CN103773015A - Rosin soap emulsified asphalt water-proof material - Google Patents
Rosin soap emulsified asphalt water-proof material Download PDFInfo
- Publication number
- CN103773015A CN103773015A CN201410023425.4A CN201410023425A CN103773015A CN 103773015 A CN103773015 A CN 103773015A CN 201410023425 A CN201410023425 A CN 201410023425A CN 103773015 A CN103773015 A CN 103773015A
- Authority
- CN
- China
- Prior art keywords
- parts
- water
- proof material
- emulsified bitumen
- rosined
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000010426 asphalt Substances 0.000 title claims abstract description 41
- 239000000344 soap Substances 0.000 title claims abstract description 23
- 239000000463 material Substances 0.000 title claims abstract description 20
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 title abstract 3
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 title abstract 3
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 title abstract 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 24
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims abstract description 23
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 claims abstract description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 9
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims abstract description 8
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 claims abstract description 8
- 235000011941 Tilia x europaea Nutrition 0.000 claims abstract description 8
- 239000010425 asbestos Substances 0.000 claims abstract description 8
- 239000004571 lime Substances 0.000 claims abstract description 8
- 235000019353 potassium silicate Nutrition 0.000 claims abstract description 8
- 229910052895 riebeckite Inorganic materials 0.000 claims abstract description 8
- 235000011121 sodium hydroxide Nutrition 0.000 claims abstract description 8
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000002383 tung oil Substances 0.000 claims abstract description 8
- 210000002268 wool Anatomy 0.000 claims abstract description 8
- 239000013008 thixotropic agent Substances 0.000 claims abstract description 7
- 239000000203 mixture Substances 0.000 claims description 18
- 239000011301 petroleum pitch Substances 0.000 claims description 11
- 239000003921 oil Substances 0.000 claims description 9
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 5
- 238000005336 cracking Methods 0.000 abstract description 2
- 230000032683 aging Effects 0.000 abstract 1
- 239000002283 diesel fuel Substances 0.000 abstract 1
- 239000003208 petroleum Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- 239000007789 gas Substances 0.000 description 5
- 238000005187 foaming Methods 0.000 description 4
- 239000011295 pitch Substances 0.000 description 4
- 238000013019 agitation Methods 0.000 description 3
- 125000000129 anionic group Chemical group 0.000 description 3
- 125000002091 cationic group Chemical group 0.000 description 3
- 230000018044 dehydration Effects 0.000 description 3
- 238000006297 dehydration reaction Methods 0.000 description 3
- 238000007599 discharging Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 235000019219 chocolate Nutrition 0.000 description 2
- 239000010779 crude oil Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000011280 coal tar Substances 0.000 description 1
- 238000005056 compaction Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000011271 tar pitch Substances 0.000 description 1
- -1 trieline hydrocarbon Chemical class 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
Abstract
The invention discloses a rosin soap emulsified asphalt water-proof material, which comprises the following components in parts by mass: 100 parts of petroleum asphalt, 1-2 parts of water glass, 8-14 parts of heavy diesel oil, 2-4 parts of caustic soda, 6-12 parts of asbestos wool, 25-40 parts of lime paste, 15-20 parts of tung oil, 5-10 parts of chlorobenzene, 5-8 parts of thixotropic agent, 6-8 parts of diethylenetriamine, 2-5 parts of rosin soap, 1-2 parts of methylbenzene and 50-60 parts of water. The product is resistant to the high temperature of 80-100 DEG C, does not bubble or flow at 90 DEG C within 5 hours, is water-impermeable, and does not change under the dynamic water pressure of 0.1-0.2MPa within 5 hours. The product is high in aging resistance and weather resistance, waterproof and cracking-resistant, and can be produced on a large scale to replace the conventional material continuously.
Description
Technical field
The application belongs to asphalt waterproofing Material Field, relates in particular to a kind of rosined soap emulsified bitumen water-proof material.
