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CN103749481B - Sterilization pesticide oil-suspending agent - Google Patents

Sterilization pesticide oil-suspending agent Download PDF

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Publication number
CN103749481B
CN103749481B CN201410038345.6A CN201410038345A CN103749481B CN 103749481 B CN103749481 B CN 103749481B CN 201410038345 A CN201410038345 A CN 201410038345A CN 103749481 B CN103749481 B CN 103749481B
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CN
China
Prior art keywords
suspending agent
oil
sterilization pesticide
phenyl
present
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201410038345.6A
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Chinese (zh)
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CN103749481A (en
Inventor
陈龙弟
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chongqing Kaizhou Dongming Agricultural Development Co., Ltd.
Original Assignee
Shanghai Yanzi Chemical Technology Co Ltd
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Filing date
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Priority to CN201410038345.6A priority Critical patent/CN103749481B/en
Publication of CN103749481A publication Critical patent/CN103749481A/en
Application granted granted Critical
Publication of CN103749481B publication Critical patent/CN103749481B/en
Expired - Fee Related legal-status Critical Current
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Abstract

The present invention relates to a kind of sterilization pesticide oil-suspending agent, form: SYP-Z048 8-12% by following materials by weight percentage; Flumorph 8-12%; Surfactant 7-9%; Ethyl lactate 2-4%; Attapulgite 1-3%; Stearyl alcohol 0.1-0.3%; Propylben 0.2-0.4%; Surplus is palm oil.Sterilization pesticide oil-suspending agent of the present invention, suspensibility is high, and properties of product are stablized.The present invention is applicable to the control of plant botrytis, Peronospora, epidemic disease mycin germ.

Description

Sterilization pesticide oil-suspending agent
Technical field
The present invention relates to a kind of sterilization pesticide oil-suspending agent.
Background technology
SYP-Z048, N-methyl-3-(4-chlorine) phenyl-5-methyl-5-pyridine-3 bases-oxazoline, belongs to sterol synthesis inhibition bactericide, effectively can be controlled the occurrence and infection of the not disease of leaf on the ground by root application.There is the bactericidal activity of wide spectrum, there is protection and therapeutic action and good interior absorption simultaneously.
Flumorph, English name flumorph; SYP-190, chemical name: (E, Z) 4-[3-(37,4'-=methoxyphenyl)-3-(4-fluorophenyl) acryloyl] morpholine.Belong to morpholine class disinfectant use in agriculture.Effective especially to Peronospora, epidemic disease mycin germ.To the Oomycete on grape, potato and tomato, especially Peronosporaceae and Phytophthora bacterium have fungicidal effectiveness.
Oil-suspending agent, is called for short oil suspending agent, refers to that one or more pesticide active ingredients (wherein having at least a kind of is the former medicine of solid) form high dispersive, stable suspension system in grease dispersion medium.Oil-suspending agent is generally rear for spraying with grease dilution, also without dilution, can do ultra low volume spraying.
Summary of the invention
For solving the deficiencies in the prior art, technical problem to be solved by this invention is to provide a kind of sterilization pesticide oil-suspending agent.Be achieved especially by following technical proposals:
Sterilization pesticide oil-suspending agent, comprises the raw material: SYP-Z048 8-12% of following weight percentage; Flumorph 8-12%.
Sterilization pesticide oil-suspending agent, forms: SYP-Z048 8-12% by following materials by weight percentage; Flumorph 8-12%; Surfactant 7-9%; Ethyl lactate 2-4%; Attapulgite 1-3%; Stearyl alcohol 0.1-0.3%; Propylben 0.2-0.4%; Surplus is palm oil.
Described surfactant is poly-(Oxy-1, the 2-ethylidene) non-ionic surface active agent of cumene sodium sulfonate and/or α-[three (phenyl methyl) phenyl]-ω-hydroxyl.Preferably, described surfactant, is made up of 30-70 weight portion cumene sodium sulfonate and poly-(Oxy-1, the 2-ethylidene) non-ionic surface active agent of 30-70 weight portion α-[three (phenyl methyl) phenyl]-ω-hydroxyl.
α-[three (phenyl methyl) phenyl]-ω-hydroxyl gathers (Oxy-1,2-ethylidene) non-ionic surface active agent, CAS:64422-66-8.Cumene sodium sulfonate, No. CAS: 28348-53-0.
Sterilization pesticide oil-suspending agent of the present invention can adopt the general method in this area to be prepared, as:
(1) in mixing kettle, add SYP-Z048, flumorph, surfactant, ethyl lactate, attapulgite, stearyl alcohol, propylben and palm oil, be uniformly mixed;
(2) be placed in sand mill and carry out ultramicro grinding, controlling average grain diameter is 3 μm;
(3) check, qualified rear packing.
Sterilization pesticide oil-suspending agent of the present invention has higher suspension rate, stable during long-term storage.The present invention is applicable to the control of plant botrytis, Peronospora, epidemic disease mycin germ.
Embodiment
Embodiment 1
(1) each raw material is taken by table 1 corresponding embodiment 1 data;
(2) in mixing kettle, add SYP-Z048, flumorph, surfactant, ethyl lactate, attapulgite, stearyl alcohol, propylben and palm oil, be uniformly mixed;
(3) be placed in sand mill and carry out ultramicro grinding, controlling average grain diameter is 3 μm;
(4) check, qualified rear packing.
Table 1: sterilization pesticide oil-suspending agent formula table unit: kilogram
Embodiment 2
Take raw material by table 1 corresponding embodiment 2 data, be prepared by the method for embodiment 1.
Embodiment 3
Take raw material by table 1 corresponding embodiment 3 data, be prepared by the method for embodiment 1.
Test case
High temperature storage 14 days under room temperature storage 14 days, 54 DEG C ± 2 DEG C conditions respectively, adopt " GB/T14825-2006 agricultural-chemical suspension rate assay method " to survey suspensibility, concrete data see the following form 2.As suspensibility >85%, then think that this product is certified products.
Table 2: agricultural-chemical suspension rate determination data list position: %
Embodiment 1 Embodiment 2 Embodiment 3
Room temperature storage is after 14 days 98.5 97.8 97.1
High temperature storage is after 14 days 98.0 97.1 96.2
Suspension refers to that former powder of dispersion keeps the ability of suspension time length in suspension, usually represents with suspensibility.A good suspending agent, should have good storage stability, namely higher suspensibility.
Sterilization pesticide oil-suspending agent of the present invention, suspensibility is high, plate-out ability and good penetrability, and properties of product are stablized.
α-[three (phenyl methyl) phenyl]-ω-hydroxyl gathers (Oxy-1,2-ethylidene) non-ionic surface active agent is mainly used in suppressing the corrosion in linear cutter and galvano-cautery, sludge in softening working groove, is used as rust-inhibiting additive in low-speed WEDM production process.In prior art, do not have and this raw material is used for any technology enlightenment that agricultural chemicals reagent plays dispersion moistening effect.In the present invention, poly-(the Oxy-1 of α-[three (phenyl methyl) phenyl]-ω-hydroxyl being originally used for rust-inhibiting additive in a creative way, 2-ethylidene) non-ionic surface active agent is diverted in insecticidal suspending agent, plays dispersion moistening effect.Especially, cumene sodium sulfonate and α-[three (phenyl methyl) phenyl]-ω-hydroxyl are gathered (Oxy-1,2-ethylidene) non-ionic surface active agent composite, Synergistic, effectively improves suspensibility.

