CN103773301A - Thixotropic light adhesive for bonding buoyancy material module - Google Patents
Thixotropic light adhesive for bonding buoyancy material module Download PDFInfo
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- CN103773301A CN103773301A CN201310730225.8A CN201310730225A CN103773301A CN 103773301 A CN103773301 A CN 103773301A CN 201310730225 A CN201310730225 A CN 201310730225A CN 103773301 A CN103773301 A CN 103773301A
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- 239000000463 material Substances 0.000 title claims abstract description 40
- 230000009974 thixotropic effect Effects 0.000 title claims abstract description 13
- 239000000853 adhesive Substances 0.000 title abstract 6
- 230000001070 adhesive effect Effects 0.000 title abstract 6
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 85
- 239000003822 epoxy resin Substances 0.000 claims abstract description 30
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 30
- 239000011521 glass Substances 0.000 claims abstract description 24
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 18
- 239000003085 diluting agent Substances 0.000 claims abstract description 16
- 239000004593 Epoxy Substances 0.000 claims abstract description 14
- 239000013008 thixotropic agent Substances 0.000 claims abstract description 14
- 239000002270 dispersing agent Substances 0.000 claims abstract description 13
- 238000009736 wetting Methods 0.000 claims abstract description 13
- 238000004513 sizing Methods 0.000 claims description 61
- 238000002360 preparation method Methods 0.000 claims description 34
- 239000002518 antifoaming agent Substances 0.000 claims description 12
- 229920001296 polysiloxane Polymers 0.000 claims description 12
- YSUQLAYJZDEMOT-UHFFFAOYSA-N 2-(butoxymethyl)oxirane Chemical compound CCCCOCC1CO1 YSUQLAYJZDEMOT-UHFFFAOYSA-N 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 6
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- FQYUMYWMJTYZTK-UHFFFAOYSA-N Phenyl glycidyl ether Chemical compound C1OC1COC1=CC=CC=C1 FQYUMYWMJTYZTK-UHFFFAOYSA-N 0.000 claims description 5
- -1 organobentonite Chemical compound 0.000 claims description 5
- SJECZPVISLOESU-UHFFFAOYSA-N 3-trimethoxysilylpropan-1-amine Chemical compound CO[Si](OC)(OC)CCCN SJECZPVISLOESU-UHFFFAOYSA-N 0.000 claims description 4
- 150000001408 amides Chemical class 0.000 claims description 4
- JAYXSROKFZAHRQ-UHFFFAOYSA-N n,n-bis(oxiran-2-ylmethyl)aniline Chemical compound C1OC1CN(C=1C=CC=CC=1)CC1CO1 JAYXSROKFZAHRQ-UHFFFAOYSA-N 0.000 claims description 4
- 229920000768 polyamine Polymers 0.000 claims description 4
- RNLHGQLZWXBQNY-UHFFFAOYSA-N 3-(aminomethyl)-3,5,5-trimethylcyclohexan-1-amine Chemical compound CC1(C)CC(N)CC(C)(CN)C1 RNLHGQLZWXBQNY-UHFFFAOYSA-N 0.000 claims description 3
- 229910002012 Aerosil® Inorganic materials 0.000 claims description 3
- 238000005516 engineering process Methods 0.000 claims description 3
- 239000010445 mica Substances 0.000 claims description 3
- 229910052618 mica group Inorganic materials 0.000 claims description 3
- CBEVWPCAHIAUOD-UHFFFAOYSA-N 4-[(4-amino-3-ethylphenyl)methyl]-2-ethylaniline Chemical compound C1=C(N)C(CC)=CC(CC=2C=C(CC)C(N)=CC=2)=C1 CBEVWPCAHIAUOD-UHFFFAOYSA-N 0.000 claims description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 2
- NSOXQYCFHDMMGV-UHFFFAOYSA-N Tetrakis(2-hydroxypropyl)ethylenediamine Chemical compound CC(O)CN(CC(C)O)CCN(CC(C)O)CC(C)O NSOXQYCFHDMMGV-UHFFFAOYSA-N 0.000 claims description 2
- 125000002723 alicyclic group Chemical group 0.000 claims description 2
- 150000008431 aliphatic amides Chemical class 0.000 claims description 2
- 125000003118 aryl group Chemical group 0.000 claims description 2