Background technology
Emulsified bitumen is divided into cationic emulsified bitumen, anionic emulsified bitumen and non ionic emulsified bitumen.The bitumen particle of cationic emulsified bitumen is positively charged, and anionic emulsified bitumen particulate is electronegative.In the time that cationic emulsified bitumen contacts with aggregate surface, due to electrically charged difference, there is a natural attraction between the sexes in generation, and both can make bitumen particle wrap at aggregate surface in the situation that having moisture film, still can fine absorption combination.Thereby still can construct under dark and damp, low temperature condition.But anionic emulsified bitumen is just in time contrary, it and moist aggregate surface are all electronegative, make it produce two like magnetic poles repel each other, and bitumen particle can not stick to aggregate surface very soon, must be after moisture evaporation in emulsion, so be just difficult to construction while meeting dark and damp or low temperature season.Pitch is a kind of product of Crude Oil Processing, is thick liquid or the solid of black or chocolate at normal temperatures, and it is the organic material as a form of gel of a kind of brownish black, comprises four kinds of rock asphalt, petroleum pitch, shale tar pitch and coal-tar pitches etc.Main component is bituminous matter and resin, and next has the compound of high boiling point mineral oil and a small amount of oxygen, sulphur and chlorine.Glossy, be liquid, semisolid or solid state, when low temperature, matter is crisp, and cohesiveness and antiseptic property are good.
Normal temperature asphalt refers to mix at normal temperatures, the asphalt of making under normal temperature.Also can make cold laid asphaltic compound.Normal temperature compound binder used is eu-bitumen or emulsified bitumen.For save energy, protection of the environment.Emulsified Asphalt Mixture is to adopt emulsified bitumen and mine material mixture mix under normal temperature state, after making and compaction moulding, forms bituminous pavement, is divided into emulsified bitumen macadam-aggregate mix and emulsified bitulith compound according to the grating type of mineral aggregate.In Emulsified Asphalt Mixture, basic identical to the quality of gathering materials and specification requirement and hot-mix asphalt mixture, the grating of emulsified bitumen macadam-aggregate mix can be with reference to the grating of hot-mix asphalt mixture AM, and the grating of emulsified bitulith compound can be with reference to the grating of hot-mixed asphaltic concrete compound AC type.Pitch is a kind of product of Crude Oil Processing, is thick liquid or the solid of black or chocolate at normal temperatures, and mainly containing can solution trieline hydrocarbon derivative, and its character and composition change with the difference of source and generation method.Pitch is the same with oil, is complicated organic mixture, there is no fixing chemical composition and physical constant, and many oil field things form continuous series with passage type.This brings a lot of difficulties just to classification and discriminating.Along with the development of social city, technicalization, hommization, design a kind of good weatherability, the emulsified bitumen water-proof material of heat-resisting waterproof, to meet the need of market, is very important.
Summary of the invention
the technical problem solving:
The application is the technical problem such as poor and thermo-labile waterproof for existing rosined soap emulsified bitumen water-proof material weathering resistance, and a kind of rosined soap emulsified bitumen water-proof material is provided.
technical scheme:
A kind of rosined soap emulsified bitumen water-proof material, be made up of following raw materials according, take mass fraction representation as 100 parts, petroleum pitch; Water glass 1-2 part; Heavy gas oil 8-14 part; Caustic soda 2-4 part; Asbestos wool 6-12 part; Lime putty 25-40 part; Tung oil 15-20 part; Chlorobenzene is 5-10 part; Thixotropic agent is 5-8 part; Diethylenetriamine 6-8 part; Rosined soap 2-5 part; Toluene 1-2 part; Water 50-60 part.
As a preferred technical solution of the present invention: described rosined soap emulsified bitumen water-proof material, its moiety, take mass fraction representation as 100 parts, petroleum pitch; 1.5 parts of water glass; 11 parts of heavy gas oil; 3 parts, caustic soda; 9 parts of asbestos wools; 32 parts of lime putties; 18 parts of tung oil; Chlorobenzene is 8 parts; Thixotropic agent is 6 parts; 7 parts of diethylenetriamines; 3.5 parts of rosined soaps; 1.5 parts of toluene; 55 parts, water.
As a preferred technical solution of the present invention: described thixotropic agent adopts wilkinite.
beneficial effect:
A kind of rosined soap emulsified bitumen water-proof material of the present invention adopts above technical scheme compared with prior art, has following technique effect: 1, the product celsius temperature of resistance to 80-100; 2,5h is non-foaming at 90 ℃ does not trickle; 3, watertightness, at hydrodynamic pressure 0.1-0.2MPa, unchanged under 5h; 4, product resistance to deterioration is good, good weatherability, and waterproof and freedom from cracking, can the not division of history into periods of widespread production replace current material.
