CN103756696B - Double fluidized bed combustible solid waste pyrolysis oil-gas coproduction device and method - Google Patents
Double fluidized bed combustible solid waste pyrolysis oil-gas coproduction device and method Download PDFInfo
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Abstract
本发明公开了一种双流化床可燃固体废弃物热解油气联产装置及方法,所述包括竖直设置的热解反应器和燃烧反应器;所述热解反应器内设置有热解反应器底部布风装置和热解反应器管式布风装置,所述燃烧反应器内设置有燃烧反应器板式布风装置,所述热解反应器排风口接入热解反应器旋风分离器,所述燃烧反应器排风口接入燃烧反应器旋风分离器。本发明结合城市垃圾热解技术中存在的原料来源与成分复杂的现状,解决了农林废弃物热解技术在实际工业应用中面对的农林废弃物生产量供应不稳定和种类变化大等问题,控制方便、运行稳定且运行参数调整范围广。
The invention discloses a dual-fluidized bed combustible solid waste pyrolysis oil-gas cogeneration device and method, which comprises a vertically arranged pyrolysis reactor and a combustion reactor; the pyrolysis reactor is equipped with a pyrolysis The air distribution device at the bottom of the reactor and the tubular air distribution device of the pyrolysis reactor, the combustion reactor is equipped with a plate type air distribution device inside the combustion reactor, and the air outlet of the pyrolysis reactor is connected to the pyrolysis reactor for cyclone separation The exhaust port of the combustion reactor is connected to the cyclone separator of the combustion reactor. Combining the current situation of complex raw material sources and components existing in the pyrolysis technology of urban waste, the present invention solves the problems of unstable production and supply of agricultural and forestry waste and large variety changes in the actual industrial application of the pyrolysis technology of agricultural and forestry waste. The control is convenient, the operation is stable and the operation parameters can be adjusted in a wide range.
Description
技术领域technical field
本发明涉及一种双流化床可燃固体废弃物热解油气联产装置及方法,用于包括农林废弃物和城市生活垃圾在内的可燃固体废弃物的再利用,属于可燃固体废弃物的热处理再利用技术。The invention relates to a dual-fluidized bed combustible solid waste pyrolysis oil-gas cogeneration device and method, which is used for the reuse of combustible solid waste including agricultural and forestry waste and urban domestic waste, and belongs to the heat treatment of combustible solid waste reuse technology.
背景技术Background technique
我国是农林大国,在每年的农林生产中产生的农林废弃物总量相当可观,每年仅农作物秸秆和林业采伐加工剩余物的数量就多达十多亿吨,大约相当于5亿吨标准煤。其中,作为农业生产中最为常见的副产品秸秆,随着我国农业的连年增产其全国产量已经突破8亿吨,约合3.8亿吨标准煤。就林业废弃物而言,“十一五”期间,我国每年产生的林业采伐剩余物量达到1.09亿吨。因此,对总量如此之大的农林废弃物进行高效利用,不论是对于我国能源问题的缓解还是对于我国可持续发展战略的实施都具有重要的意义与影响。当前涉及农林废弃物的能源转换再利用技术很多,热解技术在众多选项中,由于其生产技术相对易于操作、工业化放大难度较低同时热解产生的气体与固体能源产物能量密度较高且使用方便而得到广泛的关注与应用。但是由于农林废弃物的产生具有一定的季节性以及地域性,使得农林废弃物热解技术实现稳定工业化运行的过程中存在一定困难,具体表现为热解生产的农林废弃物生产供应量波动较大,而且农林废弃物的成分构成变化频繁使得产物组成比例也存在一定的不稳定性。my country is a large country in agriculture and forestry. The total amount of agricultural and forestry waste produced in the annual agricultural and forestry production is quite considerable. The amount of crop straw and forestry logging and processing residues alone reaches more than one billion tons each year, equivalent to about 500 million tons of standard coal. Among them, as the most common by-product of agricultural production, straw, its national output has exceeded 800 million tons, equivalent to about 380 million tons of standard coal. As far as forestry waste is concerned, during the "Eleventh Five-Year Plan" period, the amount of forestry logging residues produced in my country reached 109 million tons every year. Therefore, the efficient utilization of such a large amount of agricultural and forestry wastes is of great significance and influence both for the alleviation of my country's energy problems and for the implementation of my country's sustainable development strategy. There are currently many energy conversion and reuse technologies involving agricultural and forestry wastes. Among the many options, pyrolysis technology is relatively easy to operate and less difficult to industrialize. It is convenient and widely concerned and applied. However, due to the seasonality and regionality of agricultural and forestry wastes, there are certain difficulties in the process of realizing stable industrial operation of agricultural and forestry waste pyrolysis technology, which is specifically manifested in the large fluctuations in the production and supply of agricultural and forestry waste produced by pyrolysis , and the frequent changes in the composition of agricultural and forestry waste make the product composition ratio also have certain instability.
另一方面,随着我国经济的高速增长和生活水平的稳步提高,城市固体废弃物的产量迅速增加,热值也在不断提高。如何对数量急剧增长的城市垃圾进行安全干净地处理同时合理利用城市垃圾转化为有效能源,吸引了越来越多研究者的重视,而当前被广泛注意的一种城市垃圾处理技术正是热解技术。城市生活垃圾热解能够处理不适于焚烧和填埋的难处理物,同时声称可燃性的气体或液体。但是由于城市垃圾的组成相当复杂,导致实际工业应用中城市垃圾的热解控制有一定困难同时产物的各组成成分比例变化也较明显。On the other hand, with the rapid growth of my country's economy and the steady improvement of living standards, the output of municipal solid waste has increased rapidly, and its calorific value has also continued to increase. How to safely and cleanly deal with the rapidly increasing amount of urban waste and rationally use urban waste to convert it into effective energy has attracted more and more researchers' attention. At present, a kind of urban waste treatment technology that is widely paid attention to is pyrolysis. technology. Municipal solid waste pyrolysis can process refractory materials that are not suitable for incineration and landfill, and at the same time claim flammable gases or liquids. However, due to the complex composition of municipal waste, it is difficult to control the pyrolysis of municipal waste in practical industrial applications, and the proportion of each component of the product also changes significantly.
发明内容Contents of the invention
发明目的:针对农林废弃物热解技术在实际工业应用中面对的农林废弃物生产量供应不稳定和种类变化大等问题,结合城市垃圾热解技术中存在的原料来源与成分复杂的现状,本发明目的是提供一种控制方便、运行稳定且运行参数调整范围广,适用于主要包括农林废弃物与城市垃圾的多种可燃固体垃圾交替利用的双流化床热解油气联产装置及方法。Purpose of the invention: Aiming at the problems of unstable production and supply of agricultural and forestry waste and large variety of types of agricultural and forestry waste pyrolysis technology in practical industrial applications, combined with the current situation of complex raw material sources and components in urban waste pyrolysis technology, The object of the present invention is to provide a dual-fluidized bed pyrolysis oil-gas cogeneration device and method that is convenient to control, stable in operation, and has a wide range of adjustment of operating parameters, and is suitable for the alternate utilization of various combustible solid wastes mainly including agricultural and forestry wastes and urban wastes .