- 239000012752 auxiliary agent Substances 0.000 claims description 2
- 239000011353 cycloaliphatic epoxy resin Substances 0.000 claims description 2
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- 239000000344 soap Substances 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims description 2
- 239000007787 solid Substances 0.000 abstract description 22
- 239000011324 bead Substances 0.000 abstract 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000013530 defoamer Substances 0.000 abstract 1
- 230000002349 favourable effect Effects 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 239000010703 silicon Substances 0.000 abstract 1
- 238000003756 stirring Methods 0.000 description 11
- 230000006835 compression Effects 0.000 description 6
- 238000007906 compression Methods 0.000 description 6
- QNYBOILAKBSWFG-UHFFFAOYSA-N 2-(phenylmethoxymethyl)oxirane Chemical compound C1OC1COCC1=CC=CC=C1 QNYBOILAKBSWFG-UHFFFAOYSA-N 0.000 description 2
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000007667 floating Methods 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- CUFXMPWHOWYNSO-UHFFFAOYSA-N 2-[(4-methylphenoxy)methyl]oxirane Chemical compound C1=CC(C)=CC=C1OCC1OC1 CUFXMPWHOWYNSO-UHFFFAOYSA-N 0.000 description 1
- NFVPEIKDMMISQO-UHFFFAOYSA-N 4-[(dimethylamino)methyl]phenol Chemical compound CN(C)CC1=CC=C(O)C=C1 NFVPEIKDMMISQO-UHFFFAOYSA-N 0.000 description 1
- 239000009261 D 400 Substances 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 241001074085 Scophthalmus aquosus Species 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Adhesives Or Adhesive Processes (AREA)
- Surface Treatment Of Glass Fibres Or Filaments (AREA)
Abstract
The invention relates to a thixotropic light adhesive for bonding a buoyancy material module. The adhesive is composed of a component A and a component B, wherein the component A comprises epoxy resin, an epoxy active diluent, a thixotropic agent, an organic silicon defoamer, a wetting dispersant, a silane coupling agent and hollow glass beads; the component B comprises a curing agent, a catalyst and a diluent. The thixotropic light adhesive provided by the invention has the thixotropy so that the hollow glass beads in the adhesive can be prevented from being floated and layered; a solid of the thixotropic light adhesive has low density and high strength, so that the density increment of the prepared solid buoyancy material is not higher than 0.02g/cm<3>; all batches of solid buoyancy materials have favorable density repeatability, so that the solid buoyancy materials can be conveniently produced according to the density, size and shape required by a user.
Description
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Technical field
The present invention relates to a kind of composite foam sizing agent, be specifically related to a kind of bonding buoyancy material module thixotropic lightweight sizing agent.
Background technology
The sixties in 20th century, 7000 meters of manned submersibles of U.S. Emerson & Cuming Developed are with processing solid buoyancy material, and this material is to adopt the bonding buoyancy material module making of sizing agent to form.
U.S. Pat P 2007,293,603 has reported a kind of bicomponent epoxy resin light structures sizing agent.First component is made up of two functionality epoxy resin, three-functionality-degree epoxy resin, epoxy terminated fluid rubber toughner, hollow glass micropearl density adjuster and catalyzer.Component B is made up of polymeric amide, modified fatty amine.Solidification value 70--120 ℃, stripping strength and lap shear strength after solidifying are all higher, are a kind of intermediate temperature setting structure-type sizing agents.
