CN103757619A - Metal surface treating agent - Google Patents
Metal surface treating agent Download PDFInfo
- Publication number
- CN103757619A CN103757619A CN201310726192.XA CN201310726192A CN103757619A CN 103757619 A CN103757619 A CN 103757619A CN 201310726192 A CN201310726192 A CN 201310726192A CN 103757619 A CN103757619 A CN 103757619A
- Authority
- CN
- China
- Prior art keywords
- mass parts
- amine
- metal surface
- treating agent
- lauryl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 19
- 239000002184 metal Substances 0.000 title claims abstract description 19
- -1 laurinol Chemical compound 0.000 claims abstract description 29
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 claims abstract description 24
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 claims abstract description 22
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims abstract description 18
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 12
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims abstract description 12
- FJLUATLTXUNBOT-UHFFFAOYSA-N 1-Hexadecylamine Chemical compound CCCCCCCCCCCCCCCCN FJLUATLTXUNBOT-UHFFFAOYSA-N 0.000 claims abstract description 6
- BMVXCPBXGZKUPN-UHFFFAOYSA-N 1-hexanamine Chemical compound CCCCCCN BMVXCPBXGZKUPN-UHFFFAOYSA-N 0.000 claims abstract description 6
- REYJJPSVUYRZGE-UHFFFAOYSA-N Octadecylamine Chemical compound CCCCCCCCCCCCCCCCCCN REYJJPSVUYRZGE-UHFFFAOYSA-N 0.000 claims abstract description 6
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 6
- 150000001412 amines Chemical class 0.000 claims abstract description 6
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000012964 benzotriazole Substances 0.000 claims abstract description 6
- JRBPAEWTRLWTQC-UHFFFAOYSA-N dodecylamine Chemical compound CCCCCCCCCCCCN JRBPAEWTRLWTQC-UHFFFAOYSA-N 0.000 claims abstract description 6
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 claims abstract description 6
- HKUFIYBZNQSHQS-UHFFFAOYSA-N n-octadecyloctadecan-1-amine Chemical compound CCCCCCCCCCCCCCCCCCNCCCCCCCCCCCCCCCCCC HKUFIYBZNQSHQS-UHFFFAOYSA-N 0.000 claims abstract description 6
- JACMPVXHEARCBO-UHFFFAOYSA-N n-pentylpentan-1-amine Chemical compound CCCCCNCCCCC JACMPVXHEARCBO-UHFFFAOYSA-N 0.000 claims abstract description 6
- IOQPZZOEVPZRBK-UHFFFAOYSA-N octan-1-amine Chemical compound CCCCCCCCN IOQPZZOEVPZRBK-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 6
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 6
- MCJGNVYPOGVAJF-UHFFFAOYSA-N quinolin-8-ol Chemical compound C1=CN=C2C(O)=CC=CC2=C1 MCJGNVYPOGVAJF-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims abstract description 6
- 235000017557 sodium bicarbonate Nutrition 0.000 claims abstract description 6
- 239000003760 tallow Substances 0.000 claims abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 6
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 claims description 10
- 239000002253 acid Substances 0.000 claims description 6
- VRNDMQIKCQJEBH-UHFFFAOYSA-N CO[SiH](OC)OC.CC1C(O1)OC1C(C)O1 Chemical class CO[SiH](OC)OC.CC1C(O1)OC1C(C)O1 VRNDMQIKCQJEBH-UHFFFAOYSA-N 0.000 claims description 5
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 5
- MHZGKXUYDGKKIU-UHFFFAOYSA-N Decylamine Chemical compound CCCCCCCCCCN MHZGKXUYDGKKIU-UHFFFAOYSA-N 0.000 claims description 5
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 5
- 229920006184 cellulose methylcellulose Polymers 0.000 claims description 5
- 239000011153 ceramic matrix composite Substances 0.000 claims description 5
