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CN103774164A - Water-based metal-degreasing cleaning agent - Google Patents

Water-based metal-degreasing cleaning agent Download PDF

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Publication number
CN103774164A
CN103774164A CN201410057954.6A CN201410057954A CN103774164A CN 103774164 A CN103774164 A CN 103774164A CN 201410057954 A CN201410057954 A CN 201410057954A CN 103774164 A CN103774164 A CN 103774164A
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China
Prior art keywords
water
agent
mass ratio
cleaning agent
based metal
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Pending
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CN201410057954.6A
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Chinese (zh)
Inventor
杨伟帅
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Suzhou Lotte Chemical Technology Co Ltd
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Suzhou Lotte Chemical Technology Co Ltd
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Priority to CN201410057954.6A priority Critical patent/CN103774164A/en
Publication of CN103774164A publication Critical patent/CN103774164A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a water-based metal-degreasing cleaning agent. The water-based metal-degreasing cleaning agent comprises the components in percent by weight: 10-30% of composite surface active agent, 5-10% of cleaning additive, 2-5% of corrosion inhibiting agent, 0.4-0.8% of hard-water resistant agent, 0.05-0.2% of defoaming agent and the balance of deionized water. By mass, the composite surface active agent is a mixture compounded by LAS (sodium alkyl benzene sulfonate), AEO-9 (Fatty alcohol polyoxyethylene ether) and TX-10 (alkylphenol ethoxylates) according to the mass ratio of 1:2:1; the corrosion inhibiting agent is a mixture compounded by benzotriazole (BTA) and benzimidazole (BIA) according to the mass ratio of 1:1; the cleaning additive is a mixture compounded by 4A zeolite, sodium metasilicate and sodium carbonate according to the mass ratio of 1:1:1; the defoaming agent is a polyether-modified organic silicon defoaming agent. The water-based metal-degreasing cleaning agent disclosed by the invention has the characteristics of low surface tension, fast defoaming, long foam-inhibiting time, low cost and less use amount and the like.