Chinese patent CN200610043524.4 has reported a kind of workable solid buoyancy material for deep sea, this material is the solid buoyancy material blank of being prepared by cenosphere filling epoxy resin, through working methods such as car, saw, plane, brills, prepare solid buoyancy material standard module, according to the difform solid buoyancy material of the bonding module making of sizing agent for design requirements, to meet the needs of different occasions.Chinese patent CN101121868 has reported a kind of two component epoxy sizing agent, and A component is made up of E--44 bisphenol A epoxide resin, epoxy active diluent, silane coupling agent, crystal powder, and B component is modified fatty amine curing agent.Ultrasonic wave deaeration in preparation process, 80--200 ℃ of intermediate temperature setting.There is higher shearing resistance and lower rate of expansion, be widely used in aerospace navigational field.Above patent is not all reported the preparation method of bonding solid buoyancy material module thixotropic light foam sizing agent.
summary of the invention
The present invention overcomes the deficiencies in the prior art, a kind of bonding buoyancy material module thixotropic lightweight sizing agent is proposed, feature of the present invention is that sizing agent has thixotropy, prevent the layering of hollow glass micropearl floating, its cured article has low density, high strength, and the solid buoyancy material density increase making is not more than 0.02g/cm
3.Solid buoyancy material is used more convenient, range of application is more extensive.
Technical scheme of the present invention is, thixotropic lightweight sizing agent for a kind of bonding buoyancy material module, described sizing agent is by first, second two components form, first component comprises epoxy resin, epoxy active diluent, thixotropic agent, silicone antifoam agent, wetting dispersing agent, silane coupling agent and hollow glass micropearl, component B comprises solidifying agent, catalyzer, thinner, the preparation method of first component is: by the epoxy resin of metering, epoxy active diluent, thixotropic agent, silicone antifoam agent, wetting dispersing agent, silane coupling agent, hollow glass micropearl mixes preparation first component, the preparation method of component B is: take solidifying agent, catalyzer, mixing diluents and evenly prepare component B, take in proportion first, second two component preparation sizing agents, the chemical constitution of sizing agent is counted by 100 mass parts epoxy resin: epoxy resin 100, epoxy active diluent 30--50, thixotropic agent 1--6, silane coupling agent 2--5, hollow glass micropearl 45--70, thinner 0--20, solidifying agent 20--80, auxiliary agent 0.5--2.
By the sizing agent bonding buoyancy material module of preparation, prepare solid buoyancy material through solidifying.
Preparation technology is:
The epoxy resin of metering, epoxy active diluent, thixotropic agent, silicone antifoam agent, wetting dispersing agent, silane coupling agent, hollow glass micropearl are placed in to the there-necked flask that has an agitator and mix preparation first component; Take solidifying agent, catalyzer, thinner mixes and prepares component B in the there-necked flask that has agitator; Take in proportion first, second two component preparation sizing agents;
Epoxy resin described above: bisphenol A epoxide resin (E-51, E-52, E-44), bisphenol-s epoxy resin (830S), cycloaliphatic epoxy resin (H-71,6201) or heterocyclic-type epoxy resin (TDE-85,712).
Epoxy active diluent described above: n-butyl glycidyl ether (BGE), phenyl glycidyl ether (PGE), diglycidylether (DGE), diglycidylaniline (DGA) or trihydroxymethylpropanyltri diglycidyl ether (TMPGE).
Solidifying agent described above: polymeric amide (300#, 400#, 650,651), aromatic polyamine (DDM, MBOEA)), aliphatic amide (593), alicyclic polyamine (IPDA), polyetheramine (D--400, T--403) or phenolic aldehyde quadrol (T--31).
Silane coupling agent described above: 3-(2,3-glycidoxy) propyl trimethoxy silicane (KH560), 3-aminopropyl trimethoxysilane (KH550) or r-methacryloxypropyl trimethoxy silane (KH570).
Hollow glass micropearl described above: the U.S.'s three M company hollow glass micropearls, density range 0.125-0.60g/cm
3, Bangbu frp industry design and research institute hollow glass micropearl, density range 0.22-0.51g/cm
3, mine research institute of Ma'an Mountain hollow glass micropearl, density range 0.15-0.60g/cm
3.
