CN103771657B - A kind of processing method of chlopyrifos waste water - Google Patents
A kind of processing method of chlopyrifos waste water Download PDFInfo
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- CN103771657B CN103771657B CN201310706962.4A CN201310706962A CN103771657B CN 103771657 B CN103771657 B CN 103771657B CN 201310706962 A CN201310706962 A CN 201310706962A CN 103771657 B CN103771657 B CN 103771657B
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- waste water
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- sodium alcoholate
- trichloro pyridyl
- chlopyrifos
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- 239000002351 wastewater Substances 0.000 title claims abstract description 45
- 238000003672 processing method Methods 0.000 title claims abstract description 11
- 238000000034 method Methods 0.000 claims abstract description 13
- MFTSCJIEOYYRPN-UHFFFAOYSA-N ClC=1C(=C(C(=NC1)[Na])Cl)Cl Chemical compound ClC=1C(=C(C(=NC1)[Na])Cl)Cl MFTSCJIEOYYRPN-UHFFFAOYSA-N 0.000 claims abstract description 12
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 14
- 238000006243 chemical reaction Methods 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 6
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 6
- 238000005273 aeration Methods 0.000 claims description 6
- 229910052698 phosphorus Inorganic materials 0.000 claims description 6
- 239000011574 phosphorus Substances 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 6
- 238000007254 oxidation reaction Methods 0.000 claims description 4
- 229910021578 Iron(III) chloride Inorganic materials 0.000 claims description 3
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 claims description 3
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 3
- 239000003054 catalyst Substances 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 238000010790 dilution Methods 0.000 claims description 3
- 239000012895 dilution Substances 0.000 claims description 3
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims description 3
- 239000000395 magnesium oxide Substances 0.000 claims description 3
- 230000000813 microbial effect Effects 0.000 claims description 3
- 238000002203 pretreatment Methods 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- 230000003647 oxidation Effects 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 6
- 239000000126 substance Substances 0.000 abstract description 4
- 230000015556 catabolic process Effects 0.000 abstract description 3
- 238000006731 degradation reaction Methods 0.000 abstract description 3
- 230000000593 degrading effect Effects 0.000 abstract description 3
- 238000005868 electrolysis reaction Methods 0.000 abstract description 3
- CKMXBZGNNVIXHC-UHFFFAOYSA-L ammonium magnesium phosphate hexahydrate Chemical compound [NH4+].O.O.O.O.O.O.[Mg+2].[O-]P([O-])([O-])=O CKMXBZGNNVIXHC-UHFFFAOYSA-L 0.000 abstract description 2
- 230000007423 decrease Effects 0.000 abstract description 2
- 238000007599 discharging Methods 0.000 abstract description 2
- 238000001704 evaporation Methods 0.000 abstract description 2
- 230000008020 evaporation Effects 0.000 abstract description 2
- 244000005700 microbiome Species 0.000 abstract description 2
- 150000003839 salts Chemical class 0.000 abstract description 2
- 239000002699 waste material Substances 0.000 abstract description 2
- VMHZXXPDUOVTHD-UHFFFAOYSA-N 2,3,4-trichloropyridine Chemical compound ClC1=CC=NC(Cl)=C1Cl VMHZXXPDUOVTHD-UHFFFAOYSA-N 0.000 description 2
- -1 Chloropyridine sodium alkoxide Chemical class 0.000 description 2
- 230000003851 biochemical process Effects 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000000575 pesticide Substances 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 235000009024 Ceanothus sanguineus Nutrition 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 241000219146 Gossypium Species 0.000 description 1
- 240000003553 Leptospermum scoparium Species 0.000 description 1
- 235000015459 Lycium barbarum Nutrition 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 241000209140 Triticum Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000009418 agronomic effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000001055 chewing effect Effects 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000012851 eutrophication Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- NNKVPIKMPCQWCG-UHFFFAOYSA-N methamidophos Chemical compound COP(N)(=O)SC NNKVPIKMPCQWCG-UHFFFAOYSA-N 0.000 description 1