Description

A kind of water-base metal degreased cleaning agent
Technical field
The present invention relates to clean-out system field, particularly relate to a kind of water-base metal degreased cleaning agent.
Background technology
In the time of the maintenance and repair of the processing of thermal treatment machinery and auto parts, mostly adopt petroleum solvent to carry out cleaning components, be easy to like this wash the dirt of metallic surface, but inflammable, harmful to the person, seriously polluted, and clean after metal parts be easy to get rusty, so adopted now aq. type metal degreasing clean-out system substitute.
High-effective low foam shaped metal clean-out system is to be made up of tensio-active agent and cleaning additive etc. as basis take water, there is the ability of good perviousness, emulsifying property and removing greasy dirt, while being directly used in metalwork cleaning, can not produce any spot corrosion, oxidation or other harmful reaction, it is the clear first agent clean metal part of petroleum replacing solvent-borne type well, and low price, be well suited for mechanized cleaning.But general water-base metal degreased cleaning agent contains the objectionable impurities such as phosphorus and nitrite, do not there is environmental-protecting performance, and the clean-out system of the heavy duty detergent having on the market and environment-friendly type is civilian and clean-out systems family expenses, the cleaning action of the metal parts that is unsuitable for using in machinery.
Summary of the invention
The technical problem that the present invention mainly solves is to provide a kind of water-base metal degreased cleaning agent, using kinds of surface promoting agent, composite and inorganic builders is as basal component, it is a kind of high-effective low foam shaped metal clean-out system, have soil removability strong, to the free from corrosion performance of metal, after cleaning, also there is certain antirust ability, and the objectionable impurities such as not phosphorous and nitrite.
For solving the problems of the technologies described above, the technical scheme that the present invention adopts is: a kind of water-base metal degreased cleaning agent is provided, comprise: complexed surfactant 10-30%, washing assistant 5-10%, inhibiter 2-5%, anti-hard water agent 0.4-0.8%, the deionized water of defoamer 0.05-0.2% and surplus, in mass, described complexed surfactant is LAS(sodium alkyl benzene sulfonate), AEO-9(fatty alcohol-polyoxyethylene ether) and TX-10(alkylphenol polyoxyethylene) carry out composite mixture with mass ratio 1:2:1, described inhibiter is that benzotriazole (BTA) and benzoglyoxaline (BIA) carry out composite mixture with mass ratio 1:1.
In a preferred embodiment of the present invention, described washing assistant is that 4A zeolite, Starso and sodium carbonate carry out composite mixture with mass ratio 1:1:1.
In a preferred embodiment of the present invention, described anti-hard water agent is one or both in EDETATE DISODIUM and citric acid.
In a preferred embodiment of the present invention, described defoamer is Polyether Modified Polysiloxanes Defoaming Agent.
The invention has the beneficial effects as follows: water-base metal degreased cleaning agent of the present invention is by adopting the composite and inorganic builders of kinds of surface promoting agent to generate a kind of high-effective low foam shaped metal clean-out system as basal component, there is soil removability strong, corrosion-free to metal, after cleaning, there is the effect of certain antirust ability, in this clean-out system, the objectionable impurities such as not phosphorous and nitrite, has realized the efficient and environmental protection that metal parts cleans.
Embodiment
To the technical scheme in the embodiment of the present invention be clearly and completely described below, obviously, described embodiment is only a part of embodiment of the present invention, rather than whole embodiment.Based on the embodiment in the present invention, those of ordinary skills, not making all other embodiment that obtain under creative work prerequisite, belong to the scope of protection of the invention.
The embodiment of the present invention comprises:
A kind of water-base metal degreased cleaning agent, comprise: the deionized water of complexed surfactant 10-30%, washing assistant 5-10%, inhibiter 2-5%, anti-hard water agent 0.4-0.8%, defoamer 0.05-0.2% and surplus, in mass, described complexed surfactant is LAS(sodium alkyl benzene sulfonate), AEO-9(fatty alcohol-polyoxyethylene ether) and TX-10(alkylphenol polyoxyethylene) carry out composite mixture with mass ratio 1:2:1, described inhibiter is that benzotriazole (BTA) and benzoglyoxaline (BIA) carry out composite mixture with mass ratio 1:1.
Described washing assistant is that 4A zeolite, Starso and sodium carbonate carry out composite mixture with mass ratio 1:1:1.
Described anti-hard water agent is one or both in EDETATE DISODIUM and citric acid.
Described defoamer is Polyether Modified Polysiloxanes Defoaming Agent.
In the present invention, described tensio-active agent is divided into ionogenic surfactant and nonionic surface active agent, select the tensio-active agent that cleaning performance is good very important, therefore selected tensio-active agent will have the effect of good removal metal surface greasy dirt, tensio-active agent can strengthen soaking metallic surface dirt, infiltration, solubilising, the effects such as emulsification, LAS(sodium alkyl benzene sulfonate) be class application anion surfactant very widely, outward appearance is white or micro-yellow powder, there is decontamination, moistening, foaming, emulsification, disperse, the performances such as solubilising, biology is down to Xie Xinghao, stable within the scope of wider PH,
