CN103774164A - Water-based metal-degreasing cleaning agent - Google Patents
Water-based metal-degreasing cleaning agent Download PDFInfo
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- CN103774164A CN103774164A CN201410057954.6A CN201410057954A CN103774164A CN 103774164 A CN103774164 A CN 103774164A CN 201410057954 A CN201410057954 A CN 201410057954A CN 103774164 A CN103774164 A CN 103774164A
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- 239000012459 cleaning agent Substances 0.000 title claims abstract description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 17
- 238000005238 degreasing Methods 0.000 title abstract description 5
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 16
- 239000002131 composite material Substances 0.000 claims abstract description 16
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000012964 benzotriazole Substances 0.000 claims abstract description 14
- -1 sodium alkyl benzene Chemical class 0.000 claims abstract description 14
- 239000000203 mixture Substances 0.000 claims abstract description 13
- 239000008233 hard water Substances 0.000 claims abstract description 12
- 239000004094 surface-active agent Substances 0.000 claims abstract description 12
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 10
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 9
- HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical compound C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000011734 sodium Substances 0.000 claims abstract description 6
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 6
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 5
- 229940077388 benzenesulfonate Drugs 0.000 claims abstract description 5
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 5
- ONJQDTZCDSESIW-UHFFFAOYSA-N polidocanol Chemical compound CCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO ONJQDTZCDSESIW-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 5
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 5
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 5
- 239000010457 zeolite Substances 0.000 claims abstract description 5
- 239000008367 deionised water Substances 0.000 claims abstract description 4
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 4
- 239000010953 base metal Substances 0.000 claims description 13
- 239000013530 defoamer Substances 0.000 claims description 10
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 9
- 238000005406 washing Methods 0.000 claims description 9
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 5
- 229920000570 polyether Polymers 0.000 claims description 5
- 229920001296 polysiloxane Polymers 0.000 claims description 5
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 claims description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 4
- 229940124274 edetate disodium Drugs 0.000 claims description 3
- 238000004140 cleaning Methods 0.000 abstract description 19
- 239000006260 foam Substances 0.000 abstract description 8
- 238000005260 corrosion Methods 0.000 abstract description 6
- 230000007797 corrosion Effects 0.000 abstract description 5
- 239000000654 additive Substances 0.000 abstract description 3
- 230000000996 additive effect Effects 0.000 abstract description 3
- 230000002401 inhibitory effect Effects 0.000 abstract 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 1
- 239000004115 Sodium Silicate Substances 0.000 abstract 1
- 150000002191 fatty alcohols Chemical class 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 239000010703 silicon Substances 0.000 abstract 1
- 235000019795 sodium metasilicate Nutrition 0.000 abstract 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052911 sodium silicate Inorganic materials 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 description 20
- 239000002184 metal Substances 0.000 description 20
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 7
- 239000013543 active substance Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 239000000843 powder Substances 0.000 description 5
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 4
- 238000004945 emulsification Methods 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- 230000001737 promoting effect Effects 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- 238000005202 decontamination Methods 0.000 description 3
- 230000003588 decontaminative effect Effects 0.000 description 3
- 230000001804 emulsifying effect Effects 0.000 description 3
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 3
- 231100000252 nontoxic Toxicity 0.000 description 3
- 230000003000 nontoxic effect Effects 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000002689 soil Substances 0.000 description 3
- 230000009967 tasteless effect Effects 0.000 description 3
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical group [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 2
- 241000628997 Flos Species 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 229910001424 calcium ion Inorganic materials 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 230000009965 odorless effect Effects 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 235000019832 sodium triphosphate Nutrition 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
- 101710194948 Protein phosphatase PhpP Proteins 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 229910001425 magnesium ion Inorganic materials 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
The invention discloses a water-based metal-degreasing cleaning agent. The water-based metal-degreasing cleaning agent comprises the components in percent by weight: 10-30% of composite surface active agent, 5-10% of cleaning additive, 2-5% of corrosion inhibiting agent, 0.4-0.8% of hard-water resistant agent, 0.05-0.2% of defoaming agent and the balance of deionized water. By mass, the composite surface active agent is a mixture compounded by LAS (sodium alkyl benzene sulfonate), AEO-9 (Fatty alcohol polyoxyethylene ether) and TX-10 (alkylphenol ethoxylates) according to the mass ratio of 1:2:1; the corrosion inhibiting agent is a mixture compounded by benzotriazole (BTA) and benzimidazole (BIA) according to the mass ratio of 1:1; the cleaning additive is a mixture compounded by 4A zeolite, sodium metasilicate and sodium carbonate according to the mass ratio of 1:1:1; the defoaming agent is a polyether-modified organic silicon defoaming agent. The water-based metal-degreasing cleaning agent disclosed by the invention has the characteristics of low surface tension, fast defoaming, long foam-inhibiting time, low cost and less use amount and the like.