技术方案:为实现上述目的,本发明采用的技术方案为:Technical scheme: in order to achieve the above object, the technical scheme adopted in the present invention is:
一种双流化床可燃固体废弃物热解油气联产装置,包括竖直设置的热解反应器和燃烧反应器;A dual-fluidized bed combustible solid waste pyrolysis oil-gas cogeneration device, including a vertically arranged pyrolysis reactor and a combustion reactor;
所述热解反应器内设置有热解反应器底部布风装置和热解反应器管式布风装置,在热解反应器的侧壁上由上至下设置有热解反应器溢料口、热解反应器进料口、热解反应器双向返料器返料口和热解反应器单向返料器返料口,在热解反应器的底部设置有热解反应器排渣口,在热解反应器的顶部设置有热解反应器排风口;所述热解反应器管式布风装置位置高于热解反应器底部布风装置,热解反应器进料口位置高于热解反应器管式布风装置,热解反应器双向返料器返料口和热解反应器单向返料器返料口位置高度置于热解反应器底部布风装置和热解反应器管式布风装置之间;原料加料器与热解反应器进料口相连;The pyrolysis reactor is provided with a pyrolysis reactor bottom air distribution device and a pyrolysis reactor tubular air distribution device, and a pyrolysis reactor overflow port is arranged on the side wall of the pyrolysis reactor from top to bottom , pyrolysis reactor feed port, pyrolysis reactor two-way feeder return port and pyrolysis reactor one-way feeder return port, pyrolysis reactor slag discharge port is set at the bottom of the pyrolysis reactor , the top of the pyrolysis reactor is provided with a pyrolysis reactor air outlet; the position of the pyrolysis reactor tubular air distribution device is higher than that of the pyrolysis reactor bottom air distribution device, and the position of the pyrolysis reactor feed port is high In the pyrolysis reactor tubular air distribution device, the height of the position of the return port of the pyrolysis reactor's two-way feeder and the pyrolysis reactor's one-way feeder is placed at the bottom of the pyrolysis reactor. Between the tubular air distribution devices of the reactor; the raw material feeder is connected to the feed port of the pyrolysis reactor;
所述燃烧反应器内设置有燃烧反应器板式布风装置,在燃烧反应器的侧壁上由上至下设置有燃烧反应器溢料口、燃烧反应器进料口和燃烧反应器返料口,在燃烧反应器的底部设置有燃烧反应器排渣口,在燃烧反应器的顶部设置有燃烧反应器排风口;所述燃烧反应器返料口位置高于燃烧反应器板式布风装置;辅助燃料加料器与燃烧反应器进料口相连;The combustion reactor is equipped with a combustion reactor plate-type air distribution device, and the combustion reactor overflow port, the combustion reactor feed port and the combustion reactor return port are arranged on the side wall of the combustion reactor from top to bottom. , the bottom of the combustion reactor is provided with a combustion reactor slag outlet, and the top of the combustion reactor is provided with a combustion reactor air outlet; the position of the combustion reactor return port is higher than the combustion reactor plate air distribution device; The auxiliary fuel feeder is connected with the feed port of the combustion reactor;
所述热解反应器排风口接入热解反应器旋风分离器,所述热解反应器旋风分离器的下出料端通过第一返料下降管与双向返料器的进料管相连,双向返料器的第一返料斜管和第二返料斜管分别与热解反应器双向返料器返料口和燃烧反应器返料口相连;所述热解反应器溢料口通过向下倾斜的第一斜管与第一返料下降管连通,在第一斜管上设置有热解反应器溢料装置;所述热解反应器旋风分离器的上排气端接入第一级冷凝器进行热解产品回收;The air outlet of the pyrolysis reactor is connected to the cyclone separator of the pyrolysis reactor, and the lower discharge end of the cyclone separator of the pyrolysis reactor is connected to the feed pipe of the two-way feeder through the first return material drop pipe , the first inclined pipe and the second inclined pipe of the two-way feeder are respectively connected to the return port of the bidirectional return device of the pyrolysis reactor and the return port of the combustion reactor; the overflow port of the pyrolysis reactor The first inclined pipe that is inclined downward communicates with the first return material descending pipe, and a pyrolysis reactor overflow device is arranged on the first inclined pipe; the upper exhaust end of the cyclone separator of the pyrolysis reactor is connected to The first-stage condenser recovers pyrolysis products;
所述燃烧反应器排风口接入燃烧反应器旋风分离器,所述燃烧反应器旋风分离器的下出料端通过第二返料下降管与单向返料器的进料端相连,单向返料器的出料端与热解反应器单向返料器返料口相连;所述燃烧反应器溢料口通过向下倾斜的第二斜管与第二返料下降管连通,在第二斜管上设置有燃烧反应器溢料装置;所述燃烧反应器旋风分离器的上排气端接入热管换热器进行热能回收。The exhaust port of the combustion reactor is connected to the cyclone separator of the combustion reactor, and the lower discharge end of the cyclone separator of the combustion reactor is connected to the feed end of the one-way return feeder through the second return material drop pipe, and the single The discharge end of the feeder is connected with the return port of the one-way feeder of the pyrolysis reactor; the overflow port of the combustion reactor is communicated with the second return drop pipe through the second inclined pipe inclined downward, A combustion reactor overflow device is arranged on the second inclined pipe; the upper exhaust end of the combustion reactor cyclone separator is connected to a heat pipe heat exchanger for heat energy recovery.
优选的,所述热解反应器旋风分离器的上排气端接入第一级冷凝器;第一级冷凝器的液体出口接入第一热解油收集罐,第一级冷凝器的气体出口接入第二级冷凝器;第二级冷凝器的液体出口接入第二热解油收集罐,第二级冷凝器的气体出口接入脱水塔;脱水塔气体出口分为两路,一路接入热解气产品输出通道,另一路接入热管换热器下端入口;Preferably, the upper exhaust end of the pyrolysis reactor cyclone separator is connected to the first-stage condenser; the liquid outlet of the first-stage condenser is connected to the first pyrolysis oil collection tank, and the gas in the first-stage condenser The outlet is connected to the second-stage condenser; the liquid outlet of the second-stage condenser is connected to the second pyrolysis oil collection tank, and the gas outlet of the second-stage condenser is connected to the dehydration tower; the gas outlet of the dehydration tower is divided into two paths, one It is connected to the output channel of pyrolysis gas products, and the other is connected to the lower inlet of the heat pipe heat exchanger;
所述燃烧反应器旋风分离器的上排气端接入热管换热器上端入口;热管换热器上端出口与热解反应器管式布风装置和热解反应器底部布风装置相连,热管换热器下端出口与烟气净化装置相连,烟气净化装置气体出口与布袋除尘器相连。The upper exhaust end of the cyclone separator of the combustion reactor is connected to the upper inlet of the heat pipe heat exchanger; the upper outlet of the heat pipe heat exchanger is connected with the pyrolysis reactor tubular air distribution device and the pyrolysis reactor bottom air distribution device, and the heat pipe The outlet at the lower end of the heat exchanger is connected to the flue gas purification device, and the gas outlet of the flue gas purification device is connected to the bag filter.
优选的,所述热解反应器溢料装置调节热解反应器工作于鼓泡流化态、湍流流化态或快速流化态;所述燃烧反应器溢料装置调节燃烧反应器工作于鼓泡流化态、湍流流化态或快速流化态。Preferably, the pyrolysis reactor overflow device adjusts the pyrolysis reactor to work in a bubbling fluidized state, a turbulent fluidized state or a fast fluidized state; the combustion reactor overflow device adjusts the combustion reactor to work in a drum bubbly fluidization, turbulent fluidization or fast fluidization.
优选的,所述热解反应器的高度为H,由热解反应器的底部起:热解反应器管式布风装置的高度为0.2~0.3H,热解反应器进料口的高度为0.35~0.45H,热解反应器溢料口的高度为0.6~0.8H,热解反应器双向返料器返料口和热解反应器单向返料器返料口的高度为0.05~0.15H,并且热解反应器双向返料器返料口的高度不低于热解反应器单向返料器的高度;热解反应器的直径为D;热解反应器底部布风装置为小口在下的锥形布风板,其底沿置于热解反应器底部,中轴线竖直,锥面与水平面的夹角为60°;第一斜管与水平面的夹角为45°。Preferably, the height of the pyrolysis reactor is H, from the bottom of the pyrolysis reactor: the height of the pyrolysis reactor pipe-type air distribution device is 0.2 to 0.3H, and the height of the pyrolysis reactor inlet is 0.35~0.45H, the height of the pyrolysis reactor overflow port is 0.6~0.8H, the height of the pyrolysis reactor two-way feeder return port and the pyrolysis reactor one-way feeder return port is 0.05~0.15H H, and the height of the return port of the pyrolysis reactor two-way feeder is not lower than the height of the pyrolysis reactor one-way feeder; the diameter of the pyrolysis reactor is D; the air distribution device at the bottom of the pyrolysis reactor is a small opening The bottom edge of the lower conical air distribution plate is placed at the bottom of the pyrolysis reactor, the central axis is vertical, the angle between the conical surface and the horizontal plane is 60°; the angle between the first inclined pipe and the horizontal plane is 45°.
优选的,所述燃烧反应器的高度为L,L=0.8~1H,由燃烧反应器的底部起:燃烧反应器进料口的高度为0.3~0.4L,燃烧反应器溢料口的高度为0.6~0.8L,燃烧反应器返料口的高度为0.15~0.25L;燃烧反应器的至今为W,W=0.8~1.2D;燃烧反应器底部为小端在下的锥形结构,燃烧反应器板式布风装置设置在锥形结构的大端位置,锥形结构与燃烧反应器板式布风装置共同构成燃烧反应器风室,锥形结构的锥面与水平面的夹角为60°;第二斜管与水平面的夹角为45°。Preferably, the height of the combustion reactor is L, L=0.8~1H, from the bottom of the combustion reactor: the height of the combustion reactor inlet is 0.3~0.4L, and the height of the combustion reactor overflow port is 0.6 ~ 0.8L, the height of the combustion reactor return port is 0.15 ~ 0.25L; the height of the combustion reactor is W, W = 0.8 ~ 1.2D; The plate-type air distribution device is set at the large end of the conical structure. The conical structure and the combustion reactor plate-type air distribution device together constitute the combustion reactor air chamber. The angle between the conical surface of the conical structure and the horizontal plane is 60°; the second The angle between the inclined pipe and the horizontal plane is 45°.
