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CN103773204A - Composition with lubricating and heat-conducting effects and its manufacturing method - Google Patents

Composition with lubricating and heat-conducting effects and its manufacturing method Download PDF

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Publication number
CN103773204A
CN103773204A CN201210396113.9A CN201210396113A CN103773204A CN 103773204 A CN103773204 A CN 103773204A CN 201210396113 A CN201210396113 A CN 201210396113A CN 103773204 A CN103773204 A CN 103773204A
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heat
composition
powder
lubricating
substrate
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CN201210396113.9A
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Chinese (zh)
Inventor
吕国丰
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LV JIANXIONG
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LV JIANXIONG
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Priority to CN201210396113.9A priority Critical patent/CN103773204A/en
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Abstract

A composition with lubricating and heat conducting effects and a manufacturing method thereof are provided, the composition comprises a substrate and a heat conducting lubricating layer, the heat conducting lubricating layer is uniformly coated on the surface of the substrate, and the heat conducting lubricating layer comprises a mixture of polyethylene oxide and a high molecular compound. The manufacturing method comprises the steps of adding polyoxyethylene powder and a high molecular compound into water, uniformly stirring at a normal temperature of 25-35 ℃ to form a mixture of the polyoxyethylene and the high molecular compound, coating the mixture on the surface of the substrate, drying at a high temperature of 100 ℃, and forming the heat-conducting lubricating layer on the surface of the substrate to finish the composition with lubricating and heat-conducting effects.