Thixotropic agent described above: aerosil, organobentonite, diatomite, mica powder or metal soap powder.
the present invention has following beneficial effect:,
Thixotropic lightweight sizing agent of the present invention, because having thixotropy, can prevent the layering of sizing agent hollow core glass microballon floating, and its cured article has low density, high strength, and the solid buoyancy material density increase making is not more than 0.02g/cm
3, and between each batch of solid buoyancy material, density circulation ratio is good, is convenient to produce solid buoyancy material by the density of user's requirement, size, shape.
Embodiment:
Lightweight sizing agent is made up of first and second liang of components:
The preparation of first component:
Take 100 grams of epoxy resin, 40 grams of phenylcarbinol glycidyl ether thinners, 5 grams of organobentonite thixotropic agent, 1.5 grams of silicone antifoam agents, 1 gram of wetting dispersing agent, 3 grams of silane coupling agents, 60 grams of density are 0.25g/cm
3hollow glass micropearl is placed in the 500mL there-necked flask that has agitator, stirs and makes lightweight sizing agent first component.
The preparation of component B:
Take 80 gram of 651 polymeric amide, 20 grams of phenolic aldehyde quadrol amine hardeners, 5 gram 2,4,6 three (dimethylamino methyl) phenol catalyzer stirs and makes lightweight sizing agent component B in the 500mL there-necked flask that has agitator.
Take first, second two components, in mass ratio as 100 than 25--50 preparation sizing agent, be 120 minutes the working life of sizing agent.4 hours initial cure of room temperature, one week completely curing, or 80 ℃ solidify 4 hours.Sizing agent density 0.62g/cm
3, ultimate compression strength 38.6Mpa, and the cohesive strength of solid buoyancy material: be that buoyancy material destroys after tested.
?
embodiment 2
Lightweight sizing agent is made up of first and second liang of components:
The preparation of first component:
Take 100 grams of epoxy resin, 40 grams of phenylcarbinol glycidyl ether thinners, 5 grams of organobentonite thixotropic agent, 1.5 grams of silicone antifoam agents, 1 gram of wetting dispersing agent, 3 grams of silane coupling agents, 60 grams of density are 0.25g/cm
3hollow glass micropearl is placed in the 500mL there-necked flask that has agitator, stirs and makes lightweight sizing agent first component.
The preparation of component B:
Take the 70 grams of fine modification diethylenetriamine of propylene multipolymers, 30 grams of phenolic aldehyde quadrols, 5 gram 2,4,6 three-(dimethylamino methyl) phenol catalyzer stir and make lightweight sizing agent component B in the 500mL there-necked flask that has agitator.
Take first, second two components, in mass ratio as 100 than 25--35 preparation sizing agent, be 90 minutes the working life of sizing agent.4 hours initial cure of room temperature, one week completely curing, or 80 ℃ solidify 4 hours.Sizing agent density 0.67g/cm
3, ultimate compression strength 41.7Mpa, with the cohesive strength of solid buoyancy material, buoyancy material destroys after tested.
?
embodiment 3
Lightweight sizing agent is made up of first and second liang of components:
The preparation of first component:
Take 100 grams of epoxy resin, 40 grams of epoxy propane butyl ether thinners, 1.5 grams of aerosils, 0.5 gram of silicone antifoam agent, 1 gram of wetting dispersing agent, 3 grams of silane coupling agents, 60 grams of density are 0.32g/cm
3hollow glass micropearl is placed in the 500mL there-necked flask that has agitator, stirs and makes lightweight sizing agent first component.
The preparation of component B:
Take 90 gram 3,3
,-diethyl-4,4
,-diaminodiphenyl-methane, 10 gram 2,4,6 three-(dimethylamino methyl) phenol, 20 grams of hydrogenated castor oils stir and make lightweight sizing agent component B in the 500mL there-necked flask that has agitator.