优选的,所述双向返料器包括长方体容腔,所述长方体容腔通过T型隔板隔成三个腔室,其中后方的一个腔室为进料室,前方的两个腔室分别为第一返料室和第二返料室,进料室与第一返料下降管相连,第一返料室与第一返料斜管相连,第二返料室与第二返料斜管相连;所述进料室内设置布风板,隔离出下方的进料室风室;所述第一返料室内设置有布风板,隔离出下方的第一返料室风室;所述第二返料室内设置有布风板,隔离出下方的第二返料室风室;Preferably, the two-way feeder includes a cuboid cavity, and the cuboid cavity is divided into three chambers by a T-shaped partition, wherein the rear chamber is a feeding chamber, and the front two chambers are respectively The first return chamber and the second return chamber, the feed chamber is connected with the first return descending pipe, the first return chamber is connected with the first return inclined pipe, the second return chamber is connected with the second return inclined pipe connected; the air distribution plate is set in the feed chamber to isolate the air chamber of the feed chamber below; the air distribution plate is arranged in the first return chamber to isolate the first return chamber air chamber below; The second return chamber is equipped with an air distribution plate, which isolates the second return chamber air chamber below;
所述进料室的宽度b2和第一返料室的宽度/第二返料室的宽度b1相等,第一返料室的长度a1和第二返料室的长度a2相等;第一返料下降管的直径为d1,第一返料斜管的直径为d2,第二返料斜管的直径为d3,d2=d3=0.625d1;第一返料斜管与竖直方向的夹角为α,第二返料斜管与竖直方向的夹角为β,α和β均小于45°;所述布风板的开孔率均为10~15%。The width b2 of the feeding chamber is equal to the width b1 of the width of the first returning chamber/the width b1 of the second returning chamber, and the length a1 of the first returning chamber is equal to the length a2 of the second returning chamber; The diameter of the first return descending pipe is d 1 , the diameter of the first return inclined pipe is d 2 , the diameter of the second return inclined pipe is d 3 , d 2 =d 3 =0.625d 1 ; the first return The angle between the inclined pipe and the vertical direction is α, the angle between the second return inclined pipe and the vertical direction is β, and both α and β are less than 45°; the opening ratio of the air distribution plate is 10-15° %.
上述装置中的热解反应器与燃烧反应器分别设置有溢料结构和气固分离装置,实现了对鼓泡流化态、湍流流化态和快速流化态等多种工作状态的良好适应性,通过运行参数的调整可在一个较大范围内改变混合物料在床内的停留时间与混合特性,使得该装置可以适应复杂种类的燃料。应当指出,当热解反应器或燃烧反应器处于快速流化态运行状态时应关闭对应溢流管道上的阀门。The pyrolysis reactor and combustion reactor in the above device are respectively equipped with overflow structure and gas-solid separation device, which realizes good adaptability to various working states such as bubbling fluidization state, turbulent fluidization state and rapid fluidization state , the residence time and mixing characteristics of the mixed material in the bed can be changed in a large range through the adjustment of the operating parameters, so that the device can adapt to complex types of fuels. It should be pointed out that when the pyrolysis reactor or combustion reactor is in the fast fluidized state, the valve on the corresponding overflow pipe should be closed.
上述装置中的热解反应器设置有管式布风装置和底部布风装置,通过分级通入流化气体加强了热解反应器内的物料的混合程度,并且使得热解气体产物能够被迅速带离热解反应器,使得整个装置具有较好的反应效率。The pyrolysis reactor in the above-mentioned device is equipped with a pipe-type air distribution device and a bottom air distribution device, and the degree of mixing of the materials in the pyrolysis reactor is enhanced by feeding fluidized gas in stages, and the pyrolysis gas product can be quickly carried From the pyrolysis reactor, the whole device has better reaction efficiency.
上述装置的两反应器间的物料循环通过气动控制的返料器(单向返料器和双向返料器)控制,输送流量可根据两反应器实际运行状况调节以提高反应效率;通过双向返料器可控地分配由此送入热解反应器与燃烧反应器的固体通量,使得整个装置可以根据两反应器内温度控制送入燃烧反应器燃烧的物质量从而实现准确控制整个装置内部温度的目的。The material circulation between the two reactors of the above device is controlled by a pneumatically controlled feeder (one-way feeder and two-way feeder), and the delivery flow can be adjusted according to the actual operating conditions of the two reactors to improve reaction efficiency; The feeder can controlly distribute the solid flux sent into the pyrolysis reactor and the combustion reactor, so that the whole device can control the amount of material sent into the combustion reactor according to the temperature in the two reactors, so as to achieve accurate control of the interior of the whole device temperature purpose.
一种双流化床可燃固体废弃物热解油气联产方法,包括如下步骤:A dual-fluidized-bed combustible solid waste pyrolysis oil-gas cogeneration method, comprising the following steps:
(1)通过辅助燃料加料器向燃烧反应器内加入辅助燃料,辅助燃料被由燃烧反应器板式布风装置注入的空气流化并燃烧,用以提升燃烧反应器内温度达到运行要求;高温惰性固体床料经单向返料器进入热解反应器,为热解反应器提供热解所需的热量,使热解反应器内温度逐渐上升;(1) Add auxiliary fuel into the combustion reactor through the auxiliary fuel feeder, and the auxiliary fuel is fluidized and burned by the air injected by the plate-type air distribution device of the combustion reactor to increase the temperature in the combustion reactor to meet the operating requirements; high temperature inert The solid bed material enters the pyrolysis reactor through the one-way feeder, which provides the heat required for pyrolysis for the pyrolysis reactor, so that the temperature in the pyrolysis reactor gradually rises;
(2)将可燃固体废弃物通过原料加料器加入至热解反应器中,通过热解反应器管式布风装置和热解反应器底部布风装置向热解反应器内供应热解气,所述热解气作为流化混合床料;(2) Add combustible solid waste into the pyrolysis reactor through the raw material feeder, and supply pyrolysis gas into the pyrolysis reactor through the pyrolysis reactor tubular air distribution device and the pyrolysis reactor bottom air distribution device, The pyrolysis gas is used as fluidized mixed bed material;
(3)根据可燃固体废弃物的热解特性以及热解固体产物的燃烧特性,通过流化气量的调节、热解反应器溢料装置阀门的开关调节和燃烧反应器溢料装置阀门的开关调节,调整热解反应器和燃烧反应器内的流化状态,使得热解气与热解油产量得到优化组合;(3) According to the pyrolysis characteristics of combustible solid waste and the combustion characteristics of pyrolysis solid products, through the adjustment of fluidization gas volume, the switch adjustment of the valve of the pyrolysis reactor overflow device and the switch adjustment of the valve of the combustion reactor overflow device , adjust the fluidization state in the pyrolysis reactor and the combustion reactor, so that the output of pyrolysis gas and pyrolysis oil can be optimally combined;
(4)随着反应逐渐稳定,热解反应器气体产物经过旋风分离器分离输出,经第一级冷凝器与第二级冷凝器冷却收集生物油至第一热解油收集罐和热解油第二收集罐中,剩余气体产物经脱水塔脱除水分后得到热解气,一部分热解气通过热解气产品输出通道输出,另一部分热解气接入热管换热器、作为热解反应器的内部热解气;若作为热解反应器的内部热解气供应不足,则通过向热管换热器并行通入外部热解气进行补充,所述内部热解气和外部热解气共同构成热解反应器的热解气;(4) As the reaction gradually stabilizes, the gas products of the pyrolysis reactor are separated and output by the cyclone separator, and the bio-oil is collected by cooling the first-stage condenser and the second-stage condenser to the first pyrolysis oil collection tank and pyrolysis oil In the second collection tank, the remaining gas products are dehydrated by the dehydration tower to obtain pyrolysis gas, part of the pyrolysis gas is output through the output channel of the pyrolysis gas product, and the other part of the pyrolysis gas is connected to the heat pipe heat exchanger for pyrolysis reaction The internal pyrolysis gas of the pyrolysis reactor; if the supply of the internal pyrolysis gas as the pyrolysis reactor is insufficient, it will be supplemented by feeding the external pyrolysis gas into the heat pipe heat exchanger in parallel, and the internal pyrolysis gas and the external pyrolysis gas are jointly the pyrolysis gas constituting the pyrolysis reactor;
(5)热解反应器固体产物经过热解反应器旋风分离器分离后被送入双向返料器,根据双向返料器内部温度状况、通过调节双向返料器流化风量调节送入燃烧反应器内燃烧的热解固体产物的流量;(5) The solid product of the pyrolysis reactor is sent to the two-way feeder after being separated by the pyrolysis reactor cyclone separator, and is sent to the combustion reaction by adjusting the fluidization air volume of the two-way feeder according to the internal temperature of the two-way feeder The flow rate of pyrolysis solid products burned in the vessel;
(6)燃烧反应器生成的烟气经燃烧反应器旋风分离器气固分离后得到的烟气被送入热管换热器用于预热热解反应器的热解气,随后烟气被送入烟气净化器进行净化,并经过布袋除尘器除尘后输出;(6) The flue gas generated by the combustion reactor is separated from the gas and solid by the cyclone separator in the combustion reactor, and the flue gas is sent to the heat pipe heat exchanger for preheating the pyrolysis gas of the pyrolysis reactor, and then the flue gas is sent into The flue gas purifier is used for purification, and is output after being dedusted by the bag filter;
(7)热解反应器固体产物中的惰性固体床料经热解反应器旋风分离器分离后被送入双向返料器,再被双向返料器送回燃烧反应器重新被加热形成高温惰性固体床料;所述高温惰性固体床料经燃烧反应器旋风分离器分离后被送入单向返料器,在被单向返料器送至热解反应器,形成双流化床反应器间的能量与物质循环。(7) The inert solid bed material in the solid product of the pyrolysis reactor is separated by the pyrolysis reactor cyclone separator and sent to the two-way feeder, and then sent back to the combustion reactor by the two-way feeder to be reheated to form high-temperature inertness Solid bed material; the high-temperature inert solid bed material is sent to the one-way feeder after being separated by the cyclone separator in the combustion reactor, and is sent to the pyrolysis reactor by the one-way feeder to form a double fluidized bed reactor. energy and matter cycle.