Description

Composition and the manufacture method thereof of the lubricated and heat-conducting effect of tool
Technical field
The present invention is applied to the technical field of printed circuit board (PCB) (PCB) processing and IC support plate, espespecially its technical composition and manufacture method thereof that the lubricated and heat-conducting effect of a kind of tool is provided, this heat conduction lubricant film can give drilling needle surface and lubricates and dispel the heat, and slow down drill point feed power, help avoid the tolerance range that drill point fractures and promotes boring.
Background technology
Along with the intensive and microminiaturized degree of IC promotes day by day, it is more and more less that electronic component becomes, intensive being fixed on circuit card mostly of these a little electronic components, and the function of circuit card is to carry and be electrically connected each electronic component, these electronic components can be electrically connected to each other, and current modal circuit card is printed circuit board (PCB) (PCB), printed circuit board (PCB) is the flat board made from electrically nonconducting material, on this flat board, common corresponding electronic component is provided with affixed with hole, respectively this hole wears after the pin of electronic component, stick to PCB and form circuit with the metal electrode of electroconductibility again.
Known in the upper method that forms small holes of printed circuit board (PCB) (PCB), on a base plate, place the PCB of number wish boring, and arrange a cover sheet in the top.The function of this cover sheet is for preventing PCB impaired or generation burr in the time holing, and can be for drill point buffering and heat radiation, but, along with the densification day by day of the hole on PCB, the respectively relative microminiaturization of the diameter of this hole, be used for processing the essential high speed of drill point rotating speed of these a little holes, the essential microminiaturization of size, cause drill point intensity to be difficult to take into account, can produce chip very and in boring procedure in hole, cause broken needle or hole inner wall coarse, in addition, in the time of drill point high speed rotating, under high-speed friction derivative heat energy cannot effectively fall apart from, cause drilling needle surface easily to damage, and then the work-ing life of shortening drill point, for this reason, providing a kind of can sufficient lubrication drill point be necessity with the product with heat-conducting effect in fact.
Therefore for the existing problem points of above-mentioned known cover sheet, how to develop a kind of innovative product that has more desirable practicality, real human consumer eagerly looks forward to, and also relevant dealer must make great efforts target and the direction that research and development break through.
In view of this, contriver this in manufacturing development and the design experiences of being engaged in for many years related products, for above-mentioned target, in detail after design and scrupulous assessment, eventually the present invention of a true tool practicality.
Summary of the invention
The object of the invention is to; composition and the manufacture method thereof of the lubricated and heat-conducting effect of a kind of tool are provided; the technical problem point that wish solves: known in the upper method that forms small holes of printed circuit board (PCB) (PCB); on a base plate, place the PCB of number wish boring, and arrange a cover sheet in topmost.But, along with the densification day by day of the hole on PCB, be used for processing the essential high speed of drill point rotating speed, the essential microminiaturization of size of these a little holes, cause drill point intensity to be difficult to take into account, can produce chip very and in boring procedure in hole, cause broken needle or hole inner wall coarse, in addition, in the time of drill point high speed rotating, under high-speed friction derivative heat energy cannot effectively fall apart from, cause drilling needle surface easily to damage, and then shorten work-ing life of drill point, for this reason, providing a kind of can sufficient lubrication drill point be necessity with the product with heat-conducting effect in fact.
The technical characterstic that the present invention deals with problems: for improving above-mentioned problem, the invention provides the composition of the lubricated and heat-conducting effect of a kind of tool, include: a substrate and coat the heat conduction lubricant film of this substrate surface, this substrate is an aluminium sheet, this heat conduction lubricant film comprises with polyoxyethylene (Polyethylene oxides, PEO) be major ingredient, and puddle the macromolecular compound in polyoxyethylene, this macromolecular compound can be polyvinyl alcohol (Polyvinylalcohol, PVA) powder, polyacrylamide (Polyacrylamide, PAM) solution, vinylformic acid and methacrylate polymer (Acrylate dispersion prespex) solution, polyoxyethylene glycol (Polyethyleneglycols, PEG) powder, aqurous ployurethane (Polyurethane dispersions, PUD) solution, ether of cellulose (Cellulose ethers) powder and Polyvinylpyrolidone (PVP) (Polyvinyl pyrrolidone, PVP) one of in powder or the mixture of several compositions.Polyoxyethylene be difficult for sticking, the material of the lubricated and heat-conducting effect of tool, it is white particulate powder, completely water-soluble, its solution has very high viscosity under lower concentration, is to have flexibility, high-intensity thermoplastic resin, and the water absorbability in atmosphere is little, the polyoxyethylene of high molecular has very strong thickening capabilities, very low concentration can make solution retrogradation, and its molecular weight is larger, and thickening effectiveness is better.
Wherein, the molecular weight of this polyoxyethylene is 20,000 to 1 × 10 6scope.
The mixture of the polyoxyethylene that wherein, this heat conduction lubricant film comprises 5 to 95 weight percents and the macromolecular compound of 5 to 95 weight percents.