Embodiment
embodiment 1:
A kind of rosined soap emulsified bitumen water-proof material, its composition is take mass fraction representation as 100 parts, petroleum pitch; 1 part of water glass; 8 parts of heavy gas oil; 2 parts, caustic soda; 6 parts of asbestos wools; 25 parts of lime putties; 15 parts of tung oil; Chlorobenzene is 5 parts; Wilkinite is 5 parts; 6 parts of diethylenetriamines; 2 parts of rosined soaps; 1 part of toluene; 50 parts, water.Petroleum pitch is cut into small pieces, puts into reactor and be heated to 250 ℃ and dissolve dehydration, under agitation add all the other components, be cooled to 120 ℃ after stirring 30min, continue to stir discharging after 1h.
Resistance to 80 celsius temperatures of product; At 90 ℃, 5h is non-foaming does not trickle; Watertightness, at hydrodynamic pressure 0.1MPa, unchanged under 5h.
embodiment 2:
A kind of rosined soap emulsified bitumen water-proof material, its composition is take mass fraction representation as 100 parts, petroleum pitch; 2 parts of water glass; 14 parts of heavy gas oil; 4 parts, caustic soda; 12 parts of asbestos wools; 40 parts of lime putties; 20 parts of tung oil; Chlorobenzene is 10 parts; Wilkinite is 8 parts; 8 parts of diethylenetriamines; 5 parts of rosined soaps; 2 parts of toluene; 60 parts, water.Petroleum pitch is cut into small pieces, puts into reactor and be heated to 250 ℃ and dissolve dehydration, under agitation add all the other components, be cooled to 120 ℃ after stirring 30min, continue to stir discharging after 1h.
Resistance to 90 celsius temperatures of product; At 90 ℃, 5h is non-foaming does not trickle; Watertightness, at hydrodynamic pressure 0.15MPa, unchanged under 5h.
embodiment 3:
A kind of rosined soap emulsified bitumen water-proof material, its composition is take mass fraction representation as 100 parts, petroleum pitch; 1.5 parts of water glass; 11 parts of heavy gas oil; 3 parts, caustic soda; 9 parts of asbestos wools; 32 parts of lime putties; 18 parts of tung oil; Chlorobenzene is 8 parts; Wilkinite is 6 parts; 7 parts of diethylenetriamines; 3.5 parts of rosined soaps; 1.5 parts of toluene; 55 parts, water.Petroleum pitch is cut into small pieces, puts into reactor and be heated to 250 ℃ and dissolve dehydration, under agitation add all the other components, be cooled to 120 ℃ after stirring 30min, continue to stir discharging after 1h.
Resistance to 100 celsius temperatures of product; At 90 ℃, 5h is non-foaming does not trickle; Watertightness, at hydrodynamic pressure 0.2MPa, unchanged under 5h.
All components in above embodiment all can business be bought.
Above-described embodiment is just for content of the present invention is set forth, rather than restriction, and therefore any change in implication and the scope suitable with claims of the present invention, all should think to be included in the scope of claims.
Claims (3)
1. a rosined soap emulsified bitumen water-proof material, is characterized in that: its composition is take mass fraction representation as 100 parts, petroleum pitch; Water glass 1-2 part; Heavy gas oil 8-14 part; Caustic soda 2-4 part; Asbestos wool 6-12 part; Lime putty 25-40 part; Tung oil 15-20 part; Chlorobenzene is 5-10 part; Thixotropic agent is 5-8 part; Diethylenetriamine 6-8 part; Rosined soap 2-5 part; Toluene 1-2 part; Water 50-60 part.
2. a kind of rosined soap emulsified bitumen water-proof material according to claim 1, is characterized in that: its composition is take mass fraction representation as 100 parts, petroleum pitch; 1.5 parts of water glass; 11 parts of heavy gas oil; 3 parts, caustic soda; 9 parts of asbestos wools; 32 parts of lime putties; 18 parts of tung oil; Chlorobenzene is 8 parts; Thixotropic agent is 6 parts; 7 parts of diethylenetriamines; 3.5 parts of rosined soaps; 1.5 parts of toluene; 55 parts, water.