上述方法中,可根据可燃固体废弃物的热解特性及热解固体产物的燃烧特性分别调整热解反应器与燃烧反应器的运行状态;具体而言,对于热解油产率相对较低的燃料可降低流化气量增大可燃原料在热解反应器内的停留时间,从而通过热解反应获得更多热解气,以实现对原料较高的利用效率;另一方面,对于在空气氛围中的燃烧反应速率相对较低的热解固体产物,通过降低燃烧反应器内流化气量使得热解固体产物有足够的时间燃烧完全。In the above method, the operating states of the pyrolysis reactor and the combustion reactor can be adjusted respectively according to the pyrolysis characteristics of the combustible solid waste and the combustion characteristics of the pyrolysis solid product; specifically, for the relatively low yield of pyrolysis oil The fuel can reduce the amount of fluidizing gas and increase the residence time of combustible raw materials in the pyrolysis reactor, so that more pyrolysis gas can be obtained through pyrolysis reaction to achieve higher utilization efficiency of raw materials; on the other hand, for For pyrolysis solid products with a relatively low combustion reaction rate, the pyrolysis solid products have enough time to burn completely by reducing the amount of fluidizing gas in the combustion reactor.
上述方法在热解反应器内应用分层流化方法,通过合理控制分两层设置的布风装置流化气量加强热解反应器内的气-固、固-固混合强度,并使得热解气体产物能够更容易得离开热解反应区域,起到提高反应效率和加快反应速率的效果。The above method applies the layered fluidization method in the pyrolysis reactor, and strengthens the gas-solid and solid-solid mixing intensity in the pyrolysis reactor by reasonably controlling the fluidization gas volume of the air distribution device arranged in two layers, and makes the pyrolysis Gas products can more easily leave the pyrolysis reaction area, which can improve the reaction efficiency and speed up the reaction rate.
上述方法要求热解反应器内的工作温度为450~650℃,燃烧反应器内的工作温度为1000~1100℃;应注意防止燃烧反应器内温度过高使残渣熔融造成流化操作困难,同时应防止燃烧反应器内温度过低造成二噁英不能完全分解。The above method requires the working temperature in the pyrolysis reactor to be 450-650°C, and the working temperature in the combustion reactor to be 1000-1100°C; care should be taken to prevent the temperature in the combustion reactor from being too high to melt the residue and cause difficulty in fluidization operation. It should be prevented that the temperature in the combustion reactor is too low and the dioxin cannot be completely decomposed.
有益效果:本发明提供的双流化床可燃固体废弃物热解油气联产装置及方法,相对于现有技术,具有如下优势:Beneficial effects: Compared with the prior art, the dual fluidized bed combustible solid waste pyrolysis oil and gas cogeneration device and method provided by the present invention have the following advantages:
1、该装置的热解反应器和燃烧反应器可以适应大范围调节参数的运行要求,使得两个反应器既可以作为鼓泡床反应器也可以作为快速床反应器运行,亦可理解为该装置能够满足常规热裂解与快速热裂解的要求,能够有效应对处理复杂种类可燃固体废弃物,并且通过运行参数的调整能够最大限度的提高反应效率,从而实现物质与能量的高效利用;1. The pyrolysis reactor and combustion reactor of the device can adapt to the operating requirements of a wide range of adjustment parameters, so that the two reactors can be operated as either a bubbling bed reactor or a fast bed reactor, which can also be understood as the The device can meet the requirements of conventional pyrolysis and rapid pyrolysis, can effectively deal with complex types of combustible solid waste, and can maximize the reaction efficiency through the adjustment of operating parameters, so as to realize the efficient use of materials and energy;
2、设置有热解油与热解气的收集处理系统,能够适应热解油与热解气的联产要求;2. It is equipped with a collection and treatment system for pyrolysis oil and pyrolysis gas, which can meet the requirements of co-production of pyrolysis oil and pyrolysis gas;
3、通过调整工作参数能够适应物料成分的变化,可以在不停止装置工作的情况下满足包括农林废弃物和城市固体垃圾在内多类可燃固体废弃物的交替处理;3. By adjusting the working parameters, it can adapt to the change of material composition, and can meet the alternate treatment of various types of combustible solid waste including agricultural and forestry waste and urban solid waste without stopping the work of the device;
4、采用热解反应器与燃烧反应器耦合的结构形式,以惰性颗粒床料为热载体,在两反应器之间循环,实现了能量的高效利用;同时通过气动返料阀控制床料循环量,达到了准确控制热解反应器内温度的目的。4. The structural form of the coupling of the pyrolysis reactor and the combustion reactor is adopted, and the inert granular bed material is used as the heat carrier to circulate between the two reactors, realizing the efficient utilization of energy; at the same time, the circulation of the bed material is controlled by the pneumatic return valve amount, to achieve the purpose of accurately controlling the temperature in the pyrolysis reactor.
附图说明Description of drawings
图1为本发明的结构示意图;Fig. 1 is a structural representation of the present invention;
图2为热解反应器的结构尺寸图;Fig. 2 is the structural dimension figure of pyrolysis reactor;
图3为燃烧反应器的结构尺寸图;Fig. 3 is the structural dimension drawing of combustion reactor;
图4为双向返料器的结构尺寸图;Figure 4 is a structural dimension diagram of the bidirectional feeder;
包括:原料加料器1,热解反应器管式布风装置2,热解反应器底部布风装置3,热解反应器4,热解反应器旋风分离器5,热解反应器溢料装置6,双向返料器7,第一返料下降管7-1,第一返料斜管7-2,第二返料斜管7-3,进料室7-4,第一返料室7-5,第二返料室7-6,第一返料室风室7-7,第二返料室风室7-8,进料室风室7-9,热解反应器排渣口8,燃烧反应器旋风分离器9,燃烧反应器溢料装置10,单向返料器11,燃烧反应器12,燃烧反应器板式布风装置13,燃烧反应器排渣口14,辅助燃料加料器15,第一级冷凝器16,第一级喷嘴16-1,第二级喷嘴16-2,循环喷淋液热交换器17,第一热解油收集罐18,第二级冷凝器19,第二热解油收集罐20,脱水塔21,热管换热器22,烟气净化装置23,布袋除尘器24。Including: raw material feeder 1, pyrolysis reactor tubular air distribution device 2, pyrolysis reactor bottom air distribution device 3, pyrolysis reactor 4, pyrolysis reactor cyclone separator 5, pyrolysis reactor overflow device 6. Two-way feeding device 7, the first feeding down pipe 7-1, the first feeding inclined pipe 7-2, the second feeding inclined pipe 7-3, the feeding chamber 7-4, the first feeding chamber 7-5, the second return chamber 7-6, the first return chamber air chamber 7-7, the second return chamber air chamber 7-8, the feed chamber air chamber 7-9, pyrolysis reactor slag discharge Port 8, combustion reactor cyclone separator 9, combustion reactor overflow device 10, one-way return device 11, combustion reactor 12, combustion reactor plate air distribution device 13, combustion reactor slag outlet 14, auxiliary fuel Feeder 15, first-stage condenser 16, first-stage nozzle 16-1, second-stage nozzle 16-2, circulating spray liquid heat exchanger 17, first pyrolysis oil collection tank 18, second-stage condenser 19. Second pyrolysis oil collection tank 20, dehydration tower 21, heat pipe heat exchanger 22, flue gas purification device 23, bag filter 24.
可燃固体废弃物a,热解反应器第一级流化风b,热解反应器第二级流化风c,辅助燃料d,燃烧反应器流化风e,第二级冷凝器冷凝介质f,热解气产品g,外部热解气h,烟气i,进料室流化风j-1,第一返料风j-2,第二返料风j-3。Combustible solid waste a, pyrolysis reactor first-stage fluidization air b, pyrolysis reactor second-stage fluidization air c, auxiliary fuel d, combustion reactor fluidization air e, second-stage condenser condensing medium f , pyrolysis gas product g, external pyrolysis gas h, flue gas i, fluidization air j-1 in the feed chamber, first return air j-2, and second return air j-3.