- PZXOQEXFMJCDPG-UHFFFAOYSA-N omethoate Chemical compound CNC(=O)CSP(=O)(OC)OC PZXOQEXFMJCDPG-UHFFFAOYSA-N 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 150000002903 organophosphorus compounds Chemical class 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 230000032696 parturition Effects 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 230000016776 visual perception Effects 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/30—Wastewater or sewage treatment systems using renewable energies
- Y02W10/37—Wastewater or sewage treatment systems using renewable energies using solar energy
Landscapes
- Treatment Of Water By Oxidation Or Reduction (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
Abstract
The invention discloses the processing method of a kind of chlopyrifos waste water, comprise the following steps: the degradation efficiency of organophosphor of the present invention is high, the general electrolysis of ratio, the biodegrading process such as Fenton process is easier to up to standard；Phos after degraded is prepared as guanite, and indices therein has all reached country and utilized standard, produces a large amount of abraum salt waste organic matters than evaporation and decreases secondary pollution；After organophosphor is degraded, the biodegradability of waste water is greatly improved, the indices of bio-chemical effluent all can meet discharging standards, simultaneously, trichloro pyridyl sodium alcoholate in the basic degrading waste water of microorganism energy of specific culture, water outlet trichloro pyridyl sodium alcoholate concentration is less than 1ppm, and after solar irradiation, waste water no longer reddens.
Description
Technical field
The invention mainly relates to a kind of method, particularly relate to the processing method of a kind of chlopyrifos waste water.
Background technology
Chlopyrifos is a kind of broad spectrum activity organophosphorus compounds that first Dow Chemical company developed in nineteen sixty-five
Insecticide, has efficiently, wide spectrum, low-residual and low drug-fast feature, have tag, stomach toxicity and steaming three
Recast use, to chewing type multiple on paddy rice, wheat, cotton, fruit tree, vegetables, tea tree and sucking mouth parts evil
Worm is respectively provided with favorable effect.Toxicity is low compared with conventional pesticide, to natural enemies security, is to substitute high-toxic organic phosphorus agriculture
The first-selected medicament of medicine (such as 1605, acephatemet, omethoate etc.).Chlopyrifos to preventing and treating diseases and pests of agronomic crop and
Ectozoa of domestic animals is the most significant.
Chlopyrifos pesticides produces in waste water containing the hardly degraded organic substance such as substantial amounts of organophosphor, trichloropyridine alcohol, has
Machine phosphorus can cause the serious ecological environment problems such as body eutrophication after entering water body.Additionally waste water contains
Trichloro pyridyl sodium alcoholate enables to water body and becomes red under the irradiation of sunshine, extremely affects visual perception.One
As organism P wastewater processing method include evaporative crystallization method, electrolysis, Fenton oxidation method etc., but these sides
Method treatment effeciency is low, and organic phosphorus degrading is thorough, often easily forms the water after secondary pollution, and process
Can not qualified discharge.Catalyzing hydrolysis oxidizing process is to utilize hydrogen peroxide and catalyst under the acid condition of HTHP
Be hydrolyzed reaction to the organic matter in chlopyrifos waste water so that the organophosphor in water body becomes phosphoric acid salt, then
The method removed by the precipitation method.It is high that the method has treatment effeciency, and the features such as cost is relatively low successfully solve
Chlopyrifos waste water difficult degradation, high saliferous, easy to change wait challenge.
Summary of the invention
The object of the invention is just to provide the processing method of a kind of chlopyrifos waste water.
