber obtained, and the life-span is long.
Description
Technical field
The present invention relates to fishing tackle field, is exactly a kind of environmental protection carbon fiber modifying agent for fishing rod carbon fiber.
Background technology
Carbon fiber (carbonfiber), as the term suggests it not only has the intrinsic intrinsic property of material with carbon element, having again the soft machinability of textile fabric concurrently, is fortifying fibre of new generation.Compared with traditional glass fibre (GF), Young's modulus is that they are more than 3 times; It is compared with Kafra fiber (KF-49), and not only Young's modulus is its about 2 times, and insoluble not swollen in organic solvent, acid, alkali, and corrosion resistance is transcendent.Have scholar to be immersed in highly basic NaOH solution in 1981 by PAN base CF, time-out goes more than 30 year, and it still keeps fibre morphology so far.
The manufacturing technique of the fine pole of carbon is the same with glass pole, all impregnated fabric is cut into narrow trapezoidal of a head breadth one to twist on conical punching block core, then rolled tightly from the beginning to the end with clear glass band curl, be placed on again in electric furnace and glue is dried, take out from stove again and horizontal core is exited, remove the glass tape on pole body, through repair, polish, draw paint, assembling after fishing pole.Because the cloth of firm dipped glue is soft, glass tape is rolled up again very tight, pole body is strangled into rugged helical form, instead of carbon fiber cloth or glass-fiber-fabric spirality are rolled into.
Summary of the invention
The object of the present invention is to provide a kind of environmental protection carbon fiber modifying agent for fishing rod carbon fiber
Above-mentioned purpose is realized by following scheme:
For an environmental protection carbon fiber modifying agent for fishing rod carbon fiber, it is characterized in that:
Obtained after being mixed at 22-26 DEG C by the raw material of following weight parts:
Tri (propylene glycol) diacrylate 3-4, CNT 1-2, double pentaerythritol methacrylate 4-5, antioxidant NBC 1-2, anilinomethyl triethoxysilane 2-3, auxiliary agent 4-5;
Auxiliary agent is made up of the raw material of following weight portion: propyl alcohol 4-6, peregal 2-4, nano-sized carbon 1-2, silane coupler DL6022-3, magnetic 1.5-2.5, aluminium oxide 0.8-1.5, sodium peroxydisulfate 1-2, di-n-octyl sebacate 2-4, ethoxylated dodecyl alcohol 1-2, potassium permanganate 0.1-0.2; The preparation method of auxiliary agent is by after each raw material blending, after stirring 15-18 minute, to obtain final product under 300-400rpm.
Described a kind of environmental protection carbon fiber modifying agent for fishing rod carbon fiber, it is characterized in that: using method is: take out after 1-2 hour in carbon fiber surface modifier after carbon fibre is immersed 1-2 hour of ageing, with distilled water flushing carbon fiber until rinsing rear liquid is after neutrality, carbon fiber is put into 80-90 DEG C of baking oven 12-18h, after taking out cooling, to obtain final product.
Beneficial effect of the present invention is: the present invention is easy to use, and modified effect is good, and fishing rod good springiness made by the carbon fiber obtained, and the life-span is long.
Detailed description of the invention
For an environmental protection carbon fiber modifying agent for fishing rod carbon fiber,
Obtained after being mixed at 24 DEG C by the raw material of following weight parts:
Tri (propylene glycol) diacrylate 4, CNT 1, double pentaerythritol methacrylate 5, antioxidant NBC 2, anilinomethyl triethoxysilane 3, auxiliary agent 4;
Auxiliary agent is made up of the raw material of following weight kg: propyl alcohol 5, peregal 3, nano-sized carbon 1, silane coupler DL6023, magnetic 2.5, aluminium oxide 1.5, sodium peroxydisulfate 2, di-n-octyl sebacate 4, ethoxylated dodecyl alcohol 2, potassium permanganate 0.2; The preparation method of auxiliary agent is by after each raw material blending, stirs after 15 minutes, to obtain final product under 350rpm.