Tool of the present invention composition lubricated and heat-conducting effect is added to the water polyoxyethylene powder and macromolecular compound, at 25 ℃~35 ℃ normality temperature, uniform stirring becomes the mixture of polyoxyethylene and macromolecular compound, coated again this substrate surface, through the hyperthermia drying of 100 ℃, form this heat conduction lubricant film at this substrate surface, complete the composition of the lubricated and heat-conducting effect of tool.
Wherein, the blending ratio of this polyoxyethylene powder and macromolecular compound is 5: 95 to 95: 5 weight ratios.
Wherein, this polyoxyethylene powder adds that the weight of macromolecular compound and the blending ratio of water are 25: 75 to 40: 60 weight ratios.
Wherein, the thickness of this heat conduction lubricant film is the scope of 5 to 100 μ m.
Wherein, the weight percent of polyoxyethylene is higher, and the lubricated and heat-conducting effect of this heat conduction lubricant film better.
Effect of contrast prior art:
One, the composition of the lubricated and heat-conducting effect of tool of the present invention, this heat conduction lubricant film can give drilling needle surface lubricated and heat radiation, and slows down drill point feed power, helps avoid the tolerance range that drill point fractureed, reduced drill point abrasion and promotes boring.
Two, the composition of the lubricated and heat-conducting effect of tool of the present invention, this heat conduction lubricant film tool is difficult for sticking characteristic, is easy to strip off after this tool composition lubricated and heat-conducting effect is stacked use.
Three, the composition of the lubricated and heat-conducting effect of tool of the present invention, this heat conduction lubricant film and substrate adherence are good, there is incrust characteristic, make drill point under the situation of size microminiaturization, to improve penetration rate, and frangibility not, and this heat conduction lubricant film provides this drill point against buffering, make this drill point be difficult for sliding and can hole more accurately, and then promoting quality and the production capacity of printed circuit board (PCB).
Four, the composition of the lubricated and heat-conducting effect of tool of the present invention, this heat conduction lubricant film has good aqueous solubility, can prevent that chip from sticking in drilling needle surface or hole.
Relevant the technology used in the present invention, means and effect thereof, hereby lift a preferred embodiment and coordinate after graphic being described in more detail in, and believes the above-mentioned object of the present invention, structure and feature, when can by deeply and concrete understanding.
Accompanying drawing explanation
Fig. 1: the schematic diagram of one embodiment of the present invention.
Fig. 2: the composition manufacturing step schema of the lubricated and heat-conducting effect of tool of the present invention.
Embodiment
Consult shown in Fig. 1 to Fig. 2, the invention provides the composition of the lubricated and heat-conducting effect of a kind of tool, comprising:
One substrate 10, this substrate 10 is an aluminium sheet; And
One heat conduction lubricant film 20, this heat conduction lubricant film 20 is evenly coated this substrate 10 surfaces, the mixture of the polyoxyethylene that this heat conduction lubricant film 20 comprises 5 to 95 weight percents and the macromolecular compound of 5 to 95 weight percents, wherein the molecular weight of this polyoxyethylene is 20,000 to 1 × 10 6scope.
Wherein, this macromolecular compound can be polyvinyl alcohol (Polyvinyl alcohol, PVA) powder, polyacrylamide (Polyacrylamide, PAM) solution, vinylformic acid and methacrylate polymer (Acrylatedispersion prespex) solution, polyoxyethylene glycol (Polyethylene glycols, PEG) powder, aqurous ployurethane (Polyurethane dispersions, PUD) solution, ether of cellulose (Cellulose ethers) powder and Polyvinylpyrolidone (PVP) (Polyvinyl pyrrolidone, PVP) one of in powder or the mixture of several compositions.
Wherein, this aqurous ployurethane (Polyurethane dispersions, PUD) solution can be cation type polyurethane (Cationic polyethylene dispersions) solution, anionic polyurethane (Anionicpolyethylene dispersions) solution, nonionic polyurethane (Nonionic polyethylenedispersions) solution or anion-nonionic type polyurethane (Anionic-nonionic polyethylenedispersions) solution.
Wherein, the thickness of this heat conduction lubricant film 20 is the scope of 5 to 100 μ m.
Wherein, the weight percent of polyoxyethylene is higher, and the lubricated and heat-conducting effect of this heat conduction lubricant film 20 better.
Consult shown in Fig. 2, the manufacture method of the composition of the lubricated and heat-conducting effect of this tool, the steps include:
Step 1; 30. prepare water;
Step 2; 40. prepare polyoxyethylene powder;
Step 3; 50. prepare macromolecular compound;
Step 4; 60. are added to the water polyoxyethylene powder and macromolecular compound, at 25 ℃~35 ℃ normality temperature, uniform stirring becomes the mixture of polyoxyethylene and macromolecular compound, wherein, the blending ratio of this polyoxyethylene powder and macromolecular compound is 5: 95 to 95: 5 weight ratios, and this polyoxyethylene powder adds that the weight of macromolecular compound and the blending ratio of water are 25: 75 to 40: 60 weight ratios;
Step 5; 70. will be via step 4; 60 mixtures that modulate are coated this substrate 10 surfaces, through the hyperthermia drying of 100 ℃, form these heat conduction lubricant films 20 on this substrate 10 surfaces, complete the composition of the lubricated and heat-conducting effect of tool.
Be that technical characterictic of the present invention is specifically described for preferred embodiment of the present invention above; Only, person skilled in the art is when can the present invention being changed and be revised not departing under spirit of the present invention and principle, and these change and modification, all should be covered by the category that following claim defines.