具体实施方式Detailed ways
下面结合附图对本发明作更进一步的说明。The present invention will be further described below in conjunction with the accompanying drawings.
如图1所示为一种一种双流化床可燃固体废弃物热解油气联产装置,包括竖直设置的热解反应器4和燃烧反应器12。As shown in FIG. 1 , a dual-fluidized bed combustible solid waste pyrolysis oil-gas cogeneration device includes a vertical pyrolysis reactor 4 and a combustion reactor 12 .
所述热解反应器4内设置有热解反应器底部布风装置3和热解反应器管式布风装置2,在热解反应器4的侧壁上由上至下设置有热解反应器溢料口、热解反应器进料口、热解反应器双向返料器返料口和热解反应器单向返料器返料口,在热解反应器4的底部设置有热解反应器排渣口8,在热解反应器4的顶部设置有热解反应器排风口;所述热解反应器管式布风装置2位置高于热解反应器底部布风装置3,热解反应器进料口位置高于热解反应器管式布风装置2,热解反应器双向返料器返料口和热解反应器单向返料器返料口位置高度置于热解反应器底部布风装置3和热解反应器管式布风装置2之间;原料加料器1与热解反应器进料口相连,可燃固体废弃物a通过原料加料器1送入热解反应器4内。The pyrolysis reactor 4 is provided with a pyrolysis reactor bottom air distribution device 3 and a pyrolysis reactor tubular air distribution device 2, and a pyrolysis reaction device is arranged on the side wall of the pyrolysis reactor 4 from top to bottom. The overflow port of the pyrolysis reactor, the feed port of the pyrolysis reactor, the return port of the two-way feeder of the pyrolysis reactor and the return port of the one-way feeder of the pyrolysis reactor are provided with a pyrolysis reactor at the bottom of the pyrolysis reactor 4. Reactor slag outlet 8, pyrolysis reactor air outlet is provided on the top of pyrolysis reactor 4; The position of the pyrolysis reactor tubular air distribution device 2 is higher than the pyrolysis reactor bottom air distribution device 3, The position of the feed inlet of the pyrolysis reactor is higher than that of the tubular air distribution device 2 of the pyrolysis reactor. Between the air distribution device 3 at the bottom of the pyrolysis reactor and the tubular air distribution device 2 of the pyrolysis reactor; the raw material feeder 1 is connected to the feed port of the pyrolysis reactor, and the combustible solid waste a is sent into the pyrolysis reactor through the raw material feeder 1 Inside Reactor 4.
所述燃烧反应器12内设置有燃烧反应器板式布风装置13,在燃烧反应器12的侧壁上由上至下设置有燃烧反应器溢料口、燃烧反应器进料口和燃烧反应器返料口,在燃烧反应器12的底部设置有燃烧反应器排渣口14,在燃烧反应器12的顶部设置有燃烧反应器排风口;所述燃烧反应器返料口位置高于燃烧反应器板式布风装置13;辅助燃料加料器15与燃烧反应器进料口相连,辅助燃料d通过辅助燃料加料器15送入燃烧反应器12内。The combustion reactor 12 is provided with a combustion reactor plate-type air distribution device 13, and on the side wall of the combustion reactor 12, a combustion reactor overflow port, a combustion reactor feed port and a combustion reactor are arranged from top to bottom. The return port is provided with a combustion reactor slag outlet 14 at the bottom of the combustion reactor 12, and a combustion reactor air exhaust port is provided at the top of the combustion reactor 12; the position of the combustion reactor return port is higher than that of the combustion reaction The plate-type air distribution device 13; the auxiliary fuel feeder 15 is connected with the feed port of the combustion reactor, and the auxiliary fuel d is sent into the combustion reactor 12 through the auxiliary fuel feeder 15.
所述热解反应器排风口接入热解反应器旋风分离器5,所述热解反应器旋风分离器5的下出料端通过第一返料下降管7-1与双向返料器7的进料管7-1相连,双向返料器7的第一返料斜管7-2和第二返料斜管7-3分别与热解反应器双向返料器返料口和燃烧反应器返料口相连;所述热解反应器溢料口通过向下倾斜的第一斜管与第一返料下降管连通,在第一斜管上设置有热解反应器溢料装置6;所述热解反应器旋风分离器5的上排气端接入第一级冷凝器16;第一级冷凝器16的液体出口接入第一热解油收集罐18,第一级冷凝器16的气体出口接入第二级冷凝器19;第二级冷凝器19的液体出口接入第二热解油收集罐20,第二级冷凝器19的气体出口接入脱水塔21;脱水塔21气体出口分为两路,一路接入热解气产品输出通道,另一路接入热管换热器22下端入口。The air outlet of the pyrolysis reactor is connected to the pyrolysis reactor cyclone separator 5, and the lower discharge end of the pyrolysis reactor cyclone separator 5 passes through the first return material descending pipe 7-1 and the two-way return feeder The feed pipe 7-1 of 7 links to each other, and the first inclined pipe 7-2 and the second inclined pipe 7-3 of the two-way feeder 7 are respectively connected with the feed port and the combustion chamber of the two-way feeder of the pyrolysis reactor. The reactor return port is connected; the overflow port of the pyrolysis reactor is communicated with the first return drop pipe through the first inclined pipe inclined downward, and the pyrolysis reactor overflow device 6 is arranged on the first inclined pipe The upper exhaust end of the pyrolysis reactor cyclone separator 5 is connected to the first-stage condenser 16; the liquid outlet of the first-stage condenser 16 is connected to the first pyrolysis oil collection tank 18, and the first-stage condenser The gas outlet of 16 is connected to the second-stage condenser 19; the liquid outlet of the second-stage condenser 19 is connected to the second pyrolysis oil collection tank 20, and the gas outlet of the second-stage condenser 19 is connected to the dehydration tower 21; the dehydration tower 21 The gas outlet is divided into two paths, one path is connected to the pyrolysis gas product output channel, and the other path is connected to the lower end inlet of the heat pipe heat exchanger 22 .
所述燃烧反应器排风口接入燃烧反应器旋风分离器9,所述燃烧反应器旋风分离器9的下出料端通过第二返料下降管与单向返料器11的进料端相连,单向返料器11的出料端与热解反应器单向返料器返料口相连;所述燃烧反应器溢料口通过向下倾斜的第二斜管与第二返料下降管连通,在第二斜管上设置有燃烧反应器溢料装置10;所述燃烧反应器旋风分离器9的上排气端接入热管换热器22上端入口;热管换热器22上端出口与热解反应器管式布风装置2和热解反应器底部布风装置3相连,热管换热器22下端出口与烟气净化装置23相连,烟气净化装置23气体出口与布袋除尘器24相连。The exhaust port of the combustion reactor is connected to the combustion reactor cyclone separator 9, and the lower discharge end of the combustion reactor cyclone separator 9 passes through the second return material downcomer and the feed end of the one-way return feeder 11 connected, the discharge end of the one-way feeder 11 is connected with the return port of the one-way feeder of the pyrolysis reactor; The pipes are connected, and a combustion reactor overflow device 10 is provided on the second inclined pipe; the upper exhaust end of the combustion reactor cyclone separator 9 is connected to the upper end inlet of the heat pipe heat exchanger 22; the upper end outlet of the heat pipe heat exchanger 22 It is connected with the pyrolysis reactor tubular air distribution device 2 and the bottom air distribution device 3 of the pyrolysis reactor, the lower end outlet of the heat pipe heat exchanger 22 is connected with the flue gas purification device 23, and the gas outlet of the flue gas purification device 23 is connected with the bag filter 24 connected.
所述热解反应器溢料装置6调节热解反应器4工作于鼓泡流化态、湍流流化态或快速流化态;所述燃烧反应器溢料装置10调节燃烧反应器12工作于鼓泡流化态、湍流流化态或快速流化态。The pyrolysis reactor overflow device 6 adjusts the pyrolysis reactor 4 to work in a bubbling fluidized state, a turbulent fluidized state or a fast fluidized state; the combustion reactor overflow device 10 regulates the combustion reactor 12 to work in Bubble fluidized state, turbulent fluidized state or fast fluidized state.