Described a kind of environmental protection carbon fiber modifying agent for fishing rod carbon fiber, using method is: take out after 2 hours in carbon fiber surface modifier after carbon fibre is immersed 2 hours of ageing, with distilled water flushing carbon fiber until rinsing rear liquid is after neutrality, carbon fiber is put into 82 DEG C of baking oven 18h, after taking out cooling, to obtain final product.
The preparation method of fishing rod is:
(1) will the obtained carbon fibre initial rinse fabric of modified carbon fiber be utilized to have cut for subsequent use;
(2) the punching block core brushing mould release toasted after 30 minutes at 65 DEG C, was wound around thereon by the carbon fibre initial rinse fabric cut;
(3) rolled tightly with opp film outside, post-drying, punching block core exits again, and removes the opp film on pole body, after repairing, polish, draw paint, assembling, namely obtain fishing rod.
Prepare the fishing rod of total length 5.3m, test.1000,1500, the weight of 2000g act on the point of fishing rod respectively state under fishing rod is placed in the horizontal plane, thereafter, be center of rotation with fishing rod afterbody the point front end of fishing rod is lifted gradually obliquely from horizontal plane, then, the angle between horizontal plane when weight leaves horizontal plane and fishing rod afterbody is measured.1. described sample is the present embodiment, and 2. described sample is general common carbon fibers fishing rod, and its result as shown in table 1 below.
Table 1
As shown in table 1 with sample 2. compared with, the raising of the present embodiment sample 1. bendability can be found out especially under each different loads.
Claims (2)
1. for an environmental protection carbon fiber modifying agent for fishing rod carbon fiber, it is characterized in that: obtained after being mixed at 22-26 DEG C by the raw material of following weight parts: tri (propylene glycol) diacrylate 3-4, CNT 1-2, double pentaerythritol methacrylate 4-5, antioxidant NBC 1-2, anilinomethyl triethoxysilane 2-3, auxiliary agent 4-5; Auxiliary agent is made up of the raw material of following weight portion: propyl alcohol 4-6, peregal 2-4, nano-sized carbon 1-2, silane coupler DL6022-3, magnetic 1.5-2.5, aluminium oxide 0.8-1.5, sodium peroxydisulfate 1-2, di-n-octyl sebacate 2-4, ethoxylated dodecyl alcohol 1-2, potassium permanganate 0.1-0.2; The preparation method of auxiliary agent is by after each raw material blending, after stirring 15-18 minute, to obtain final product under 300-400rpm.
2. a kind of environmental protection carbon fiber modifying agent for fishing rod carbon fiber according to claim 1, it is characterized in that: using method is: carbon fiber is immersed in the carbon fiber surface modifier after ageing 1-2 hour and take out after 1-2 hour, with distilled water flushing carbon fiber until rinsing rear liquid is after neutrality, carbon fiber is put into 80-90 DEG C of baking oven 12-18h, after taking out cooling, to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410011153.6A CN103774422B (en) | 2014-01-09 | 2014-01-09 | A kind of environmental protection carbon fiber modifying agent for fishing rod carbon fiber |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410011153.6A CN103774422B (en) | 2014-01-09 | 2014-01-09 | A kind of environmental protection carbon fiber modifying agent for fishing rod carbon fiber |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103774422A CN103774422A (en) | 2014-05-07 |
| CN103774422B true CN103774422B (en) | 2015-12-09 |
Family
ID=50567139
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410011153.6A Expired - Fee Related CN103774422B (en) | 2014-01-09 | 2014-01-09 | A kind of environmental protection carbon fiber modifying agent for fishing rod carbon fiber |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103774422B (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW591157B (en) * | 2001-05-25 | 2004-06-11 | Mitsubishi Rayon Co | Sizing agent for carbon fiber, its water dispersing solution, carbon fiber with sizing handling, sheet matter with using the carbon fiber and carbon fiber reinforced composite |
| CN100999867A (en) * | 2006-12-20 | 2007-07-18 | 中国科学院山西煤炭化学研究所 | Temp, resisting type carbon fibre emulsion sizing agent and its preparation process and application |