Claims (6)

1.一种具润滑及导热效果的组合物,其特征在于,包括:1. A composition with lubricating and heat-conducting effects, characterized in that it comprises: 一基板;及a substrate; and 一导热润滑层,该导热润滑层均匀涂布于该基板表面,该导热润滑层包含5至95重量百分比的聚氧化乙烯及5至95重量百分比的高分子化合物的混合物,其中该聚氧化乙烯的分子量为20,000至1×106的范围。A thermally conductive lubricating layer, the thermally conductive lubricating layer is evenly coated on the surface of the substrate, the thermally conductive lubricating layer comprises a mixture of 5 to 95 weight percent polyethylene oxide and 5 to 95 weight percent polymer compounds, wherein the polyethylene oxide The molecular weight ranges from 20,000 to 1 x 106 . 2.如权利要求1所述的具润滑及导热效果的组合物,其特征在于,该高分子化合物为聚乙烯醇(Polyvinyl alcohol,PVA)粉末、聚丙烯酰胺(Polyacrylamide,PAM)溶液、丙烯酸和甲基丙烯酸聚合物(Acrylate dispersion prespex)溶液、聚乙二醇(Polyethylene glycols,PEG)粉末、水溶性聚氨酯(Polyurethanedispersions,PUD)溶液、纤维素醚(Cellulose ethers)粉末及聚乙烯基吡咯烷酮(Polyvinyl pyrrolidone,PVP)粉末中之一或者几种组成的混合物。2. The composition of tool lubrication and heat conduction effect as claimed in claim 1, is characterized in that, this polymer compound is polyvinyl alcohol (Polyvinyl alcohol, PVA) powder, polyacrylamide (Polyacrylamide, PAM) solution, acrylic acid and Methacrylic acid polymer (Acrylate dispersion prespex) solution, polyethylene glycol (Polyethylene glycols, PEG) powder, water-soluble polyurethane (Polyurethanedispersions, PUD) solution, cellulose ether (Cellulose ethers) powder and polyvinyl pyrrolidone (Polyvinyl pyrrolidone) , PVP) powder or a mixture of several components. 3.如权利要求2所述的具润滑及导热效果的组合物,其特征在于,该水溶性聚氨酯(Polyurethane dispersions,PUD)溶液为阳离子型聚氨酯(CationicPolyurethane dispersions)溶液、阴离子型聚氨酯(Anionic Polyurethanedispersions)溶液、非离子型聚氨酯(Nonionic Polyurethane dispersions)溶液或阴-非离子型聚氨酯(Anionic-nonionic Polyurethane dispersions)溶液。3. The composition with lubricating and heat-conducting effects as claimed in claim 2, wherein the water-soluble polyurethane (Polyurethane dispersions, PUD) solution is a cationic polyurethane dispersion, an anionic polyurethane dispersion solution, nonionic polyurethane dispersions or anionic-nonionic polyurethane dispersions. 4.如权利要求1所述的具润滑及导热效果的组合物,其特征在于,该基板为一铝板。4. The composition with lubricating and heat conducting effects as claimed in claim 1, wherein the substrate is an aluminum plate. 5.如权利要求1所述的具润滑及导热效果的组合物,其特征在于,该导热润滑层的厚度为5至100μm的范围。5 . The composition having lubricating and heat-conducting effects as claimed in claim 1 , wherein the thickness of the heat-conducting lubricating layer is in the range of 5 to 100 μm. 6.一种如权利要求1所述的组合物的制造方法,其步骤为:6. a manufacture method of composition as claimed in claim 1, its steps are: (1)制备水;(1) prepare water; (2)制备聚氧化乙烯粉末;(2) prepare polyethylene oxide powder; (3)制备高分子化合物;(3) Preparation of polymer compounds; (4)将聚氧化乙烯粉末及高分子化合物加入水中,在25℃~35℃常态温度下均匀搅拌成聚氧化乙烯及高分子化合物的混合物,其中该聚氧化乙烯粉末及高分子化合物的混合比例为5∶95至95∶5重量比,该聚氧化乙烯粉末加上高分子化合物的重量和水的混合比例为25∶75至40∶60重量比;(4) Add polyethylene oxide powder and polymer compound into water, and stir evenly at a normal temperature of 25°C to 35°C to form a mixture of polyethylene oxide and polymer compound, wherein the mixing ratio of polyethylene oxide powder and polymer compound 5:95 to 95:5 weight ratio, the polyoxyethylene powder plus the weight of the polymer compound and the mixing ratio of water is 25:75 to 40:60 weight ratio; (5)将经由步骤4调制出的混合物涂布于该基板表面,经过100℃的高温烘干,在该基板表面形成该导热润滑层,完成具润滑及导热效果的组合物。(5) Apply the mixture prepared in step 4 on the surface of the substrate, and dry at a high temperature of 100° C. to form the thermally conductive lubricating layer on the surface of the substrate, and complete the composition with lubricating and thermally conductive effects.
CN201210396113.9A 2012-10-18 2012-10-18 Composition with lubricating and heat-conducting effects and its manufacturing method Pending CN103773204A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104342276A (en) * 2014-09-25 2015-02-11 无锡康柏斯机械科技有限公司 Special cutting fluid for aluminum profile, and preparation method thereof
CN105642519A (en) * 2014-11-13 2016-06-08 杨淑静 Manufacturing method of lubricating heat-conducting auxiliary plate
CN108395832A (en) * 2018-01-19 2018-08-14 昆山久文电子材料有限公司 Overlay film aluminium sheet aqueous polyurethane coating and preparation method thereof
CN109411115A (en) * 2018-09-04 2019-03-01 苏州泰吉诺新材料科技有限公司 A kind of high torque heat-conduction insulation spacer material and its production technology