Description
Technical field
The present invention relates to clean-out system field, particularly relate to a kind of water-base metal degreased cleaning agent.
Background technology
In the time of the maintenance and repair of the processing of thermal treatment machinery and auto parts, mostly adopt petroleum solvent to carry out cleaning components, be easy to like this wash the dirt of metallic surface, but inflammable, harmful to the person, seriously polluted, and clean after metal parts be easy to get rusty, so adopted now aq. type metal degreasing clean-out system substitute.
High-effective low foam shaped metal clean-out system is to be made up of tensio-active agent and cleaning additive etc. as basis take water, there is the ability of good perviousness, emulsifying property and removing greasy dirt, while being directly used in metalwork cleaning, can not produce any spot corrosion, oxidation or other harmful reaction, it is the clear first agent clean metal part of petroleum replacing solvent-borne type well, and low price, be well suited for mechanized cleaning.But general water-base metal degreased cleaning agent contains the objectionable impurities such as phosphorus and nitrite, do not there is environmental-protecting performance, and the clean-out system of the heavy duty detergent having on the market and environment-friendly type is civilian and clean-out systems family expenses, the cleaning action of the metal parts that is unsuitable for using in machinery.
Summary of the invention
The technical problem that the present invention mainly solves is to provide a kind of water-base metal degreased cleaning agent, using kinds of surface promoting agent, composite and inorganic builders is as basal component, it is a kind of high-effective low foam shaped metal clean-out system, have soil removability strong, to the free from corrosion performance of metal, after cleaning, also there is certain antirust ability, and the objectionable impurities such as not phosphorous and nitrite.
For solving the problems of the technologies described above, the technical scheme that the present invention adopts is: a kind of water-base metal degreased cleaning agent is provided, comprise: complexed surfactant 10-30%, washing assistant 5-10%, inhibiter 2-5%, anti-hard water agent 0.4-0.8%, the deionized water of defoamer 0.05-0.2% and surplus, in mass, described complexed surfactant is LAS(sodium alkyl benzene sulfonate), AEO-9(fatty alcohol-polyoxyethylene ether) and TX-10(alkylphenol polyoxyethylene) carry out composite mixture with mass ratio 1:2:1, described inhibiter is that benzotriazole (BTA) and benzoglyoxaline (BIA) carry out composite mixture with mass ratio 1:1.
In a preferred embodiment of the present invention, described washing assistant is that 4A zeolite, Starso and sodium carbonate carry out composite mixture with mass ratio 1:1:1.
In a preferred embodiment of the present invention, described anti-hard water agent is one or both in EDETATE DISODIUM and citric acid.
In a preferred embodiment of the present invention, described defoamer is Polyether Modified Polysiloxanes Defoaming Agent.
The invention has the beneficial effects as follows: water-base metal degreased cleaning agent of the present invention is by adopting the composite and inorganic builders of kinds of surface promoting agent to generate a kind of high-effective low foam shaped metal clean-out system as basal component, there is soil removability strong, corrosion-free to metal, after cleaning, there is the effect of certain antirust ability, in this clean-out system, the objectionable impurities such as not phosphorous and nitrite, has realized the efficient and environmental protection that metal parts cleans.
Embodiment
To the technical scheme in the embodiment of the present invention be clearly and completely described below, obviously, described embodiment is only a part of embodiment of the present invention, rather than whole embodiment.Based on the embodiment in the present invention, those of ordinary skills, not making all other embodiment that obtain under creative work prerequisite, belong to the scope of protection of the invention.