Take first, second two components, in mass ratio as 100 than 30--40 preparation sizing agent, be 60 minutes the working life of sizing agent.24 hours initial cure of room temperature, 80 ℃ of heating cures 4 hours.Sizing agent density 0.61 g/cm
3, ultimate compression strength 35.8Mpa, and the cohesive strength of solid buoyancy material: be that buoyancy material destroys after tested.
?
embodiment 4
Lightweight sizing agent is made up of first and second liang of components:
The preparation of first component:
Take 100 grams of epoxy resin, 40 grams of phenyl glycidyl ether thinners, 2 grams of aerosil thixotropic agent, 1.5 grams of silicone antifoam agents, 1 gram of wetting dispersing agent, 3 grams of silane coupling agents, 60 grams of density are 0.32g/cm
3hollow glass micropearl is placed in the 500mL there-necked flask that has agitator, stirs and makes lightweight sizing agent first component.
Component B: isophorone diamine
Take first, second two components, in mass ratio as 100 than 20--30 preparation sizing agent, be 60 minutes the working life of sizing agent.4 hours initial cure of room temperature, 80 ℃ of heating cures 4 hours.Sizing agent density 0.64g/cm
3, ultimate compression strength 53.6Mpa, and the cohesive strength of solid buoyancy material: be that buoyancy material destroys after tested.
?
embodiment 5
Lightweight sizing agent is made up of first and second liang of components:
The preparation of first component:
Take 100 grams of epoxy resin, 40 grams of propyl carbinol glycidyl ethers reactive diluents, 2.5 gram of 800 order mica powder, 1 gram of silicone antifoam agent, 2 grams of wetting dispersing agents, 3 grams of silane coupling agents, 60 grams of density are 0.38g/cm
3hollow glass micropearl is placed in the 500mL there-necked flask that has agitator, stirs and makes lightweight sizing agent first component.
The preparation of component B:
Take 70 grams of diethylenetriamines and butylglycidyl ether affixture, 30 grams of phenolic aldehyde quadrols stir and make lightweight sizing agent component B in the 500mL there-necked flask that has agitator.
Take first, second two components, in mass ratio as 100 than 20--30 preparation sizing agent, be 60 minutes the working life of sizing agent.24 hours initial cure of room temperature, one week completely curing, or 80 ℃ solidify 4 hours.Sizing agent density 0.66g/cm
3, ultimate compression strength 47Mpa, and the cohesive strength of solid buoyancy material: be that buoyancy material destroys after tested.
embodiment 6
Lightweight sizing agent is made up of first and second liang of components:
The preparation of first component:
Take 100 grams of epoxy resin, 40 grams of cresylglycidylether thinners, 5 grams of diatomite, 1.5 grams of silicone antifoam agents, 1 gram of wetting dispersing agent, 3 grams of silane coupling agents, 60 grams of density are 0.38g/cm
3hollow glass micropearl is placed in the 500mL there-necked flask that has agitator, stirs and makes lightweight sizing agent first component.
The preparation of component B:
Take 70 grams of T-403 polyetheramines, 30 grams of D-400 polyetheramines, 10 grams of nonyl phenol catalyzer stir and make lightweight sizing agent component B in the 500mL there-necked flask that has agitator.
Take first, second two components, in mass ratio as 100 than 45--60 preparation sizing agent, be 90 minutes the working life of sizing agent.3 hours initial cure of room temperature, one week completely curing, or 80 ℃ solidify 4 hours.Sizing agent density 0.68g/cm
3, ultimate compression strength 53Mpa, with the cohesive strength of solid buoyancy material, buoyancy material destroys after tested.