AEO-9(fatty alcohol-polyoxyethylene ether) genus nonionogenic tenside, outward appearance is white paste, has good emulsifying, decontamination and dispersive ability, and anti-performance of hard water is good, and thering is the effect that unique anti-dirt deposits again, normal and anion surfactant is composite has synergy;
TX-10(alkylphenol polyoxyethylene) be nonionogenic tenside, the dirt of metallic surface is there is to the ability of good wetting, decontamination, emulsification, dispersion, anti-performance of hard water is good, stable in wide temperature range, can with various surfactant compounds.
In the present invention, the 4A zeolite that described washing assistant adopts claims again 4A molecular sieve, white solid particle, network-like structure, a kind of nontoxic, odorless, the tasteless and good white powder of mobility, have stronger calcium ion exchange capacity, environmentally safe, is to substitute the desirable non-phosphorus washing assistant of tripoly phosphate sodium STPP;
Starso is a kind of nontoxic, tasteless, non-harmful white powder or crystalline particle, soluble in water, be insoluble to alcohol and acid, the aqueous solution is alkalescence, there is de-sludging, emulsification, dispersion, moistening, perviousness and PH value is had to surge capability, metal carrying, for anti-corrosion protection, is therefore widely used in all kinds of cleanings and washes industry;
Under sodium carbonate normal temperature, be white powder or particle, soluble in water, be insoluble to ethanol, the aqueous solution is strong basicity, pH11.6.Be widely used in metal cleaner, the greasy dirt of metallic surface is had to good emulsifying removal effect.
In the present invention, described inhibiter is selected benzotriazole (BTA) and benzoglyoxaline (BIA), benzotriazole (BTA) is tiltedly side or monoclinic crystal of white, has good chemical stability, is dissolved in hot water, ethanol, acid solution; Benzoglyoxaline (BIA) is tiltedly side or monoclinic crystal of white, has good chemical stability, is dissolved in hot water, ethanol, acid solution; Benzotriazole (BTA) and benzoglyoxaline (BIA) combine, and can reduce toxicity, can also form rapidly the protective membrane of one deck densification in metallic surface, effectively suppress the corrosion of metallic surface, can also increase cleaning performance.
In the present invention, described anti-hard water agent EDTA disodium salt is white odorless, tasteless, colourless crystallization powder, in water, almost can form stable inner complex with all metal ions, reduces water hardness, prevent that calcium ions and magnesium ions from forming soap in water, improve cleaning performance.
In the present invention, described defoamer adopts Polyether Modified Polysiloxanes Defoaming Agent, in the time having tensio-active agent to exist in system, just be easy to produce foam, the existence of foam has increased the touch opportunity of metallic surface and air, get rusty and can hardly be avoided, so should add defoamer in formula, reduce the generation of bubble and reduce the oxygenizement of metallic surface; And the Polyether Modified Polysiloxanes Defoaming Agent adopting is here a kind of new and effective defoamer, it has, and surface tension is low, froth breaking rapidly, press down the features such as long, cost is low, consumption is few, wide application of bubble time.
Specific embodiment:
Get complexed surfactant 25%, washing assistant 8%, inhibiter 3%, anti-hard water agent 0.2%, defoamer 0.1%, water surplus, be mixed and made into 100g clean-out system raw material;
Example formulations the performance test results:
Test item stipulates actual detected result by JB/T4323.1-1999 standard
Outward appearance: uniform liquid, not stratified, without precipitation uniform liquid, not stratified, without precipitation
PH value: 7.0-11.0 9.0
Cleansing power: >=90 97
Antifoam performance :≤5 0.4
Hard water stability: without floss, without precipitate without floss, without precipitate
Water-insoluble (%) :≤0.1 0.01
Rinsing: the visible clean-out system residue of nothing is without visible clean-out system residue
Can be to going out conclusion in conjunction with great many of experiments by above-mentioned data, this clean-out system has the advantages that cleaning quality is good, efficiency is high, piece surface cleaning after cleaning, and there is certain rust-proof effect, by environment measuring safety non-toxic, not endangering operator healthy, is the high-tech product of a environmental protection.
The beneficial effect of a kind of water-base metal degreased cleaning agent of the present invention is:
One, and inorganic builders composite by employing kinds of surface promoting agent generates a kind of high-effective low foam shaped metal clean-out system as basal component, there is soil removability strong, corrosion-free to metal, after cleaning, there is the performance characteristics of certain antirust ability, in this clean-out system, the objectionable impurities such as not phosphorous and nitrite, has realized the efficient and environmental protection that metal parts cleans;
Two, there is and inorganic builders composite using kinds of surface promoting agent as basal component compared with common water-base metal degreased cleaning agent, through performance detects, develop the high-effective low foam shaped metal clean-out system that mechanical component clean use, realize the efficient and environmental protection that metal parts cleans, this achievement is the technological breakthrough that practicality is stronger in metal parts cleaning field, can be widely used in the surface cleaning of metal parts, there is good economic and social benefit.
The foregoing is only embodiments of the invention; not thereby limit the scope of the claims of the present invention; every equivalent structure or conversion of equivalent flow process that utilizes description of the present invention to do; or be directly or indirectly used in other relevant technical field, be all in like manner included in scope of patent protection of the present invention.