- 238000012710 chemistry, manufacturing and control Methods 0.000 claims description 5
- 150000002148 esters Chemical class 0.000 claims description 5
- 229960004418 trolamine Drugs 0.000 claims description 5
- 239000011248 coating agent Substances 0.000 abstract description 2
- 238000000576 coating method Methods 0.000 abstract description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 abstract 3
- 239000003795 chemical substances by application Substances 0.000 abstract 3
- DAFHKNAQFPVRKR-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylpropanoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)C DAFHKNAQFPVRKR-UHFFFAOYSA-N 0.000 abstract 1
- DKCPKDPYUFEZCP-UHFFFAOYSA-N 2,6-di-tert-butylphenol Chemical compound CC(C)(C)C1=CC=CC(C(C)(C)C)=C1O DKCPKDPYUFEZCP-UHFFFAOYSA-N 0.000 abstract 1
- 239000005725 8-Hydroxyquinoline Substances 0.000 abstract 1
- 229920002101 Chitin Polymers 0.000 abstract 1
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 230000007797 corrosion Effects 0.000 abstract 1
- 238000005260 corrosion Methods 0.000 abstract 1
- MJCJUDJQDGGKOX-UHFFFAOYSA-N n-dodecyldodecan-1-amine Chemical compound CCCCCCCCCCCCNCCCCCCCCCCCC MJCJUDJQDGGKOX-UHFFFAOYSA-N 0.000 abstract 1
- 229960003540 oxyquinoline Drugs 0.000 abstract 1
- 229910000077 silane Inorganic materials 0.000 abstract 1
- 238000000034 method Methods 0.000 description 4
- 230000002421 anti-septic effect Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Landscapes
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a metal surface treating agent. The metal surface treating agent comprises the following components: vinyl trimethoxy silane, laurinol, 2,2,4-Trimethyl-1,3-pentanediol monoisobutyrate, hydroquinone, ethanol, water, gamma-allyl glycidyl ether trimethoxy silane, benzotriazole, 4,4-methylene (2,6-di-tert-butylphenol), tallow amine, octyl amine, decyl alkyl amine, triethylamine, 8-hydroxyquinoline, hexyl amine, diamylamine, water-soluble chitin, nonox, didodecylamine, dioctadecylamine, triethanolamine, dodecylamine, hexadecylamine, octadecylamine, resorcinol, pyrocatechol, catechol, 2,6-di-tert-butyl-alpha-dimethylamino hydroquinone, fatty alcohol-polyoxyethylene ether, alkylphenol ethoxylates, polyoxyethylene stearates, and sodium bicarbonate. The metal surface treating agent obviously improves the adhesive force on the metal surface and realizes the corrosion resistance during coating of the whole metal.
Description
Technical field
The present invention relates to metal conditioner.
Background technology
At present, at paint industry, metal products is the application of sheet material especially, conventionally adopts phosphating process to improve the sticking power of coating and metal.But Phosphating Solution use temperature need reach 45 ~ 65 ℃, and energy consumption is high; In parkerizing process, generate a large amount of sediments, not only wasted pharmaceutical chemicals but also increased and removed the workload of waste residue, as dealt with the quality that also can affect phosphatize phosphate coat improperly; Complex procedures, production continuity is poor.Meanwhile, in scale removal process, need to use a large amount of strong acid and highly basic, increase pollutant emission load.
Summary of the invention
The object of the present invention is to provide a kind of metal conditioner, the sticking power that it has significantly improved metallic surface, is conducive to the antiseptic property of whole coated metal.