所述热解反应器2的高度为H,由热解反应器2的底部起:热解反应器管式布风装置2的高度为0.2~0.3H,热解反应器进料口的高度为0.35~0.45H,热解反应器溢料口的高度为0.6~0.8H,热解反应器双向返料器返料口和热解反应器单向返料器返料口的高度为0.05~0.15H,并且热解反应器双向返料器返料口的高度不低于热解反应器单向返料器的高度;热解反应器2的直径为D;热解反应器底部布风装置3为小口在下的锥形布风板,其底沿置于热解反应器2底部,中轴线竖直,锥面与水平面的夹角为60°;第一斜管与水平面的夹角为45°。The height of the pyrolysis reactor 2 is H, from the bottom of the pyrolysis reactor 2: the height of the pyrolysis reactor tubular air distribution device 2 is 0.2~0.3H, and the height of the pyrolysis reactor inlet is 0.35~0.45H, the height of the pyrolysis reactor overflow port is 0.6~0.8H, the height of the pyrolysis reactor two-way feeder return port and the pyrolysis reactor one-way feeder return port is 0.05~0.15H H, and the height of the return port of the pyrolysis reactor two-way feeder is not lower than the height of the pyrolysis reactor one-way feeder; the diameter of the pyrolysis reactor 2 is D; the bottom air distribution device of the pyrolysis reactor 3 It is a conical air distribution plate with a small opening on the bottom, its bottom edge is placed at the bottom of the pyrolysis reactor 2, the central axis is vertical, the angle between the cone surface and the horizontal plane is 60°; the angle between the first inclined tube and the horizontal plane is 45° .
所述燃烧反应器12的高度为L,L=0.8~1H,由燃烧反应器12的底部起:燃烧反应器进料口的高度为0.3~0.4L,燃烧反应器溢料口的高度为0.6~0.8L,燃烧反应器返料口的高度为0.15~0.25L;燃烧反应器12的至今为W,W=0.8~1.2D;燃烧反应器12底部为小端在下的锥形结构,燃烧反应器板式布风装置13设置在锥形结构的大端位置,锥形结构与燃烧反应器板式布风装置13共同构成燃烧反应器风室,锥形结构的锥面与水平面的夹角为60°;第二斜管与水平面的夹角为45°。The height of the combustion reactor 12 is L, L=0.8~1H, from the bottom of the combustion reactor 12: the height of the combustion reactor inlet is 0.3~0.4L, and the height of the combustion reactor overflow port is 0.6 ~0.8L, the height of the combustion reactor return port is 0.15~0.25L; the height of the combustion reactor 12 is W, W=0.8~1.2D; the bottom of the combustion reactor 12 is a conical structure with the small end down, and the combustion reaction The plate-type air distribution device 13 is arranged at the large end of the conical structure. The conical structure and the combustion reactor plate-type air distribution device 13 together constitute the combustion reactor air chamber. The angle between the conical surface of the conical structure and the horizontal plane is 60° ; The angle between the second inclined pipe and the horizontal plane is 45°.
所述双向返料器7包括长方体容腔,所述长方体容腔通过T型隔板隔成三个腔室,其中后方的一个腔室为进料室7-4,前方的两个腔室分别为第一返料室7-5和第二返料室7-6,进料室7-4与第一返料下降管7-1相连,第一返料室7-5与第一返料斜管7-2相连,第二返料室7-6与第二返料斜管7-3相连;所述进料室7-4内设置布风板,隔离出下方的进料室风室7-9;所述第一返料室7-5内设置有布风板,隔离出下方的第一返料室风室7-7;所述第二返料室7-6内设置有布风板,隔离出下方的第二返料室风室7-8;The two-way feeder 7 includes a cuboid cavity, and the cuboid cavity is divided into three chambers by a T-shaped partition, wherein a chamber at the rear is a feed chamber 7-4, and the two chambers at the front are respectively It is the first material return chamber 7-5 and the second material return chamber 7-6, the feed chamber 7-4 is connected with the first material return descending pipe 7-1, and the first material return chamber 7-5 is connected with the first material return chamber The inclined pipe 7-2 is connected, and the second return chamber 7-6 is connected with the second return inclined pipe 7-3; the air distribution plate is arranged in the feed chamber 7-4 to isolate the feed chamber air chamber below 7-9; the first return chamber 7-5 is provided with an air distribution plate to isolate the first return chamber air chamber 7-7 below; the second return chamber 7-6 is provided with a cloth The air plate isolates the second return chamber air chamber 7-8 below;
所述进料室7-4的宽度b2和第一返料室7-5的宽度/第二返料室7-6的宽度b1相等,第一返料室7-5的长度a1和第二返料室7-6的长度a2相等;第一返料下降管7-1的直径为d1,第一返料斜管7-2的直径为d2,第二返料斜管7-3的直径为d3,d2=d3=0.625d1;第一返料斜管7-2与竖直方向的夹角为α,第二返料斜管7-3与竖直方向的夹角为β,α和β均小于45°;所述布风板的开孔率均为10~15%。The width b 2 of the feed chamber 7-4 is equal to the width b 1 of the first return chamber 7-5/the width b 1 of the second return chamber 7-6, and the length a 1 of the first return chamber 7-5 It is equal to the length a 2 of the second material return chamber 7-6; the diameter of the first material return descending pipe 7-1 is d 1 , the diameter of the first material return inclined tube 7-2 is d 2 , and the second material return inclined tube 7-2 is d 2 . The diameter of the pipe 7-3 is d 3 , d 2 =d 3 =0.625d 1 ; the included angle between the first return inclined pipe 7-2 and the vertical direction is α, and the angle between the second return inclined pipe 7-3 and the vertical direction The included angle in the vertical direction is β, and both α and β are less than 45°; the opening ratio of the air distribution plate is 10-15%.
向进料室风室7-9内通入进料室流化风j-1,向第一返料室风室7-7内通入第一返料风j-2,向第二返料室风室7-8内通入第二返料风j-3;通过调节通入双向返料器7内的流化气体(进料室流化风j-1、第一返料风j-2和第二返料风j-3)流量与分配比例可以控制循环物料的通量。Pass into the feed chamber air chamber 7-9 into the feed chamber fluidization air j-1, pass into the first return chamber air chamber 7-7 into the first return air j-2, and feed the second return air The second return air j-3 is passed into the chamber air chamber 7-8; 2 and the second return air j-3) The flow and distribution ratio can control the flux of the circulating material.
基于上述装置的双流化床可燃固体废弃物热解油气联产方法,包括如下步骤:The dual-fluidized-bed combustible solid waste pyrolysis oil-gas cogeneration method based on the above-mentioned device comprises the following steps:
(1)通过辅助燃料加料器15向燃烧反应器12内加入辅助燃料,辅助燃料被由燃烧反应器板式布风装置13注入的空气流化并燃烧,用以提升燃烧反应器12内温度达到运行要求;高温惰性固体床料经单向返料器11进入热解反应器4,为热解反应器4提供热解所需的热量,使热解反应器4内温度逐渐上升;(1) Add auxiliary fuel into the combustion reactor 12 through the auxiliary fuel feeder 15, and the auxiliary fuel is fluidized and burned by the air injected by the combustion reactor plate air distribution device 13, so as to increase the temperature in the combustion reactor 12 to reach the operating temperature. Requirements: The high-temperature inert solid bed material enters the pyrolysis reactor 4 through the one-way feeder 11, and provides the heat required for pyrolysis for the pyrolysis reactor 4, so that the temperature in the pyrolysis reactor 4 gradually rises;
(2)将可燃固体废弃物通过原料加料器1加入至热解反应器4中,通过热解反应器管式布风装置2和热解反应器底部布风装置3向热解反应器4内供应热解气,所述热解气作为流化混合床料;(2) Add the combustible solid waste into the pyrolysis reactor 4 through the raw material feeder 1, and flow into the pyrolysis reactor 4 through the pyrolysis reactor tubular air distribution device 2 and the pyrolysis reactor bottom air distribution device 3 Supplying pyrolysis gas, said pyrolysis gas is used as fluidized mixed bed material;
(3)根据可燃固体废弃物的热解特性以及热解固体产物的燃烧特性,通过流化气量的调节、热解反应器溢料装置6阀门的开关调节和燃烧反应器溢料装置10阀门的开关调节,调整热解反应器4和燃烧反应器12内的流化状态,使得热解气与热解油产量得到优化组合;(3) According to the pyrolysis characteristics of combustible solid waste and the combustion characteristics of pyrolysis solid products, through the regulation of fluidization gas volume, the switch adjustment of pyrolysis reactor overflow device 6 valves and the combustion reactor overflow device 10 valves Switch adjustment, adjust the fluidization state in the pyrolysis reactor 4 and the combustion reactor 12, so that the output of pyrolysis gas and pyrolysis oil can be optimally combined;
(4)随着反应逐渐稳定,热解反应器4气体产物经过旋风分离器5分离输出,经第一级冷凝器16与第二级冷凝器19冷却收集生物油至第一热解油收集罐18和热解油第二收集罐20中,剩余气体产物经脱水塔21脱除水分后得到热解气,一部分热解气通过热解气产品输出通道输出,另一部分热解气接入热管换热器22、作为热解反应器4的内部热解气;若作为热解反应器4的内部热解气供应不足,则通过向热管换热器22并行通入外部热解气进行补充,所述内部热解气和外部热解气共同构成热解反应器4的热解气;(4) As the reaction gradually stabilizes, the gas product of the pyrolysis reactor 4 is separated and exported by the cyclone separator 5, and the bio-oil is cooled and collected by the first-stage condenser 16 and the second-stage condenser 19 to the first pyrolysis oil collection tank 18 and the second collection tank 20 for pyrolysis oil, the remaining gas products are dehydrated by the dehydration tower 21 to obtain pyrolysis gas, part of the pyrolysis gas is output through the output channel of the pyrolysis gas product, and the other part of the pyrolysis gas is connected to the heat pipe for exchange Heater 22, as the internal pyrolysis gas of pyrolysis reactor 4; If the supply of internal pyrolysis gas as pyrolysis reactor 4 is insufficient, it will be supplemented by feeding external pyrolysis gas into heat pipe heat exchanger 22 in parallel, so The internal pyrolysis gas and the external pyrolysis gas together constitute the pyrolysis gas of the pyrolysis reactor 4;