Claims (4)

1. a water-base metal degreased cleaning agent, it is characterized in that, comprise: complexed surfactant 10-30%, washing assistant 5-10%, inhibiter 2-5%, anti-hard water agent 0.4-0.8%, the deionized water of defoamer 0.05-0.2% and surplus, in mass, described complexed surfactant is LAS(sodium alkyl benzene sulfonate), AEO-9(fatty alcohol-polyoxyethylene ether) and TX-10(alkylphenol polyoxyethylene) carry out composite mixture with mass ratio 1:2:1, described inhibiter is that benzotriazole (BTA) and benzoglyoxaline (BIA) carry out composite mixture with mass ratio 1:1.
2. water-base metal degreased cleaning agent according to claim 1, is characterized in that, described washing assistant is that 4A zeolite, Starso and sodium carbonate carry out composite mixture with mass ratio 1:1:1.
3. water-base metal degreased cleaning agent according to claim 1, is characterized in that, described anti-hard water agent is one or both in EDETATE DISODIUM and citric acid.
4. water-base metal degreased cleaning agent according to claim 1, is characterized in that, described defoamer is Polyether Modified Polysiloxanes Defoaming Agent.
CN201410057954.6A 2014-02-20 2014-02-20 Water-based metal-degreasing cleaning agent Pending CN103774164A (en)

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Application Number Priority Date Filing Date Title
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Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104099624A (en) * 2014-07-10 2014-10-15 安徽通润汽车零部件有限公司 Non-phosphorus derusting water-based metal cleaning agent
CN104357260A (en) * 2014-11-27 2015-02-18 新疆水处理工程技术研究中心有限公司 Efficient detergent used in industrial circulating water and preparation method of efficient detergent
CN104451852A (en) * 2014-11-26 2015-03-25 成都川硬合金材料有限责任公司 Electrolytic cleaning technology applicable to aluminum surface
CN104928695A (en) * 2015-04-29 2015-09-23 安徽长城输送机械制造有限公司 Steel material surface scrubbing liquid
CN105132931A (en) * 2015-09-28 2015-12-09 苏州龙腾万里化工科技有限公司 Water-based metal cleaning agent
CN106637259A (en) * 2016-11-22 2017-05-10 孙祎 Preparation method of efficient environment-friendly water-base metal degreasant
CN107090584A (en) * 2017-04-26 2017-08-25 安徽普瑞普勒传热技术有限公司 A kind of plate type heat exchanger degreased cleaning agent and its preparation
CN107245723A (en) * 2017-06-24 2017-10-13 山东天力润滑油有限公司 A kind of metal greasy dirt cleaning agent
CN107267998A (en) * 2017-06-15 2017-10-20 潍坊万方环保科技有限公司 A kind of metal detergent formula and preparation method thereof
CN107904609A (en) * 2017-12-05 2018-04-13 苏州市宽道模具机械有限公司 A kind of normal temperature metal degreaser and preparation method thereof
CN108315748A (en) * 2018-02-09 2018-07-24 东莞华拓研磨材料有限公司 A kind of metal cleaner and preparation method thereof
CN108342738A (en) * 2018-01-18 2018-07-31 长沙艾森设备维护技术有限公司 A kind of nuclear power generating equipment aqueous cleaning agent and preparation method thereof
CN110195231A (en) * 2019-05-21 2019-09-03 邵东县中南锻压工具制造有限公司 A kind of waste and old handware recycling and reusing preparation method
CN110284143A (en) * 2019-08-14 2019-09-27 重庆市联坤科技开发有限责任公司 A kind of metal cleaner
CN111348735A (en) * 2018-12-24 2020-06-30 上海梅山钢铁股份有限公司 Reagent and method for removing hexavalent chromium in organic chromium-containing fingerprint-resistant waste liquid
CN111979060A (en) * 2020-09-04 2020-11-24 安徽省玉环清洗设备制造有限公司 Environment-friendly efficient anti-corrosion vehicle hub cleaning agent
CN111979058A (en) * 2020-07-06 2020-11-24 广州市艾威航空科技有限公司 Special cleaning agent for aviation operation
WO2022016688A1 (en) * 2020-07-24 2022-01-27 苏州波菲特新材料科技有限公司 Powder degreasing agent, preparation method therefor and drying device thereof
CN114107999A (en) * 2021-11-29 2022-03-01 厦门普诺尔新材料科技有限公司 Plane grinding cleaning agent and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1156756A (en) * 1996-02-06 1997-08-13 北京·松下彩色显象管有限公司 Aquo-deoiling detergent for metallic parts of kinescope and its preparing process
EP0864638A2 (en) * 1997-03-12 1998-09-16 Showa Denko Kabushiki Kaisha Detergent composition
CN101440332A (en) * 2008-12-30 2009-05-27 潘惠凯 Environment protection efficient water-based circuit board cleaning agent and preparation thereof
CN102109321A (en) * 2009-12-25 2011-06-29 江苏金源锻造有限公司 Near-infrared vision sensing detection device for large-scale high-temperature forgeable piece
CN103184117A (en) * 2011-12-27 2013-07-03 施一飞 Method for preparing detergent by using drainage oil