For achieving the above object, technical scheme of the present invention is a kind of metal conditioner of design, following component, consists of:
4-5 mass parts vinyltrimethoxy silane, 0.5 mass parts lauryl alcohol, 2 mass parts lauryl alcohol esters, 0.3 mass parts Resorcinol, 13 mass parts ethanol, 95 mass parts water, 8 mass parts γ-epoxypropyl ether Trimethoxy silanes, 0.1 mass parts benzotriazole, 0.2 mass parts 4, 4-methylene radical (2, 6-DI-tert-butylphenol compounds), 0.8 mass parts tallow amine, 0.1 mass parts octyl amine, 0.4 mass parts decyl amine, 0.3 mass parts triethylamine, 0.2 mass parts oxine, 0.3 mass parts hexyl amine, 0.1 mass parts diamylamine, 12 mass parts N,O-CMCs, 0.2 mass parts nonox, the two lauryl amines of 0.1 mass parts, 0.2 mass parts dioctadecylamine, 0.4 mass parts trolamine, 0.2 mass parts lauryl amine, 0.1 mass parts cetylamine, 0.5 mass parts octadecylamine, 0.8 mass parts Resorcinol, 0.7 mass parts pyrocatechol, 0.5 mass parts catechol, 0.3 mass parts 2, 6-di-t-butyl-alpha, alpha-dimethyl amido Pyrogentisinic Acid, 0.4 mass parts fatty alcohol-polyoxyethylene ether, 0.7 mass parts alkylphenol polyoxyethylene, 0.5 mass parts polyoxyethylene stearic acid ester, 0.7 mass parts sodium bicarbonate.
Advantage of the present invention and beneficial effect are: a kind of metal conditioner is provided, and the sticking power that it has significantly improved metallic surface, is conducive to the antiseptic property of whole coated metal.
Embodiment
Below in conjunction with embodiment, the specific embodiment of the present invention is further described.Following examples are only for technical scheme of the present invention is more clearly described, and can not limit the scope of the invention with this.
The concrete technical scheme of implementing of the present invention is:
Embodiment 1
A kind of metal conditioner, is comprised of following component:
5 mass parts vinyltrimethoxy silanes, 0.5 mass parts lauryl alcohol, 2 mass parts lauryl alcohol esters, 0.3 mass parts Resorcinol, 13 mass parts ethanol, 95 mass parts water, 8 mass parts γ-epoxypropyl ether Trimethoxy silanes, 0.1 mass parts benzotriazole, 0.2 mass parts 4, 4-methylene radical (2, 6-DI-tert-butylphenol compounds), 0.8 mass parts tallow amine, 0.1 mass parts octyl amine, 0.4 mass parts decyl amine, 0.3 mass parts triethylamine, 0.2 mass parts oxine, 0.3 mass parts hexyl amine, 0.1 mass parts diamylamine, 12 mass parts N,O-CMCs, 0.2 mass parts nonox, the two lauryl amines of 0.1 mass parts, 0.2 mass parts dioctadecylamine, 0.4 mass parts trolamine, 0.2 mass parts lauryl amine, 0.1 mass parts cetylamine, 0.5 mass parts octadecylamine, 0.8 mass parts Resorcinol, 0.7 mass parts pyrocatechol, 0.5 mass parts catechol, 0.3 mass parts 2, 6-di-t-butyl-alpha, alpha-dimethyl amido Pyrogentisinic Acid, 0.4 mass parts fatty alcohol-polyoxyethylene ether, 0.7 mass parts alkylphenol polyoxyethylene, 0.5 mass parts polyoxyethylene stearic acid ester, 0.7 mass parts sodium bicarbonate.
Embodiment 2
A kind of metal conditioner, is comprised of following component:
4 mass parts vinyltrimethoxy silanes, 0.5 mass parts lauryl alcohol, 2 mass parts lauryl alcohol esters, 0.3 mass parts Resorcinol, 13 mass parts ethanol, 95 mass parts water, 8 mass parts γ-epoxypropyl ether Trimethoxy silanes, 0.1 mass parts benzotriazole, 0.2 mass parts 4, 4-methylene radical (2, 6-DI-tert-butylphenol compounds), 0.8 mass parts tallow amine, 0.1 mass parts octyl amine, 0.4 mass parts decyl amine, 0.3 mass parts triethylamine, 0.2 mass parts oxine, 0.3 mass parts hexyl amine, 0.1 mass parts diamylamine, 12 mass parts N,O-CMCs, 0.2 mass parts nonox, the two lauryl amines of 0.1 mass parts, 0.2 mass parts dioctadecylamine, 0.4 mass parts trolamine, 0.2 mass parts lauryl amine, 0.1 mass parts cetylamine, 0.5 mass parts octadecylamine, 0.8 mass parts Resorcinol, 0.7 mass parts pyrocatechol, 0.5 mass parts catechol, 0.3 mass parts 2, 6-di-t-butyl-alpha, alpha-dimethyl amido Pyrogentisinic Acid, 0.4 mass parts fatty alcohol-polyoxyethylene ether, 0.7 mass parts alkylphenol polyoxyethylene, 0.5 mass parts polyoxyethylene stearic acid ester, 0.7 mass parts sodium bicarbonate.