Claims (1)

1. sterilization pesticide oil-suspending agent, is characterized in that, forms: SYP-Z048 8-12% by following materials by weight percentage; Flumorph 8-12%; Surfactant 7-9%; Ethyl lactate 2-4%; Attapulgite 1-3%; Stearyl alcohol 0.1-0.3%; Propylben 0.2-0.4%; Surplus is palm oil;
Described surfactant is made up of 30-70 weight portion cumene sodium sulfonate and poly-(Oxy-1, the 2-ethylidene) non-ionic surface active agent of 30-70 weight portion α-[three (phenyl methyl) phenyl]-ω-hydroxyl.
CN201410038345.6A 2014-01-26 2014-01-26 Sterilization pesticide oil-suspending agent Expired - Fee Related CN103749481B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410038345.6A CN103749481B (en) 2014-01-26 2014-01-26 Sterilization pesticide oil-suspending agent

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Application Number Priority Date Filing Date Title
CN201410038345.6A CN103749481B (en) 2014-01-26 2014-01-26 Sterilization pesticide oil-suspending agent

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CN103749481A CN103749481A (en) 2014-04-30
CN103749481B true CN103749481B (en) 2016-03-02

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Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107183036A (en) * 2017-06-08 2017-09-22 合肥龙滨化工科技有限公司 A kind of pesticide oil suspension floats agent

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103355318A (en) * 2013-07-31 2013-10-23 海利尔药业集团股份有限公司 Sterilization composition containing pyrisoxazole and flumorph
CN103371184A (en) * 2013-06-27 2013-10-30 王学权 Fungicidal composition containing prochloraz manganese complex
CN103371149A (en) * 2013-06-27 2013-10-30 王学权 Compounded synergia sterilizing composite

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR122019015114B1 (en) * 2012-06-20 2020-04-07 Basf Se pesticide mixture, composition, agricultural composition, methods for combating or controlling invertebrate pests, for the protection of growing plants or plant propagation material, for the protection of plant propagation material, use of a pesticide mixture and methods for the combat harmful phytopathogenic fungi and to protect plants from harmful phytopathogenic fungi

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103371184A (en) * 2013-06-27 2013-10-30 王学权 Fungicidal composition containing prochloraz manganese complex
CN103371149A (en) * 2013-06-27 2013-10-30 王学权 Compounded synergia sterilizing composite
CN103355318A (en) * 2013-07-31 2013-10-23 海利尔药业集团股份有限公司 Sterilization composition containing pyrisoxazole and flumorph

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Effective date of registration: 20181129

Address after: 405400 West 512 Kaizhou Avenue, Yunfeng Street, Kaizhou District, Chongqing

Patentee after: Chongqing Kaizhou Dongming Agricultural Development Co., Ltd.

Address before: 201111 E2128 first, 5500 Yuanjiang Road, Minhang District, Shanghai.

Patentee before: Shanghai Yanzi Chemical Technology Co., Ltd.

CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20160302

Termination date: 20190126