(5)热解反应器4固体产物经过热解反应器旋风分离器5分离后被送入双向返料器7,根据双向返料器7内部温度状况、通过调节双向返料器7流化风量调节送入燃烧反应器12内燃烧的热解固体产物的流量;(5) The solid product of the pyrolysis reactor 4 is sent to the two-way feeder 7 after being separated by the pyrolysis reactor cyclone separator 5, and is adjusted according to the internal temperature conditions of the two-way feeder 7 by adjusting the fluidization air volume of the two-way feeder 7 Regulate the flow rate of the pyrolysis solid product sent into the combustion reactor 12 for combustion;
(6)燃烧反应器12生成的烟气经燃烧反应器旋风分离器9气固分离后得到的烟气被送入热管换热器22用于预热热解反应器4的热解气,随后烟气被送入烟气净化器23进行净化,并经过布袋除尘器24除尘后输出;(6) The flue gas that combustion reactor 12 generates is sent into heat pipe heat exchanger 22 for the pyrolysis gas of preheating pyrolysis reactor 4 after the flue gas that combustion reactor cyclone separator 9 gas-solid separation obtains, then The flue gas is sent to the flue gas purifier 23 for purification, and is output after being dedusted by the bag filter 24;
(7)热解反应器4固体产物中的惰性固体床料经热解反应器旋风分离器5分离后被送入双向返料器7,再被双向返料器7送回燃烧反应器12重新被加热形成高温惰性固体床料;所述高温惰性固体床料经燃烧反应器旋风分离器9分离后被送入单向返料器11,在被单向返料器11送至热解反应器4,形成双流化床反应器间的能量与物质循环。(7) The inert solid bed material in the pyrolysis reactor 4 solid products is sent into the two-way feeder 7 after being separated by the pyrolysis reactor cyclone separator 5, and is sent back to the combustion reactor 12 by the two-way feeder 7 again Heated to form a high-temperature inert solid bed material; the high-temperature inert solid bed material is sent to the one-way feeder 11 after being separated by the combustion reactor cyclone separator 9, and then sent to the pyrolysis reactor 4 by the one-way feeder 11 , to form energy and material circulation between double fluidized bed reactors.
基于上述装置与方法,下面结合实施例对本发明做出进一步的说明。Based on the above devices and methods, the present invention will be further described below in conjunction with the embodiments.
实施例1Example 1
原料选择秸秆,惰性固体床料选用石英砂(主要是SiO2)。由于秸秆热解制油效果比较好,同时其热解固体产物在空气氛围中燃烧反应速率较快,因而通过关闭热解反应器溢流装置6上设置的阀门使热解反应器4作为快速流化床运行并满足快速热解的运行要求,控制热解反应器4内平均停留时间为1~3s;通过关闭燃烧反应器溢流装置10上设置的阀门使燃烧反应器12作为快速流化床运行,控制燃烧反应器12内平均停留时间为7~9s。热解反应器4流化风气量分配为:热解反应器管式布风装置2为35%~45%、热解反应器底部布风装置3为55%~65%。The raw material is straw, and the inert solid bed material is quartz sand (mainly SiO 2 ). Since the pyrolysis effect of straw pyrolysis is relatively good, and the pyrolysis solid product has a fast combustion reaction rate in the air atmosphere, the pyrolysis reactor 4 can be used as a fast flow by closing the valve set on the overflow device 6 of the pyrolysis reactor. The fluidized bed operates and meets the operation requirements of fast pyrolysis, and the average residence time in the pyrolysis reactor 4 is controlled to be 1 to 3 s; by closing the valve set on the overflow device 10 of the combustion reactor, the combustion reactor 12 can be used as a fast fluidized bed Operation, the average residence time in the combustion reactor 12 is controlled to be 7-9s. The distribution of fluidizing air volume in the pyrolysis reactor 4 is: 35%-45% for the tubular air distribution device 2 of the pyrolysis reactor, and 55%-65% for the air distribution device 3 at the bottom of the pyrolysis reactor.
启动装置时,以煤作为辅助燃料经辅助燃料加料器15送入燃烧反应器12,空气通过燃烧反应器板式布风装置13被送入燃烧反应器12中用于流化床料并提供助燃气体(O2)。燃烧反应器12内混合床料与烟气共流化上升后在燃烧反应器旋风分离器9处气固分离,高温惰性固体床料经过单向返料器11进入热解反应器4内并在此释放热量。分离出的高温烟气则被送入热管换热器22用于预热热解反应器4的流化气体,换热后的烟气经过净化处理与除尘后排放。同时,利用外部热解气作为热解反应器4的流化气体,分别经热解反应器底部布风装置3和热解反应器管式布风装置2进入热解反应器4内用于流化床料。随着燃烧进行,热解反应器4与燃烧反应器12内的温度逐渐提高。控制热解反应器4内温度为500±50℃,控制燃烧反应器12内温度为1000±50℃。When the device is started, coal is used as auxiliary fuel and sent into the combustion reactor 12 through the auxiliary fuel feeder 15, and air is sent into the combustion reactor 12 through the combustion reactor plate-type air distribution device 13 for fluidized bed material and providing combustion-supporting gas (O 2 ). The mixed bed material and flue gas in the combustion reactor 12 co-fluidize and rise, and then the gas-solid separation is carried out at the cyclone separator 9 of the combustion reactor, and the high-temperature inert solid bed material enters the pyrolysis reactor 4 through the one-way feeder 11 and is This releases heat. The separated high-temperature flue gas is sent to the heat pipe heat exchanger 22 for preheating the fluidized gas of the pyrolysis reactor 4, and the flue gas after heat exchange is discharged after purification and dust removal. At the same time, the external pyrolysis gas is used as the fluidization gas of the pyrolysis reactor 4, and enters the pyrolysis reactor 4 through the air distribution device 3 at the bottom of the pyrolysis reactor and the tubular air distribution device 2 of the pyrolysis reactor respectively for fluidization. Bed material. As the combustion proceeds, the temperatures in the pyrolysis reactor 4 and the combustion reactor 12 gradually increase. The temperature inside the pyrolysis reactor 4 is controlled to be 500±50°C, and the temperature inside the combustion reactor 12 is controlled to be 1000±50°C.
当热解反应器4内温度达到运行温度要求后,由原料加料器1向热解反应器4加入经过干燥并粉碎的秸秆,秸秆在此被快速流化,剧烈混合的床内物质发生热解。热解生成的混合产物与部分惰性固体床料被流化气体带入热解反应器旋风分离器5,在此进行气固分离后,气体产物由上端进入第一级冷凝器16,固体产物向下进入双向返料器7。气体产物在第一级冷凝器16和第二级冷凝器17分别经过喷淋冷却与间接冷却降温至40~70℃,在冷却过程中可凝结气体凝结为热解油进入第一热解油收集罐18与热解油被第二热解油收集罐20。剩余的不可凝结气体被送入脱水塔21被去除多余的水分,得到热解气。热解气经脱水塔处理后被分为两路,一路作为热解气产品g输出,另一路作为流化气体被送入热管换热器22被高温烟气预热后回到热解反应器4内。包含有热解固体产物与惰性固体床料的固体物料在双向返料器7内被根据两反应器内温度状况按比例分别经第一返料斜管7-2与第二返料斜管7-3送入热解反应器4与燃烧反应器12。进入燃烧反应器12内的热解固体产物(主要是焦)在空气氛围中迅速完全燃烧,惰性固体床料则在燃烧反应器12内重新被加热,形成两反应器间物质与能量的循环。至装置运行稳定且反应温度达到要求后逐渐减少辅助燃料煤的加入量,装置依靠热解固体产物燃烧提供的能量维持装置的运行。When the temperature in the pyrolysis reactor 4 reaches the operating temperature requirement, the raw material feeder 1 feeds the dried and crushed straw into the pyrolysis reactor 4, where the straw is rapidly fluidized, and the violently mixed bed material undergoes pyrolysis . The mixed product generated by pyrolysis and part of the inert solid bed material are brought into the cyclone separator 5 of the pyrolysis reactor by the fluidization gas. After the gas-solid separation is carried out here, the gas product enters the first-stage condenser 16 from the upper end, and the solid product flows to the first-stage condenser 16. Enter the two-way feeder 7 down. The gas product is cooled to 40-70°C by spray cooling and indirect cooling in the first-stage condenser 16 and the second-stage condenser 17 respectively. During the cooling process, the condensable gas condenses into pyrolysis oil and enters the first pyrolysis oil collection. The tank 18 and the pyrolysis oil are collected by the second pyrolysis oil collection tank 20 . The remaining non-condensable gas is sent to the dehydration tower 21 to remove excess moisture to obtain pyrolysis gas. After the pyrolysis gas is processed by the dehydration tower, it is divided into two paths, one path is output as the pyrolysis gas product g, and the other path is sent to the heat pipe heat exchanger 22 as the fluidization gas and returned to the pyrolysis reactor after being preheated by high-temperature flue gas 4 within. The solid materials containing pyrolysis solid products and inert solid bed materials are passed through the first inclined pipe 7-2 and the second inclined pipe 7 in proportion according to the temperature conditions in the two reactors in the two-way feeder 7 -3 into the pyrolysis reactor 4 and the combustion reactor 12. The pyrolysis solid products (mainly coke) entering the combustion reactor 12 are rapidly and completely combusted in the air atmosphere, and the inert solid bed material is reheated in the combustion reactor 12, forming a cycle of matter and energy between the two reactors. After the operation of the device is stable and the reaction temperature meets the requirements, the amount of auxiliary fuel coal added is gradually reduced, and the device relies on the energy provided by the combustion of pyrolysis solid products to maintain the operation of the device.