Embodiment 3
A kind of metal conditioner, is comprised of following component:
4.5 mass parts vinyltrimethoxy silanes, 0.5 mass parts lauryl alcohol, 2 mass parts lauryl alcohol esters, 0.3 mass parts Resorcinol, 13 mass parts ethanol, 95 mass parts water, 8 mass parts γ-epoxypropyl ether Trimethoxy silanes, 0.1 mass parts benzotriazole, 0.2 mass parts 4, 4-methylene radical (2, 6-DI-tert-butylphenol compounds), 0.8 mass parts tallow amine, 0.1 mass parts octyl amine, 0.4 mass parts decyl amine, 0.3 mass parts triethylamine, 0.2 mass parts oxine, 0.3 mass parts hexyl amine, 0.1 mass parts diamylamine, 12 mass parts N,O-CMCs, 0.2 mass parts nonox, the two lauryl amines of 0.1 mass parts, 0.2 mass parts dioctadecylamine, 0.4 mass parts trolamine, 0.2 mass parts lauryl amine, 0.1 mass parts cetylamine, 0.5 mass parts octadecylamine, 0.8 mass parts Resorcinol, 0.7 mass parts pyrocatechol, 0.5 mass parts catechol, 0.3 mass parts 2, 6-di-t-butyl-alpha, alpha-dimethyl amido Pyrogentisinic Acid, 0.4 mass parts fatty alcohol-polyoxyethylene ether, 0.7 mass parts alkylphenol polyoxyethylene, 0.5 mass parts polyoxyethylene stearic acid ester, 0.7 mass parts sodium bicarbonate.
The above is only the preferred embodiment of the present invention; it should be pointed out that for those skilled in the art, do not departing under the prerequisite of the technology of the present invention principle; can also make some improvements and modifications, these improvements and modifications also should be considered as protection scope of the present invention.
Claims (1)
1. metal conditioner, is characterized in that, following component, consists of:
4-5 mass parts vinyltrimethoxy silane, 0.5 mass parts lauryl alcohol, 2 mass parts lauryl alcohol esters, 0.3 mass parts Resorcinol, 13 mass parts ethanol, 95 mass parts water, 8 mass parts γ-epoxypropyl ether Trimethoxy silanes, 0.1 mass parts benzotriazole, 0.2 mass parts 4, 4-methylene radical (2, 6-DI-tert-butylphenol compounds), 0.8 mass parts tallow amine, 0.1 mass parts octyl amine, 0.4 mass parts decyl amine, 0.3 mass parts triethylamine, 0.2 mass parts oxine, 0.3 mass parts hexyl amine, 0.1 mass parts diamylamine, 12 mass parts N,O-CMCs, 0.2 mass parts nonox, the two lauryl amines of 0.1 mass parts, 0.2 mass parts dioctadecylamine, 0.4 mass parts trolamine, 0.2 mass parts lauryl amine, 0.1 mass parts cetylamine, 0.5 mass parts octadecylamine, 0.8 mass parts Resorcinol, 0.7 mass parts pyrocatechol, 0.5 mass parts catechol, 0.3 mass parts 2, 6-di-t-butyl-alpha, alpha-dimethyl amido Pyrogentisinic Acid, 0.4 mass parts fatty alcohol-polyoxyethylene ether, 0.7 mass parts alkylphenol polyoxyethylene, 0.5 mass parts polyoxyethylene stearic acid ester, 0.7 mass parts sodium bicarbonate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310726192.XA CN103757619A (en) | 2013-12-26 | 2013-12-26 | Metal surface treating agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310726192.XA CN103757619A (en) | 2013-12-26 | 2013-12-26 | Metal surface treating agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103757619A true CN103757619A (en) | 2014-04-30 |