Claims (3)
1. a thixotropic lightweight sizing agent for bonding buoyancy material module, it is characterized in that: described sizing agent is made up of first, second two components, first component comprises epoxy resin, epoxy active diluent, thixotropic agent, silicone antifoam agent, wetting dispersing agent, silane coupling agent and hollow glass micropearl, and component B comprises solidifying agent, catalyzer, thinner; The preparation method of first component is: the epoxy resin of metering, epoxy active diluent, thixotropic agent, silicone antifoam agent, wetting dispersing agent, silane coupling agent, hollow glass micropearl are mixed to preparation first component; The preparation method of component B is: take solidifying agent, catalyzer, mixing diluents and evenly prepare component B; Take in proportion first, second two component preparation sizing agents; The chemical constitution of sizing agent is counted by 100 mass parts epoxy resin: epoxy resin 100, epoxy active diluent 30--50, thixotropic agent 1--6, silane coupling agent 2--5, hollow glass micropearl 45--70, thinner 0--20, solidifying agent 20--80, auxiliary agent 0.5--2.
2. thixotropic lightweight sizing agent for bonding buoyancy material module according to claim 1, is characterized in that: its preparation technology is:
The epoxy resin of metering, epoxy active diluent, thixotropic agent, silicone antifoam agent, wetting dispersing agent, silane coupling agent, hollow glass micropearl are placed in to the there-necked flask that has an agitator and mix preparation first component; Take solidifying agent, catalyzer, thinner mixes and prepares component B in the there-necked flask that has agitator; Take in proportion first, second two component preparation sizing agents.
3. thixotropic lightweight sizing agent for bonding buoyancy material module according to claim 1 and 2, is characterized in that: epoxy resin described above is: bisphenol A epoxide resin (E-51, E-52, E-44), bisphenol-s epoxy resin (830S), cycloaliphatic epoxy resin (H-71,6201) or heterocyclic-type epoxy resin (TDE-85,712);
Epoxy active diluent described above is: n-butyl glycidyl ether (BGE), phenyl glycidyl ether (PGE), diglycidylether (DGE), diglycidylaniline (DGA) or trihydroxymethylpropanyltri diglycidyl ether (TMPGE);
Solidifying agent described above is: polymeric amide (300#, 400#, 650,651), aromatic polyamine (DDM, MBOEA)), aliphatic amide (593), alicyclic polyamine (IPDA), polyetheramine (D--400, T--403) or phenolic aldehyde quadrol (T--31);
Silane coupling agent described above is: 3-(2,3-glycidoxy) propyl trimethoxy silicane (KH560), 3-aminopropyl trimethoxysilane (KH550) or r-methacryloxypropyl trimethoxy silane (KH570);
Hollow glass micropearl density range described above is 0.125-0.60g/cm
3, 0.22-0.51g/cm
3, or 0.15-0.60g/cm
3;
Thixotropic agent described above is: aerosil, organobentonite, diatomite, mica powder or metal soap powder.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201310730225.8A CN103773301A (en) | 2013-12-26 | 2013-12-26 | Thixotropic light adhesive for bonding buoyancy material module |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310730225.8A CN103773301A (en) | 2013-12-26 | 2013-12-26 | Thixotropic light adhesive for bonding buoyancy material module |
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| CN103773301A true CN103773301A (en) | 2014-05-07 |
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| CN106800905A (en) * | 2017-02-27 | 2017-06-06 | 湖南工业大学 | A kind of ceramic base abrading block binding metal matrix epoxy adhesive and its preparation method and application |
| CN108929645A (en) * | 2017-05-22 | 2018-12-04 | 卡本复合材料（天津）有限公司 | Epoxy structural rubber is used in a kind of bridge subsection splicing of high thixotropic |