The present invention is achieved by the following technical solutions:
The processing method of a kind of chlopyrifos waste water, comprises the following steps:
(1) waste water per ton adds hydrochloric acid 18-22 kilogram that mass fraction is 13-15% and reclaim three in waste water
Chloropyridine sodium alkoxide, solid trichloro pyridyl sodium alcoholate is used for reproduction；
(2) waste water after reclaiming trichloro pyridyl sodium alcoholate adds quality and accounts for the hydrogen peroxide of waste water total amount 0.5%,
Pre-oxidation, preoxidation time is 7-9 hour；
(3) waste water after the pre-treatment adds the ferric chloride (FeCl36H2O) that consumption is waste water weight 0.1-0.15%
As catalyst, it is stirring evenly and then adding into high pressure reaction assembly, opens stirring, be warming up to 110-120 DEG C, and
It is incubated 6-8 hour；
(4) reaction cools the temperature to 35-45 DEG C after terminating, and opens emission-control equipment, slowly opens aeration,
Aeration time is 0.5-1 hour；
(5) continue cooling and sample, analyzing total phosphorus and the concentration of ammonia nitrogen, and put into successively according to concentration quantitatively
Magnesia and ammoniacal liquor, regulation pH value to 8.5, stir 10-13 minute, after standing filtration；
(6) salinity of the waste water after analytical reactions, according to concentration Low-salinity wastewater dilution to can be biochemical dense
Degree, qualified discharge after the microbial biochemical process that special type is cultivated；
(7) filter the solid produced indices after analyzing all to be up to state standards, be sold to available
Unit.
The processing method of a kind of chlopyrifos waste water, the mass fraction of described hydrogen peroxide is 30-35%.
The invention have the advantage that
The biodegrading process such as the degradation efficiency of organophosphor of the present invention is high, the general electrolysis of ratio, Fenton process are easier to
Up to standard；Phos after degraded is prepared as guanite, and indices therein has all reached country and utilized standard,
Produce a large amount of abraum salt waste organic matters than evaporation and decrease secondary pollution；After organophosphor is degraded, giving birth to of waste water
The property changed is greatly improved, and the indices of bio-chemical effluent all can meet discharging standards, meanwhile, and specific culture
Trichloro pyridyl sodium alcoholate in the basic degrading waste water of microorganism energy, in water outlet, trichloro pyridyl sodium alcoholate concentration is less than 1ppm,
After solar irradiation, waste water no longer reddens.
Detailed description of the invention
Embodiment 1
The processing method of a kind of chlopyrifos waste water, comprises the following steps:
(1) waste water per ton adds the hydrochloric acid 20 kilograms that mass fraction is 15% and reclaim the trichloropyridine in waste water
Sodium alkoxide, solid trichloro pyridyl sodium alcoholate is used for reproduction；
(2) waste water after reclaiming trichloro pyridyl sodium alcoholate adds quality and accounts for the hydrogen peroxide of waste water total amount 0.5%,
Pre-oxidation, preoxidation time is 7 hours；
(3) adding consumption in waste water after the pre-treatment is that the ferric chloride (FeCl36H2O) of waste water weight 0.1% is as urging
Agent, is stirring evenly and then adding into high pressure reaction assembly, opens stirring, is warming up to 120 DEG C, and is incubated 8 hours；
(4) reaction cools the temperature to 35 DEG C after terminating, and opens emission-control equipment, slowly opens aeration, aeration
Time is 1 hour；
(5) continue cooling and sample, analyzing total phosphorus and the concentration of ammonia nitrogen, and put into successively according to concentration quantitatively
Magnesia and ammoniacal liquor, regulation pH value to 8.5, stir 13 minutes, after standing filtration；
(6) salinity of the waste water after analytical reactions, according to concentration Low-salinity wastewater dilution to can be biochemical dense
Degree, qualified discharge after the microbial biochemical process that special type is cultivated；
(7) filter the solid produced indices after analyzing all to be up to state standards, be sold to available
Unit.
The processing method of a kind of chlopyrifos waste water, the mass fraction of described hydrogen peroxide is 35%.