| CN101858038A (en) * | 2010-06-18 | 2010-10-13 | 济南大学 | A kind of carbon fiber emulsion sizing agent and its preparation method and application |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5584476A (en) * | 1978-12-21 | 1980-06-25 | Toray Industries | Sizing agent for carbon fiber |
| JP3222512B2 (en) * | 1991-11-11 | 2001-10-29 | 三菱レイヨン株式会社 | Sizing agent for carbon fiber |
| US6491891B1 (en) * | 1999-09-10 | 2002-12-10 | Ut-Battelle, Inc. | Gelcasting polymeric precursors for producing net-shaped graphites |
-
2014
- 2014-01-09 CN CN201410011153.6A patent/CN103774422B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW591157B (en) * | 2001-05-25 | 2004-06-11 | Mitsubishi Rayon Co | Sizing agent for carbon fiber, its water dispersing solution, carbon fiber with sizing handling, sheet matter with using the carbon fiber and carbon fiber reinforced composite |
| CN100999867A (en) * | 2006-12-20 | 2007-07-18 | 中国科学院山西煤炭化学研究所 | Temp, resisting type carbon fibre emulsion sizing agent and its preparation process and application |
| CN101858038A (en) * | 2010-06-18 | 2010-10-13 | 济南大学 | A kind of carbon fiber emulsion sizing agent and its preparation method and application |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103774422A (en) | 2014-05-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103351675B (en) | A kind of washability exterior coating and preparation method thereof | |
| CN103351679B (en) | A kind of thermal-insulation exterior coating and preparation method thereof | |
| CN103351672B (en) | A kind of environmental protection exterior coating and preparation method thereof | |
| CN103614754B (en) | A kind of chip ferrite product treatment process before plating | |
| CN103770340B (en) | A kind of high resiliency carbon fiber fishing rod | |
| CN104004469A (en) | Preparation method for glutinous rice glue | |
| CN104073369A (en) | Traceless detergent for automobile glass | |
| CN104139446B (en) | A kind of round bamboo tip bend processing method for the manufacture of full bamboo furniture | |
| CN103332869B (en) | A kind of method preparing multi-functional compound ZnO/In coated glass | |
| CN104942939A (en) | Method for treating birch bark | |
| CN103774423B (en) | A kind of fishing rod manufacture modified carbon fiber | |
| CN103774422B (en) | A kind of environmental protection carbon fiber modifying agent for fishing rod carbon fiber | |
| CN103774424B (en) | The corrosion-resistant carbon fiber modifying agent of a kind of fishing rod | |
| CN103790004B (en) | A kind of high-strength carbon fiber fishing rod | |
| CN103790008B (en) | A kind of antibacterial fishing rod carbon fiber modifying agent | |
| CN108102511B (en) | A kind of anti-icing coating applied to transmission line and preparation method thereof | |
| CN104446662A (en) | Retouching composition for ceramic part of white glaze insulator and retouching method | |
| CN105427962B (en) | A kind of automatically cleaning line Materials And Manufacturing Processes | |
| CN104553225A (en) | Preparation method of heat insulation pad and heat insulation pad prepared thereby | |
| CN108583140B (en) | Light and light-permeable lacquer painting art manufacturing process | |
| CN103351680B (en) | A kind of nano multifunctional outer wall coating and preparation method thereof | |
| CN106786198A (en) | Cable peeling is constructed | |
| CN204690469U (en) | A kind of multi-function glass fibre rope | |
| CN202829840U (en) | Hydrophobic glass | |
| CN106314011A (en) | Manufacturing process for waterproof canvas |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C56 | Change in the name or address of the patentee | ||
| CP01 | Change in the name or title of a patent holder |
Address after: 242100 Langxi City, Anhui Province Town Development Zone Patentee after: ANHUI GUANTING TECHNOLOGY Co.,Ltd. Address before: 242100 Langxi City, Anhui Province Town Development Zone Patentee before: LANG XI PU RUI TAI FISHING TACKLE Co.,Ltd. |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20210415 Address after: 226100 No. 38 Zhonghua East Road, three Factory Street, Haimen City, Nantong, Jiangsu Patentee after: Nantong an art design Co.,Ltd. Address before: 242100 Cross Town Development Zone, Langxi County, Xuancheng City, Anhui Province Patentee before: ANHUI GUANTING TECHNOLOGY Co.,Ltd. |
|
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20151209 Termination date: 20220109 |