| CN109868106A (en) * | 2019-02-21 | 2019-06-11 | 北京石油化工学院 | A kind of adhesive and its preparation and application for historic building structure reparation |
| US10611100B2 (en) | 2015-06-12 | 2020-04-07 | 3M Innovative Properties Company | Buoyancy module |
| CN112011300A (en) * | 2020-08-05 | 2020-12-01 | 中山市卡施力顿建材有限公司 | Multifunctional plate adhesive and preparation method thereof |
| CN112029457A (en) * | 2020-08-03 | 2020-12-04 | 河北天启通宇航空器材科技发展有限公司 | Light bonding material and preparation method thereof |
| CN118755429A (en) * | 2024-07-16 | 2024-10-11 | 咸宁海威复合材料制品有限公司 | A low-density adhesive for bonding buoyancy materials and a preparation method thereof |
| CN120056487A (en) * | 2025-04-25 | 2025-05-30 | 洛阳船舶材料研究所(中国船舶集团有限公司第七二五研究所) | A method for forming a large complex structure buoyancy material |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5639811A (en) * | 1989-09-14 | 1997-06-17 | Avery Dennison Corporation | Tackified dual cure pressure-sensitive adhesive |
| US20020115736A1 (en) * | 2000-10-10 | 2002-08-22 | Koshy Vettithara C. | Two component thermosettable compositions useful for producing structural reinforcing adhesives |
| CN101287794A (en) * | 2005-08-24 | 2008-10-15 | 亨克尔两合股份公司 | Epoxy composition with improved impact resistance |
| CN102876273A (en) * | 2012-10-08 | 2013-01-16 | 合肥杰事杰新材料股份有限公司 | Room temperature cured anti-flow sealing adhesive used for engineering plastic methane tank, and application thereof |
-
2013
- 2013-12-26 CN CN201310730225.8A patent/CN103773301A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5639811A (en) * | 1989-09-14 | 1997-06-17 | Avery Dennison Corporation | Tackified dual cure pressure-sensitive adhesive |
| US20020115736A1 (en) * | 2000-10-10 | 2002-08-22 | Koshy Vettithara C. | Two component thermosettable compositions useful for producing structural reinforcing adhesives |
| CN101287794A (en) * | 2005-08-24 | 2008-10-15 | 亨克尔两合股份公司 | Epoxy composition with improved impact resistance |
| CN102876273A (en) * | 2012-10-08 | 2013-01-16 | 合肥杰事杰新材料股份有限公司 | Room temperature cured anti-flow sealing adhesive used for engineering plastic methane tank, and application thereof |
Non-Patent Citations (1)
| Title |
|---|
| 贺罗曼: "《环氧树脂胶粘剂》", 30 April 2004, 中国石化出版社 * |
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| CN104356606A (en) * | 2014-10-20 | 2015-02-18 | 哈尔滨工程大学 | Light heat-preservation heat-insulation material for marine deep water pipelines and preparation method thereof |
| US10611100B2 (en) | 2015-06-12 | 2020-04-07 | 3M Innovative Properties Company | Buoyancy module |
| CN106800905A (en) * | 2017-02-27 | 2017-06-06 | 湖南工业大学 | A kind of ceramic base abrading block binding metal matrix epoxy adhesive and its preparation method and application |
| CN108929645A (en) * | 2017-05-22 | 2018-12-04 | 卡本复合材料（天津）有限公司 | Epoxy structural rubber is used in a kind of bridge subsection splicing of high thixotropic |
| CN109868106A (en) * | 2019-02-21 | 2019-06-11 | 北京石油化工学院 | A kind of adhesive and its preparation and application for historic building structure reparation |
| CN112029457A (en) * | 2020-08-03 | 2020-12-04 | 河北天启通宇航空器材科技发展有限公司 | Light bonding material and preparation method thereof |
| CN112011300A (en) * | 2020-08-05 | 2020-12-01 | 中山市卡施力顿建材有限公司 | Multifunctional plate adhesive and preparation method thereof |
| CN118755429A (en) * | 2024-07-16 | 2024-10-11 | 咸宁海威复合材料制品有限公司 | A low-density adhesive for bonding buoyancy materials and a preparation method thereof |
| CN118755429B (en) * | 2024-07-16 | 2025-06-17 | 咸宁海威复合材料制品有限公司 | A low-density adhesive for bonding buoyancy materials and a preparation method thereof |
| CN120056487A (en) * | 2025-04-25 | 2025-05-30 | 洛阳船舶材料研究所(中国船舶集团有限公司第七二五研究所) | A method for forming a large complex structure buoyancy material |
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