Claims (1)
1. the processing method of a chlopyrifos waste water, it is characterised in that comprise the following steps:
(1) adding hydrochloric acid 18-22 kilogram that mass fraction is 13-15% in waste water per ton and reclaim the trichloro pyridyl sodium alcoholate in waste water, solid trichloro pyridyl sodium alcoholate is used for reproduction；
(2) adding quality in the waste water after reclaiming trichloro pyridyl sodium alcoholate and account for the hydrogen peroxide of waste water total amount 0.5%, pre-oxidation, preoxidation time is 7-9 hour；
(3) waste water after the pre-treatment adds consumption be the ferric chloride (FeCl36H2O) of waste water weight 0.1-0.15% as catalyst, be stirring evenly and then adding into high pressure reaction assembly, open stirring, be warming up to 110-120 DEG C, and be incubated 6-8 hour；
(4) reaction cools the temperature to 35-45 DEG C after terminating, and opens emission-control equipment, slowly opens aeration, and aeration time is 0.5-1 hour；
(5) continuing cooling and sample, analyzing total phosphorus and the concentration of ammonia nitrogen, and put into quantitative magnesia and ammoniacal liquor according to concentration successively, regulation pH value, to 8.5, stirs 10-13 minute, filters after standing；
(6) salinity of the waste water after analytical reactions, according to concentration Low-salinity wastewater dilution to can be biochemical concentration, the microbial biochemical cultivated through special type process after qualified discharge；
(7) filter the solid produced indices after analyzing all to be up to state standards, be sold to available unit；
The mass fraction of described hydrogen peroxide is 30-35%.
Priority Applications (1)
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| CN201310706962.4A CN103771657B (en) | 2013-12-20 | 2013-12-20 | A kind of processing method of chlopyrifos waste water |
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| CN201310706962.4A CN103771657B (en) | 2013-12-20 | 2013-12-20 | A kind of processing method of chlopyrifos waste water |
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| CN103771657A CN103771657A (en) | 2014-05-07 |
| CN103771657B true CN103771657B (en) | 2016-08-24 |
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Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104447520A (en) * | 2014-11-13 | 2015-03-25 | 安徽国星生物化学有限公司 | Pretreatment process of synthetic waste liquid of 3,5-6-trichloropyridin-2-ol sodium |
| CN104445811A (en) * | 2014-11-13 | 2015-03-25 | 安徽国星生物化学有限公司 | Treatment process for 3,5,6-trichloropyridine-2-sodium alkoxide production wastewater |
| CN105084605B (en) * | 2015-09-15 | 2017-03-22 | 聊城大学 | Pretreatment technique of pyrazolone production wastewater |
| CN105481137A (en) * | 2015-12-04 | 2016-04-13 | 安徽国星生物化学有限公司 | Recycling treatment process for wastewater from chlorpyrifos production |
| CN110372150A (en) * | 2019-07-09 | 2019-10-25 | 安徽红太阳新材料有限公司 | A kind of processing method of chlopyrifos waste water |
| CN110723869B (en) * | 2019-10-09 | 2021-07-02 | 合肥停弦渡生物科技有限公司 | Improved Fenton sewage treatment method based on pre-oxidant |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS56152790A (en) * | 1980-04-25 | 1981-11-26 | Ebara Infilco Co Ltd | Treatment of waste water containing phosphorus and cod component |
| CN102531279A (en) * | 2011-12-06 | 2012-07-04 | 安徽锦邦化工股份有限公司 | N-(phosphonomethyl)iminodiacetic acid wastewater treatment process |
| CN102603094A (en) * | 2011-12-14 | 2012-07-25 | 湖北犇星农化有限责任公司 | Method for treating waste water during production of chlorpyrifos |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2553840C3 (en) * | 1975-11-29 | 1981-01-29 | Bayer Ag, 5090 Leverkusen | Pressure hydrolytic treatment of waste water |
| CN102774954A (en) * | 2012-07-18 | 2012-11-14 | 常州大学 | Method for removing high-concentration phosphorus from malathion waste water |
-
2013
- 2013-12-20 CN CN201310706962.4A patent/CN103771657B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS56152790A (en) * | 1980-04-25 | 1981-11-26 | Ebara Infilco Co Ltd | Treatment of waste water containing phosphorus and cod component |
| CN102531279A (en) * | 2011-12-06 | 2012-07-04 | 安徽锦邦化工股份有限公司 | N-(phosphonomethyl)iminodiacetic acid wastewater treatment process |
| CN102603094A (en) * | 2011-12-14 | 2012-07-25 | 湖北犇星农化有限责任公司 | Method for treating waste water during production of chlorpyrifos |
Non-Patent Citations (1)
| Title |
|---|
| 农药行业污染防治技术政策要点解析;程迪等;《中国农药》;20101231;第23-31页 * |
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| CN103771657A (en) | 2014-05-07 |
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