The embodiment of the present invention comprises:
A kind of water-base metal degreased cleaning agent, comprise: the deionized water of complexed surfactant 10-30%, washing assistant 5-10%, inhibiter 2-5%, anti-hard water agent 0.4-0.8%, defoamer 0.05-0.2% and surplus, in mass, described complexed surfactant is LAS(sodium alkyl benzene sulfonate), AEO-9(fatty alcohol-polyoxyethylene ether) and TX-10(alkylphenol polyoxyethylene) carry out composite mixture with mass ratio 1:2:1, described inhibiter is that benzotriazole (BTA) and benzoglyoxaline (BIA) carry out composite mixture with mass ratio 1:1.
Described washing assistant is that 4A zeolite, Starso and sodium carbonate carry out composite mixture with mass ratio 1:1:1.
Described anti-hard water agent is one or both in EDETATE DISODIUM and citric acid.
Described defoamer is Polyether Modified Polysiloxanes Defoaming Agent.
In the present invention, described tensio-active agent is divided into ionogenic surfactant and nonionic surface active agent, select the tensio-active agent that cleaning performance is good very important, therefore selected tensio-active agent will have the effect of good removal metal surface greasy dirt, tensio-active agent can strengthen soaking metallic surface dirt, infiltration, solubilising, the effects such as emulsification, LAS(sodium alkyl benzene sulfonate) be class application anion surfactant very widely, outward appearance is white or micro-yellow powder, there is decontamination, moistening, foaming, emulsification, disperse, the performances such as solubilising, biology is down to Xie Xinghao, stable within the scope of wider PH,
AEO-9(fatty alcohol-polyoxyethylene ether) genus nonionogenic tenside, outward appearance is white paste, has good emulsifying, decontamination and dispersive ability, and anti-performance of hard water is good, and thering is the effect that unique anti-dirt deposits again, normal and anion surfactant is composite has synergy;
TX-10(alkylphenol polyoxyethylene) be nonionogenic tenside, the dirt of metallic surface is there is to the ability of good wetting, decontamination, emulsification, dispersion, anti-performance of hard water is good, stable in wide temperature range, can with various surfactant compounds.
In the present invention, the 4A zeolite that described washing assistant adopts claims again 4A molecular sieve, white solid particle, network-like structure, a kind of nontoxic, odorless, the tasteless and good white powder of mobility, have stronger calcium ion exchange capacity, environmentally safe, is to substitute the desirable non-phosphorus washing assistant of tripoly phosphate sodium STPP;
Starso is a kind of nontoxic, tasteless, non-harmful white powder or crystalline particle, soluble in water, be insoluble to alcohol and acid, the aqueous solution is alkalescence, there is de-sludging, emulsification, dispersion, moistening, perviousness and PH value is had to surge capability, metal carrying, for anti-corrosion protection, is therefore widely used in all kinds of cleanings and washes industry;
Under sodium carbonate normal temperature, be white powder or particle, soluble in water, be insoluble to ethanol, the aqueous solution is strong basicity, pH11.6.Be widely used in metal cleaner, the greasy dirt of metallic surface is had to good emulsifying removal effect.
In the present invention, described inhibiter is selected benzotriazole (BTA) and benzoglyoxaline (BIA), benzotriazole (BTA) is tiltedly side or monoclinic crystal of white, has good chemical stability, is dissolved in hot water, ethanol, acid solution; Benzoglyoxaline (BIA) is tiltedly side or monoclinic crystal of white, has good chemical stability, is dissolved in hot water, ethanol, acid solution; Benzotriazole (BTA) and benzoglyoxaline (BIA) combine, and can reduce toxicity, can also form rapidly the protective membrane of one deck densification in metallic surface, effectively suppress the corrosion of metallic surface, can also increase cleaning performance.
In the present invention, described anti-hard water agent EDTA disodium salt is white odorless, tasteless, colourless crystallization powder, in water, almost can form stable inner complex with all metal ions, reduces water hardness, prevent that calcium ions and magnesium ions from forming soap in water, improve cleaning performance.