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1156756A (en) * 1996-02-06 1997-08-13 北京·松下彩色显象管有限公司 Aquo-deoiling detergent for metallic parts of kinescope and its preparing process
EP0864638A2 (en) * 1997-03-12 1998-09-16 Showa Denko Kabushiki Kaisha Detergent composition
CN101440332A (en) * 2008-12-30 2009-05-27 潘惠凯 Environment protection efficient water-based circuit board cleaning agent and preparation thereof
CN102109321A (en) * 2009-12-25 2011-06-29 江苏金源锻造有限公司 Near-infrared vision sensing detection device for large-scale high-temperature forgeable piece
CN103184117A (en) * 2011-12-27 2013-07-03 施一飞 Method for preparing detergent by using drainage oil

Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104099624A (en) * 2014-07-10 2014-10-15 安徽通润汽车零部件有限公司 Non-phosphorus derusting water-based metal cleaning agent
CN104451852A (en) * 2014-11-26 2015-03-25 成都川硬合金材料有限责任公司 Electrolytic cleaning technology applicable to aluminum surface
CN104357260A (en) * 2014-11-27 2015-02-18 新疆水处理工程技术研究中心有限公司 Efficient detergent used in industrial circulating water and preparation method of efficient detergent
CN104928695A (en) * 2015-04-29 2015-09-23 安徽长城输送机械制造有限公司 Steel material surface scrubbing liquid
CN105132931A (en) * 2015-09-28 2015-12-09 苏州龙腾万里化工科技有限公司 Water-based metal cleaning agent
CN106637259A (en) * 2016-11-22 2017-05-10 孙祎 Preparation method of efficient environment-friendly water-base metal degreasant
CN107090584A (en) * 2017-04-26 2017-08-25 安徽普瑞普勒传热技术有限公司 A kind of plate type heat exchanger degreased cleaning agent and its preparation
CN107267998A (en) * 2017-06-15 2017-10-20 潍坊万方环保科技有限公司 A kind of metal detergent formula and preparation method thereof
CN107245723B (en) * 2017-06-24 2019-08-23 山东天力润滑油有限公司 A kind of metal greasy dirt cleaning agent
CN107245723A (en) * 2017-06-24 2017-10-13 山东天力润滑油有限公司 A kind of metal greasy dirt cleaning agent
CN107904609A (en) * 2017-12-05 2018-04-13 苏州市宽道模具机械有限公司 A kind of normal temperature metal degreaser and preparation method thereof
CN108342738A (en) * 2018-01-18 2018-07-31 长沙艾森设备维护技术有限公司 A kind of nuclear power generating equipment aqueous cleaning agent and preparation method thereof
CN108315748A (en) * 2018-02-09 2018-07-24 东莞华拓研磨材料有限公司 A kind of metal cleaner and preparation method thereof
CN111348735A (en) * 2018-12-24 2020-06-30 上海梅山钢铁股份有限公司 Reagent and method for removing hexavalent chromium in organic chromium-containing fingerprint-resistant waste liquid
CN110195231A (en) * 2019-05-21 2019-09-03 邵东县中南锻压工具制造有限公司 A kind of waste and old handware recycling and reusing preparation method
CN110284143A (en) * 2019-08-14 2019-09-27 重庆市联坤科技开发有限责任公司 A kind of metal cleaner
CN111979058A (en) * 2020-07-06 2020-11-24 广州市艾威航空科技有限公司 Special cleaning agent for aviation operation
WO2022016688A1 (en) * 2020-07-24 2022-01-27 苏州波菲特新材料科技有限公司 Powder degreasing agent, preparation method therefor and drying device thereof
CN111979060A (en) * 2020-09-04 2020-11-24 安徽省玉环清洗设备制造有限公司 Environment-friendly efficient anti-corrosion vehicle hub cleaning agent
CN114107999A (en) * 2021-11-29 2022-03-01 厦门普诺尔新材料科技有限公司 Plane grinding cleaning agent and preparation method thereof

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Application publication date: 20140507