实施例2Example 2
原料选择林业采伐剩余物,惰性固体床料选择石英砂。由于木料与秸秆相比木质素比例较大,同时木料粉碎达到快速热解的粒径要求所需要的流程相对复杂,使得利用林业采伐剩余物进行热解油并不如秸秆合适。因此,通过打开热解反应器溢流装置6上设置的阀门使热解反应器4作为鼓泡流化床运行,调节热解反应器4内平均停留时间为200~300s;通过关闭燃烧反应器溢流装置10上设置的阀门使燃烧反应器12作为快速流化床运行,调节燃烧反应器12内气体停留时间为7~9s。控制热解反应器4内温度为500±50℃,控制燃烧反应器12内温度为1000±50℃。热解反应器流化风气量分配为:热解反应器管式布风装置2为35%~45%、热解反应器底部布风装置3为55%~65%。The raw material is forestry harvesting residue, and the inert solid bed material is quartz sand. Compared with straw, the proportion of lignin in wood is relatively large, and the process required for wood crushing to meet the particle size requirements of fast pyrolysis is relatively complicated, so it is not suitable to use forestry harvesting residues for pyrolysis oil as straw. Therefore, by opening the valve provided on the pyrolysis reactor overflow device 6, the pyrolysis reactor 4 is operated as a bubbling fluidized bed, and the average residence time in the pyrolysis reactor 4 is adjusted to be 200-300s; by closing the combustion reactor The valve provided on the overflow device 10 makes the combustion reactor 12 operate as a fast fluidized bed, and adjusts the gas residence time in the combustion reactor 12 to 7-9s. The temperature inside the pyrolysis reactor 4 is controlled to be 500±50°C, and the temperature inside the combustion reactor 12 is controlled to be 1000±50°C. The distribution of the fluidizing air volume of the pyrolysis reactor is as follows: 35% to 45% for the tubular air distribution device 2 of the pyrolysis reactor, and 55% to 65% for the air distribution device 3 at the bottom of the pyrolysis reactor.
利用煤作为辅助燃料在燃烧反应器12内燃烧为装置的初始运行提供所需能量。当装置稳定运行后,通过原料加料器1向热解反应器4加入经过干燥与粉碎的原料,在运行于鼓泡态的热解反应器4内,原料被深层热解,得到的热解气体产物主要为小分子的不可冷凝气体,经过第一级冷凝器16与第二级冷凝器17去除少量焦油后,热解气由脱水塔21脱除水分后分两路作为流化气与产品气输出。热解得到的固体产物则被送入燃烧反应器12与空气混合燃烧为装置的运行提供热量。Coal is used as an auxiliary fuel to burn in the combustion reactor 12 to provide the required energy for the initial operation of the device. When the device is running stably, feed the dried and pulverized raw materials into the pyrolysis reactor 4 through the raw material feeder 1, and the raw materials are deeply pyrolyzed in the bubbling pyrolysis reactor 4, and the obtained pyrolysis gas The product is mainly non-condensable gas with small molecules. After a small amount of tar is removed by the first-stage condenser 16 and the second-stage condenser 17, the pyrolysis gas is dehydrated by the dehydration tower 21 and divided into two paths as fluidization gas and product gas. output. The solid product obtained by pyrolysis is sent to the combustion reactor 12 and mixed with air for combustion to provide heat for the operation of the device.
实施例3Example 3
原料选择城市生活垃圾,惰性循环床料选择石英砂。由于城市生活垃圾热解的固体产物中含有一定的污染物,尤其是二噁英,因而需要在燃烧反应器12内对热解固体产物进行稍长时间的高温处理以去除污染物。通过关闭热解反应器溢流装置6上设置的阀门使热解反应器4作为快速流化床运行并满足快速热解的运行要求,控制热解反应器4内平均停留时间为1~3s;通过打开燃烧反应器溢流装置10上设置的阀门使燃烧反应器12作为鼓泡流化床运行,控制燃烧反应器12内平均停留时间为200~300s。控制热解反应器4内温度为550±50℃,控制燃烧反应器12内温度为1150±50℃。热解反应器流化风气量分配为:热解反应器管式布风装置2为35%~45%、热解反应器底部布风装置3为55%~65%。Municipal solid waste is selected as the raw material, and quartz sand is selected as the inert circulating bed material. Since the solid products of municipal solid waste pyrolysis contain certain pollutants, especially dioxins, the pyrolysis solid products need to be treated at high temperature for a long time in the combustion reactor 12 to remove pollutants. By closing the valve provided on the pyrolysis reactor overflow device 6, the pyrolysis reactor 4 is operated as a fast fluidized bed and meets the operating requirements of fast pyrolysis, and the average residence time in the control pyrolysis reactor 4 is 1 to 3 s; The combustion reactor 12 is operated as a bubbling fluidized bed by opening the valve provided on the overflow device 10 of the combustion reactor, and the average residence time in the combustion reactor 12 is controlled to be 200-300s. The temperature inside the pyrolysis reactor 4 is controlled to be 550±50°C, and the temperature inside the combustion reactor 12 is controlled to be 1150±50°C. The distribution of the fluidizing air volume of the pyrolysis reactor is as follows: 35% to 45% for the tubular air distribution device 2 of the pyrolysis reactor, and 55% to 65% for the air distribution device 3 at the bottom of the pyrolysis reactor.
利用煤作为辅助燃料在燃烧反应器12内燃烧为装置的初始运行提供所需能量。当装置稳定运行后,通过原料加料器1向热解反应器4加入经过分拣并干燥粉碎的原料,在热解反应器4内,原料快速热解得到的气体产物经热解反应器旋风分离器5气固分离后,经过第一级冷凝器16与第二级冷凝器17完成对热解油的收集,同时在第一级冷凝器16内经过喷淋去除了不可凝热解气中少量的酸性气体,热解气由脱水塔21脱除水分后分两路作为流化气与产品气输出。热解得到的固体产物则被送入燃烧反应器12与空气混合燃烧为装置的运行提供热量。热解固体产物较长时间处于超过1100℃的燃烧反应器12中,可以完全分解原料中的二噁英和呋喃等污染物Coal is used as an auxiliary fuel to burn in the combustion reactor 12 to provide the required energy for the initial operation of the device. After the device is running stably, feed the sorted, dried and pulverized raw materials into the pyrolysis reactor 4 through the raw material feeder 1, and in the pyrolysis reactor 4, the gas products obtained by rapid pyrolysis of the raw materials are separated by the pyrolysis reactor cyclone After the gas-solid separation in the device 5, the collection of pyrolysis oil is completed through the first-stage condenser 16 and the second-stage condenser 17, and a small amount of non-condensable pyrolysis gas is removed by spraying in the first-stage condenser 16 The acid gas and pyrolysis gas are dehydrated by the dehydration tower 21 and then output in two ways as fluidization gas and product gas. The solid product obtained by pyrolysis is sent to the combustion reactor 12 and mixed with air for combustion to provide heat for the operation of the device. The pyrolysis solid product is placed in the combustion reactor 12 at over 1100°C for a long time, which can completely decompose pollutants such as dioxin and furan in the raw material
以上所述仅是本发明的优选实施方式,应当指出:对于本技术领域的普通技术人员来说,在不脱离本发明原理的前提下,还可以做出若干改进和润饰,这些改进和润饰也应视为本发明的保护范围。The above is only a preferred embodiment of the present invention, it should be pointed out that for those of ordinary skill in the art, without departing from the principle of the present invention, some improvements and modifications can also be made, and these improvements and modifications are also possible. It should be regarded as the protection scope of the present invention.
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