In the present invention, described defoamer adopts Polyether Modified Polysiloxanes Defoaming Agent, in the time having tensio-active agent to exist in system, just be easy to produce foam, the existence of foam has increased the touch opportunity of metallic surface and air, get rusty and can hardly be avoided, so should add defoamer in formula, reduce the generation of bubble and reduce the oxygenizement of metallic surface; And the Polyether Modified Polysiloxanes Defoaming Agent adopting is here a kind of new and effective defoamer, it has, and surface tension is low, froth breaking rapidly, press down the features such as long, cost is low, consumption is few, wide application of bubble time.
Specific embodiment:
Get complexed surfactant 25%, washing assistant 8%, inhibiter 3%, anti-hard water agent 0.2%, defoamer 0.1%, water surplus, be mixed and made into 100g clean-out system raw material;
Example formulations the performance test results:
Test item stipulates actual detected result by JB/T4323.1-1999 standard
Outward appearance: uniform liquid, not stratified, without precipitation uniform liquid, not stratified, without precipitation
PH value: 7.0-11.0 9.0
Cleansing power: >=90 97
Antifoam performance :≤5 0.4
Hard water stability: without floss, without precipitate without floss, without precipitate
Water-insoluble (%) :≤0.1 0.01
Rinsing: the visible clean-out system residue of nothing is without visible clean-out system residue
Can be to going out conclusion in conjunction with great many of experiments by above-mentioned data, this clean-out system has the advantages that cleaning quality is good, efficiency is high, piece surface cleaning after cleaning, and there is certain rust-proof effect, by environment measuring safety non-toxic, not endangering operator healthy, is the high-tech product of a environmental protection.
The beneficial effect of a kind of water-base metal degreased cleaning agent of the present invention is:
One, and inorganic builders composite by employing kinds of surface promoting agent generates a kind of high-effective low foam shaped metal clean-out system as basal component, there is soil removability strong, corrosion-free to metal, after cleaning, there is the performance characteristics of certain antirust ability, in this clean-out system, the objectionable impurities such as not phosphorous and nitrite, has realized the efficient and environmental protection that metal parts cleans;
Two, there is and inorganic builders composite using kinds of surface promoting agent as basal component compared with common water-base metal degreased cleaning agent, through performance detects, develop the high-effective low foam shaped metal clean-out system that mechanical component clean use, realize the efficient and environmental protection that metal parts cleans, this achievement is the technological breakthrough that practicality is stronger in metal parts cleaning field, can be widely used in the surface cleaning of metal parts, there is good economic and social benefit.
The foregoing is only embodiments of the invention; not thereby limit the scope of the claims of the present invention; every equivalent structure or conversion of equivalent flow process that utilizes description of the present invention to do; or be directly or indirectly used in other relevant technical field, be all in like manner included in scope of patent protection of the present invention.
Claims (4)
1. a water-base metal degreased cleaning agent, it is characterized in that, comprise: complexed surfactant 10-30%, washing assistant 5-10%, inhibiter 2-5%, anti-hard water agent 0.4-0.8%, the deionized water of defoamer 0.05-0.2% and surplus, in mass, described complexed surfactant is LAS(sodium alkyl benzene sulfonate), AEO-9(fatty alcohol-polyoxyethylene ether) and TX-10(alkylphenol polyoxyethylene) carry out composite mixture with mass ratio 1:2:1, described inhibiter is that benzotriazole (BTA) and benzoglyoxaline (BIA) carry out composite mixture with mass ratio 1:1.
2. water-base metal degreased cleaning agent according to claim 1, is characterized in that, described washing assistant is that 4A zeolite, Starso and sodium carbonate carry out composite mixture with mass ratio 1:1:1.
3. water-base metal degreased cleaning agent according to claim 1, is characterized in that, described anti-hard water agent is one or both in EDETATE DISODIUM and citric acid.
4. water-base metal degreased cleaning agent according to claim 1, is characterized in that, described defoamer is Polyether Modified Polysiloxanes Defoaming Agent.
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CN104099624A (en) * | 2014-07-10 | 2014-10-15 | 安徽通润汽车零部件有限公司 | Non-phosphorus derusting water-based metal cleaning agent |
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CN104451852A (en) * | 2014-11-26 | 2015-03-25 | 成都川硬合金材料有限责任公司 | Electrolytic cleaning technology applicable to aluminum surface |
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