3. a kind of rosined soap emulsified bitumen water-proof material according to claim 1, is characterized in that: described thixotropic agent adopts wilkinite.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410023425.4A CN103773015A (en) | 2014-01-20 | 2014-01-20 | Rosin soap emulsified asphalt water-proof material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410023425.4A CN103773015A (en) | 2014-01-20 | 2014-01-20 | Rosin soap emulsified asphalt water-proof material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103773015A true CN103773015A (en) | 2014-05-07 |
Family
ID=50565809
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410023425.4A Withdrawn CN103773015A (en) | 2014-01-20 | 2014-01-20 | Rosin soap emulsified asphalt water-proof material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103773015A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115651541A (en) * | 2022-11-15 | 2023-01-31 | 广东复特新型材料科技有限公司 | Self-adhesion anti-aging superstrong ecological liquid waterproofing membrane |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN85105330A (en) * | 1985-07-10 | 1987-03-04 | 河南省商业科学研究所 | " Authracene oil-based " paint and method for making thereof |
| CN87102242A (en) * | 1987-03-20 | 1987-11-18 | 项晓红 | A kind of building water-proof paint |
| CN1096527A (en) * | 1993-06-18 | 1994-12-21 | 中国石化齐鲁石油化工公司 | Method for preparing thick modified asphalt waterproof paint |
| US5656733A (en) * | 1995-06-07 | 1997-08-12 | Hercules Incorporated | Lignin-containing resinous compositions |
| CN1300807A (en) * | 1999-12-17 | 2001-06-27 | 邵秋生 | Water-proof cold adhesive |
| US6512090B1 (en) * | 2000-11-15 | 2003-01-28 | Hercules Incorporated | Asphalt emulsion containing solidified pyrolytic wood tar oil |
| CN103086650A (en) * | 2012-11-12 | 2013-05-08 | 张家港市森达外加剂有限公司 | Emulsified asphalt waterproof agent for cement and fiber base plates and preparation method of emulsified asphalt waterproof agent |
| CN103205204A (en) * | 2013-04-17 | 2013-07-17 | 昆明风行防水材料有限公司 | High-strength rubber asphalt waterproof paint and preparation method thereof |
-
2014
- 2014-01-20 CN CN201410023425.4A patent/CN103773015A/en not_active Withdrawn
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN85105330A (en) * | 1985-07-10 | 1987-03-04 | 河南省商业科学研究所 | " Authracene oil-based " paint and method for making thereof |
| CN87102242A (en) * | 1987-03-20 | 1987-11-18 | 项晓红 | A kind of building water-proof paint |
| CN1096527A (en) * | 1993-06-18 | 1994-12-21 | 中国石化齐鲁石油化工公司 | Method for preparing thick modified asphalt waterproof paint |
| US5656733A (en) * | 1995-06-07 | 1997-08-12 | Hercules Incorporated | Lignin-containing resinous compositions |
| CN1300807A (en) * | 1999-12-17 | 2001-06-27 | 邵秋生 | Water-proof cold adhesive |
| US6512090B1 (en) * | 2000-11-15 | 2003-01-28 | Hercules Incorporated | Asphalt emulsion containing solidified pyrolytic wood tar oil |
| CN103086650A (en) * | 2012-11-12 | 2013-05-08 | 张家港市森达外加剂有限公司 | Emulsified asphalt waterproof agent for cement and fiber base plates and preparation method of emulsified asphalt waterproof agent |
| CN103205204A (en) * | 2013-04-17 | 2013-07-17 | 昆明风行防水材料有限公司 | High-strength rubber asphalt waterproof paint and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 周学良等: "《精细化工产品手册 涂料》", 31 May 2002, 化学工业出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115651541A (en) * | 2022-11-15 | 2023-01-31 | 广东复特新型材料科技有限公司 | Self-adhesion anti-aging superstrong ecological liquid waterproofing membrane |
| CN115651541B (en) * | 2022-11-15 | 2024-03-22 | 广东复特新型材料科技有限公司 | Self-adhesive anti-aging super-strong ecological liquid waterproof coiled material |
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| PB01 | Publication | ||
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Application publication date: 20140507 |