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201073837Y (en) * 2007-05-08 2008-06-18 合正科技股份有限公司 Auxiliary material for prolonging service life of high-speed drill point
JP2010001450A (en) * 2007-10-18 2010-01-07 Kobe Steel Ltd Lubricant composition, lubricant composition-coated metal plate and manufacturing method thereof
US20100278600A1 (en) * 2006-10-12 2010-11-04 Ohtomo Chemical Ins., Corp. Support board for perforation processing and method of perforation processing
CN102119074A (en) * 2008-06-10 2011-07-06 三菱瓦斯化学株式会社 Entry sheet for drilling

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100278600A1 (en) * 2006-10-12 2010-11-04 Ohtomo Chemical Ins., Corp. Support board for perforation processing and method of perforation processing
CN201073837Y (en) * 2007-05-08 2008-06-18 合正科技股份有限公司 Auxiliary material for prolonging service life of high-speed drill point
JP2010001450A (en) * 2007-10-18 2010-01-07 Kobe Steel Ltd Lubricant composition, lubricant composition-coated metal plate and manufacturing method thereof
CN102119074A (en) * 2008-06-10 2011-07-06 三菱瓦斯化学株式会社 Entry sheet for drilling

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104342276A (en) * 2014-09-25 2015-02-11 无锡康柏斯机械科技有限公司 Special cutting fluid for aluminum profile, and preparation method thereof
CN105642519A (en) * 2014-11-13 2016-06-08 杨淑静 Manufacturing method of lubricating heat-conducting auxiliary plate
CN108395832A (en) * 2018-01-19 2018-08-14 昆山久文电子材料有限公司 Overlay film aluminium sheet aqueous polyurethane coating and preparation method thereof
CN109411115A (en) * 2018-09-04 2019-03-01 苏州泰吉诺新材料科技有限公司 A kind of high torque heat-conduction insulation spacer material and its production technology
CN109411115B (en) * 2018-09-04 2020-02-28 苏州泰吉诺新材料科技有限公司 High-torque heat-conducting insulating gasket material and production process thereof

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Application publication date: 20140507