Family
ID=50524933
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310726192.XA Pending CN103757619A (en) | 2013-12-26 | 2013-12-26 | Metal surface treating agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103757619A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104099630A (en) * | 2014-06-30 | 2014-10-15 | 张家港沙龙精密管业有限公司 | Cleaning agent for surface of metal pipe |
| CN104593763A (en) * | 2015-01-22 | 2015-05-06 | 南通恒隆化工有限公司 | Metal surface treatment agent |
| CN104862681A (en) * | 2015-04-08 | 2015-08-26 | 安徽豪鼎金属制品有限公司 | Sericin emulsified metal surface treating agent |
| CN105463437A (en) * | 2015-12-09 | 2016-04-06 | 常熟市常宝电动过跨平车厂 | Electric rail car |
| CN107513703A (en) * | 2017-08-24 | 2017-12-26 | 南通市烨达汽车零部件有限公司 | A kind of automobile using surface metal inorganic agent |
| CN110100044A (en) * | 2016-12-22 | 2019-08-06 | 汉高股份有限及两合公司 | The pre-formed reaction product of catechin compounds and functionalization coreaction compound reduces the purposes of bare metal surface oxidation |
| US11407921B2 (en) | 2016-12-22 | 2022-08-09 | Henkel Ag & Co. Kgaa | Reaction products of catechol compounds and functionalized co-reactant compounds for metal pretreatment applications |
| US11891534B2 (en) | 2016-12-22 | 2024-02-06 | Henkel Ag & Co. Kgaa | Treatment of conversion-coated metal substrates with preformed reaction products of catechol compounds and functionalized co-reactant compounds |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104099630A (en) * | 2014-06-30 | 2014-10-15 | 张家港沙龙精密管业有限公司 | Cleaning agent for surface of metal pipe |
| CN104593763A (en) * | 2015-01-22 | 2015-05-06 | 南通恒隆化工有限公司 | Metal surface treatment agent |
| CN104862681A (en) * | 2015-04-08 | 2015-08-26 | 安徽豪鼎金属制品有限公司 | Sericin emulsified metal surface treating agent |
| CN105463437A (en) * | 2015-12-09 | 2016-04-06 | 常熟市常宝电动过跨平车厂 | Electric rail car |
| CN110100044A (en) * | 2016-12-22 | 2019-08-06 | 汉高股份有限及两合公司 | The pre-formed reaction product of catechin compounds and functionalization coreaction compound reduces the purposes of bare metal surface oxidation |
| US11407921B2 (en) | 2016-12-22 | 2022-08-09 | Henkel Ag & Co. Kgaa | Reaction products of catechol compounds and functionalized co-reactant compounds for metal pretreatment applications |
| US11891534B2 (en) | 2016-12-22 | 2024-02-06 | Henkel Ag & Co. Kgaa | Treatment of conversion-coated metal substrates with preformed reaction products of catechol compounds and functionalized co-reactant compounds |
| US12227668B2 (en) | 2016-12-22 | 2025-02-18 | Henkel Ag & Co. Kgaa | Use of preformed reaction products of catechol compounds and functionalized co-reactant compounds to reduce oxidation of bare metal surfaces |
| CN107513703A (en) * | 2017-08-24 | 2017-12-26 | 南通市烨达汽车零部件有限公司 | A kind of automobile using surface metal inorganic agent |
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Application publication date: 20140430 |